scholarly journals Experimental Dielectric Measurements for Cost-fewer Polyvinyl Chloride Nanocomposites

Author(s):  
Ahmed Thabet ◽  
Youssef Mobarak

<span>Polymer nanocomposites possess promising high performances as engineering materials, if they are prepared and fabricated properly. In this research, it has been processed samples of nanocomposite polymers as electrical insulating materials for application on the electric power cables by using the latest techniques of nanotechnology. This paper has been investigated enhanced dielectric and electrical properties of Polyvinyl chloride PVC as matrix have shown that trapping properties are highly modified by the presence of costless nanofillers clay and fumed silica. An experimental work for dielectric loss and capacitance of the new nanocomposite materials have been investigated and compared with unfilled industrial materials. It is found that a good correlation exists in respect of capacitance and dielectric loss values measured with percentage of nanofillers. Thus, it has been investigated the influence of costless nanofillers material and its concentration on dielectric properties of industrial polymers-based composite systems. A comparative study is performed between the unfilled base polymers, the systems containing one type of nanoparticles clay<em><span> </span></em>or fumed silica inside the host polymer with various concentrations.</span>

2019 ◽  
Vol 9 (4) ◽  
pp. 4315-4321 ◽  
Author(s):  
M. Danikas ◽  
D. Verginadis ◽  
R. Sarathi

A new class of insulating materials is the class of polymer nanocomposites. In the past twenty-five years, a lot of attention was paid to the various electrical, thermal and mechanical properties of polymer nanocomposite materials. In the present work, epoxy resin samples without and with nanoparticles (0 wt%, 1 wt%, 3 wt%, 5 wt%, and 10 wt%) are investigated regarding the surface discharges and the flashover voltages. Four different water droplet arrangements were used, with eight different water conductivities in order to see the effect of the nanoparticle.


Nanomaterials ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 10
Author(s):  
Jawad Sarfraz ◽  
Tina Gulin-Sarfraz ◽  
Julie Nilsen-Nygaard ◽  
Marit Kvalvåg Pettersen

There is a strong drive in industry for packaging solutions that contribute to sustainable development by targeting a circular economy, which pivots around the recyclability of the packaging materials. The aim is to reduce traditional plastic consumption and achieve high recycling efficiency while maintaining the desired barrier and mechanical properties. In this domain, packaging materials in the form of polymer nanocomposites (PNCs) can offer the desired functionalities and can be a potential replacement for complex multilayered polymer structures. There has been an increasing interest in nanocomposites for food packaging applications, with a five-fold rise in the number of published articles during the period 2010–2019. The barrier, mechanical, and thermal properties of the polymers can be significantly improved by incorporating low concentrations of nanofillers. Furthermore, antimicrobial and antioxidant properties can be introduced, which are very relevant for food packaging applications. In this review, we will present an overview of the nanocomposite materials for food packaging applications. We will briefly discuss different nanofillers, methods to incorporate them in the polymer matrix, and surface treatments, with a special focus on the barrier, antimicrobial, and antioxidant properties. On the practical side migration issues, consumer acceptability, recyclability, and toxicity aspects will also be discussed.


Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 721 ◽  
Author(s):  
Jorge A. Ramírez-Gómez ◽  
Javier Illescas ◽  
María del Carmen Díaz-Nava ◽  
Claudia Muro-Urista ◽  
Sonia Martínez-Gallegos ◽  
...  

Atrazine (ATZ) is an herbicide which is applied to the soil, and its mechanism of action involves the inhibition of photosynthesis. One of its main functions is to control the appearance of weeds in crops, primarily in corn, sorghum, sugar cane, and wheat; however, it is very toxic for numerous species, including humans. Therefore, this work deals with the adsorption of ATZ from aqueous solutions using nanocomposite materials, synthesized with two different types of organo-modified clays. Those were obtained by the free radical polymerization of 4-vinylpyridine (4VP) and acrylamide (AAm) in different stoichiometric ratios, using tetrabutylphosphonium persulfate (TBPPS) as a radical initiator and N,N′-methylenebisacrylamide (BIS) as cross-linking agent. The structural, morphological, and textural characteristics of clays, copolymers, and nanocomposites were determined through different analytical and instrumental techniques, i.e., X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). Adsorption kinetics experiments of ATZ were determined with the modified and synthesized materials, and the effect of the ratio between 4VP and AAm moieties on the removal capacities of the obtained nanocomposites was evaluated. Finally, from these sets of experiments, it was demonstrated that the synthesized nanocomposites with higher molar fractions of 4VP obtained the highest removal percentages of ATZ.


2021 ◽  
Vol 13 ◽  
Author(s):  
S. K. Parida

: This presented review article is constructed to be an extensive source for polymer nanocomposite researchers covering the relation of structure with property, manufacturing techniques, and potential applications when a small number of nanosized particles are added to a host polymer matrix. The exceptional structural, mechanical, and electrical properties of polymer nanocomposites after the addition of inorganic solid nanoparticles are elucidated by the large surface area of doped nanoparticles that interact with host polymer matrices. Due to the generation of ideas, the conventional methods of preparation of polymer nanocomposites are made more interesting. Hence, this brief review presents a sketch of different synthesis techniques, characterization, applications, and safety concerns for polymer nanocomposites.


2019 ◽  
Vol 201 (1) ◽  
pp. 218-223
Author(s):  
M. A. Ramazanov ◽  
H. A. Shirinova ◽  
F. V. Hajiyeva ◽  
A. Kh. Karimova

In the present study, the influence of the temperature–time mode of crystallization (TTC) on the electrophysical properties of polymer-based PP + Fe3O4 nanocomposite materials was investigated. Also, the effect of the temperature-time mode of crystallization of nanocomposites on the negative magnetoresistance (NMR) effect that observed in this material was investigated. It was found that dielectric permittivity of polymer nanocomposites rises with increasing of cooling rate. The cooling rate of nanocomposites after hot-pressing also affects the NMR effect of these materials. The conductivity of the material under the influence of magnetic field improves with increasing of its cooling rate, which leads to increasing of NMR effect.


RSC Advances ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 7065-7072
Author(s):  
Jianxin Zhang ◽  
Jiachen Ma ◽  
Luqing Zhang ◽  
Chuanyong Zong ◽  
Anhou Xu ◽  
...  

Preparation of high-performance dielectric composite films using PDFMA@BT hybrid nanoparticles as fillers.


Author(s):  
Pradip Majumdar ◽  
Amartya Chakrabarti

Polymer nanocomposites are unique materials reinforced with nanoscale additives. Among a variety of nanomaterials available to act as filler additives in different polymer matrices, graphene is the most versatile one. Graphene-based polymer nanocomposites have improved electrical, mechanical, chemical, and thermal properties, which make them suitable for applications in the electronics, energy, sensor, and space sectors. Graphene, the nanosized filler, can be prepared using either a top-down or a bottom-up approach and dispersed in the polymer matrix utilizing different conventional techniques. The nanocomposite materials find usage in suitable area of applications depending on their specific characteristics. This chapter discusses the current state-of-the-art manufacturing techniques for graphene and graphene-based nanocomposite materials. Application of graphene-based polymer nanocomposites in the various fields with an emphasis on the areas high heat flux applications requiring enhanced thermal conductivity will be an additional major focus of this chapter.


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