scholarly journals Determination of Mobility and Charge Carriers Concentration from Ionic Conductivity in Sodium Germanate Glasses above and below Tg

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
Marcio Luis Ferreira Nascimento
Keyword(s):  
Ionic Conductivity ◽  
Charge Carrier ◽  
Formation Enthalpy ◽  
Large Temperature ◽  
Complete Test ◽  
Ionic Displacement ◽  
The Difference ◽  
And Migration ◽  
Positively Charged

The ionic conductivity and viscous flow data of xNa2O·(1−x)GeO2, 0.05<x<0.296, have been collected in a large temperature range, below and above their glass transition temperatures (Tg). A microscopic model is proposed, assuming that the ionic displacement would result from the migration of interstitial positively charged cationic pairs whose concentration is an activated function of temperature. Below Tg, their migration is also an activated mechanism, but a “free volume” would prevail above this temperature. This discontinuity in the migration mechanism justifies a Dienes-Macedo-Litovitz (DML) relationship to be representative of conductivity data above Tg and an Arrhenius law below. According to this model, the enthalpy deduced by the fit of high temperature data using a DML equation would correspond to the charge carrier formation, whose migration enthalpy, below Tg, could be deduced by the difference between the activation energy measured in the Arrhenius domain and the charge carrier formation enthalpy. To reduce the number of adjustable parameters numerical values were physically justified. We also applied a complete test for conductivity below Tg, using the so-called weak electrolyte model, splitting activation enthalpy EσA into formation and migration enthalpies and also explaining the variation of pre-exponential term of conductivity with composition.

Determination of the Activation Energy for Formation and Migration of Thermal Vacancies in 401.0 Casting Aluminum Alloy

2013 ◽  
Vol 337-338 ◽  
pp. 1-4
Author(s):  
N.A. Kamel ◽  
S.A. Aly ◽  
A.A. Ibrahim ◽  
E.A. Badawi
Keyword(s):  
Aluminum Alloy ◽  
Formation Enthalpy ◽  
Electrical Measurements ◽  
Quenching Rate ◽  
Self Diffusion ◽  
A Value ◽  
Casting Aluminum Alloy ◽  
Casting Aluminum ◽  
And Migration

Electrical techniques have been used to study the thermal vacancies in 401.0 casting aluminum alloy. Quenching experiments were usually performed on thin specimens to ensure a uniform quenching rate throughout the specimen. After grinding, polishing and etching, samples of 401.0 were homogenized for 12h at 673K and annealed for 90min., before quenched in water (277K) and then subjected to electrical measurements. From such measurements it is possible to deduce the vacancy formation enthalpy, which in combination with the results of self-diffusion measurements, give a value for the migration enthalpy of the vacancy.

scholarly journals Metamorphism of Dry Snow as a Result of Temperature Gradient and Vapor Density Differences

1983 ◽  
Vol 4 ◽  
pp. 3-9 ◽  
Author(s):  
E. E. Adams ◽  
R. L. Brown
Keyword(s):  
Temperature Gradient ◽  
Heat Conduction Equation ◽  
Temperature Gradients ◽  
Large Temperature ◽  
Local Minima ◽  
Vapor Density ◽  
Snow Density ◽  
Local Maxima ◽  
The Difference

A heat conduction equation for the determination of the temperature profile in a snowpack is developed. The magnitude of the temperature gradient tends to increase as the snow surface is approached, with local minima through layers of high snow density and local maxima above and below these layers. Calculations are made of the difference in vapor density in the pore and over the ice grain surfaces which border the pore. In the presence of sufficient temperature and temperature gradient, faceted crystals will develop near the top of the pore, as ice is sublimed away from the surfaces in the lower region. There will be a reduction in the percentage of rounded grains as the faceted form develops. The process is demonstrated to be enhanced at warm temperatures and large temperature gradients in low density snow.

scholarly journals Metamorphism of Dry Snow as a Result of Temperature Gradient and Vapor Density Differences

1983 ◽  
Vol 4 ◽  
pp. 3-9 ◽  
Author(s):  
E. E. Adams ◽  
R. L. Brown
Keyword(s):  
Temperature Gradient ◽  
Heat Conduction Equation ◽  
Temperature Gradients ◽  
Large Temperature ◽  
Local Minima ◽  
Vapor Density ◽  
Snow Density ◽  
Local Maxima ◽  
The Difference

A heat conduction equation for the determination of the temperature profile in a snowpack is developed. The magnitude of the temperature gradient tends to increase as the snow surface is approached, with local minima through layers of high snow density and local maxima above and below these layers. Calculations are made of the difference in vapor density in the pore and over the ice grain surfaces which border the pore. In the presence of sufficient temperature and temperature gradient, faceted crystals will develop near the top of the pore, as ice is sublimed away from the surfaces in the lower region. There will be a reduction in the percentage of rounded grains as the faceted form develops. The process is demonstrated to be enhanced at warm temperatures and large temperature gradients in low density snow.

Determination of the Activation Energy for Formation and Migration of Thermal Vacancies in 2024 Aircraft Material Using Different Techniques and Methods

2013 ◽  
Vol 337-338 ◽  
pp. 19-27
Author(s):  
N.A. Kamel
Keyword(s):  
Formation Enthalpy ◽  
Quenching Rate ◽  
Positron Annihilation Lifetime ◽  
Self Diffusion ◽  
A Value ◽  
2024 Alloy ◽  
And Migration ◽  
Induced Defects ◽  
Irradiation Induced Defects

Positron annihilation lifetime (PAL) , electrical and mechanical techniques have been used to study the thermal vacancies in one of the most important engineering aluminum alloys which is 2024 alloy. Quenching experiments were usually performed on thin specimens to ensure a uniform quenching rate throughout the specimen. The specimens were prepared with dimensions of 0.15 × 1.5 × 1.5cm3. After grinding, polishing and etching, samples of 2024 were homogenized for 12 h at 673 K and annealed for 90-min., before quenched in water (277 K) and then subject to positron lifetime, electrical and mechanical for measurements. From such measurements it is possible to deduce the vacancy formation enthalpy, which in combination with the results of self-diffusion measurements, give a value for migration enthalpy of the vacancy. These are very important quantities in the study of the annealing of irradiation induced defects.

FRACTIONAL DETERMINATIONS OF URINARY 17-KETOSTEROIDS IN HYPEREMESIS GRAVIDARUM

1962 ◽  
Vol 41 (1) ◽  
pp. 123-128 ◽  
Author(s):  
Pentti A. Järvinen ◽  
Sykkö Pesonen ◽  
Pirkko Väänänen
Keyword(s):  
Hyperemesis Gravidarum ◽  
First Trimester ◽  
Control Group ◽  
Before And After ◽  
Daily Urine ◽  
First Trimester Of Pregnancy ◽  
The Difference

ABSTRACT The fractional determination of 17-ketosteroids in the daily urine was performed in nine cases of hyperemesis gravidarum and in four control cases, in the first trimester of pregnancy both before and after corticotrophin administration. The excretion of total 17-KS is similar in the two groups. Only in the hyperemesis group does the excretion of total 17-KS increase significantly after corticotrophin administration. The fractional determination reveals no difference between the two groups of patients with regard to the values of the fractions U (unidentified 17-KS), A (androsterone) and Rest (11-oxygenated 17-KS). The excretion of dehydroepiandrosterone is significantly higher in the hyperemesis group than in the control group. The excretion of androstanolone seems to be lower in the hyperemesis group than in the control group, but the difference is not statistically significant. The differences in the correlation between dehydroepiandrosterone and androstanolone in the two groups is significant. The high excretion of dehydroepiandrosterone and low excretion of androstanolone in cases of hyperemesis gravidarum is a sign of adrenal dysfunction.

Explaining the magnetism of gold

2017 ◽  
Author(s):  
Robson de Farias
Keyword(s):  
Gas Phase ◽  
Computational Study ◽  
Formation Enthalpy ◽  
Gold Atom ◽  
Orbital Energy ◽  
Knudsen Effusion ◽  
Energy Diagram ◽  
Unpaired Electrons ◽  
The Difference ◽  
Good Agreement

<p>In the present work, a computational study is performed in order to clarify the possible magnetic nature of gold. For such purpose, gas phase Au<sub>2</sub> (zero charge) is modelled, in order to calculate its gas phase formation enthalpy. The calculated values were compared with the experimental value obtained by means of Knudsen effusion mass spectrometric studies [5]. Based on the obtained formation enthalpy values for Au<sub>2</sub>, the compound with two unpaired electrons is the most probable one. The calculated ionization energy of modelled Au<sub>2</sub> with two unpaired electrons is 8.94 eV and with zero unpaired electrons, 11.42 eV. The difference (11.42-8.94 = 2.48 eV = 239.29 kJmol<sup>-1</sup>), is in very good agreement with the experimental value of 226.2 ± 0.5 kJmol<sup>-1</sup> to the Au-Au bond<sup>7</sup>. So, as expected, in the specie with none unpaired electrons, the two 6s<sup>1</sup> (one of each gold atom) are paired, forming a chemical bond with bond order 1. On the other hand, in Au<sub>2</sub> with two unpaired electrons, the s-d hybridization prevails, because the relativistic contributions. A molecular orbital energy diagram for gas phase Au<sub>2</sub> is proposed, explaining its paramagnetism (and, by extension, the paramagnetism of gold clusters and nanoparticles).</p>

THE SUBJECT FIELD OF INSTITUTIONAL EDUCATION: THE SENSE AND PROSPECTS OF DEVELOPMENT IN UKRAINE

2020 ◽  
pp. 25-38
Author(s):  
Irina Mordous
Keyword(s):  
Decisive Role ◽  
Subject Field ◽  
National Education ◽  
Progressive Development ◽  
Separate Area ◽  
Economic Transformations ◽  
The Difference ◽  
The Individual ◽  
Political Economic

The development of modern civilization attests to its decisive role in the progressive development of institutions. They identified the difference between Western civilization and the rest of the world. Confirmation of the institutional advantages of the West was its early industrialization. The genesis and formation of institutionalism in its ideological and conceptualmethodological orientation occurs as a process alternative to neoclassic in the context of world heterodoxia, which quickly spread in social science. Highlighting institutional education as a separate area of sociocultural activity is determined by the factor of differentiation of institutional theory as a whole. A feature of institutional education is its orientation toward the individual and his/her transformation into a personality. The content of institutional education is revealed through the analysis of the institution, which includes a set of established customs, traditions, ways of thinking, behavioral stereotypes of individuals and social groups. The dynamics of socio-political, economic transformations in Ukraine requires a review of the foundations of national education and determination of the prospects for its development in the 21st century in the context of institutionalism.

scholarly journals Possibility of Human Gender Recognition Using Raman Spectra of Teeth

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 3983
Author(s):  
Ozren Gamulin ◽  
Marko Škrabić ◽  
Kristina Serec ◽  
Matej Par ◽  
Marija Baković ◽  
...  
Keyword(s):  
Raman Spectra ◽  
Principal Component ◽  
Support Vector ◽  
Gender Recognition ◽  
Proof Of Concept ◽  
Male And Female ◽  
Tooth Type ◽  
Tooth Apex ◽  
The Difference

Gender determination of the human remains can be very challenging, especially in the case of incomplete ones. Herein, we report a proof-of-concept experiment where the possibility of gender recognition using Raman spectroscopy of teeth is investigated. Raman spectra were recorded from male and female molars and premolars on two distinct sites, tooth apex and anatomical neck. Recorded spectra were sorted into suitable datasets and initially analyzed with principal component analysis, which showed a distinction between spectra of male and female teeth. Then, reduced datasets with scores of the first 20 principal components were formed and two classification algorithms, support vector machine and artificial neural networks, were applied to form classification models for gender recognition. The obtained results showed that gender recognition with Raman spectra of teeth is possible but strongly depends both on the tooth type and spectrum recording site. The difference in classification accuracy between different tooth types and recording sites are discussed in terms of the molecular structure difference caused by the influence of masticatory loading or gender-dependent life events.

scholarly journals Intranasal delivery of mitochondria for treatment of Parkinson’s Disease model rats lesioned with 6-hydroxydopamine

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jui-Chih Chang ◽  
Yi-Chun Chao ◽  
Huei-Shin Chang ◽  
Yu-Ling Wu ◽  
Hui-Ju Chang ◽  
...  
Keyword(s):  
Parkinson’S Disease ◽  
Parkinson's Disease ◽  
Olfactory Bulb ◽  
Disease Model ◽  
Intranasal Delivery ◽  
The Difference ◽  
And Migration ◽  
6 Hydroxydopamine ◽  
Locomotor Behaviors ◽  
Migratory Stream

AbstractThe feasibility of delivering mitochondria intranasally so as to bypass the blood–brain barrier in treating Parkinson's disease (PD), was evaluated in unilaterally 6-OHDA-lesioned rats. Intranasal infusion of allogeneic mitochondria conjugated with Pep-1 (P-Mito) or unconjugated (Mito) was performed once a week on the ipsilateral sides of lesioned brains for three months. A significant improvement of rotational and locomotor behaviors in PD rats was observed in both mitochondrial groups, compared to sham or Pep-1-only groups. Dopaminergic (DA) neuron survival and recovery > 60% occurred in lesions of the substantia nigra (SN) and striatum in Mito and P-Mito rats. The treatment effect was stronger in the P-Mito group than the Mito group, but the difference was insignificant. This recovery was associated with restoration of mitochondrial function and attenuation of oxidative damage in lesioned SN. Notably, P-Mito suppressed plasma levels of inflammatory cytokines. Mitochondria penetrated the accessory olfactory bulb and doublecortin-positive neurons of the rostral migratory stream (RMS) on the ipsilateral sides of lesions and were expressed in striatal, but not SN DA neurons, of both cerebral hemispheres, evidently via commissural fibers. This study shows promise for intranasal delivery of mitochondria, confirming mitochondrial internalization and migration via RMS neurons in the olfactory bulb for PD therapy.

scholarly journals Influence of Erythrocytes on Direct Potentiometric Determination of Sodium and Potassium

1983 ◽  
Vol 20 (2) ◽  
pp. 116-120 ◽  
Author(s):  
P Bijster ◽  
H L Vader ◽  
C L J Vink
Keyword(s):  
Whole Blood ◽  
Potassium Concentration ◽  
Reference Electrode ◽  
Sodium Concentration ◽  
General Phenomenon ◽  
Liquid Junction ◽  
Direct Potentiometry ◽  
The Difference ◽  
Sodium And Potassium

We have shown that the sodium concentration in whole blood measured by direct potentiometry is higher than in plasma. The ‘erythrocyte-effect’, already described by Siggaard Andersen, is most pronounced for instruments equipped with a reference electrode with an open static liquid junction and is thus a general phenomenon. Instruments with a modified liquid junction show less interference. The same phenomenon appears for the determination of the potassium concentration, although the difference between whole blood and plasma, when measured with instruments equipped with a modified liquid junction, can be neglected in practice.

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