Advances in polystyrene/graphene nanoplatelet nanocomposites

2021 ◽  
pp. 875608792110296
Author(s):  
Ayesha Kausar
Keyword(s):  
Physical Properties ◽  
Electromagnetic Interference ◽  
Structural Features ◽  
Graphene Nanoplatelet ◽  
Practical Applications ◽  
Polystyrene Matrix ◽  
Melt Synthesis ◽  
Technological Impact ◽  
Nanofiller Content

This article analyses research trials on noteworthy features and technological impact of the polystyrene/graphene nanoplatelet nanocomposites. In polystyrene matrix, graphene nanoplatelets have been used as remarkable nanofiller. Substantial improvements in polystyrene physical properties occurs by adding low nanofiller content. Simple in situ, emulsion, solution, or melt synthesis strategies have been used to develop polystyrene/graphene nanoplatelet nanocomposite. The polystyrene/graphene nanoplatelet nanocomposites possess enhanced structural features, morphology, glass transition temperature, thermal stability, mechanical strength, electrical characteristics, sensing, capacitance, and other physical properties. The performance of the polystyrene/graphene nanoplatelet nanocomposites have been explored for the practical applications in the fields of sensing, electromagnetic interference shielding, and flame retardant materials.

In situ TEM Studies of agglomeration of sub-nanometer Ru layers in Ru/C multilayers

1992 ◽  
Vol 50 (1) ◽  
pp. 256-257
Author(s):  
Tai D. Nguyen ◽  
Ronald Gronsky ◽  
Jeffrey B. Kortright
Keyword(s):  
Layered Structure ◽  
Driving Force ◽  
High Energy ◽  
Superior Performance ◽  
In Situ Tem ◽  
Rayleigh Instability ◽  
Practical Applications ◽  
Transmission Electron ◽  
Diffraction Patterns

Nanometer period Ru/C multilayers are one of the prime candidates for normal incident reflecting mirrors at wavelengths < 10 nm. Superior performance, which requires uniform layers and smooth interfaces, and high stability of the layered structure under thermal loadings are some of the demands in practical applications. Previous studies however show that the Ru layers in the 2 nm period Ru/C multilayer agglomerate upon moderate annealing, and the layered structure is no longer retained. This agglomeration and crystallization of the Ru layers upon annealing to form almost spherical crystallites is a result of the reduction of surface or interfacial energy from die amorphous high energy non-equilibrium state of the as-prepared sample dirough diffusive arrangements of the atoms. Proposed models for mechanism of thin film agglomeration include one analogous to Rayleigh instability, and grain boundary grooving in polycrystalline films. These models however are not necessarily appropriate to explain for the agglomeration in the sub-nanometer amorphous Ru layers in Ru/C multilayers. The Ru-C phase diagram shows a wide miscible gap, which indicates the preference of phase separation between these two materials and provides an additional driving force for agglomeration. In this paper, we study the evolution of the microstructures and layered structure via in-situ Transmission Electron Microscopy (TEM), and attempt to determine the order of occurence of agglomeration and crystallization in the Ru layers by observing the diffraction patterns.

scholarly journals Ring-Forming Polymerization toward Perfluorocyclobutyl and Ortho-Diynylarene-Derived Materials: From Synthesis to Practical Applications

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1486
Author(s):  
Eugene B. Caldona ◽  
Ernesto I. Borrego ◽  
Ketki E. Shelar ◽  
Karl M. Mukeba ◽  
Dennis W. Smith
Keyword(s):  
Chemical Resistance ◽  
Structural Features ◽  
Review Article ◽  
Aryl Ether ◽  
Aromatic Rings ◽  
Practical Applications ◽  
Repeat Units ◽  
Wide Range ◽  
Synthetic Routes ◽  
The Cost

Many desirable characteristics of polymers arise from the method of polymerization and structural features of their repeat units, which typically are responsible for the polymer’s performance at the cost of processability. While linear alternatives are popular, polymers composed of cyclic repeat units across their backbones have generally been shown to exhibit higher optical transparency, lower water absorption, and higher glass transition temperatures. These specifically include polymers built with either substituted alicyclic structures or aromatic rings, or both. In this review article, we highlight two useful ring-forming polymer groups, perfluorocyclobutyl (PFCB) aryl ether polymers and ortho-diynylarene- (ODA) based thermosets, both demonstrating outstanding thermal stability, chemical resistance, mechanical integrity, and improved processability. Different synthetic routes (with emphasis on ring-forming polymerization) and properties for these polymers are discussed, followed by their relevant applications in a wide range of aspects.

scholarly journals Microstructural Characteristics of Frazil Particles and the Physical Properties of Frazil Ice in the Yellow River, China

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 617
Author(s):  
Yaodan Zhang ◽  
Zhijun Li ◽  
Yuanren Xiu ◽  
Chunjiang Li ◽  
Baosen Zhang ◽  
...  
Keyword(s):  
Physical Properties ◽  
Yellow River ◽  
The Yellow River ◽  
Ice Crystal ◽  
Microstructural Characteristics ◽  
Air Bubble ◽  
Frazil Ice ◽  
Sediment Content ◽  
Crystal Diameter

Frazil particles, ice crystals or slushy granules that form in turbulent water, change the freezing properties of ice to create “frazil ice”. To understand the microstructural characteristics of these particles and the physical properties of frazil ice in greater depth, an in situ sampler was designed to collect frazil particles in the Yellow River. The ice crystal microstructural characteristics of the frazil particles (morphology, size, air bubble, and sediment) were observed under a microscope, and their nucleation mechanism was analyzed according to its microstructure. The physical properties of frazil ice (ice crystal microstructure, air bubble, ice density, and sediment content) were also observed. The results showed that these microstructures of frazil particles can be divided into four types: granular, dendritic, needle-like, and serrated. The size of the measured frazil particles ranged from 0.1 to 25 mm. Compared with columnar ice, the crystal microstructure of frazil ice is irregular, with a mean crystal diameter less than 5 mm extending in all directions. The crystal grain size and ice density of frazil ice are smaller than columnar ice, but the bubble and sediment content are larger.

scholarly journals A Novel Cobalt Metallopolymer with Redox-Matched Conjugated Organic Backbone via Electropolymerization of a Readily Available N4 Cobalt Complex

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1667
Author(s):  
Mikhail Karushev
Keyword(s):  
Redox Reactions ◽  
Repeat Unit ◽  
Cobalt Complex ◽  
Radical Cations ◽  
Electrochemical Quartz Crystal Microbalance ◽  
Practical Applications ◽  
Sensing Applications ◽  
Novel Approach ◽  
Redox Switching

Fast and reversible cobalt-centered redox reactions in metallopolymers are the key to using these materials in energy storage, electrocatalytic, and sensing applications. Metal-centered electrochemical activity can be enhanced via redox matching of the conjugated organic backbone and cobalt centers. In this study, we present a novel approach to redox matching via modification of the cobalt coordination site: a conductive electrochemically active polymer was electro-synthesized from [Co(Amben)] complex (Amben = N,N′-bis(o-aminobenzylidene)ethylenediamine) for the first time. The poly-[Co(Amben)] films were investigated by cyclic voltammetry, electrochemical quartz crystal microbalance (EQCM), in situ UV‑vis-NIR spectroelectrochemistry, and in situ conductance measurements between −0.9 and 1.3 V vs. Ag/Ag+. The polymer displayed multistep redox processes involving reversible transfer of the total of 1.25 electrons per repeat unit. The findings indicate consecutive formation of three redox states during reversible electrochemical oxidation of the polymer film, which were identified as benzidine radical cations, Co(III) ions, and benzidine di-cations. The Co(II)/Co(III) redox switching is retained in the thick polymer films because it occurs at potentials of high polymer conductivity due to the optimum redox matching of the Co(II)/Co(III) redox pair with the organic conjugated backbone. It makes poly-[Co(Amben)] suitable for various practical applications based on cobalt-mediated redox reactions.

Magnetic matchstick micromotors with switchable motion modes

2021 ◽  
Author(s):  
Xiaoliang Zhang ◽  
Wenqing Xie ◽  
Huaguang Wang ◽  
Zexin Zhang
Keyword(s):  
Practical Applications ◽  
Motion Modes

The ability to in situ tune various motion modes of micromotors is challenging, yet critical for any practical applications of micromotors in complex microenvironments. Here, we designed and synthesized magnetic...

In situ polymerized poly(butylene succinate)/silica nanocomposites: Physical properties and biodegradation

2008 ◽  
Vol 93 (5) ◽  
pp. 889-895 ◽  
Author(s):  
Sang-Il Han ◽  
Jung Seop Lim ◽  
Dong Kook Kim ◽  
Mal Nam Kim ◽  
Seung Soon Im
Keyword(s):  
Physical Properties ◽  
Butylene Succinate ◽  
Silica Nanocomposites

scholarly journals Flow-law hypotheses for ice-sheet modeling

1992 ◽  
Vol 38 (129) ◽  
pp. 245-256 ◽  
Author(s):  
Richard B. Alley
Keyword(s):  
Physical Properties ◽  
Ice Sheets ◽  
Diffusion Control ◽  
Ice Streams ◽  
Ice Shelves ◽  
Dislocation Glide ◽  
Ice Sheet Modeling ◽  
Flow Law ◽  
Power Law Creep

AbstractIce-flow modeling requires a flow law relating strain rates to stresses in situ, but a flow law cannot be measured directly in ice sheets. Microscopic processes such as dislocation glide and boundary diffusion control both the flow law for ice and the development of physical properties such as grain-size andc-axis fabric. These microscopic processes can be inferred from observations of the physical properties, and the flow law can then be estimated from the microscopic processes.A review of available literature shows that this approach can be imperfectly successful. Interior regions of large ice sheets probably have depth-varying flow-law “constants”, with the stress exponent,n, for power-law creep less than 3 in upper regions and equal to 3 only in deep ice;nprobably equals 3 through most of the thickness of ice shelves and ice streams.

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