Rapid determination of products of phenol hydrogenation in a supercritical water system using headspace gas chromatography
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AbstractThis paper reports a headspace analysis technique for the determination of products, i.e., cyclohexanone (CE) and cyclohexanol (CL), of phenol hydrogenation in a supercritical water reaction system (SWRS) with water removal by hydrate formation. An addition of anhydrous calcium chloride leads to water absorption resulting in crystal water; thus, the samples can be quantitatively measured without the influence of water. After achieving equilibrium at 150°C and maintaining it for 5 min, the obtained results showed a relative standard deviation of less than 5.3 % and the recovery ranged from 93 % to 104 %. The presented method is simple and accurate for the analysis of CL, CE and phenol in samples from phenol conversion in SWRS.
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2013 ◽
Vol 295-298
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pp. 950-953
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2021 ◽
2013 ◽
Vol 448-453
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pp. 359-362
2014 ◽
Vol 1350
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pp. 10-14
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