scholarly journals Physico-Chemical Characteristics and Level of Some Selected Metal in Edible Oils

2016 ◽  
Vol 2016 ◽  
pp. 1-7
Author(s):  
Bereket Tesfaye ◽  
Alemayehu Abebaw
Keyword(s):  
Palm Oil ◽  
Edible Oils ◽  
Chemical Properties ◽  
Acid Value ◽  
Human Consumption ◽  
Essential Metals ◽  
Flame Atomic Absorption Spectroscopy ◽  
Flame Atomic Absorption ◽  
Physico Chemical ◽  
Wet Chemical

The physico-chemical properties and level of some essential metals of four edible oils, two imported (Viking and Avena) and two processed in Ethiopia (Selam and Nur) oil samples, were analyzed using classical wet chemical method and flame atomic absorption spectroscopy techniques, respectively. The result of physico-chemical properties shows that acid value in Avena and Viking oils which is 0.091±0.0042 mgKOH/g and 0.082±0.0047 mgKOH/g, respectively, from palm oil variety and in Selam and Nur oils 0.276±0.0056 mgKOH/g and 0.188±0.0050 mgKOH/g, respectively, from noug oil variety, saponification value in Avena and Viking oils which is 190.27±3.528 mgKOH/g and 189.80±3.528 mgKOH/g, respectively, and in Selam and Nur oils 187.00±5.668 mgKOH/g and 143.05±8.527 mgKOH/g, respectively, iodine value in Viking and Avena oils which is 97.545±0.6345 g and 53.807±1.0150 g, respectively, and Nur and Selam oils 116.410±0.3863 g and 88.153±0.5300 g, respectively, and peroxide value in Viking and Avena oils which is 1.413±0.0808 meq/kg and 1.233±0.0305 meq/kg, respectively, from palm oil variety and in Selam and Nur oils 0.893±0.0503 meq/kg and 1.460±0.0600 meq/kg, respectively, from noug oil variety were obtained. The level of essential metals in edible oil samples was analyzed after wet digestion. The results show that levels of Cu in Viking and Avena oils that were 0.62±0.022 mg and 0.28±0.004 mg, respectively, and in Selam and Nur oils 0.86±0.003 mg and 0.42±0.005 mg, respectively, and the levels of Zn in Viking and Avena oils that were 1.58±0.154 mg and 1.27±0.255 mg, respectively, and in Selam and Nur oils 1.19±0.160 mg and 1.47±0.567 mg, respectively, were obtained. The physico-chemical properties and level of essential metal revealed that four edible oils were acceptable to human consumption.

scholarly journals Engineering Process Of Deodorization To Improve Product Quality Of Red Palm Oil With Rich Of Carotene

2018 ◽  
Vol 1 (1) ◽  
pp. 20-26
Author(s):  
Mursalin Mursalin
Keyword(s):  
Fatty Acid ◽  
Free Fatty Acid ◽  
Palm Oil ◽  
Chemical Properties ◽  
Absolute Temperature ◽  
Odor Intensity ◽  
Process Duration ◽  
Red Palm Oil ◽  
Physico Chemical

Efforts to develop the production technology of high quality red palm-oil (RPO) in order to provide source of food ingredient that naturally rich of nutrients, become urgents regarding the need of such products drastically increased recently. Application of deodorization technology by temperature, time, and deodorizer pressure combinations (engineering of deodorization process) are studied and evaluated to obtain good quality of RPO. Crude palm oil (CPO) used in this research were supplied by PT. Salim Ivomas (Bimoli) Jakarta. The equipments used were degumming and neutralization unit, deodorization unit and other equipment units to analize the oil physico-chemical properties. The research consisted of 5 stages as the following: characterising CPO physico-chemical properties, conducting chemically degumming and deacidification, process enginering of deodorization, characterizing of physico-chemical properties and organoleptic of RPO resulted, and analyzing data for product resulted from process engineering applied. Deodorization with the range of temperature and process duration of 135–145 oC (408–418 K) and 1–4 hours have led to carotene retention decreasing (%) following the equation “Carotene Retention (%) = -764 x ln(absolute temperature) + 4693” and process duration with the equation “Carotene Retention (%) = -7.81 x ln(process duration) + 91.02”; and also resulted odor intensity with the equation “Odor Intensity = 0.08 x (squared absolute temperature) – 66.88 x (absolute temperature) + 13823” and duration process with the equation “Odor Intensity = 0.315 x (squared process duration) – 1.52 x (process duration) + 5.268”. Effective deodorization to produce RPO with the content of free fatty acid and peroxide value that met the requirements of Indonesian National Standard (SNI) quality of carotene content above 400 ppm and odor scale below 3.3, were the combination of temperature (T) of 141.34 oC, heat process duration (t) of 2.35 hours and vacuum pressure of (P) of 20 mmHg. The resulted RPO contained free fatty acid and peroxide value of 0.11% dan 0.12 meq/kg oil respectively, total carotene of 444.09 ppm and odor value of 3.21  

scholarly journals Synthesis and Characterization of Cocozone Oil as Skin Care Ingredient

2018 ◽  
Vol 7 (3.32) ◽  
pp. 147
Author(s):  
Enjarlis . ◽  
Sri Handayani ◽  
Yenny Anwar
Keyword(s):  
Fatty Acid ◽  
Unsaturated Fatty Acids ◽  
Chemical Properties ◽  
Coconut Oil ◽  
Total Content ◽  
Acid Value ◽  
Skin Care ◽  
Optimal Time ◽  
Physico Chemical ◽  
Ozonation Process

Cocozone Oil (CCO) is one of the ozonated oils, obtained by the ozonation process of Virgin Coconut Oil (VCO), that can be used as a material for skin care products. The purpose of this study was to determine: (1) the optimum time and ozone dose for CCO synthesis from VCO using ozonation; (2) the changes in physico-chemical properties of the oil; (3) the change in saturated-unsaturated fatty acids content and the existence any new substances in the CCO. The ozonation of VCO was carried out for 25 hours, with monitoring at the intervals of 4, 8, 12, 16, 20 and 25 hours, at a constant temperature (25 °C) with an ozone flow of 0.25 g/hr. From this study it can be concluded that: (1) The optimal time or dose of ozone required for the synthesis of CCO from VCO through the ozonation process was 25 hours or equivalent to 0.0208 gr O3/ml VCO, (2) Physico-chemical characteristics of the CCO produced: resulting acid value (AV) was 2.71 mg/gram i.e. an increase of 630%; the peroxide value (PV) obtained was 238,77 mgrek/kg i.e. increase  of 3,453 %; the Iodine value (IV) was 0 (zero) i.e. a decrease of 100%; and, the viscosity was 13.30 centipoice i.e. it rose 116%; (3) the total content of saturated fatty acid increased by 3.34%  whereas the unsaturated fatty acid decreased by 98.83; and based on the analysis results of 13C and 1H NMR spectra, the resultant CCO contains a new substance, that is aldehydes.  

scholarly journals Wet-chemical method for the metallization of a para-aramid filament yarn wound on a cylindrical dyeing package

2016 ◽  
Vol 87 (10) ◽  
pp. 1192-1202 ◽  
Author(s):  
Toty Onggar ◽  
Gosbert Amrhein ◽  
Anwar Abdkader ◽  
Rolf-Dieter Hund ◽  
Chokri Cherif
Keyword(s):  
Composite Materials ◽  
High Performance ◽  
Glass Fibers ◽  
Chemical Properties ◽  
Filament Yarn ◽  
Silver Layer ◽  
Physico Chemical ◽  
Before And After ◽  
Physical Examinations ◽  
Wet Chemical

High-performance yarns such as aramid fibers are nowadays used to reinforce composite materials due to their advantageous physico-chemical properties and their low weight. They are also resistant to heat and fire. Para-aramid filament yarns (p-AFs) wound on a cylindrical dyeing package have been silvered successfully by means of a newly developed wet-chemical filament yarn metallization process on a laboratory scale. The surface morphology of untreated and silvered p-AF was determined by means of scanning electron microscopy. The chemical structure of the surfaces (contents of carbon, oxygen, nitrogen and silver) was determined by means of energy-dispersive X-ray spectroscopy (EDX). The eliminated and newly formed groups of p-AF before and after silvering were detected by infrared spectroscopy (Fourier transform—attenuated total reflectance). After metallization, the silver layer thickness, the mass-related silver content and washing and rubbing fastness were assessed. Furthermore, textile-physical examinations concerning Young's modulus, elongation at break and electrical conductivity were performed. Subsequently, the electrically conductive p-AFs were integrated in thermoset composite materials reinforced by glass fibers and para-aramid.

scholarly journals SYNTHESIS AND PROPERTIES OF ETHOXYLATED GLYCEROL MONOOLEATE AS PALM OIL BASED NONIONIC SURFACTANTS

2015 ◽  
Vol 17 (1) ◽  
pp. 49-55 ◽  
Author(s):  
Indri Badria Adilina ◽  
Egi Agustian ◽  
Yenny Meliana ◽  
Anny Sulaswatty
Keyword(s):  
Palm Oil ◽  
Nonionic Surfactants ◽  
Chemical Properties ◽  
Acid Value ◽  
Molar Ratio ◽  
Alkaline Catalyst ◽  
Surface Active Agents ◽  
Hydrophilic Lipophilic Balance ◽  
Physical And Chemical ◽  
Glycerol Monooleate

Palm oil based nonionic surfactants were synthesized by reacting glycerol monooleate with ethylene oxide at 80 ºC in the prescence of an alkaline catalyst. Purification of the products was conducted by use of acetic acid and black carbon which gave ethoxylated products (EGMO) with a higher level of viscocity and greater solubility in water. Physical and chemical properties of the product such as surface activity, cloud point, acid value, ester value, hydroxyl value, and hydrophilic-lipophilic balance was also determined and results varied depending on the reagent molar ratio. The synthesized EGMO were soluble in water and therefore show potential use as surface active agents in personal care and cosmetic products.Keywords:   nonionic surfactant, ethoxylation, glycerol monooleate, palm oil

scholarly journals Effect of Clonal Variation on Oil Content and Oil Properties of Calophyllum inophyllum L: A Multi Purpose Tree

2021 ◽  
pp. 48-57
Author(s):  
R. Anandalakshmi ◽  
V. Sivakumar ◽  
A. Vijayaraghavan ◽  
K. Suresh Kumar ◽  
C. Rajesh ◽  
...  
Keyword(s):  
Chemical Properties ◽  
Acid Value ◽  
Tree Breeding ◽  
Oil Yield ◽  
Clonal Variation ◽  
Calophyllum Inophyllum ◽  
Potential Source ◽  
Physico Chemical ◽  
Apparent Variation ◽  
Edible Seed

Calophyllum inophyllum is a potential source of non-edible seed oil. Calophyllum oil is used as a biofuel and also for medicinal purposes. At the Institute of Forest Genetics and Tree Breeding, Coimbatore carried out a study in 2019, on five different clones of C. inophyllum  to investigate the effect of clonal variabilty on oil yield and oil physico-chemical properties for use as a biofuel. Oil yield significantly varied among the five clones and ranged from 48.6% to 55.8%. Among the physical properties, except Kinematic Viscosity, Specific Gravity and Refractive Index, the properties such as Flash point, Fire point, Pour point and Cloud point did not vary significantly. However, all the chemical properties studied, such as Acid value, Saponification value, Iodine value and Peroxide value showed apparent variation. From the study it could be derived that clone 15 is more suitable as tree crop for biofuel purpose and the variations among the clones indicate prevalence of scope for tree improvement of C. inophyllum for specific use.

scholarly journals Extraction, Charaterization and Preparation of Soap from Legenaria siceraria Seed Oil

2020 ◽  
pp. 1-6
Author(s):  
Williams Nashuka Kaigama ◽  
Abu Emmanuel Benjamin ◽  
Ibrahim Usman ◽  
Thankgod Daniel
Keyword(s):  
Vegetable Oil ◽  
Seed Oil ◽  
Foam Height ◽  
Palm Kernel ◽  
Chemical Properties ◽  
Acid Value ◽  
Raw Material ◽  
Lagenaria Siceraria ◽  
Saponification Value ◽  
Physico Chemical

Due to the high demand for vegetable oil by soap industries, the quest for alternative raw material is on the increase. In this study, vegetable oil was extracted from the underutilise seeds of Lagenaria siceraria using n-hexane; The Physico-chemical properties of the oil were analysed: iodine value 65 Ig/100 g, acid value 2.50 mg/KOH/g, saponification value 256 mgKOH/g, pH 6.20, specific gravity 0.902, the refractive index of 1.47 and oil yield 52%. The properties of the oil were compared with oil extracted from other sources. The properties of the oil suggest it can use for both commercial and industrial purposes. The extracted oil was then used to prepared soap and its properties were compared with the properties of soaps prepared from other oils. The physicochemical parameters of the prepared soaps which include foam height, hardness, pH and cleansing power were evaluated. The soap made from Lagenaria siceraria seeds oil has foam height of 2.0 cm lower than palm kernel oil (2.1 cm) and higher than soya beans (0.55 cm). Soap made from Lagenaria siceraria seed oil has an appreciable degree of hardness and good cleansing power compared to soaps prepared from other oils. The pH of all the soaps prepared is within the standard of the regulating agency in Nigeria. From the result obtained, it shows the underutilised Lagenaria siceraria seed oil can use as an alternative raw material in the commercial production of soap.

scholarly journals Effect of Surfactant Addition on The Physico-Chemical Properties and Stability of Virgin Coconut Oil Nanoemulsions

Buletin Palma ◽  
2021 ◽  
Vol 22 (1) ◽  
pp. 31
Author(s):  
Linda Trivana ◽  
Nugraha E. Suyatma ◽  
Dase Hunaefi ◽  
S. Joni Munarso
Keyword(s):  
Chemical Properties ◽  
Coconut Oil ◽  
Tween 80 ◽  
Chemical Characteristic ◽  
Human Consumption ◽  
Virgin Coconut Oil ◽  
Tem Analysis ◽  
Physico Chemical ◽  
Span 80 ◽  
The Stability

<p>Virgin coconut oil (VCO) is high quality coconut oil and categorized as the healthiest oil and functional foods. Based on these benefits, the development of a VCO in emulsion product might increase the human consumption of coconut oil because consumers dislike the only taste of pure VCO. The aim of this study was to develop the water compatible form of VCO through nano-emulsification. The effect of different types and amounts of surfactants (Tween 80 and Span 80) on the physio-chemical characteristic of emulsion containing VCO was investigated. VCO based emulsions were prepared with the aid of Ultra-Turrax homogenizer. Emulsions were developed by adding and mixing VCO with surfactants. The ratio of Tween 80 and Span 80 used were 0:10, 2.5:7.5, 5:5, 7.5:2.5, and 10:0. The droplet size of nanoemulsions consisting of Tween 80:Span 80 (0:10, 2.5:7.5, 5:5, 7.5:2.5, and 10:0) were 1.343, 0.606, 0.829, 1.439, and 2.506µm, respectively. Based on the TEM analysis and polydispersity index (PDI) &gt;0.5 showed the oil droplets are in not uniform shape, indicating a unstable emulsion. VCO emulsion with ratio Tween 80:Span 80 (0:10) obtained a homogeneous emulsion (stable) compare than that of others and w/o type emulsion. The stability of emulsion is evaluated by turbidity measurement using UV-VIS spectrophotometer with wavelength 502 nm. A combination of  treatments (ambient condition, thermal treatmeant (40°C)), and centrifuge) of VCO emulsion has resulted on thermal treat, the turbidity measured from the emulsion was higher than the other emulsion, reflecting the presence of the smaller droplets in this emulsion.</p>

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