Synergistic effects of iron and hexagonal-Boron Nitride additions in copper-based composites for braking application

Author(s):  
S Govindarajan ◽  
K Syamkumar ◽  
Ninad Lamture ◽  
Shirish S Kale ◽  
T Ram Prabhu

This paper explores the addition of h-BN and iron to Cu-based brake pads on the performance benefits. It also investigates the effect of graded layering by synthesizing three and four-layer brake pads by powder compaction and sintering route. The top one or two layers are made of Cu-based composite containing Fe, h-BN, and W, while the middle layer is pure Cu and, bottom steel plate. Two different compositions were explored for the composites by varying Fe content. From the two composite compositions, brake pads with single-layer composite or two-layer composite were synthesized. Characterization of brake pad specimens was carried out using density measurements, optical microscopy, scanning electron microscopy, energy dispersive spectroscopy. The brake pads were subjected to simulated braking tests at braking energy/cycle of 60, 96, and 136 K Joules. Wear rate, coefficient of friction, stopping distance, stopping time, and hardness were measured and compared among other brake pads. The brake pad containing single-layer Fe rich Cu composite showed the best performance in the simulated braking tests. EDS analysis of wear debris shows the formation of iron (boride, nitride, oxide) complex which is indicative of a surface with superior dry lubricating properties. This surface is a result of synergetic interaction between h-BN and Fe particles. The iron particles which are scattered in the Cu matrix composite act as low friction regions on the brake pad surface that interrupt the high friction regions on the Cu matrix, thus reducing the local and bulk temperature rise. The two-layer composite brake-pad showed performance intermediate to the two single-layer brake pads. No advantage due to higher thermal conductivities in Fe deficient composite was observed as the two composite layers, showed similar Fe contents in their matrix phases.

Author(s):  
W. C. Solomon ◽  
M. T. Lilly ◽  
J. I. Sodiki

The development and evaluation of brake pads using groundnut shell (GS) particles as substitute material for asbestos were carried out in this study. This was with a view to harnessing the properties of GS, which is largely deposited as waste, and in replacing asbestos which is carcinogenic in nature despite its good tribological and mechanical properties. Two sets of composite material were developed using varying particle sizes of GS as filler material, with phenolic resin as binder with percentage compositions of 45% and 50% respectively. Results obtained indicate that the compressive strength and density increase as the sieve size of the filler material decreases, while water and oil absorption rates increase with an increase in sieve size of GS particle. This study also indicates that the cost of producing brake pad can be reduced by 19.14 percent if GS is use as filler material in producing brake pad. The results when compared with those of asbestos and industrial waste showed that GS particle can be used as an effective replacement for asbestos in producing automobile brake pad. Unlike asbestos, GS-based brake pads are environmental friendly, biodegradable and cost effective.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Leila Javazmi ◽  
Anthony Young ◽  
Gavin J. Ash ◽  
Tobias Low

AbstractFertilisers are essential in modern agriculture to enhance plant growth, crop production and product quality. Recent research has focused on the development of delivery systems designed to prolong fertiliser release. This study introduces a new technology to encapsulate and release molecules of fertilisers by using multi-layered electrospun nanofibre as a carrier. Single-layer poly L-lactic acid (PLLA) nanofibres loaded with urea were fabricated using electrospinning. Triple-layer nanofibrous structures were produced by electrospinning polyhydroxybutyrate (PHB) nanofibres as external layers with PLLA nanofibres impregnated with urea fertiliser as the middle layer. Scanning electron microscopy (SEM) and Fourier transform infrared spectrophotometry (FTIR) were employed to characterize the morphology of electrospun nanofibres. Urea release dynamic was analysed using a total nitrogen instrument (TNM-1). The results indicated that triple-layered urea-impregnated nanofibrous structures led to lower initial rate of nitrogen release and slower release rate of cumulative nitrogen which extended for more than three months. It is concluded that triple-layer nanofibrous structures have the potential for slow release delivery of fertilisers.


2021 ◽  
Vol 575 (1) ◽  
pp. 29-32
Author(s):  
D. I. Makarev ◽  
N. A. Shvetsova ◽  
A. N. Reznichenko ◽  
M. A. Lugovaya

2014 ◽  
Vol 71 (2) ◽  
Author(s):  
Hussain, S. ◽  
M.K Abdul Hamid ◽  
A.R Mat Lazim ◽  
A.R. Abu Bakar

Brake wear particles resulting from friction between the brake pad and disc are common in brake system. In this work brake wear particles were analyzed based on the size and shape to investigate the effects of speed and load applied to the generation of brake wear particles. Scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX) was used to identify the size, shape and element compositions of these particles. Two types of brake pads were studied which are non-asbestos organic and semi metallic brake pads. Results showed that the size and shape of the particles generatedvary significantly depending on the applied brake load, and less significantly on brake disc speed. The wear particle becomes bigger with increasing applied brake pressure. The wear particle size varies from 300 nm to 600 µm, and contained elements such as carbon, oxygen, magnesium, aluminum, sulfur and iron.


Author(s):  
Joseph Abutu ◽  
S.A. Lawal ◽  
M.B. Ndaliman ◽  
R. A. Lafia-Araga ◽  
M. A. Oluleye

Over many years, asbestos has been used as reinforcement material in the production of brake pads production but it has lost favour due to its carcinogenic nature, as a result, there is need to investigate other possible substitute which can offer similar tribological properties as the carcinogenic material (asbestos). Several works has been carried out using different reinforcement material with the aim of finding a possible replacement for asbestos. In this work, Rule of mixture (ROM) was ustlised for sample formulation and the tribological properties of natural based material (coconut shell and seashell) were investigated using experimental design (response surface methodology) and multi-response optimisation technique (Grey relational analysis). The multi-response performance of the formulated brake pads samples was compared with a commercial brake pad sample. The research findings revealed that sample can be produced using 52% reinforcement, 35% binder, 8% abrasive and 5% friction modifier while the Grey relational analysis (GRA) showed that optimum multi-response performance of the developed coconut shell based sample can be achieved using MP, MT and CT and HTT of 12MPa, 100 oC, 6mins and 2hrs respectively while that of the developed seashell based brake pad can be achieved using MP, MT and CT and HTT of 10MPa, 160 oC, 12mins and 2hrs respectively. Also, the Analysis of variance (ANOVA) results show a percentage error of less than 5% indicating minima noise effect. In addition, the optimized coconut shell-based brake pads falls within the category of class H (µ >0.55) type of brake pads while seashell based sample falls within the class G (µ: 0.45-0.55) type of brake pads. It therefore concluded that the use of coconut shell can serve as a better substitute for asbestos-based brake pads.


2015 ◽  
Vol 140 (4) ◽  
pp. 356-361 ◽  
Author(s):  
Dongmei Wei ◽  
Huimin Xu ◽  
Ruili Li

Anthers contain starch and neutral lipids, which have key roles in microspore ontogeny and gametophyte development. In this study, we observed the dynamic changes in starch and neutral lipids in the anther developmental processes of castor (Ricinus communis) by cytochemical methods. Starch grains and neutral lipids presented a regular dynamic distribution during anther development. In young anthers, some neutral lipids accumulated in sporogenous cells, whereas neutral lipids disappeared with microspore growth. At the late microspore stage, starch grains began to accumulate in microspores, and the starch content of bicellular pollen significantly increased after microspore mitosis. At anthesis, starch grains and neutral lipids accumulated in the mature pollen grains. Visible changes occurred in anther wall cells. The epidermis, middle layer, and tapetum were degenerated, and only a single layer of endothecium remained at anthesis. The dynamic variation of starch grains and neutral lipids in tapetal cells was consistent with the changes in microspores and pollen during anther development. All these findings demonstrated that tapetal cells directly interacted with the developing gametophytes. The tapetal cells play an important role in supplying nutritional substances for microspore absorption. Moreover, the endothecium protects the pollen and contributes to anther dehiscence. The results of this study provide a foundation for the further research on sexual reproduction in angiosperms.


2019 ◽  
Vol 7 (21) ◽  
pp. 6273-6278 ◽  
Author(s):  
Zichao Ma ◽  
Clarissa Prawoto ◽  
Zubair Ahmed ◽  
Ying Xiao ◽  
Lining Zhang ◽  
...  

Single layer etching of h-BN is achieved using a two-step remote plasma process.


2019 ◽  
Vol 65 (1) ◽  
Author(s):  
Turgay Akbulut ◽  
Nadir Ayrilmis

Abstract The aim of the study was to develop three-layer medium-density fibreboard (MDF) manufacture by adding the coarse fibres in the middle layer, like three-layer particleboard. The liquid urea–formaldehyde (UF) resin was reduced from 10.5 to 6.5 wt% in the middle layer of the MDFs. The UF resin content was kept constant at 10 wt% in the surface layers of all the MDFs. Moreover, the average density of MDFs was decreased from 730 to 650 kg/m3. The internal bond strength of three-layer MDFs decreased with decreasing UF resin content (10.5 to 8.5 wt%) in the middle layer. However, the decreases in the internal bond strength were statistically not significant. The internal bond strength values of the MDFs having density between 730 and 675 kg/m3 did not show significant differences. The cost savings of the resin were 20% when the amount of resin was reduced from 10.5 to 8.5 wt%. Three-layer MDFs had lower resin consumption at lower densities over traditional single-layer MDFs produced in the same plant with the same material components without decreasing their technological properties. In conclusion, it can be said that three-layer MDF could be produced at a lower cost than traditional single-layer MDF.


Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1487 ◽  
Author(s):  
Sihao Yin ◽  
Xinlin Ren ◽  
Peichao Lian ◽  
Yuanzhi Zhu ◽  
Yi Mei

We applied black phosphorene (BP) and hexagonal boron nitride (BN) nanosheets as flame retardants to waterborne polyurethane to fabricate a novel black phosphorus/boron nitride/waterborne polyurethane composite material. The results demonstrated that the limiting oxygen index of the flame-retarded waterborne polyurethane composite increased from 21.7% for pure waterborne polyurethane to 33.8%. The peak heat release rate and total heat release of the waterborne polyurethane composite were significantly reduced by 50.94% and 23.92%, respectively, at a flame-retardant content of only 0.4 wt%. The superior refractory performances of waterborne polyurethane composite are attributed to the synergistic effect of BP and BN in the gas phase and condensed phase. This study shows that black phosphorus-based nanocomposites have great potential to improve the fire resistance of polymers.


2018 ◽  
Vol 941 ◽  
pp. 1996-2005
Author(s):  
Ehsan Sherkatghanad ◽  
Li Hui Lang ◽  
Shi Chen Liu

Advanced materials such as aluminum alloys and composites offer great potential for weight reduction applications in automotive and aerospace vehicles construction. In order to investigate the feasibility of using such materials in the form of laminates, sheet bulging with single-layer aluminum and the aluminum/Composite laminate with the carbon cloth as the middle layer is investigated under uniform liquid pressure conditions. The aluminum sheet stress-strain, wall thickness distribution, carbon fiber radius stress-strain distribution and the effect of die entrance radius etc. are discussed and compared in details. FE results validate that the numerical method can predict the same fracture regions for bulging-blank as observed in experimental tests. Furthermore, the study validates that multi-layer sheet hydro-bulging process with composite fiber as a middle layer is not feasible to form laminates due to rupture of composite fibers near edge regions. Further study is needed to improve the methodology.


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