scholarly journals Sustainable Development of Corrosion Inhibitors from Electronic Scrap: Synthesis and Electrochemical Performance

2019 ◽  
Vol 2019 ◽  
pp. 1-14
Author(s):  
J. Porcayo-Calderon ◽  
J.J. Ramos-Hernandez ◽  
E. Porcayo-Palafox ◽  
L.M. Martínez de la Escalera ◽  
J. Canto ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earths ◽  
High Purity ◽  
Corrosion Inhibitors ◽  
Permanent Magnets ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Open Circuit ◽  
Electronic Scrap ◽  
Low Carbon

Due to its high content of rare earths, the use of permanent magnets can be a sustainable alternative for the synthesis of environmentally friendly corrosion inhibitors in order to replace the use of highly toxic inhibitors, as well as the use of rare earth salts of high purity and high cost. In this study, the recovery of rare earths from permanent magnet wastes and their synthesis to chloride salts were carried out. Rare earth chlorides were evaluated as corrosion inhibitors by electrochemical techniques on API X70 steel in a 3.5% NaCl solution. Both anodic and cathodic polarization curves were made, and measurements of both open-circuit potential, linear polarization resistance, and electrochemical impedance were made. Results show that the inhibitor synthesized is a mixture of Nd and Pr chloride. Its performance as a corrosion inhibitor is superior to that of high purity Nd chloride (analytical reagent). The results show that the use of electronic scrap is a sustainable source for the synthesis of green corrosion inhibitors with low carbon footprint.

Application of Electrochemical Techniques to Characterization of the Corrosion Behaviors of GW63 Alloys

2007 ◽  
Vol 546-549 ◽  
pp. 571-574
Author(s):  
Xing Wu Guo ◽  
Jian Wei Chang ◽  
Shang Ming He ◽  
Peng Huai Fu ◽  
Wen Jiang Ding
Keyword(s):  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Open Circuit ◽  
Cyclic Polarization ◽  
Time Curve ◽  
Completely Monotonic ◽  
Treatment Conditions ◽  
Impedance Variation ◽  
Corrosion Behaviors

The corrosion behavior of GW63 (Mg-6wt.%Gd-3wt.%Y-0.4wt.%Zr) alloys in 5% NaCl aqueous solution has been investigated by PARSTAT 2273 instrument. The Open Circuit Potential (ECORR) vs. time curve, cyclic polarization (Pitting Scans) curve and Electrochemical Impedance Spectroscopy (EIS) was measured for the GW63 alloys in as-cast and T6 heat treatment conditions. The EIS results indicated that the tendency of impedance variation for as-cast condition was monotonic decreasing, however, the tendency of variation for T6 condition was not completely monotonic but the total tendency was decreasing. The values of impedance of GW63 alloy at 0.1 Hz are about 103 ohm-cm2 for as-cast and T6 condition.

Phenylcoumarin Glucoside as a Natural Inhibitor in the Protection of Low Carbon Steel Against Corrosion

MRS Advances ◽  
2017 ◽  
Vol 2 (62) ◽  
pp. 3909-3915
Author(s):  
Héctor M. Barbosa Cásarez ◽  
Araceli Espinoza Vázquez ◽  
Francisco J. Rodríguez-Gomez
Keyword(s):  
Carbon Steel ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Low Carbon Steel ◽  
Steel Corrosion ◽  
Low Carbon ◽  
Low Concentrations ◽  
Natural Inhibitor ◽  
Polarization Studies

AbstractPhenylcoumarin glucoside (4-PC) is a compound extracted from the plant Hintona latiflora and was studied as inhibitor for AISI 1018 steel corrosion in 3% NaCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques, which may find application as eco-friendly corrosion inhibitors. The 4-PC provides inhibitor properties that protect AISI 1018 low carbon steel against corrosion at low concentrations (5 ppm) obtained by EIS. Polarization studies showed that the inhibitor was of mixed type. The inhibition efficiency by the two electrochemical techniques shows similar results. The inhibitor adsorption was demonstrated to be a combined process (physisorption and chemisorption) according to the Langmuir isotherm.

An Open-Circuit Method to Control the Hysteresis Parameters of Rare-Earth Permanent Magnets

2019 ◽  
Vol 90 (8) ◽  
pp. 576-578 ◽  
Author(s):  
V. A. Nesterin ◽  
V. S. Genin ◽  
N. A. Galanina ◽  
A. V. Nesterin
Keyword(s):  
Rare Earth ◽  
Permanent Magnets ◽  
Open Circuit

Comparative Study of the Corrosion Behavior of Low-Nickel AISI 202 and Conventional AISI 304 Stainless Steels in Citric Acid Using Electrochemical Techniques

2016 ◽  
Vol 835 ◽  
pp. 131-135 ◽  
Author(s):  
Francis Mulimbayan ◽  
Manolo G. Mena
Keyword(s):  
Stainless Steel ◽  
Citric Acid ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Corrosion Current ◽  
Open Circuit ◽  
Corrosion Mechanism ◽  
Protective Film ◽  
Aisi 304

Stainless steel (SS) is one of the most commonly used metallic food contact materials. It may be classified based on its microstructure whether ferritic, austenitic, martensitic, duplex or precipitation hardened. Austenitic SS, among mentioned grades, has the largest contribution to market due to its numerous industrial and domestic applications. In this study, the corrosion behavior of AISI 202 SS – a cheaper grade of stainless steel, in three different solution temperatures of citric acid was investigated using different electrochemical techniques such as open-circuit potential (OCP) measurements, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results were compared to that obtained from conventional AISI 304 SS. OCP, polarization and impedance measurements agreed that AISI 202 SS has comparable resistance to that of AISI 304 SS in citric acid at ambient temperature and at 50 °C. At 70 °C, results of OCP measurements suggest that AISI 304 SS exhibited greater performance as indicated by more positive OCP values in the designated solution. EIS results indicate that the two alloys have identical corrosion resistance even at 70 °C as indicated by their comparable polarization resistance (Rp). The corrosion mechanism in both alloys is charge-transfer controlled as indicated by depressed semi-circular appearance of the generated Nyquist plots. The values of corrosion current densities (icorr) extracted from polarization curves indicate that the initial corrosion rates were higher in AISI 304 than AISI 202 SS suggesting that formation of more protective film may have occurred on the former alloy.

Conducting polyaniline/multi-wall carbon nanotubes composite paints on low carbon steel for corrosion protection: electrochemical investigations

2013 ◽  
Vol 67 (8) ◽  
Author(s):  
Pravin Deshpande ◽  
Sanket Vathare ◽  
Shashikant Vagge ◽  
Elena Tomšík ◽  
Jaroslav Stejskal
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Steel ◽  
Corrosion Protection ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Open Circuit ◽  
Low Carbon ◽  
Multi Wall Carbon Nanotubes ◽  
Poly Aniline

AbstractThe coaxial coating of multi-wall carbon nanotubes (MWCNT) with poly(aniline) (PANI) was synthesised and a paint was prepared containing conducting PANI-MWCNT composite. The corrosion protection performance was assessed by open circuit potential measurements, potentiodynamic polarisation, and electrochemical impedance spectroscopy. The corrosion rate of low-carbon steel coated with 1.5 mass % of PANI-MWCNT-based paint in 3.5 mass % sodium chloride solution was found to be 0.037 mm y−1, about 5.2 times lower than that of unpainted low-carbon steel and 3.6 times lower than that of epoxy painted steel.

Electrochemical Investigation of the Effects of Acid Concentration and Dissolved Oxygen on the Corrosion Behavior of Austenitic Low-Nickel Stainless Steels in Citric Acid

2016 ◽  
Vol 835 ◽  
pp. 115-120
Author(s):  
Francis Mulimbayan ◽  
Manolo G. Mena
Keyword(s):  
Corrosion Resistance ◽  
Citric Acid ◽  
Dissolved Oxygen ◽  
Corrosion Behavior ◽  
Polarization Resistance ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Open Circuit ◽  
Human Consumption ◽  
Face Centered Cubic

All materials which are intended to have in contact with food and other commodities produced or processed for human consumption are called food contact materials (FCM’s). Stainless steel (SS) – a widely known metallic FCM is used mainly in processing equipment, containers and household utensils. It is known for having numerous industrial and domestic applications worldwide due to its special characteristics of having notable corrosion resistance. However, this corrosion resistance is not all-encompassing since SS may still undergo degradation when subjected to a specific corrosion-inducing environment. SS may be classified according to its microstructure. If the atoms which make up the SS can be viewed as having a face-centered cubic structure, then the alloy is said to be austenitic. This SS grades include the conventional 300-series and the newly-developed 200-series. The former has superior corrosion resistance while the latter is far cheaper. In this study, the corrosion behavior of AISI 202 SS in two different levels of dissolved oxygen (O2) and three acid concentrations was investigated using electrochemical techniques, namely, open-circuit potential (OCP) measurements and electrochemical impedance spectroscopy (EIS). As the concentration of citric acid is increased, the measured OCP values of the alloy decreased and the polarization resistance (Rp) decreased, indicating decrease in alloy stability and decline in the corrosion resistance, respectively. With regards to effects of dissolved O2, results revealed that increasing the level of dissolved O2 has consequently increased the polarization resistance and shifted the OCP to more positive values. All the generated Nyquist plots exhibited a depressed capacitive loops indicating that corrosion in the designated solution occurred with charge transfer as the rate-determining step.

Characterisation of Reinforced BTSE Films Deposited on Anodized Aluminium Substrate

2018 ◽  
Vol 69 (11) ◽  
pp. 2964-2968
Author(s):  
Ioana Alina Ciobotaru ◽  
Oana Claudia Ciobotea Barbu ◽  
Florin Mihai Benga ◽  
Danut Ionel Vaireanu
Keyword(s):  
Electrochemical Impedance ◽  
Corrosion Behaviour ◽  
Substrate Surface ◽  
Electrochemical Techniques ◽  
Surface Characteristics ◽  
Open Circuit ◽  
Point Of View ◽  
Aluminium Substrate ◽  
Anodised Aluminium ◽  
Deposited Films

This paper discusses the improvements achieved in the anticorrosive properties of some silane films by pretreating the metallic substrate prior to films deposition and by reinforcement with some reinforcement agents. One has compared the behaviour of silane films, deposited on aluminium substrate, and the reinforced silane films deposited on anodised aluminium substrate. The use of scanning electron microscopy highlighted the modifications of substrate surface characteristics prior and after the anodisation process, while electrochemical techniques such as open circuit potential, electrochemical impedance spectroscopy and potentiodynamic polarization were employed in order to characterize the deposited films from the corrosion behaviour point of view.

Comparison of Electrochemical Behavior of Cu-10Ni-10Zn Alloy and Cu in Aqueous Solutions

2015 ◽  
Vol 229 (3) ◽  
Author(s):  
Waheed A. Badawy ◽  
Mohamed M. El-Rabiei ◽  
Hashem M. Nady ◽  
Mohammed A. Samy
Keyword(s):  
Electrochemical Behavior ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Pure Copper ◽  
Open Circuit ◽  
Chloride Ions ◽  
Alloy Surface ◽  
Metallic Surface ◽  
Copper Dissolution ◽  
Basic Solutions

AbstractThe electrochemical behavior of Cu-10Ni-10Zn alloy and Cu was investigated in acidic, neutral and basic solutions. The effect of chloride ions in neutral solutions was also studied. Conventional electrochemical techniques and electrochemical impedance spectroscopy were used. The corrosion rate of these materials in acidic solutions is relatively high compared to that in neutral or basic solutions. The open-circuit potential of the alloy is nearly the same as that of pure copper in the different media, indicating that the processes which occur on the alloy surface are mainly governed by copper dissolution. In chloride solutions the rate of Cu corrosion is remarkably high. In the alloy, the copper dissolution was suppressed by the presence of nickel and zinc, due to the formation of complex oxide layers. The impedance data were fitted to equivalent circuit models that explain the different electrochemical processes occurring at the electrode/electrolyte interface. SEM and EDAX have shown that the alloy surface is enriched with Ni. In neutral solutions the chloride ions are penetrating the metallic surface.

Study of corrosion of copper in industrial cooling systems

2015 ◽  
Vol 6 (5) ◽  
pp. 617-635 ◽  
Author(s):  
Ioannis A Kartsonakis ◽  
Elias P. Koumoulos ◽  
Antonis Karantonis ◽  
Costas A. Charitidis ◽  
S Dessypris ◽  
...  
Keyword(s):  
Design Methodology ◽  
Corrosion Inhibitors ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Water Cooling ◽  
Optimum Structure ◽  
Copper Corrosion ◽  
Cooling Systems ◽  
Content Type ◽  
Industrial Systems

Purpose – The purpose of this paper is to perform the evaluation of copper susceptibility to corrosion in industrial cooling systems. Microstructure and defects of copper are observed, while divergences from optimum structure are discussed. Design/methodology/approach – Various types of corrosion are examined. Electrochemical techniques such as electrochemical impedance spectroscopy and potentiodynamic polarisation are applied in these materials, using corrosion inhibitors. Microscopic observations and electrochemical measurements are interpreted according to possible mechanistic scenarios. Findings – It is evident that, under specific conditions (e.g. high pH), water cooling ingredients can enhance corrosion, leading to significant copper mass loss from the inner surface of the pipe and thus leading to failure. Originality/value – Evaluation of copper corrosion in cooling industrial systems was done, as well as studies of copper corrosion in sodium chloride.

Evaluation of Ni0.5Zn0.5Fe2O4 nanoparticles as anti-corrosion pigment in organic coatings for carbon steel

2017 ◽  
Vol 64 (6) ◽  
pp. 644-653 ◽  
Author(s):  
A.U. Chaudhry ◽  
Vikas Mittal ◽  
M.I. Hashmi ◽  
Brajendra Mishra
Keyword(s):  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Open Circuit ◽  
Corrosion Layer ◽  
Organic Coatings ◽  
Metallic Oxide ◽  
Corrosion Properties ◽  
Content Type ◽  
Wide Range

Purpose Inorganic oxide addition can be synergistically beneficial in organic coatings if it can impart anti-corrosion properties and also act as an additive to enhance physical and/or chemical properties. The aim of this study was to evaluate the anti-corrosion benefits of nano nickel zinc ferrite (NZF) in the polymer film. Design/methodology/approach The time-dependent anti-corrosion ability of NZF (0.12-1.0 per cent w/w NZF/binder), applied on API 5L X-80 carbon steel, was characterized by electrochemical techniques such as open circuit potential, electrochemical impedance spectroscopy, linear polarization resistance and potentiodynamic. Characterization of corrosion layer was done by removing coatings after 216 h of immersion in 3.5 per cent w/v NaCl. Optical microscopy, field emission scanning electron microscopy and X-ray diffraction techniques were used to characterize the corroded surface. Findings Corrosion measurements confirm the electrochemical activity by metallic cations on the steel surface during corrosion process which results in improvement of anti-corrosion properties of steel. Moreover, surface techniques show compact corrosion layer coatings and presence of different metallic oxide phases for nanocomposite coatings. Originality/value The suggested protection mechanism was explained by the leaching and precipitation of metallic ion on the corroded surface which in turn slowed down the corrosion activity. Furthermore, improvement in barrier properties of rubber-based coatings was confirmed by the enhanced pore resistance. This work indicates that along with a wide range of applications of NZF, anti-corrosion properties can be taken as an addition.

Sign in / Sign up

Export Citation Format

Share Document