EFFECT OF SILVER DOPING ON INFRARED REFLECTANCE AND Tc OF SUPERCONDUCTING GdBa2Cu(1−x)3Ag3xO7

1990 ◽  
Vol 04 (11n12) ◽  
pp. 1889-1894
Author(s):  
A. MEMON ◽  
M.N. KHAN ◽  
S. AL-DALLAL ◽  
D.B. TANNER ◽  
C.D. PORTER
Keyword(s):  
Room Temperature ◽  
Phonon Mode ◽  
Resistivity Measurement ◽  
Infrared Reflectance ◽  
Optical Phonons ◽  
Ceramic Superconductor ◽  
Frequency Range ◽  
Phonon Modes ◽  
Silver Doping ◽  
Zero Resistance

Infrared reflectance of GdBa 2 Cu (1−x)3 Ag 3xO7 ceramic superconductor with the composition of x=0.025 and 0.05 have been performed in the frequency range of 100–5000 cm−1. All the infrared active phonon modes allowed by the selection rules were observed in the reflection spectra of these compounds. The optical conductivity as calculated from K-K analysis further confirms the existence of these optical phonons. Besides the increase of the reflectivity in the silver doped samples, an extra phonon mode is observed, which is normally not seen at room temperature reflectance of GdBa 2 Cu 3 O 7 compounds. The four probe resistivity measurement show zero resistance at 88 K for x=0, and 78 K for x=0.025 in GdBa 2 Cu (1−x)3 Ag 3x O 7 compound.

Infrared reflectance spectroscopy of MgAl2O4 nanoparticles substituted by K+ ions

2018 ◽  
Vol 32 (06) ◽  
pp. 1850067 ◽  
Author(s):  
Javed Ahmad ◽  
M. Qadeer Awan ◽  
Roomana Yasmin ◽  
Maria Sabir ◽  
Shafiq Anwar ◽  
...  
Keyword(s):  
Room Temperature ◽  
Longitudinal Optical ◽  
Reflectance Spectroscopy ◽  
Optical Parameters ◽  
Frequency Range ◽  
Phonon Modes ◽  
Metallic Behavior ◽  
Lorentz Oscillator ◽  
Reflectivity Spectra ◽  
Ftir Spectrometer

The infrared reflectivity spectra for potassium-doped polycrystalline magnesium aluminates Mg[Formula: see text]K[Formula: see text]Al2O4 (x=0, 0.25, 0.50, 0.75, 1) are measured in the frequency range between 10–15, 500 cm[Formula: see text] using FTIR spectrometer at room-temperature. Four optical phonon modes are observed in measured spectra, which are fitted by Lorentz oscillator model for semiconducting behavior and Lorentz–Drude model for metallic behavior. Moreover, optical parameters are also determined for these modes which may attribute to spinel structure for samples Mg[Formula: see text]K[Formula: see text]Al2O4, their reflectivity spectra shows a typical semiconducting nature. To study ionicity and effect of polarization, Born and Szigeti effective charges are calculated from longitudinal optical and transverse optical (LO–TO) splitting of modes for all samples. Optical bandgap has been estimated through optical conductivity ([Formula: see text]([Formula: see text])) and found to be x dependent.

scholarly journals Plasmonic hot electron induced layer dependent anomalous Fröhlich interaction in InSe

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Mahfujur Rahaman ◽  
Muhammad Awais Aslam ◽  
Lu He ◽  
Teresa I. Madeira ◽  
Dietrich R. T. Zahn
Keyword(s):  
Electrical Transport ◽  
Room Temperature ◽  
Gradual Decrease ◽  
Hot Electrons ◽  
Great Promise ◽  
Hot Electron ◽  
Optical Phonons ◽  
Phonon Modes ◽  
Reduced Dimensionality ◽  
Layer Number

AbstractDespite the great promise of InSe for electronic and optoelectronic applications, Fröhlich interaction plays an important role in electrical transport due to the polar nature of it, which can become more significant in reduced dimensionality. Here, we report on how the dimensionality influences the strength and nature of the Fröhlich polaronic effect in InSe with the aid of plasmonic hot electrons injection. Polar optical phonons couple to hot electrons via the Fröhlich interaction in InSe and enable us to monitor them in conventional Raman measurements. We observed that the intensity of these phonon modes initially increases gradually with decreasing layer number and then drops drastically from 7 L to 6 L (transition from quasi-direct to indirect bandgap at room temperature). Additionally, a gradual decrease of intensity of the polar modes with further decreasing layer number is observed due to the increasing indirect bandgap nature of InSe suggesting reduced Fröhlich coupling below this thickness.

scholarly journals Optical Investigation of La1-xCaxMnO3 and La1-xLixMnO3

1999 ◽  
Vol 52 (2) ◽  
pp. 197 ◽  
Author(s):  
R. A. Lewis ◽  
A. D. Martin ◽  
X. L. Wang ◽  
S. X. Dou
Keyword(s):  
Elevated Temperature ◽  
Infrared Spectrum ◽  
Spectral Region ◽  
Lower Energy ◽  
Room Temperature ◽  
Phonon Mode ◽  
Optical Investigation ◽  
Optical Study ◽  
Phonon Modes ◽  
Infrared Spectral

An optical study has been made of La0·7Ca0·3MnO3 and La0·8Li0·2MnO3 in the infrared spectral region (100 cm-1 to 4000 cm-1). The transmission of all samples is negligible. The photoconductive response is also unmeasurable. The data reported are therefore restricted to reflectivity measurements. At room temperature, both materials exhibit similar ‘bending’ and ‘stretching’ phonon modes, associated with the MnO6 octahedra, at ~330 and ~580 cm-1, respectively. The ‘external’ phonon mode observed at ~170 cm-1, corresponding to the (La,Ca/Li) cations beating against the MnO6 octahedra, is slightly shifted between the two materials, as would be expected on the basis of the different compositions. At elevated temperature (~600°C) the intensity of the light reflected decreases across the infrared spectrum, and the ‘stretching’ mode moves to lower energy.

scholarly journals Photothermal, Photoelectric, and Photothermoelectric Effects in Bi-Sb Thin Films in the Terahertz Frequency Range at Room Temperature

Photonics ◽  
2021 ◽  
Vol 8 (3) ◽  
pp. 76
Author(s):  
Mikhail K. Khodzitsky ◽  
Petr S. Demchenko ◽  
Dmitry V. Zykov ◽  
Anton D. Zaitsev ◽  
Elena S. Makarova ◽  
...  
Keyword(s):  
Thin Films ◽  
Terahertz Radiation ◽  
Room Temperature ◽  
Voltage Drop ◽  
Radiation Detection ◽  
Radiation Detectors ◽  
Thz Radiation ◽  
Terahertz Frequency ◽  
Frequency Range ◽  
Terahertz Frequency Range

The terahertz frequency range is promising for solving various practically important problems. However, for the terahertz technology development, there is still a problem with the lack of affordable and effective terahertz devices. One of the main tasks is to search for new materials with high sensitivity to terahertz radiation at room temperature. Bi1−xSbx thin films with various Sb concentrations seem to be suitable for such conditions. In this paper, the terahertz radiation influence onto the properties of thermoelectric Bi1−xSbx 200 nm films was investigated for the first time. The films were obtained by means of thermal evaporation in vacuum. They were affected by terahertz radiation at the frequency of 0.14 terahertz (THz) in the presence of thermal gradient, electric field or without these influences. The temporal dependencies of photoconductivity, temperature difference and voltage drop were measured. The obtained data demonstrate the possibility for practical use of Bi1−xSbx thin films for THz radiation detection. The results of our work promote the usage of these thermoelectric materials, as well as THz radiation detectors based on them, in various areas of modern THz photonics.

scholarly journals Dielectric Spectroscopy Analysis of Liquid Crystals Recovered from End-of-Life Liquid Crystal Displays

Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2873
Author(s):  
Ana Barrera ◽  
Corinne Binet ◽  
Frédéric Dubois ◽  
Pierre-Alexandre Hébert ◽  
Philippe Supiot ◽  
...  
Keyword(s):  
Liquid Crystals ◽  
End Of Life ◽  
Room Temperature ◽  
Liquid Crystal Displays ◽  
Dielectric Anisotropy ◽  
Frequency Range ◽  
Spectroscopy Analysis ◽  
Diamond Nanoparticles ◽  
Nematic Phases ◽  
Universal Law

In the present work, the dielectric properties of recycled liquid crystals (LCs) (non-purified, purified, and doped with diamond nanoparticles at 0.05, 0.1, and 0.2 wt%) were investigated. The studied LC mixtures were obtained from industrial recycling of end-of-life LC displays presenting mainly nematic phases. Dielectric measurements were carried out at room temperature on a frequency range from 0.1 to 106 Hz using an impedance analyzer. The amplitude of the oscillating voltage was fixed at 1 V using cells with homogeneous and homeotropic alignments. Results show that the dielectric anisotropy of all purified samples presents positive values and decreases after the addition of diamond nanoparticles to the LC mixtures. DC conductivity values were obtained by applying the universal law of dielectric response proposed by Jonscher. In addition, conductivity of the doped LC mixtures is lower than that of the undoped and non-purified LC.

High Frequency Dielectric Response of the Ionic Liquid N-Methyl-N-ethylpyrrolidinium Dicyanamide

2007 ◽  
Vol 60 (1) ◽  
pp. 6 ◽  
Author(s):  
Simon Schrödle ◽  
Gary Annat ◽  
Douglas R. MacFarlane ◽  
Maria Forsyth ◽  
Richard Buchner ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Dielectric Loss ◽  
Dielectric Relaxation ◽  
High Frequency ◽  
Dielectric Response ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Dielectric Relaxation Spectroscopy ◽  
Frequency Range ◽  
Fast Rotation

A study of the room-temperature ionic liquid N-methyl-N-ethylpyrrolidinium dicyanamide by dielectric relaxation spectroscopy over the frequency range 0.2 GHz ≤ ν ≤ 89 GHz has revealed that, in addition to the already known lower frequency processes, there is a broad featureless dielectric loss at higher frequencies. The latter is probably due to the translational (oscillatory) motions of the dipolar ions of the IL relative to each other, with additional contributions from their fast rotation.

scholarly journals Оптические свойства фазопеременных материалов системы германий--сурьма-теллур составов Ge-=SUB=-14-=/SUB=-Sb-=SUB=-29-=/SUB=-Te-=SUB=-57-=/SUB=- и Ge-=SUB=-15-=/SUB=-Sb-=SUB=-15-=/SUB=-Te-=SUB=-70-=/SUB=- в дальнем инфракрасном диапазоне

2021 ◽  
Vol 55 (7) ◽  
pp. 542
Author(s):  
В.А. Рыжов ◽  
Б.Т. Мелех ◽  
Л.П. Казакова
Keyword(s):  
Amorphous Alloy ◽  
Infrared Absorption ◽  
Crystalline State ◽  
Room Temperature ◽  
Torsional Vibrations ◽  
Phonon Modes ◽  
Absorption Bands ◽  
Structural Units ◽  
Chalcogenide Alloys ◽  
Infrared Absorption Spectra

Abstract Infrared absorption spectra of chalcogenide alloys of the GST system with the compositions Ge14Sb29Te57 and Ge15Sb15Te70 in the amorphous and crystalline state were measured and analyzed in the range of 20 – 400 cm– 1 (0.6 – 12 THz) at room temperature. Absorption at these frequencies is due to the manifestation of correlated torsional vibrations of structural units of the amorphous alloy and phonon modes of the crystal. The performed assignment of absorption bands and the revealed differences in the IR spectra make it possible to more confidently represent the possible molecular mechanism of reversible amorphous-crystalline transformations in the studied phase-changing materials

scholarly journals Подвижность ионных носителей заряда в пьезоэлектрических кристаллах Li-=SUB=-2-=/SUB=-B-=SUB=-4-=/SUB=-O-=SUB=-7-=/SUB=-

2020 ◽  
Vol 62 (3) ◽  
pp. 386
Author(s):  
Н.И. Сорокин ◽  
Ю.В. Писаревский ◽  
В.В. Гребенев ◽  
В.А. Ломонов
Keyword(s):  
Crystal Lattice ◽  
Carrier Mobility ◽  
Room Temperature ◽  
Lithium Ion ◽  
Structural Data ◽  
Crystallographic Axis ◽  
Frequency Range ◽  
Impedance Measurements ◽  
Structural Mechanism ◽  
Ag Electrodes

The impedance measurements of Li2B4O7 single crystal with Ag electrodes in the frequency range 1-3*107 Hz at room temperature have been made. The Li2B4O7 crystal (sp. gr. I41cd, Z = 8) was oriented along crystallographic axis c. Contributions from the bulk crystal and crystal / electrode boundaries in the impedance hodograph of the Ag | Li2B4O7 | Ag system were selected. The structural mechanism of lithium-ion transport in Li2B4O7 has been discussed. Based on electrophysical and structural data, the conductivity σdc = 2.3 × 10–9 S / cm, carrier mobility (vacancies VLi) μmob = 6 × 10−10 cm2 / sV and their concentration nmob = 2.4 × 1019 cm – 3 (0.14% of the amount of lithium in the crystal lattice) have been determined.

scholarly journals Symmetrical Analysis Phonon Modes of Crystal -Ag8SnSe6

2015 ◽  
Vol 16 (2) ◽  
pp. 257-260
Author(s):  
І.V. Semkiv ◽  
А.І. Kashuba ◽  
H.A. Ilchuk ◽  
M.V. Chekaylo
Keyword(s):  
Raman Spectra ◽  
Infrared Spectra ◽  
Room Temperature ◽  
Group Symmetry ◽  
Phonon Modes ◽  
Orthorhombic System ◽  
Space Group Symmetry ◽  
Space Group ◽  
Phonon Spectra

Symmetrical analysis of the phonon spectra of  lowtemperature b¢-phase of crystal Ag8SnSe6 carried out. At the room temperature argyrodite Ag8SnSe6 belong to orthorhombic system with space group symmetry Pmn21. Classification of the main phonon modes of crystal carried out. Clarified selection rules for Raman spectra and infrared spectra.

scholarly journals Смена знака магнитоемкости в парамагнитной области в катион-замещенном селениде марганца

2018 ◽  
Vol 60 (4) ◽  
pp. 670
Author(s):  
С.С. Аплеснин ◽  
М.Н. Ситников ◽  
А.М. Живулько
Keyword(s):  
Magnetic Field ◽  
Solid Solution ◽  
Magnetic Susceptibility ◽  
Dielectric Loss ◽  
Dielectric Permittivity ◽  
Room Temperature ◽  
Frequency Range ◽  
Wagner Model ◽  
Paramagnetic Region ◽  
Orbital Electron

AbstractThe capacity and the dielectric loss tangent of a Gd_ x Mn_1– x Se ( x ≤ 0.2) solid solution have been measured in the frequency range 1–300 kHz without a magnetic field and in a magnetic field of 8 kOe in the temperature range 100–450 K, and the magnetic moment of the solid solution has been measured in a field of 8.6 kOe. The magnetocapacity effect and the change in the magnetocapacity sign have been observed in room temperature in the paramagnetic region. A correlation of the changes in the dielectric permittivity and the magnetic susceptibility with temperature has been revealed. The magnetocapacity is described using the model with orbital electron ordering and the Maxwell–Wagner model.

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