Rheology of Polyaniline-Dinonylnaphthalene Disulfonic Acid (DNNDSA) Montmorillonite Clay Nanocomposites in the Sol State: Shear Thinning versus Pseudo-Solid Behavior

2008 ◽  
Vol 8 (4) ◽  
pp. 1842-1851 ◽  
Author(s):  
Ashesh Garai ◽  
Arun K. Nandi
Keyword(s):  
Shear Rate ◽  
Storage Modulus ◽  
Power Law ◽  
Network Formation ◽  
Loss Modulus ◽  
Shear Thinning ◽  
Disulfonic Acid ◽  
Clay Nanocomposites ◽  
Crossover Point ◽  
Clay Concentration

The melt rheology of polyaniline (PANI)-dinonylnaphthalenedisulfonic acid (DNNDSA) gel nanocomposites (GNCs) with organically modified (modified with cetyl trimethylammonium bromide)-montmorillonite (om-MMT) clay has been studied for three different clay concentrations at the temperature range 120–160 °C. Field emission scanning electron microscopy (FE-SEM), wide angle X-ray scattering (WAXS), differential scanning calorimetry (DSC) and dc-conductivity data (∼10–3 S/cm) indicate that the PANI-DNNDSA melt is in sol state and it is not de-doped at that condition. The WAXS data indicate that in GNC-1 sol clay tactoids are in exfoliated state but in the other sols they are in intercalated state. The zero shear viscosity (η0), storage modulus (G′) and loss modulus (G″) increase than that of pure gel in the GNCs. The pure sol and the sols of gel nanocomposites (GNCs) exhibit Newtonian behavior for low shear rate (<6 × 10–3 s–1) and power law variation for the higher shear rate region. The characteristic time (λ) increase with increasing clay concentration and the power law index (n) decreases with increase in clay concentration in the GNCs indicating increased shear thinning for the clay addition. Thus the sols of om-clay nanocomposites of PANI-DNNDSA system are easily processible. The storage modulus (G′) of GNC sols are higher than that of pure PANI-DNNDSA sol, GNC1 sol shows a maximum of 733% increase in storage modulus and the percent increase decreases with increase in temperature. Exfoliated nature of clay tactoids has been attributed for the above dramatic increase of G′. The PANI-DNNDSA sol nanocomposites behave as a pseudo-solid at higher frequency where G′ and loss modulus (G′′) show a crossover point in the frequency sweep experiment at a fixed temperature. The crossover frequency decreases with increase in clay concentration and it increases with increase in temperature for GNC sols. The pseudo-solid behavior has been explained from jamming or network formation of clay tactoids under shear. A probable explanation of the two apparently contradictory phenomena of shear thinning versus pseudo-solid behavior of the nanocomposite sols is discussed.

Correlation of Polysiloxane Molecular Structure to Shear-Thinning Power-Law Exponent Using Elastohydrodynamic Film Thickness Measurements

2015 ◽  
Vol 137 (3) ◽  
Author(s):  
Thomas J. Zolper ◽  
Paul Shiller ◽  
Manfred Jungk ◽  
Tobin J. Marks ◽  
Yip-Wah Chung ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Shear Rate ◽  
Film Thickness ◽  
Power Law ◽  
Shear Thinning ◽  
Macromolecular Structure ◽  
Polymeric Fluid ◽  
Power Law Exponent ◽  
Elastohydrodynamic Film Thickness ◽  
Thickness Measurements

Siloxane-based polymers (polysiloxanes) are susceptible to temporary shear-thinning that manifests as a reduction of elastohydrodynamic film thickness with increasing entrainment speed or effective shear rate. The departure from Newtonian film thickness can be predicted with the power-law exponent ns, an indicator of the severity of shear-thinning in a polymeric fluid that is influenced by the macromolecular structure. In this paper, a combination of extant rheological and tribological models is applied to determine the power-law exponent of several polysiloxanes using film thickness measurements. Film thickness data at several temperatures and slide-to-roll ratios are used to validate the methodology for several siloxane-based polymers with alkyl and aryl branches.

Laminar Forced Convection in Viscous Shear-Thinning Liquid Flows Inside Circular Pipes: Case for a Modified Power-Law Rheology

2020 ◽  
Vol 142 (12) ◽  
Author(s):  
J. Subedi ◽  
S. Rajendran ◽  
R. M. Manglik
Keyword(s):  
Heat Transfer ◽  
Shear Rate ◽  
Convective Heat Transfer ◽  
Power Law ◽  
Shear Thinning ◽  
Frictional Loss ◽  
Viscous Shear ◽  
Laminar Forced Convection ◽  
Rheology Model ◽  
Low Shear

Abstract Laminar forced convection in viscous, non-Newtonian polymeric liquids that exhibit pseudoplastic or shear-thinning behavior is characterized. The fluid rheology is characterized by a new asymptotic power-law (APL) model, which appropriately represents extensive data for apparent viscosity variation with shear rate—from the low-shear constant-viscosity plateau to shear thinning at high shear rates. This is contrasted with the traditional Ostwald-de-Waele or power-law (PL) model that invariably over-extends the pseudoplasticity in the very low shear-rate region. The latter's limitations are demonstrated by computationally obtaining frictional loss and convective heat transfer results for fully developed laminar flows in a circular pipe maintained at uniform heat flux. The Fanning friction factor and Nusselt number, as would be anticipated from the rheology map of pseudoplastic fluids, are functions of flow rate with the APL model unlike the Newtonian-like constant value obtained with the PL model. Comparisons of the two sets of results highlight the extent of errors inherent in the PL rheology model, which range from 23% to 68% for frictional loss and 3.8% to 13.7% for heat transfer. The new APL rheology model is thus shown to be the more precise characterization of viscous shear-thinning fluids for their thermal processing applications with convective heat transfer.

A Rational Friction Factor Correlation for Laminar Fully-Developed Pipe Flows of Shear-Thinning Non-Newtonian Fluids

2021 ◽  
Author(s):  
Robert Brewster
Keyword(s):  
Shear Rate ◽  
Friction Factor ◽  
Power Law ◽  
Fluid Model ◽  
Shear Thinning ◽  
Newtonian Fluids ◽  
Cross Model ◽  
Pipe Flows ◽  
Design Calculations ◽  
Friction Factor Correlation

Abstract A friction factor correlation for laminar, hydrodynamically fully-developed pipe flows of shear-thinning non-Newtonian fluids is derived through analysis and asymptotic considerations. The specific non-Newtonian fluid model used is the Extended Modified Power Law (EMPL) model, which is functionally equivalent to the Cross model. The EMPL model spans the entire shear rate range from the low to the high shear rate Newtonian regions, and includes the intermediate shear rate power law region. The friction factor correlation has an explicit form and is a function of three dimensionless parameters, making it well-suited to design calculations. The overall accuracy of the correlation is 6.6%, though it is much better in most cases. Graphical results for the correlation, and deviations with respect to high-accuracy numerical calculations are presented and discussed.

scholarly journals A semi-infinite hydraulic fracture driven by a shear-thinning fluid

2018 ◽  
Vol 838 ◽  
pp. 573-605 ◽  
Author(s):  
Fatima-Ezzahra Moukhtari ◽  
Brice Lecampion
Keyword(s):  
Shear Rate ◽  
Power Law ◽  
Hydraulic Fracture ◽  
Complex Structure ◽  
Shear Thinning ◽  
High Shear Rate ◽  
Asymptotic Region ◽  
High Shear ◽  
Confining Stress ◽  
Low Shear

We use the Carreau rheological model which properly accounts for the shear-thinning behaviour between the low and high shear rate Newtonian limits to investigate the problem of a semi-infinite hydraulic fracture propagating at a constant velocity in an impermeable linearly elastic material. We show that the solution depends on four dimensionless parameters: a dimensionless toughness (function of the fracture velocity, confining stress, material and fluid parameters), a dimensionless transition shear stress (related to both fluid and material behaviour), the fluid shear-thinning index and the ratio between the high and low shear rate viscosities. We solve the complete problem numerically combining a Gauss–Chebyshev method for the discretization of the elasticity equation, the quasi-static fracture propagation condition and a finite difference scheme for the width-averaged lubrication flow. The solution exhibits a complex structure with up to four distinct asymptotic regions as one moves away from the fracture tip: a region governed by the classical linear elastic fracture mechanics behaviour near the tip, a high shear rate viscosity asymptotic and power-law asymptotic region in the intermediate field and a low shear rate viscosity asymptotic far away from the fracture tip. The occurrence and order of magnitude of the extent of these different viscous asymptotic regions are estimated analytically. Our results also quantify how shear thinning drastically reduces the size of the fluid lag compared to a Newtonian fluid. We also investigate simpler rheological models (power law, Ellis) and establish the small domain where they can properly reproduce the response obtained with the complete rheology.

scholarly journals Tuning Rheological Performance of Silica Concentrated Shear Thickening Fluid by Using Graphene Oxide

2015 ◽  
Vol 2015 ◽  
pp. 1-5 ◽  
Author(s):  
Wenchao Huang ◽  
Yanzhe Wu ◽  
Ling Qiu ◽  
Cunku Dong ◽  
Jie Ding ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Shear Rate ◽  
Storage Modulus ◽  
Colloidal Silica ◽  
Loss Modulus ◽  
Shear Thickening ◽  
Light Weight ◽  
Critical Shear Rate ◽  
Shear Thickening Fluid ◽  
Significant Change

The addition of a small amount of graphene oxide into a traditional colloidal silica-based shear thickening fluid (STF) can lead to a significant change in viscosity, critical shear rate, storage modulus, and loss modulus of STF. This finding provides an effective way to prepare stronger and light-weight STFs.

Influence of κ-Carrageenan, Modified Starch and Inulin Addition on Rheological and Sensory Properties of Non-fat and Non-added Sugar Dairy Dessert

2020 ◽  
Vol 16 (4) ◽  
pp. 462-469
Author(s):  
Zhaleh Sheidaei ◽  
Bahareh Sarmadi ◽  
Seyede M. Hosseini ◽  
Fardin Javanmardi ◽  
Kianoush Khosravi-Darani ◽  
...  
Keyword(s):  
Storage Modulus ◽  
Loss Modulus ◽  
Viscoelastic Behavior ◽  
Textural Properties ◽  
Complex Viscosity ◽  
Sensory Properties ◽  
Modified Starch ◽  
Consumer Health ◽  
Added Sugar ◽  
Textural Parameters

<P>Background: The high amounts of fat, sugar and calorie existing in dairy desserts can lead to increase the risk of health problems. Therefore, the development of functional and dietary forms of these products can help the consumer health. </P><P> Objective: This study aims to investigate the effects of &#954;-carrageenan, modified starch and inulin addition on rheological and sensory properties of non-fat and non-added sugar dairy dessert. </P><P> Methods: In order to determine the viscoelastic behavior of samples, oscillatory test was carried out and the values of storage modulus (G′), loss modulus (G″), loss angle tangent (tan &#948;) and complex viscosity (&#951;*) were measured. TPA test was used for analysis of the desserts’ texture and textural parameters of samples containing different concentrations of carrageenan, starch and inulin were calculated. </P><P> Results: All treatments showed a viscoelastic gel structure with the storage modulus higher than the loss modulus values. Increasing amounts of &#954;-carrageenan and modified starch caused an increase in G′ and G″ as well as &#951;* and a decrease in tan &#948;. Also, firmness and cohesiveness were enhanced. The trained panelists gave the highest score to the treatment with 0.1% &#954;-carrageenan, 2.5% starch and 5.5% inulin (sucralose as constant = 0.25%) and this sample was the best treatment with desirable attributes for the production of non-fat and non-added sugar dairy dessert. </P><P> Conclusion: It can be concluded that the concentration of &#954;-carrageenan and starch strongly influenced the rheological and textural properties of dairy desserts, whereas the inulin content had little effect on these attributes.</P>

Electrical conductivity and rheological properties of carbon black based conductive polymer composites prior to and after annealing

2021 ◽  
pp. 096739112110012
Author(s):  
Qingsen Gao ◽  
Jingguang Liu ◽  
Xianhu Liu
Keyword(s):  
Electrical Conductivity ◽  
Carbon Black ◽  
Percolation Threshold ◽  
Rheological Properties ◽  
Network Formation ◽  
Loss Modulus ◽  
Conductive Polymer ◽  
Complex Viscosity ◽  
Electrical Percolation ◽  
Electrical Percolation Threshold

The effect of annealing on the electrical and rheological properties of polymer (poly (methyl methacrylate) (PMMA) and polystyrene (PS)) composites filled with carbon black (CB) was investigated. For a composite with CB content near the electrical percolation threshold, the formation of conductive pathways during annealing has a significant impact on electrical conductivity, complex viscosity, storage modulus and loss modulus. For the annealed samples, a reduction in the electrical and rheological percolation threshold was observed. Moreover, a simple model is proposed to explain these behaviors. This finding emphasizes the differences in network formation with respect to electrical or rheological properties as both properties belong to different physical origins.

scholarly journals Rheological and Textural Properties of Apple Pectin-Based Composite Formula with Xanthan Gum Modification for Preparation of Thickened Matrices with Dysphagia-Friendly Potential

Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 873
Author(s):  
Huaiwen Yang ◽  
Chai-Chun Tsai ◽  
Jung-Shiun Jiang ◽  
Chi-Chung Hua
Keyword(s):  
Storage Modulus ◽  
Water Consumption ◽  
Xanthan Gum ◽  
Loss Modulus ◽  
Textural Properties ◽  
Apple Pectin ◽  
Composite Matrix ◽  
Low Concentrations ◽  
Composite Formula

Modifying the consistency of a given edible fluid matrix by incorporating food thickeners is a common nursing remedy for individuals with dysphagia when adequate water consumption is a concern. As apple pectin (AP) offers nutraceutical benefits, properly formulated apple pectin (AP)-based thickeners featuring xanthan gum (XG) can be superior candidates for preparation of dysphagia-friendly matrices (DFMs). Our recruited DFMs exhibit fluid-like behavior (loss modulus > storage modulus, G” > G’) at lower AP concentrations (2 and 5%, w/w); they turn into weak/critical gels (G’ ≈ G”) as the concentration becomes higher (9%). In contrast, XG-DFMs display gel-like attributes with G’ > G”, even at rather low concentrations (<1%) and become more resistant to sugar, Na+, and Ca2+ modifications. The composite matrix of AP1.8XG0.2 (constraint at 2%) exhibits a confined viscosity of 278 ± 11.7 mPa∙s, which is considered a DFM, in comparison to only AP- or XG-thickened ones. The hardness measurements of XG0.6 and AP1.2XG0.8 are 288.33 ± 7.506 and 302.00 ± 9.849 N/m2, respectively, which potentially represent a promising formulation base for future applications with DFMs; these textural values are not significantly different from a commercially available product (p > 0.05) for dysphagia nursing administrations.

scholarly journals Certain Rheological Aspects of Functionalized Guar Gum

2013 ◽  
Vol 2013 ◽  
pp. 1-15 ◽  
Author(s):  
Meenu Kapoor ◽  
Dhriti Khandal ◽  
Ruchi Gupta ◽  
Pinklesh Arora ◽  
Geetha Seshadri ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Shear Rate ◽  
Guar Gum ◽  
Loss Modulus ◽  
Industrial Applications ◽  
Green Technology ◽  
Low Molecular Weight ◽  
Radiation Processing ◽  
Industrial Sectors ◽  
Wide Acceptance

Guar gum and its derivatives are highly important industrial hydrocolloids as they find applications in various industrial sectors. Guar is a polymer of high molecular weight and its aqueous solutions exhibit unique rheological properties, which has led to its wide acceptance by the industry. In certain industrial applications low molecular weight guar and its derivatives are needed, and conventionally chemical depolymerisation of guar is carried out for this purpose. Radiation processing is a novel and green technology for carrying out depolymerization and can be an ideal substitute for chemical depolymerisation technique. In order to study the effect of radiation on guar derivatives, three types of derivatives have been taken in the present study: carboxymethyl, hydroxyethyl, and methyl guar. The effect of 1–50 KGy radiation dose on the rheological behavior of these derivatives has been studied, and the results have been described in the present paper. The effect on storage and loss modulus with respect to frequency and effect on viscosity with respect to shear rate have been discussed in detail.

Investigation on the Rheological Behavior of Polyamide6/Montmorillonite Nanocomposites by Reactive Extrusion

2011 ◽  
Vol 233-235 ◽  
pp. 1998-2001 ◽  
Author(s):  
Ming Zhao ◽  
Xiao Zhong Lu ◽  
Kai Gu ◽  
Xiao Min Sun ◽  
Chang Qing Ji
Keyword(s):  
Activation Energy ◽  
Shear Stress ◽  
Shear Rate ◽  
Rheological Behavior ◽  
Reactive Extrusion ◽  
Shear Thinning ◽  
Experimental Results ◽  
Montmorillonite Nanocomposites

The rheological behavior of PA6/montmorillonite(MMT) by reactive extrusion was investigated using cone-and-plate rheometer. The experimental results indicated that PA6/MMT exhibited shear-thinning behavior. The shear stress of both neat PA6 and PA6/MMT increased with the increase in the shear rate. The reduction of the viscous activation energy with the increase of shear stress reflected PA6/MMT can be processed over a wider temperature.

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