Variability in the chemical content of waterfowl plumage

1975 ◽  
Vol 53 (10) ◽  
pp. 1379-1386 ◽  
Author(s):  
John P. Kelsall ◽  
W. J. Pannekoek ◽  
Roland Burton
Keyword(s):  
Chemical Elements ◽  
Canonical Analysis ◽  
Discriminant Functions ◽  
Mean Values ◽  
Chemical Content ◽  
Multivariate Discriminant

Three species of waterfowl were held for 3 years on common rations in a common enclosure. Their primary flight feathers were clipped each October and each set was analyzed for a spectrum of nine chemical elements. Multivariate discriminant functions were calculated and canonical analysis was used to examine differences by species, sex, and year-class. Least discrimination was found between sexes, although even there most mean values were significantly different one from another. Mean values between species and year-classes were all significantly different. The greatest variability was found in year-class where 88.9% of known birds could be classified accurately and where 78.5% of unknowns could be assigned correctly on the basis of discriminant functions. Some of the reasons for variability are discussed.

The Chemical Bond Across the Periodic Table: Part 1 – First Row and Simple Metals

2020 ◽  
Author(s):  
Gabriel Freire Sanzovo Fernandes ◽  
Leonardo dos Anjos Cunha ◽  
Francisco Bolivar Correto Machado ◽  
Luiz Ferrão
Keyword(s):  
Physical Chemistry ◽  
Chemical Bond ◽  
Materials Science ◽  
Chemical Elements ◽  
Orbital Theory ◽  
Solid State Physics ◽  
Band Theory ◽  
Van Der Waals Clusters ◽  
Earth Systems ◽  
Chemical Content

<p>Chemical bond plays a central role in the description of the physicochemical properties of molecules and solids and it is essential to several fields in science and engineering, governing the material’s mechanical, electrical, catalytic and optoelectronic properties, among others. Due to this indisputable importance, a proper description of chemical bond is needed, commonly obtained through solving the Schrödinger equation of the system with either molecular orbital theory (molecules) or band theory (solids). However, connecting these seemingly different concepts is not a straightforward task for students and there is a gap in the available textbooks concerning this subject. This work presents a chemical content to be added in the physical chemistry undergraduate courses, in which the framework of molecular orbitals was used to qualitatively explain the standard state of the chemical elements and some properties of the resulting material, such as gas or crystalline solids. Here in Part 1, we were able to show the transition from Van der Waals clusters to metal in alkali and alkaline earth systems. In Part 2 and 3 of this three-part work, the present framework is applied to main group elements and transition metals. The original content discussed here can be adapted and incorporated in undergraduate and graduate physical chemistry and/or materials science textbooks and also serves as a conceptual guide to subsequent disciplines such as quantum chemistry, quantum mechanics and solid-state physics.</p>

scholarly journals Research Regarding Dynamics of Chemical Content from Pasteurized Egg Melange Stored in Polyethylene Type Packings

2017 ◽  
Vol 54 (2) ◽  
pp. 368-374
Author(s):  
Roxana Nicoleta Ratu ◽  
Marius Giorgi Usturoi ◽  
Daniel Simeanu ◽  
Cristina Simeanu ◽  
Alexandru Usturoi ◽  
...  
Keyword(s):  
Amino Acids ◽  
Fatty Acids ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Storage Period ◽  
Essential Amino Acids ◽  
Storage Conditions ◽  
Mean Values ◽  
Chemical Content

n the current paper, we aimed to analyze the way in which packing (different polyethylene types) influence the quality of pasteurized melange during storage, packing being realized in units of 1 kg (Tetra Pak) (batch Lexp-1) and units of 5 kg (Bag in box) (batch Lexp-2). Products were stored during a period of 28 days at a temperature of +4�C, qualitative determinations being realized in first day (day 0), at 7 days, at 14 days, 21 days and in day 28 of storage. Were effectuated a sensorial examination and chemical analysis were was established the content in dry matter (%), water (%), proteins (%), content in essential amino acids (isoleucine, methionine, tryptophan, phenylalanine) and non-essential amino acids (alanine, histidine, glycine, serine) (mg/100g) as well as the content in lipids (%) establishing their profile by identification of some saturated fatty acids (16:0 mg/100g and 18:0 mg/100g) and unsaturated fatty acids (16:1 mg/100g and 18:1 mg/100g). After sensorial examinations, the first modifications were observed at the checking effectuated in day 21 for batch Lexp-2, the obtained score being of 18 points, and at checking effectuated in day 28 was given a score of 18 points for melange belonging to batch Lexp-1 and only 14 points for melange from batch Lexp-2. Differences were recorded also in case of chemical composition of products, so for protein content at batch Lexp-1 in first checking day was obtained a mean of 12.730�0.24% and at batch Lexp-2 12.614�0.22%. Differences between those two batches were insignificant (p[0.05). In case of fat content, at the end of storage period was obtained a mean of 11.256�0.06% for batch Lexp-1 and 11.244�0.11% for batch Lexp-2, differences being insignificant (p [ 0.05). Regarding the profile of amino acids and fatty acids, the mean values obtained during whole storage period oscillated from one stage to another, but the differences between those two batches were insignificant (p [ 0.05). Pasteurized egg melange suffers certain sensorial modifications during storage, especially on consistency and colouring, modifications which are accentuated mainly by storage conditions. Type of polyethylene utilized for this product hadn�t influenced the nutritive qualities of product.

Dry matter yield and chemical content of forage sorghums intercropping with annual legumes.

1969 ◽  
Vol 96 (3-4) ◽  
pp. 165-181 ◽  
Author(s):  
Raphael W. Colbert ◽  
Elide Valencia ◽  
James S. Beaver
Keyword(s):  
Block Design ◽  
Mucuna Pruriens ◽  
Lablab Purpureus ◽  
Mean Values ◽  
Annual Legumes ◽  
Significant Difference ◽  
Randomized Complete Block Design ◽  
Fiber Fractions ◽  
Chemical Content ◽  
Sorghum Bicolor L

Forage sorghum [Sorghum bicolor L. Moench 'Brown midrib' (BMR)] and annual legumes lablab [Lablab purpureus L. 'Rongai' (L)] and mucuna [Mucuna pruriens L. 'Vine 90 d' (M)] are suitable fodder for the dairy industry in Puerto Rico, but BMR harvested at 90 days, usually has low crude protein (CP, 6%) content, which limits its usefulness. There is the possibility of increasing the CP by intercropping legumes with BMR, but this option has been only slightly investigated. This study proposes to compare BMR in monoculture and in intercropping with 'Rongai' (SL) and 'Vine 90 d' (SM), in addition to L and M in monoculture, in terms of total leaf mass (FM) and botanical components (sorghum, legumes and weeds) and chemical (CP and fiber fractions) at two harvest times. The experimental plots (25 m2) were sown in February and August 2008 in a randomized complete block design with five replications. At each harvest time, 2 m2 MF area was sampled 90 days after sowing. Data were analyzed by using the MIXED procedure of SAS and mean separation tests were performed by using F-protected LSD at 95% level of confidence. No significant differences (combining fodder botanical component and weeds) were detected for the total MF between BMR and BMR associated with legumes in monoculture, with mean values of 8.94, 8.81, and 8.42 Mg/ha for BMR-'Rongai', BMR-'Vine 90 d', and BMR, respectively. Overall, there was no significant difference in MF between May and August (8.1 vs. 7.5 Mg/ha). 'Rongai' yield (Mg/ha) did not change between May and August (3.6 vs. 3.0) but was lower in the intercrop (2.74) than in monoculture (3.94). 'Vine 90 d' had the lowest yield of 2.8 and 1.3 Mg/ ha in May and August, respectively. No differences (P > 0.05) in NDF and ADF content between BMR and BMR-'Rongai'-'Vine 90 d', whose values were 60.1 and 63.9% and 40.1 and 46.5%, respectively. However, differences (P < 0.05) were found in CP content between monoculture and intercropping, with values of 14.1, 11.1, and 6.0% for 'Rongai', 'Vine 90 d', and sole BMR, respectively, whereas the BMR-'Rongai' and BMR- 'Vine 90 d' CP were 9.8 and 9.1%, but these last values exceed by three units the percentage in BMR. In conclusion, BMR intercropped with 'Rongai' and 'Vine 90 d' improved the forage chemistry and helps to control weeds while favoring the performance of desirable botanical components.

scholarly journals DISTRIBUTION OF CHEMICAL ELEMENTS IN SURFACE WATERS FROM THE CRNA RIVER BASIN, REPUBLIC OF MACEDONIA

2018 ◽  
Vol 39 (1) ◽  
pp. 31 ◽  
Author(s):  
Dimitri Tomovski ◽  
Trajče Stafilov ◽  
Robert Šajn ◽  
Katerina Bačeva Andonovska
Keyword(s):  
Surface Water ◽  
Surface Waters ◽  
Water Samples ◽  
Inductively Coupled Plasma ◽  
Chemical Elements ◽  
Emission Spectrometry ◽  
Anthropogenic Influence ◽  
Mean Values ◽  
Republic Of Macedonia ◽  
Surface Water Samples

An investigation of the distribution of 23 chemical elements (Ag, Al, As, B, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Sr, V and Zn) in surface water samples from the entire basin of the Crna River, Republic of Macedonia, was carried out. In total 31 water samples were collected, from which 8 samples from the Crna River and 4 samples from four main tributaries of Crna River in the Pelagonia Valley (Blato, Prilepska Reka, Dragor and Jelaška Reka). Also, surface water samples were collected from 3 locations in the Tikveš Lake, 8 locations from the Majdanska River and river of Blašnica before its inflow into the Tikveš Lake and from 7 locations of the lower course of the Crna River after the dam of Tikveš Lake until its inflow into the river of Vardar. Determination of the concen-tration of the investigated elements was performed by using atomic emission spectrometry with inductively coupled plasma (ICP-AES). All data obtained for the analyzed samples were statistically processed using software Stat Soft 11.0 where the descriptive statistical analysis of the value for the concentration of the elements was performed. The maps of spatial distribution of the concentration for each element and a histograms for the representation of elements with mean values of the concentrations by regions, were also prepared. The obtained results show that the concentration of investigated element are mainly followed the lithology of the region. However, higher concentrations of arsenic were found in the water samples from the river of Blašnica which is a result of anthropogenic influence from the abounded Allchar mine on the Kožuf Mountain. Also, the increased concentrations of nickel were found in the samples from the lower couse of the Crna River after the dam of Tikveš Lake due to the anthropogenic influence from the ferronickel smelter plant Feni Industry, which can influence the quality parameters of surface waters.

scholarly journals Energy-dispersive spectroscopy for the quantitative determination of the major chemical elements in milk

2021 ◽  
Vol 10 (10) ◽  
pp. e280101018910
Author(s):  
Igor Lima de Paula ◽  
Isis Rodrigues Toledo Renhe ◽  
Rodrigo Stephani ◽  
Ítalo Tuler Perrone ◽  
Antônio Fernandes de Carvalho ◽  
...  
Keyword(s):  
Quantitative Determination ◽  
Chemical Elements ◽  
Raw Milk ◽  
Energy Dispersive ◽  
Mean Values ◽  
Milk Samples ◽  
Application Potential ◽  
Major Chemical ◽  
Good Agreement

The present preliminary study aims at the rapid quantitative determination of the major chemical elements in the ashes of raw milk samples, using energy dispersive X-ray fluorescence spectrometry. The precision of the method was satisfactory (variation coefficient ≤ 5%). The mean values (in mmol·kg-1) obtained from the analysis of 32 raw milk samples showed good agreement with data from the Brazilian and international literature: K (26.1 ± 4.6), Ca (33.8 ± 3.7), P (28.4 ± 2.7), Na (21 ± 3.3) and Mg (4.7 ± 0.5). Residual Cl concentration (19.0 ± 3.3 mmol·kg-1) was lower than expected due to incineration losses. The results suggest a good application potential of the method for other dairy products.

scholarly journals The technology of improving almond planting material tolerance to the salt stresses of soils based on experience in phytotron

2020 ◽  
Vol 25 ◽  
pp. 05011
Author(s):  
Antar Badran ◽  
Igor Savin
Keyword(s):  
Chemical Elements ◽  
Soil Salinization ◽  
Total Carbon ◽  
Planting Material ◽  
Stalk Diameter ◽  
Saline Waters ◽  
Leaf Area Duration ◽  
Chemical Content ◽  
Bitter Almond ◽  
Irrigation Waters

There was studied impact of the bitter almond seeds preliminary steeping on the development of plants at the first stages of development in conditions of saline waters irrigation in the greenhouse experiment ambient in phytotron. It was established that steeping the seeds in excessive salt solution results in enhanced plants tolerance to the soil salinization and saline waters irrigation. This is evidenced by the obtained regularities of influence on the development of plants of biochemical character (content of proline, chlorophyll and carotinoids, total carbon); chemical (content of basic chemical elements); morphological (rate of the plants height and stalk diameter growth, leaf-area duration). The introduction of developed technology into nursery science will permit to improve the tolerance of seedlings to salinization of soils and irrigation waters.

AFP, CEA, CA 19-9 and TPA in Hepatocellular Carcinoma

1990 ◽  
Vol 5 (3) ◽  
pp. 121-126 ◽  
Author(s):  
M.L. Maussier ◽  
V. Valenza ◽  
G. Schinco ◽  
G. Gallv
Keyword(s):  
Hepatocellular Carcinoma ◽  
Diagnostic Accuracy ◽  
Predictive Value ◽  
Roc Curves ◽  
Normal Subjects ◽  
Discriminant Functions ◽  
Mean Values ◽  
High Diagnostic Accuracy ◽  
Normal Mean ◽  
Cirrhotic Patients

The present study is based on the assay of four markers (AFP, CEA, TPA, Ca 19-9) using IRMA methods in 36 normal subjects, 44 cirrhosis and 66 HCC patients. Parametric and non parametric tests were used to test differences and correlations. ROC curves and discriminant functions were also elaborated. Normal 95% “cut-off” was determined by the “boostrap” method yielding: CEA 3.4 ng/ml; Ca 19-9 55 U/ml; TPA 58U/l and AFP 5.2 ng/ml. In HCC patients the values of the four markers were, on average, significantly different from those of normal subjects. However, only AFP and TPA exhibited high diagnostic accuracy (90%) for detection of the tumor. Higher than normal mean values for all markers were, also observed in cirrhotic patients. Only AFP yielded effective discrimination between HCC and cirrhosis. The positive prediction for the presence of the tumor on cirrhotic ground was 95% for AFP values higher than 18.5 ng/ml, with a 78% negative predictive value with a 6 ng/ml threshold. Association of AFP with TPA showed only a marginal diagnostic improvement. Results were not improved at all by combining CEA and Ca 19-9 with AFP and/or TPA. In conclusion, AFP is and remains the best marker for HCC and the only one effective in discriminating of HCC from cirrhosis. TPA may be considered a valid alternative if cirrhosis is not present. CEA and Cal9-9 are of no use.

Discrimination of lichen genera and species using element concentrations

2008 ◽  
Vol 40 (2) ◽  
pp. 135-151 ◽  
Author(s):  
James P. BENNETT
Keyword(s):  
Chemical Elements ◽  
Lichen Species ◽  
Discriminant Functions ◽  
Euclidean Distance Matrix ◽  
Element Space ◽  
Parmelia Sulcata ◽  
Element Concentrations ◽  
Zn Concentration ◽  
Additive Trees ◽  
Punctelia Rudecta

Abstract:The importance of organic chemistry in the classification of lichens is well established, but inorganic chemistry has been largely overlooked. Six lichen species were studied over a period of 23 years that were growing in 11 protected areas of the northern Great Lakes ecoregion, which were not greatly influenced by anthropogenic particulates or gaseous air pollutants. The elemental data from these studies were aggregated in order to test the hypothesis that differences among species in tissue element concentrations were large enough to discriminate between taxa faithfully. Concentrations of 16 chemical elements that were found in tissue samples from Cladonia rangiferina, Evernia mesomorpha, Flavopunctelia flaventior, Hypogymnia physodes, Parmelia sulcata, and Punctelia rudecta were analyzed statistically using multivariate discriminant functions and CART analyses, as well as t-tests. Genera and species were clearly separated in element space, and elemental discriminant functions were able to classify 91–100 of the samples correctly into species. At the broadest level, a Zn concentration of 51 ppm in tissues of four of the lichen species effectively discriminated foliose from fruticose species. Similarly, a S concentration of 680 ppm discriminated C. rangiferina and E. mesomorpha, and a Ca concentration of 10 436 ppm discriminated H. physodes from P. sulcata. For the three parmelioid species, a Ca concentration >32 837 ppm discriminated Punctelia rudecta from the other two species, while a Zn concentration of 56 ppm discriminated Parmelia sulcata from F. flaventior. Foliose species also had higher concentrations than did fruticose species of all elements except Na. Elemental signatures for each of the six species were developed using standardized means. Twenty-four mechanisms explaining the differences among species are summarized. Finally, the relationships of four species based on element concentrations, using additive-trees clustering of a Euclidean-distance matrix, produced identical relationships as did analyses based on secondary product chemistry that used additive-trees clustering of a Jaccard similarity matrix. At least for these six species, element composition has taxonomic significance, and may be useful for discriminating other taxa.

scholarly journals Leaves of trees and shrubs as bioindicators of air pollution by particulate matter in Saint Petersburg

2020 ◽  
Vol 13 (1) ◽  
pp. 224-232 ◽  
Author(s):  
Nataliia V. Terekhina ◽  
Margarita D. Ufimtseva
Keyword(s):  
Particulate Matter ◽  
Chemical Elements ◽  
Common Species ◽  
Tilia Cordata ◽  
Rosa Rugosa ◽  
Central District ◽  
Chemical Content ◽  
Ulmus Laevis ◽  
The City ◽  
Trees And Shrubs

Accumulation of chemical elements by leaves of trees and shrubs in urban (Central District of St. Petersburg) and background habitats were studied. To determine proportion of pollutants accumulating on the surface of leaves, chemical content of washed and unwashed leaves were analyzed. The results of the study showed that big part (19-62%) of pollutants is deposited on the surface of leaves of urban lindens, and only 10% on the surface of leaves from background places. Average difference between quantity of particulate matter for them is 4 times. Tilia cordata and Ulmus laevis has the highest value of ash content between washing and washing leaves. The level of contamination (Kk) showed high values for Fe (8.83), Co (7.47), Cr (5.62), Pb (4.31), Zn (3.04) for unwashed leaves of urban lindens; for the washed leaves this index slightly increased only for Fe (3.12) and Pb (2.13). Accumulative ability depends on the structure of leaf blade of each species, and the ecological situation of the habitat. Ulmus laevis, Tilia cordata, Populus sp., and Rosa rugosa accumulate more pollutants, and can be recommended for protective green plantings. Tilia cordata, as the most common species in the city green spaces, can be used as an indicator of the level of atmospheric pollution.

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