Effect of Quaternary Ammonium-Modified Montmorillonites on Mechanical Properties of Polypropylene

1998 ◽  
Vol 520 ◽  
Author(s):  
Y. H. Zhang ◽  
K. C. Gong

ABSTRACTHybrids of quaternary ammonium-modified montmorillonites and polypropylene were prepared by melting intercalation. Results of mechanical property measurements show that, tensile strength, modulus and impact strength of PP composites are greatly enhanced simultaneously by a small addition amount of modified montmorillonites.

2019 ◽  
Vol 956 ◽  
pp. 229-236
Author(s):  
Jian Lin Xu ◽  
Zhou Chen ◽  
Lei Niu ◽  
Cheng Hu Kang ◽  
Xiao Qi Liu

In this paper, Sb2O3/PP composite specimens were prepared by ball milling and melt blending. The effects of Sb2O3 particle size and filling amount on the toughening, reinforcing effect and crystallinity of PP composites were analyzed by notch impact test, tensile test, SEM, XRD and DSC characterization. The experimental results show that the filling of Sb2O3 particles can improve the mechanical properties and crystallization properties of Sb2O3/PP composites. With the increase of filling amount of Sb2O3 particles, the tensile strength and impact strength of Sb2O3/PP composite increased first and then decreased. When the content of Sb2O3 is 2 wt.%, the tensile strength and impact strength of Sb2O3/PP composites reach the maximum. When the filling amount is the same, the crystallization and mechanical properties of nanoSb2O3/PP composites are better than those of micron Sb2O3/PP composites.


2011 ◽  
Vol 391-392 ◽  
pp. 274-277
Author(s):  
Na Wang ◽  
Jiao Wang ◽  
Jing Zhang ◽  
Chi Ma ◽  
Er Fan Chen

Effects of different pore size nano-mesoporous molecular sieves fillers, i. e. MCM-41, SBA-15, together with organic-montmorillonite (OMMT), mixture of OMMT/MCM-41 or OMMT/SBA-15 (m (OMMT): m (MCM-41)/m (SBA-15) =1:1) and their amounts on mechanical properties of the polymethylmethacrylate (PMMA) composites were investigated. When the amount of OMMT/SBA-15 mixture was 0.5 %, tensile strength of the nano-composite reached maximum values of 46.3 MPa. When OMMT/SBA-15 mixture addition amount w (filler) was 1.2 %, impact strength of the nano-composite reached maximum values of 14 KJ/m2. In comparison with PMMA without any filler, the tensile strength and impact strength of nano-composite were increased by 8.4 % and 48 %, respectively.


2011 ◽  
Vol 284-286 ◽  
pp. 1842-1845
Author(s):  
Jue Wang ◽  
Gui Xiang Hou

Polystyrene(PS)/Polystyrene-expanded graphite(EG)(PS/PSEG) composites were prepared by melt blending, using a variety of PSEG. The electrical and mechanical properties of the PS/PSEG were measured. Mechanical property measurements of composites indicated higher impact strength and lower tensile strength with increasing content of PSEG. Exfoliated graphite has seen a significant reduction for composites in electrical resistivity.


2010 ◽  
Vol 146-147 ◽  
pp. 310-313
Author(s):  
Ying Peng ◽  
Jian Hua Liu

The synergistic toughening of UPR composite by rigid particles of organic PA6 and inorganic nano-SiO2 was studied. The effects of PA6 and SiO2 on the notched impact and tensile strength of the UPR composite were studied by means of the mechanical properties test. The experimental results indicated that the notched impact strength was improved and its effect was evident when 7-9%rigid particles were applied and the tensile strength was improved when the 2-5% rigid particles were applied. The composite of PA6/SiO2 ( 2/1) exhibited good mechanical property in the synergistic toughening. By the micromechanical analysis of composite, we thought that the stiffness of composite materials was determined by the stress suffered the rigid particles and the deformation of UPR polymer phase.


2020 ◽  
Vol 27 (1) ◽  
pp. 139-147
Author(s):  
Jianlin Xu ◽  
Jinqiang Zhao ◽  
Chenghu Kang ◽  
Lei Niu ◽  
Jianbin Zhang ◽  
...  

AbstractIn view of the limitation of wide application of polypropylene(PP) with low strength, poor low-temperature brittleness and easy combustion, a kind of PP matrix nanocomposites was designed and prepared. Sb2O3 nanoparticles (nano-Sb2O3) modified by silane coupling agent of KH550 were dispersed into brominated polystyrene(BPS)-PP matrix by ball milling dispersion and melt blending method, respectively. And the nano-Sb2O3/BPS-PP composites samples were obtained by injection molding method. The effects of nano-Sb2O3 particles on mechanical properties of nano-Sb2O3/BPS-PP composites were investigated. The results showed that the surface of nano-Sb2O3 particles was successfully modified by the KH550 and the interfacial adhesion between nano-Sb2O3 and PP matrix was improved. With increasing of the mass fraction of nano-Sb2O3, the tensile strength and impact strength of nano-Sb2O3/BPS-PP composites were improved accompanying by increasing of crystallinity and refining grain of the composites. When the mass fraction of nano-Sb2O3 was 3 wt%, the tensile strength of nano-Sb2O3/BPS-PP composites was 43 MPa, which was 30.3% higher than that of PP. When the mass fraction of nano-Sb2O3 was 2 wt%, the impact strength of the composites was 44.19 kJ·m−2, which was 30.8% higher than that of PP.


2014 ◽  
Vol 910 ◽  
pp. 153-156
Author(s):  
Ching Wen Lou ◽  
Jo Mei Liao ◽  
Zheng Lan Lin ◽  
Jia Horng Lin

This study uses carbon fibers (CF) to reinforce polylactic acid (PLA) matrices to form CF/PLA biocomposites. Tensile test, flexural test, and impact test are performed on biocomposites to evaluate their mechanical properties. The results of tests show that an increment of the CF content results in an increase in tensile strength, flexural strength, flexural modulus, and impact strength. The combination of 15 wt% CF provides the resulting biocomposites with a 72 % increase in tensile strength, a 322 % increase in flexural modulus, and a 96 % increase in impact strength.


2010 ◽  
Vol 163-167 ◽  
pp. 1991-1994 ◽  
Author(s):  
Gui Xiang Hou ◽  
Sheng Yuan Liu ◽  
Xiao Ming Sang

Polystyrene (PS)/Poly(S-co-MA)/expanded graphite(EG)(PS/PSMA/EG) nanocomposites were prepared by melt blending, using a variety of PSMA/EG.. The electrical and mechanical properties of the PS/PSMA/EG were measured. Mechanical property measurements of composites indicated higher impact strength and lower tensile strength with increasing concentration of PSMA/EG. Exfoliated graphite has seen a significant reduction for composites in electrical resistivity.


2014 ◽  
Vol 1025-1026 ◽  
pp. 215-220 ◽  
Author(s):  
Sasirada Weerasunthorn ◽  
Pranut Potiyaraj

Fumed silica particles (SiO2) were directly added into poly (butylene succinate) (PBS) by melt mixing process. The effects of amount of fumed silica particles on mechanical properties of PBS/fumed silica composites, those are tensile strength, tensile modulus, impact strength as well as flexural strength, were investigated. It was found that the mechanical properties decreased with increasing fumed silica loading (0-3 wt%). In order to increase polymer-filler interaction, fumed silica was treated with 3-glycidyloxypropyl trimethoxysilane (GPMS), and its structure was analyzed by FT-IR spectrophotometry. The PBS/modified was found to possess better tensile strength, tensile modulus, impact strength and flexural strength that those of PBS/fumed silica composites.


2021 ◽  
Vol 11 (12) ◽  
pp. 5317
Author(s):  
Rafał Malinowski ◽  
Aneta Raszkowska-Kaczor ◽  
Krzysztof Moraczewski ◽  
Wojciech Głuszewski ◽  
Volodymyr Krasinskyi ◽  
...  

The need for the development of new biodegradable materials and modification of the properties the current ones possess has essentially increased in recent years. The aim of this study was the comparison of changes occurring in poly(ε-caprolactone) (PCL) due to its modification by high-energy electron beam derived from a linear electron accelerator, as well as the addition of natural fibers in the form of cut hemp fibers. Changes to the fibers structure in the obtained composites and the geometrical surface structure of sample fractures with the use of scanning electron microscopy were investigated. Moreover, the mechanical properties were examined, including tensile strength, elongation at break, flexural modulus and impact strength of the modified PCL. It was found that PCL, modified with hemp fibers and/or electron radiation, exhibited enhanced flexural modulus but the elongation at break and impact strength decreased. Depending on the electron radiation dose and the hemp fibers content, tensile strength decreased or increased. It was also found that hemp fibers caused greater changes to the mechanical properties of PCL than electron radiation. The prepared composites exhibited uniform distribution of the dispersed phase in the polymer matrix and adequate adhesion at the interface between the two components.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Sekar Sanjeevi ◽  
Vigneshwaran Shanmugam ◽  
Suresh Kumar ◽  
Velmurugan Ganesan ◽  
Gabriel Sas ◽  
...  

AbstractThis investigation is carried out to understand the effects of water absorption on the mechanical properties of hybrid phenol formaldehyde (PF) composite fabricated with Areca Fine Fibres (AFFs) and Calotropis Gigantea Fibre (CGF). Hybrid CGF/AFF/PF composites were manufactured using the hand layup technique at varying weight percentages of fibre reinforcement (25, 35 and 45%). Hybrid composite having 35 wt.% showed better mechanical properties (tensile strength ca. 59 MPa, flexural strength ca. 73 MPa and impact strength 1.43 kJ/m2) under wet and dry conditions as compared to the other hybrid composites. In general, the inclusion of the fibres enhanced the mechanical properties of neat PF. Increase in the fibre content increased the water absorption, however, after 120 h of immersion, all the composites attained an equilibrium state.


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