scholarly journals Coconut Shell Activated Carbon/CoFe2O4 Composite for the Removal of Rhodamine B from Aqueous Solution

2020 ◽  
Vol 2020 ◽  
pp. 1-12
Author(s):  
Le Phuong Hoang ◽  
Huu Tap Van ◽  
Thi Thuy Hang Nguyen ◽  
Van Quang Nguyen ◽  
Phan Quang Thang
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Rhodamine B ◽  
Adsorption Process ◽  
Coconut Shell ◽  
Molar Ratio ◽  
Maximum Adsorption Capacity ◽  
Electron Microscopic ◽  
X Ray ◽  
Coconut Shell Activated Carbon

Coconut shell activated carbon loaded with cobalt ferrite (CoFe2O4) composites (CAC/CoFe2O4) was synthesized via the single-step refluxing router method to manufacture adsorbents. The adsorbents were then applied to remove Rhodamine B (RhB) from aqueous environments via adsorption. The properties of coconut shell activated carbon (CAC) and CAC/CoFe2O4 were investigated through the usage of electron microscopic methods (SEM: Scanning Electron Microscopy, EDS: Energy Dispersive X-ray), powder X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). A series of batch experiments were implemented to evaluate the influences of various experimental parameters (initial pH, RhB concentration, contact time, and dosage of CAC/CoFe2O4) on the adsorption process. It was found that CoFe2O4 was successfully attached to activated carbon particles and had the suitable adsorption capacity for RhB at a molar ratio of 1 : 2:200 corresponding to the Co : Fe:CAC order. The removal efficiency and adsorption of RhB were optimal at a pH level of 4. The maximum adsorption capacity was 94.08 mg/g at an initial concentration of 350 mg/L and adsorbent dosage of 0.05 g/25 mL. Freundlich and Langmuir's models fitted well with the results obtained from the experimental data. The pseudo-second-order model also suited the most for RhB adsorption with the most remarkable correlation coefficient (R2 = 0.934). The adsorption process was controlled by a chemisorption mechanism through electrostatic attraction, hydrogen bonding interactions, and π-π interactions.

Equilibrium and Kinetic Studies of Benzene and Toluene Adsorption onto Microwave Irradiated-Coconut Shell Activated Carbon

2014 ◽  
Vol 1043 ◽  
pp. 219-223 ◽  
Author(s):  
Noor Shawal Nasri ◽  
Jibril Mohammed ◽  
Muhammad Abbas Ahmad Zaini ◽  
Usman Dadum Hamza ◽  
Husna Mohd. Zain ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Kinetic Studies ◽  
Coconut Shell ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Volatile Organic ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Coconut Shell Activated Carbon

Concern about environmental protection has increased over the years and the presence of volatile organic compounds (VOCs) in water poses a threat to the environment. In this study, coconut shell activated carbon (PHAC) was produced by potassium hydroxide activation via microwave for benzene and toluene removal. Equilibrium data were fitted to Langmuir, Freundlich and Tempkin isotherms with all the models having R2 > 0.94. The equilibrium data were best fitted by Langmuir isotherm, with maximum adsorption capacity of 212 and 238mg/g for benzene and toluene, respectively. The equilibrium parameter (RL) falls between 0 and 1 confirming the favourability of the Langmuir model. Pseudo-second-order kinetic model best fitted the kinetic data. The PHAC produced can be used to remediate water polluted by VOCs.

scholarly journals Phenol Removal from Aqueous Solution by Adsorption Technique Using Coconut Shell Activated Carbon

2021 ◽  
Vol 1 (2) ◽  
pp. 98-107
Author(s):  
Zhi Hoong Ho ◽  
Liyana Amalina Adnan
Keyword(s):  
Activated Carbon ◽  
Second Order ◽  
Coconut Shell ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Phenol Removal ◽  
Agriculture Waste ◽  
Before And After ◽  
Elovich Equation ◽  
Coconut Shell Activated Carbon

Adsorption is one of the simplest techniques with low economic requirements. Coconut shell is an abundant agriculture waste which is inexpensive and easy to be obtained in Malaysia. This agriculture waste was transformed to activated carbon via 600°C of carbonization and zinc chloride activation. The ability of coconut shell-based activated carbon to remove phenolic compounds from aqueous solutions was evaluated. From the experiment, the equilibrium time for the adsorption of phenol onto coconut shell-based activated carbon is 120 minutes. The effect of the operating parameters, such as contact time, initial concentration, agitation speed, adsorbent dosage, and pH of the phenolic solution were studied. Adsorption kinetics models (pseudo-first-order, pseudo-second-order, and Elovich equation) and isotherm models (Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich) were used to fit the experimental data.Pseudo-second-order was found to be the best fitted kinetics model to describe the adsorption of phenol on coconut shell-based activated carbon. While the equilibrium experiment data was well expressed by the Temkin isotherm model, The maximum adsorption capacity is determined as 19.02 mg/g, which is comparatively lower than the previous research. Meanwhile, 92% of removal efficiency was achieved by a dosage of 10g/L. Meanwhile, the adsorption of phenol by activated carbon was more favorable under acidic conditions. The favourable isotherm behavior was indicated by the dimensionless separation factor. The functional group and compound class of activated carbon before and after the experiment were determined through the analysis of Fourier-transform infrared (FTIR) spectroscopy.

A novel iron modified montmorillonite composite and its enhanced performance for tetracycline hydrochloride adsorption

2019 ◽  
Vol 12 (02) ◽  
pp. 1950014 ◽  
Author(s):  
Wei Yang ◽  
Sheng Guo ◽  
Jinyi Chen ◽  
Abdul Naeem ◽  
Hussain Fida ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Adsorption Capacity ◽  
Photoelectron Spectroscopy ◽  
Adsorption Process ◽  
Interlayer Spacing ◽  
Tetracycline Hydrochloride ◽  
Maximum Adsorption Capacity ◽  
X Ray ◽  
Modified Montmorillonite ◽  
Wide Ph Range

Iron-modified montmorillonite (Mt) composites with controlled interlayer spacing were successfully synthesized through Fenton-like process with the addition of different concentrations of Rhodamine B (RhB). The physicochemical properties of the resulting samples were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). It was worth noting that the adsorption efficiency of the composite for tetracycline hydrochloride (TC) increased with the increase of the RhB concentration during preparation. The maximum adsorption capacity of the as-prepared composite toward TC was 192.4[Formula: see text]mg/g, which was much higher than that of the Mt (144.9[Formula: see text]mg/g). Moreover, the as-prepared adsorbent showed high adsorption capacity of TC in a wide pH range of 3.0–9.0. The adsorption process followed the pseudo-second-order equation and the Langmuir isotherm model, suggesting the mono-layer chemisorption of the adsorption process. The present work may provide a new strategy for the design and fabrication of functional clay-based materials.

Adsorption of Chloride Anion from Aqueous Solution by Calcined (Mg-Al) Hydrotalcites of Different Mg/Al Ratio

2011 ◽  
Vol 233-235 ◽  
pp. 420-426 ◽  
Author(s):  
Dong Jin Wan ◽  
Dan Qu ◽  
Hua Xiao ◽  
Yong De Liu ◽  
Ting Lu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Chloride Ion ◽  
Interlayer Spacing ◽  
Precipitation Method ◽  
Molar Ratio ◽  
Maximum Adsorption Capacity ◽  
Batch Mode ◽  
X Ray ◽  
Electric Charge Density

Hydrotalcites (HT-X) of different Mg/Al ratio (X is Mg/Al molar ratio, 3 and 4) was synthesized by co-precipitation method. Calcined HTLCs (CHT-X) at 500°C have been shown to recover their original layered structure by taking up chloride ion from aqueous solution. Adsorption of chloride by CHT-X was investigated in batch mode. The kinetics study showed that the pseudo-second-order kinetics model could be used to describe the adsorption process satisfactorily. The equilibrium isotherm showed that the Langmuir model gave a better fit to the experimental data than the Freundlich model. The maximum adsorption capacity of CHT-3 was 83.33 mg/g; CHT-4 was 90.09 mg/g .The samples of different Mg/Al ratio have different crystallite size, thus showing different adsorption capacity. As the Mg/Al ratio increases from 3 to 4; the electric charge density between the layers becomes weaker; the interlayer spacing increases; the sample shows greater adsorption capacity. The HT-X where characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), electron dispersive X-ray analysis (EDX).

scholarly journals Adsorption of Crystal Violet Dye Using Activated Carbon of Lemon Wood and Activated Carbon/Fe3O4 Magnetic Nanocomposite from Aqueous Solutions: A Kinetic, Equilibrium and Thermodynamic Study

Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2241
Author(s):  
Rauf Foroutan ◽  
Seyed Jamaleddin Peighambardoust ◽  
Seyed Hadi Peighambardoust ◽  
Mirian Pateiro ◽  
Jose M. Lorenzo
Keyword(s):  
Activated Carbon ◽  
Aqueous Solutions ◽  
Adsorption Capacity ◽  
Crystal Violet ◽  
Fe3o4 Nanoparticles ◽  
Adsorption Process ◽  
Dye Adsorption ◽  
Magnetic Nanocomposite ◽  
Maximum Adsorption Capacity ◽  
Adsorption Enthalpy

Activated carbon prepared from lemon (Citrus limon) wood (ACL) and ACL/Fe3O4 magnetic nanocomposite were effectively used to remove the cationic dye of crystal violet (CV) from aqueous solutions. The results showed that Fe3O4 nanoparticles were successfully placed in the structure of ACL and the produced nanocomposites showed superior magnetic properties. It was found that pH was the most effective parameter in the CV dye adsorption and pH of 9 gave the maximum adsorption efficiency of 93.5% and 98.3% for ACL and ACL/Fe3O4, respectively. The Dubinin–Radushkevich (D-R) and Langmuir models were selected to investigate the CV dye adsorption equilibrium behavior for ACL and ACL/Fe3O4, respectively. A maximum adsorption capacity of 23.6 and 35.3 mg/g was obtained for ACL and ACL/Fe3O4, respectively indicating superior adsorption capacity of Fe3O4 nanoparticles. The kinetic data of the adsorption process followed the pseudo-second order (PSO) kinetic model, indicating that chemical mechanisms may have an effect on the CV dye adsorption. The negative values obtained for Gibb’s free energy parameter (−20 < ΔG < 0 kJ/mol) showed that the adsorption process using both types of the adsorbents was physical. Moreover, the CV dye adsorption enthalpy (ΔH) values of −45.4 for ACL and −56.9 kJ/mol for ACL/Fe3O4 were obtained indicating that the adsorption process was exothermic. Overall, ACL and ACL/Fe3O4 magnetic nanocomposites provide a novel and effective type of adsorbents to remove CV dye from the aqueous solutions.

scholarly journals Langmuir and Freundlich isotherm equation test on the adsorption process of Cu (II) metal ions by cassava peel waste (Manihot esculenta crantz)

2021 ◽  
Vol 2126 (1) ◽  
pp. 012022
Author(s):  
S Nuryanti ◽  
Suherman ◽  
S Rahmawati ◽  
M Amalia ◽  
T Santoso ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
Manihot Esculenta ◽  
Contact Time ◽  
Adsorption Process ◽  
Freundlich Isotherm ◽  
Maximum Adsorption Capacity ◽  
Manihot Esculenta Crantz ◽  
Isotherm Equations ◽  
Cassava Peel

Abstract This Study aims to determine the adsorption process of Cu (II) metal by cassava peel waste (Manihot esculenta crantz) meeting the Langmuir equation and Freundlich. Research method cassava peel made into activated carbon, then determine the mass, pH and optimum contact time. Then the determination of the maximum adsorption capacity was carried out by testing with the Langmuir isotherm and Freundlich isotherm equations. The results showed that the best conditions (optimal conditions) were obtained with the addition of 0.5 grams of active carbs from cassava peels. The percentage of Cu ion adsorption in these conditions was 97.72%, at pH 6 and a contact time of 60 minutes and the absorption capacity was 98.49%. The maximum adsorption capacity of cassava peel activated carbon to Cu(II) ions at the optimum condition was determined based on the Langmuir and Freundlich isotherm equations. The results obtained were-51.813 mg/g and 26,792 mg/g, respectively.

scholarly journals Adsorption of an anionic dye on a novel low-cost mesoporous adsorbent: kinetic, thermodynamic and isotherm studies

2018 ◽  
Vol 37 ◽  
pp. 02002
Author(s):  
Asmaa Msaad ◽  
Mounir Belbahloul ◽  
Abdeljalil Zouhri
Keyword(s):  
Activated Carbon ◽  
Adsorption Capacity ◽  
High Surface ◽  
High Surface Area ◽  
Second Order ◽  
Maximum Adsorption Capacity ◽  
Activated Carbon Adsorption ◽  
Freundlich Model ◽  
X Ray ◽  
Bet Analysis

Our activated carbon was prepared successfully using phosphoric acid as an activated agent. The activated carbon was characterized by Scanning Electron Micrograph (SEM), Brunauer-Emmett- Teller (BET), Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). The aim of our study is to evaluate the adsorption capacity of Methyl Orange (MO) on Ziziphus lotus activated carbon. Adsorption isotherms were studied according to Langmuir and Freundlich Model, and adsorption kinetics according to pseudo-first and second-order. Results show that the maximum adsorption was reached in the first 10min at ambient temperature with a yield of 96.31%. The Langmuir isotherm shows a correlation coefficient of 99.4 % higher than Freundlich model and the adsorption kinetic model follow a pseudo-second-order with a maximum adsorption capacity of 769.23 mg/g. FTIR and X-Ray spectroscopy indicate that our activated carbon has an amorphous structure with the presence of functional groups, where BET analysis revealed a high surface area of 553 mg/g, which facilitate the adsorption process

scholarly journals Adsorption performance of basic fuchsin on alkali-activated diatomite

2020 ◽  
Vol 38 (5-6) ◽  
pp. 151-167 ◽  
Author(s):  
Yong-Hua Zhao ◽  
Jin-Tao Geng ◽  
Jie-Chuan Cai ◽  
Yu-Fu Cai ◽  
Chun-Yan Cao
Keyword(s):  
Adsorption Capacity ◽  
Adsorption Process ◽  
Textural Properties ◽  
Alkali Activation ◽  
Maximum Adsorption Capacity ◽  
Basic Fuchsin ◽  
Activation Temperature ◽  
X Ray ◽  
Adsorption Performance ◽  
Alkali Activated

The natural diatomite was treated with NaOH to obtain alkali-activated diatomite. The materials were systematically characterized by X-ray powder diffraction, X-ray fluorescence, Fourier transform infrared spectroscopic, scanning electron microscopy, and N2 adsorption–desorption. Meanwhile, the potential use of alkali-activated diatomite as adsorbent for the removal of basic fuchsin from aqueous solution was assessed by batch experiment. Results indicated that the structure and textural properties of diatomite were obviously changed via alkali activation, and then affecting its adsorption performance. The adsorption capacity of alkali-activated diatomite for basic fuchsin was higher than that of natural diatomite. In the case of alkali-activated diatomite, its adsorption capacity was increased with increasing the activation temperature, and the diatomite activated at 115°C (alkali-activated diatomite-115) exhibited the maximum adsorption capacity. The pseudo-first-order kinetics and the Sips isotherm model were preferable to describe the adsorption process of basic fuchsin on alkali-activated diatomite-115 and the thermodynamic parameters indicated that the adsorption process was endothermic and spontaneous.

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