Development of TMCP Type Alloy625/X65 Clad Steel Plate for Pipe

Author(s):  
Shunichi Tachibana ◽  
Yota Kuronuma ◽  
Tomoyuki Yokota ◽  
Shinji Mitao ◽  
Hitoshi Sueyoshi ◽  
...  

Demand for CRAs (Corrosion Resistant Alloys) clad steel is getting increased for pipeline application of oil and gas industry because of economic advantage over solid CRAs. CRAs clad steel consists of a CRAs layer for corrosion resistance and a carbon steel for mechanical properties. Nickel based Alloy625 is known to be suitable for harsh environmental condition such as high temperature and high pressure H2S (hydrogen sulfide) condition. In this paper, the corrosion resistance of Alloy625/X65 clad steel plate for pipe produced by TMCP (Thermo-Mechanical Control Process) was investigated. TTP (Time - Temperature - Precipitation) and TTS (Time - Temperature - Sensitization) diagram of Alloy625 indicated precipitation nose, e.g. M6C and M23C6 which would cause deterioration of corrosion resistance. TMCP enable Alloy625 to avoid long time exposure to the precipitation nose. In Huey test, the corrosion rate in TMCP was almost the same as that of solution treated Alloy625 and smaller than that in Q-T (Quench and Temper). In ferric chloride pitting test, no pitting was observed in Alloy625 layer of TMCP type clad steel. In addition, the corrosion test simulating service environment using autoclave apparatus was conducted under the condition of 0.39MPa H2S - 0.53MPa CO2 - Cl− solution at 200°C. Alloy625 clad steel produced by TMCP showed neither SSC (Sulfide stress corrosion cracking) nor crevice corrosion. All the mechanical properties of base carbon steel satisfied API 5L grade X65 specification by optimizing TMCP conditions. It is notable that 85% SATT of DWTT was below −10 °C. Thus, Alloy625/X65 clad steel plate for pipe produced by TMCP with both superior corrosion resistance and low temperature toughness has been developed.

Author(s):  
Thilo Reichel ◽  
Jochem Beissel ◽  
Vitaliy Pavlyk ◽  
Gernot Heigl

The paper describes the different industrially used options to produce a clad pipe and explains in detail the manufacture of metallurgically cladded pipes starting with the production of roll bonded plates. In plate manufacturing the advantages as well as the limitations of thermo-mechanical (TM) rolling are discussed. The TM-technology is shown to improve weldability, HIC-resistance, strength and toughness properties of the carbon steel section of the pipe. Moreover, it also improves corrosion resistance of the CRA layer. The pipe manufacturing procedure, which involves two welding technologies for longitudinal welds is described. The carbon steel parts of the pipe are joined using double-sided multi-pass Submerged-Arc-Welding (SAW). The single-pass Electroslag-Welding (ESW) is subsequently used for recladding of the CRA layer. The multi-pass SAW results in excellent mechanical properties of the weld joint, whereas the ESW technique ensures low dilution of CRA with the carbon steel, a smooth weld bead shape and a high corrosion resistance of the deposited layer. With the aid of thermodynamic modeling and numerical simulations it is shown, that the high corrosion resistance is promoted by an intensive mixing within the ESW weld pool and relatively low segregation level of Cr and Mo during solidification. Furthermore, FEM analysis is applied to examine the plastic deformation and residual stresses distribution in the pipe during forming, welding and final calibration. The obtained information assists in optimization of manufacturing procedure, and can also be included in prediction of resulting pipe fatigue during operation.


Author(s):  
V.I. BOLSHAKOV ◽  
Т. О. DERHACH ◽  
D.A. SUKHOMLYN

Formulation of the problem. Corrosion of pipes used in the oil and gas industry leads to significant economic losses, therefore, increasing their corrosion resistance and durability is an urgent task. Purpose: generalization of results of developments of technologies of manufacturing and research of qualitative characteristics of oil and gas pipelines (smooth) and pump-compressor (threaded) pipes of the increased and high corrosion resistance and giving recommendations on their application in oil and gas industry in environments of various corrosion aggressiveness. Methodology. The microstructure of tubular steels and protective coatings was studied by light metallography and electron microscopy. Complex corrosion studies included laboratory tests of samples in model chloride and hydrogen sulfide-containing media, the resistance to sulfide corrosion cracking under stress (SCCS) and hydrogen cracking (НС) according to the methods of NACE TM 0177 and NACE TM 0284 as well as operational tests at the oil fields of Ukraine. Mechanical properties for stretching and impact bending of samples by standard methods. Results. The results of the development of production technologies and the study of the qualitative characteristics of oil and gas pipelines and tubing with increased and high corrosion resistance in aggressive oil and gas production environments are summarized. The influence of the chemical composition of steels and protective coatings, as well as pipe manufacturing technologies on their microstructure, corrosion resistance in various media, and mechanical properties is shown. Scientific novelty. For the first time, the presence of special low-energy boundaries in the ferrite of low-alloy ferrite-pearlite and high-alloy ferritic-austenitic steels was established, their number and energy level were estimated. The high operational reliability of threaded pipes with a protective coating is substantiated. Practical value. The results of the work and recommendations for the rational use of oil and gas pipes with increased corrosion resistance can be used to increase the economic efficiency of production in the oil and gas industry.


2020 ◽  
Vol 836 ◽  
pp. 41-45
Author(s):  
S.N. Dzhabbarov ◽  
E.I. Pryakhin

Development of an optimal technology of heat treatment for blanks of the casing pipe made of steel 40H (GOST 4543) is used in the oil and gas industry for casing. It is accompanied by quenching in various environments to ensure guaranteed obtainment of the required mechanical characteristics. These characteristics are specified in GOST 632-80 and met in order to improve the properties of the 40H steel.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Mohor Chatterjee ◽  
Yu Fan ◽  
Fang Cao ◽  
Aaron A. Jones ◽  
Giovanni Pilloni ◽  
...  

AbstractMicrobiologically influenced corrosion (MIC) is recognized as a considerable threat to carbon steel asset integrity in the oil and gas industry. There is an immediate need for reliable and broadly applicable methods for detection and monitoring of MIC. Proteins associated with microbial metabolisms involved in MIC could serve as useful biomarkers for MIC diagnosis and monitoring. A proteomic study was conducted using a lithotrophically-grown bacterium Desulfovibrio ferrophilus strain IS5, which is known to cause severe MIC in seawater environments. Unique proteins, which are differentially and uniquely expressed during severe microbial corrosion by strain IS5, were identified. This includes the detection of a multi-heme cytochrome protein possibly involved in extracellular electron transfer in the presence of the carbon steel. Thus, we conclude that this newly identified protein associated closely with severe MIC could be used to generate easy-to-implement immunoassays for reliable detection of microbiological corrosion in the field.


2019 ◽  
Vol 3 (1) ◽  
pp. 30-36
Author(s):  
Zuraini Din ◽  

In the oil and gas industry, pipeline is the major transportation medium to deliver the products. According to [1] containment of pipeline loss to indicate that corrosion has been found to be the most predominant cause for failures of buried metal pipes. MIC has been identified as one of the major causes of underground pipeline corrosion failure and Sulphate Reducing Bacteria (SRB) are the main reason causing MIC, by accelerating corrosion rate. The objectives of this study is to study the SRB growth, Desulfovibrio desulfuricans ATCC 7757 due to pH and determine the optimum value controlling the bacteria growth on the internal pipe of carbon steel grade API X70. The result shows that the optimum SRB growth is at range pH 5-5 to 6.5 and the exposure time of 7 to 14 days. At pH 6.5 the maximum corrosion rate is 1.056 mm/year. Corrosion phenomena on carbon steel in the study proven had influence by pH and time. From this result pitting corrosion strongly attack at carbon steel pipe. In the future project, it is recommended to study the effect of different pipe location for example the pipeline under seawater.


2021 ◽  
Author(s):  
Nachiket Arbad ◽  
Fernando Rincon ◽  
Catalin Teodoriu ◽  
Mahmood Amani

Abstract The catastrophic events faced by the Oil and Gas industry in the past depict the importance of maintaining the integrity of the well. The cement acts as a crucial barrier throughout the life cycle of the well. The contamination of the cement occurs due to inefficiency in cementing practices and operations. Experimental investigations have been done on the reduction in mechanical properties of different API class cement considering contamination with water-based mud and oil-based mud. This study focuses on analyzing the changes in mechanical properties of API Class C cement on varying the following parameters: OBM contamination (0%, 0.6%, 1.1%, 2.2%, 4.3%) Curing time (4 hrs, 6 hrs, 8 hrs, 1 day, 3 days, 7 days) Temperature (25˚C, 75 ˚C) API recommendations were followed for preparing the cement slurries. The destructive, as well as non-destructive tests were carried out on the cement samples at ambient room temperature to measure the uniaxial compressive strength (UCS) for OBM contaminated class C cement slurries. The general trend observed is that the UCS increases with an increase in curing time and temperature. UCS decreases with an increase in OBM contamination. Logarithmic trends were obtained for UCS vs curing time for different contaminations at a given temperature. Exceptions were observed at lower curing times where contaminated samples showed better results than the neat cement slurries. These observations play a critical role in understanding contaminated cement behavior. This widespread work was carried out only on API Class C cement to provide reliable data for future references. The correlations presented in this paper will help operators estimate the deterioration in mechanical properties of Class C cement in the presence of low OBM contamination. Email: [email protected] & [email protected]


2021 ◽  
Author(s):  
Chinedu Oragwu ◽  
Daniel Molyneux ◽  
Lukeman Lawal ◽  
Stanley Ameh

Abstract Carbon steel pipelines are used to transport hydrocarbons globally because carbon steel is relatively easier to fabricate, safe for use, raw materials are available and less expensive. Amidst these benefits, carbon steel is susceptible to severe corrosion and other anomalies. Pipeline corrosion is a significant concern in the oil and gas industry. It has caused several minor and catastrophic losses of containment with resultant fatalities, environmental pollutions, asset damage, and production downtimes. The increasing failures of in-service pipelines have led the Department of Petroleum Resources (DPR) to intensify regulatory scrutiny of pipeline integrity assessment and management in Nigeria to ensure strict compliance to the regulatory requirements by the Oil Producing Companies. According to DPR Act (Section 2.5.2.1), all pipelines greater than 6" size diameter must be inspected every five (5) years with intelligent pigs (inline inspection tools) that would provide the accurate condition of the pipeline. However, many pipelines in Nigeria are unpiggable or difficult to inspect with intelligent pigs due to the unavailability of pigging facilities (especially in brownfields), pipelines with short bend radiuses, dual diameters, flow parameters, etcetera. This paper explores case studies involving the use of advanced inline inspection technology to conduct inline inspection of difficult-to-inspect dual-diameter pipelines.


Wear ◽  
2018 ◽  
Vol 394-395 ◽  
pp. 60-70 ◽  
Author(s):  
A.H.S. Bueno ◽  
J. Solis ◽  
H. Zhao ◽  
C. Wang ◽  
T.A. Simões ◽  
...  

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