Morphology, thermal and mechanical properties of electrospun polyvinylidene/polyethylene glycol composite nanofibers as form-stabilized phase change materials

2022 ◽  
Vol 0 (0) ◽  
Author(s):  
Xing Liu ◽  
Qi’an Yin ◽  
Chaoming Wang ◽  
Zhanjiang Hu ◽  
Zhengyu Cai
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Polyethylene Glycol ◽  
Phase Change ◽  
Melting Temperature ◽  
Latent Heat ◽  
Polyvinylidene Fluoride ◽  
Average Molecular Weight ◽  
High Mass ◽  
Strength Increase

Abstract Polyvinylidene fluoride (PVDF)/polyethylene glycol (PEG) form-stabilized composite phase change nanofibers with various mass percentage of PEG1000 (with average molecular weight of 1000) loadings were fabricated by electrospinning technique, in which PEG was served as phase change material (PCM) and PVDF as the supporting matrix to afford a mechanically strong structure. Effect of PEG1000 content on nanofiber morphology, phase transition properties, thermal stability, thermal energy storage and release performance, and mechanical properties were studied experimentally. The results showed that the incorporation of PEG1000 improved the spinning solution viscosity and high mass fraction of PEG1000 in the nanofibers led to decreased fiber diameter and melting temperature, and higher latent heat of fusion. In addition, mechanical test revealed that the fracture elongation of the electrospun PVDF/PEG composite nanofibrous membranes were initially increased with unobvious tensile strength changes, while the value of the elongation would decrease, and the tensile strength increase as the mass ratio of PVDF/PEG lower to 1:1. Furthermore, the melting temperature and maximum latent heat for PVDF/PEG were determined from DSC measurement as 51.8 °C, and 73.3 J/g, when the mass radio of PVDF/PEG was 1:1 (w/w), which was suitable utilized for thermo-regulating textiles or in heat storage devices.

scholarly journals Effect of Different Pore-Forming Additives on the Formation of PVDF Microporous Membranes for Bucky-Gel Actuator

2020 ◽  
Vol 22 (2) ◽  
pp. 107
Author(s):  
O.S. Morozov ◽  
S.S. Shachneva ◽  
B.A. Bulgakov ◽  
A.V. Babkin ◽  
A.V. Kepman
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Polyethylene Glycol ◽  
Ionic Conductivity ◽  
Polyvinylidene Fluoride ◽  
Dibutyl Phthalate ◽  
Fracture Strain ◽  
Degree Of Crystallinity ◽  
Solvent Evaporation Method ◽  
Electrolyte Uptake

The microporous polyvinylidene fluoride (PVDF) membranes were prepared by the solvent evaporation method using 50 wt.% of different pore-forming additives: poly(1-ethyl-3-vinylimidazolium tetrafluoroborate) (PIL-BF4), polyethylene glycol 3000 (PEG-3K) and 40000 (PEG-40K), dibutyl phthalate (DBP). The influence of used additive on morphology, porosity, degree of crystallinity, tensile properties, electrolyte uptake and ionic conductivity of the membranes were investigated. The maximum electrolyte uptake of 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF4) was 184 wt.% for the membrane prepared with PEG-40K, however, the membrane was fragile and unsuitable for practical use. The remaining membranes showed approximately the same porosity (45‒48%) and electrolyte uptakes (169‒175%). At the same time, the membranes significantly differed in mechanical properties and ionic conductivity. The membrane prepared with PIL-BF4, unlike others, has a sponge-like structure and demonstrated high mechanical properties, namely tensile strength is 17.7 MPa and fracture strain is 132.5%. Bucky gel actuators were fabricated using membranes prepared with different additives. The blocking force of the actuators based on membranes with different additives decreased in the sequence of PIL-BF4, DBP and PEG. The actuator based on the membrane prepared with PIL-BF4 demonstrates a blocking force of 5.7 mN and a deformation of 1.35 % at 3 V DC.

scholarly journals A Robust, Tough and Multifunctional Polyurethane/Tannic Acid Hydrogel Fabricated by Physical-Chemical Dual Crosslinking

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 239 ◽  
Author(s):  
Jie Wen ◽  
Xiaopeng Zhang ◽  
Mingwang Pan ◽  
Jinfeng Yuan ◽  
Zhanyu Jia ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Polyethylene Glycol ◽  
Hydrogen Bonds ◽  
Tannic Acid ◽  
Hydroxyl Groups ◽  
Self Healing ◽  
Physical Chemical ◽  
Biomedical Field ◽  
Physical Crosslinking

Commonly synthetic polyethylene glycol polyurethane (PEG–PU) hydrogels possess poor mechanical properties, such as robustness and toughness, which limits their load-bearing application. Hence, it remains a challenge to prepare PEG–PU hydrogels with excellent mechanical properties. Herein, a novel double-crosslinked (DC) PEG–PU hydrogel was fabricated by combining chemical with physical crosslinking, where trimethylolpropane (TMP) was used as the first chemical crosslinker and polyphenol compound tannic acid (TA) was introduced into the single crosslinked PU network by simple immersion process. The second physical crosslinking was formed by numerous hydrogen bonds between urethane groups of PU and phenol hydroxyl groups in TA, which can endow PEG–PU hydrogel with good mechanical properties, self-recovery and a self-healing capability. The research results indicated that as little as a 30 mg·mL−1 TA solution enhanced the tensile strength and fracture energy of PEG–PU hydrogel from 0.27 to 2.2 MPa, 2.0 to 9.6 KJ·m−2, respectively. Moreover, the DC PEG–PU hydrogel possessed good adhesiveness to diverse substrates because of TA abundant catechol groups. This work shows a simple and versatile method to prepare a multifunctional DC single network PEG–PU hydrogel with excellent mechanical properties, and is expected to facilitate developments in the biomedical field.

In vitro evaluation of fluorocarbon leader line for use as a fabella-tibial suture

2004 ◽  
Vol 17 (01) ◽  
pp. 35-40 ◽  
Author(s):  
G. Hosgood ◽  
S. C. Kerwin ◽  
C. S. Hedlund ◽  
J. B. Metcalf ◽  
M. N. Banwell
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Ethylene Oxide ◽  
Polyvinylidene Fluoride ◽  
Cruciate Ligament ◽  
Large Diameter ◽  
Surgical Techniques ◽  
Suitable Alternative ◽  
Knot Security ◽  
Ethylene Oxide Sterilization

SummaryCranial cruciate ligament rupture is a common injury in dogs, for which a variety of surgical techniques have been described. A commonly performed surgical technique is extracapsular stabilization with a lateral fabella-tibial suture (LFS) using large diameter nylon leader line (NLL). Inherent properties of NLL such as memory, low coefficient of friction, and large diameter may compromise knot security. Fluorocarbon (polyvinylidene fluoride; PVDF) has been investigated as a biomaterial for a variety of implants and is available as a high tensile strength fluorocarbon leader line (FCL). For a given tensile strength FCL is one-half the diameter of NLL. This study evaluated the force at failure, elongation, and stiffness of FCL compared to NLL for use as a LFS. The effects of steam and ethylene oxide sterilization on FCL were also evaluated. The results of this study demonstrate similar force at failure and stiffness for FCL when compared to NLL. In addition, the use of FCL may eliminate the elongation under low load observed with NLL. The mechanical properties of FCL loops were not affected by ethylene oxide sterilization. In contrast, steam sterilization caused significant detrimental effects on the mechanical properties of FCL and is not recommended. The reduced diameter and pliable feel of FCL allow for superior handling, formation of a less bulky and potentially more secure knot, and less foreign material in the region of implantation. FCL appears to be a suitable alternative material to NLL for a lateral fabella-tibial suture.

Effect of reactive and non-reactive diluents on thermal and mechanical properties of epoxy resin

2017 ◽  
Vol 30 (10) ◽  
pp. 1159-1168 ◽  
Author(s):  
Animesh Sinha ◽  
Nazrul Islam Khan ◽  
Subhankar Das ◽  
Jiawei Zhang ◽  
Sudipta Halder
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Fracture Toughness ◽  
Tensile Strength ◽  
Polyethylene Glycol ◽  
Epoxy Resin ◽  
Mechanical Performance ◽  
Thermal And Mechanical Properties ◽  
Minor Variation ◽  
Reactive Diluents

The effect of reactive (polyethylene glycol) and non-reactive (toluene) diluents on thermal and mechanical properties (tensile strength, hardness and fracture toughness) of diglycidyl ether of bisphenol A epoxy resin (cured by triethylenetetramine) was investigated. The thermal stability and mechanical properties of the epoxy resin modified with reactive and non-reactive diluents at different wt% were investigated using thermo-gravimetric analyser, tensile test, hardness test and single-edge-notched bend test. A minor variation in thermal stability was observed for epoxy resin after addition of polyethylene glycol and toluene at 0.5 wt%; however, further addition of reactive and non-reactive diluents diminished the thermal stability. The addition of 10 wt% of polyethylene glycol in epoxy resin significantly enhances the tensile strength (∼12%), hardness (∼14%) and fracture toughness (∼24%) when compared to that of neat epoxy resin. In contrast, major drop in mechanical performance was observed after addition of toluene in epoxy. Furthermore, fracture surfaces were investigated under field emission scanning electron microscope to elucidate the failure mechanism.

Mechanical Properties and Fracture Mechanism of TiCp/ZA-12 Composites

2006 ◽  
Vol 324-325 ◽  
pp. 671-674
Author(s):  
Wang Xiang ◽  
Xiao Hua Xue
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Yield Strength ◽  
Cleavage Fracture ◽  
Fracture Mechanism ◽  
Experimental Results ◽  
Fracture Model ◽  
Strength Increase ◽  
Dimple Fracture ◽  
Mixed Fracture

TiCp/ZA-12 composites have been fabricated by XDTM method and stirring-casting techniques. The tests for mechanical properties reveal that the tensile strength and strength increase with increasing fraction of TiC particles. When the fraction of TiC particles increase up to 10%, the tensile strength and yield strength are 390MPa and 340MPa, respectively and they increase by 11% and 17% than that of matrix respectively. From the analysis of fractography we can see that mixed fracture of cleavage fracture and dimple fracture exists in the TiCp/ZA-12 composites, and fractured particles are not found. Finally the fracture model of composites has been established based on the experimental results.

Study on Microstructures and Mechanical Properties of Die Casting Mg-xGd-3Y-0.5Zr Alloys

2013 ◽  
Vol 690-693 ◽  
pp. 44-48
Author(s):  
Feng Wang ◽  
Zhi Wang ◽  
Zheng Liu ◽  
Ping Li Mao
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Tensile Strength ◽  
Solution Heat Treatment ◽  
Die Casting ◽  
Solution Treatment ◽  
Small Variation ◽  
Strength Increase ◽  
Microstructures And Mechanical Properties ◽  
Zr Alloys

In this paper, developed a non-aluminum die casting magnesium alloys were studied based on Mg-xGd-Y-Zr（x=6, 8, 12 wt.%）alloys in cold chamber press. The microstructures and mechanical properties of die casting GWK alloys have been investigated using OM, SEM, XRD, EDS and mechanical property test. The experimental results show that with increasing Gd content of Mg-xGd-Y-Zr alloys, the tensile strength increase, but elongation decrease. In particular, die casting GWK alloys after short-term and low-temperature solid solution treatment (T4) have a small variation in grain size and more uniform microstructures, and the second phases distribute at the grain boundaries in form of discontinuous rod shape or granule shape, which result in an obvious improvement in tensile mechanical properties of alloys. The Mg-12Gd-3Y-0.5Zr die casting alloy exhibit maximum tensile strength after solution heat treatment, and the value is 269MPa at room temperature. The effect of solution heat treatment on die casting Mg-xGd-Y-Zr alloys was also discussed.

scholarly journals Effect of the Alkalized Rice Straw Content on Strength Properties and Microstructure of Cemented Tailings Backfill

2021 ◽  
Vol 8 ◽  
Author(s):  
Shi Wang ◽  
Xuepeng Song ◽  
Meiliang Wei ◽  
Wu Liu ◽  
Xiaojun Wang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Rice Straw ◽  
Low Cost ◽  
Strength Properties ◽  
Hydration Reaction ◽  
Strength Increase ◽  
Improvement Effect ◽  
Naoh Solution

The tailings and rice straw are waste by-products, and the storage of tailings on the ground and the burning of rice straws will seriously damage the ecological environment. In this study, the effect of different contents of alkalized rice straw (ARS; rice straw was alkalized with 4% NaOH solution) on the mechanical properties and microstructure of cemented tailings backfill (CTB; ARSCTB) was studied through uniaxial compressive strength (UCS), scanning electron microscopy (SEM), and X-ray diffraction (XRD) tests. The results indicated that 1) the UCS of ARSCTB could be improved by ARS. However, with the increase in the ARS content from 0.1 to 0.4 wt%, the UCS showed a monotonous decreasing trend. The UCS improvement effect was best when the ARS content was 0.1 wt%, and at 7, 14, and 28 days curing ages, the UCS increased rate was 6.0, 8.3, 14.7% respectively. 2) The tensile strength of ARSCTB was generally higher than that of CTB and positively correlated with the ARS content. The tensile strength increase rate was 24.1–34.2% at 28 days curing age. 3) The SEM test indicated that the ARS was wrapped by cement hydration products, which improves its connection with the ARSCTB matrix. ARS performed a bridging role, inhibited cracks propagation, and provided drag or pulling force for the block that is about to fall off. Therefore, the mechanical properties of ARSCTB were enhanced. However, under high ARS content, the inhibition of ARS on hydration reaction and the overlap between ARS were not conducive to the improvement of the UCS of ARSCTB. 4) The post-peak residual strength and integrity effect of ARSCTB were greater. It is recommended to add 0.1–0.2 wt% ARS to the backfill with high compressive strength requirements such as the empty field subsequent filling mining method and the artificial pillar. 0.3–0.4 wt% ARS is incorporated into backfill with high tensile strength requirements such as high-stage filling with lateral exposure and artificial roof. This study further makes up for the blank of the application of plant fiber in the field of mine filling and helps to improve the mechanical properties of backfill through low-cost materials.

scholarly journals Thermal performance deterrence caused by PCM inclusion in firefighting garments: The other side of the story

2021 ◽  
Vol 2116 (1) ◽  
pp. 012018
Author(s):  
A Fonseca ◽  
S F Neves ◽  
J B L M Campos
Keyword(s):  
Heat Flux ◽  
Phase Change ◽  
Melting Temperature ◽  
Latent Heat ◽  
Thermal Performance ◽  
Heat Exposure ◽  
Negative Influence ◽  
High Heat Flux ◽  
Fire Exposure ◽  
Skin Damage

Abstract Firefighters usually encounter high heat flux exposures, which can cause severe burns. The addition of a phase change material (PCM) layer into a firefighting garment assembly has proven to be beneficial as it lowers the garments temperature during the fire exposure. However, after the fire exposure, accumulated heat in the PCM garment is discharged towards skin and environment which can have a negative influence on thermal performance. In this study, a one dimensional numerical approach was used to study the effect of environment parameters (ambient convective heat flux) as well as PCM parameters (latent heat, melting temperature) on the thermal performance of the firefighting garment, after the fire exposure. It was concluded that the amount and phase change temperature at which latent heat is discharged had a significant effect on thermal performance, depending on the heat exposure scenario. For high – intensity exposures, skin damage is promoted by an increase in both properties whilst for low intensity exposures, a decrease in melting temperature would promote greater skin damage. The results outlined in this paper could aid in the manufacture of PCM firefighting garments, as skin damage due to PCM resolidification might be an important parameter to take into account when maximizing thermal performance.

Effect of Blowing Agent and Polyethylene Glycol on Cellular Structure and Mechanical Properties of Chloroprene Rubber

2012 ◽  
Vol 217-219 ◽  
pp. 517-521 ◽  
Author(s):  
Hong Ling Yi ◽  
Ting Wei ◽  
Lin Heng ◽  
Bai Cun Zheng
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Zinc Oxide ◽  
Polyethylene Glycol ◽  
Cellular Structure ◽  
Foaming Agent ◽  
Blowing Agent ◽  
Swell Ratio ◽  
Closed Cell ◽  
Chloroprene Rubber

In this paper the closed-cell sponge of chloroprene rubber(CR) were produced by foaming agent Azodicarbonamide (AC) and Oxybis (benzene sulfonyl) hydrazide (OBSH). The blend blowing agent AC/OBSH was more effective than the pure AC as it could produce chloroprene foam with greater cell porosity, more uniform and better cell distributions. The CR foam prepared with AC/OBSH had better tensile strength and tear strength than pure AC, but higher Shore C hardness. The Polyethyene glycol (PEG) modified Zinc Oxide (ZnO) could accelerate curing and foam process simultaneously. Increase the content of PEG, CR foam has bigger swell ratio, smaller cell size, and better softness.

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