The thermal isomerisation of allyl isocyanide
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The thermal isomerisation of allyl isocyanide to allyl cyanide has been studied in the gas phase over the temperature range 130–200 °C. The reaction is homogeneous and first order, and at high pressure (20 Torr) has an activation energy of 40.8 ± 0.6 (2sdm) kcal mol−1; the corresponding range of frequency factor is 1014.77±0.30 s−1.
2002 ◽
Vol 16
(06n07)
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pp. 1003-1007
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2001 ◽
Vol 36
(3)
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pp. 589-604
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1987 ◽
Vol 52
(6)
◽
pp. 1527-1544
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