Large Scale Leach Testing of Dwpf Canister Sections

1986 ◽  
Vol 84 ◽  
Author(s):  
Dennis F. Bickford ◽  
Daniel J. Pellarin
Keyword(s):  
Surface Roughness ◽  
Large Scale ◽  
Scale Up ◽  
Test Method ◽  
Waste Form ◽  
Test Facility ◽  
Small Scale ◽  
Glass Product ◽  
Leach Test ◽  
Sampling Statistics

AbstractA Large-Scale Leach Test Facility (LSLTF) has been constructed at the U.S. Department of Energy's Savannah River Laboratory (SRL) to perform static leach tests on 24-inch (610 mm)-diameter canister sections cut from simulated (nonradioactive) waste forms cast under reference conditions. The equipment and test procedures are designed to closely correspond to MCC-l leach test criteria.Less than a factor of 3 increase in leachability results from combined scale-up, glass-cracking, leached surface area estimation, and surface roughness effects. This factor is dominated by surface roughness of saw cut surfaces. The factor is negligible when compared to the 200,000/1 ratio of glass sample masses.The MCC-l, and other small-scale leach tests have been valuable in determining the relative merits of alternative waste form compositions. However, the actual waste glass to be stored in repositories is subject to fracture, devitrification, and container/glass interactions, which are difficult to simulate on a laboratory scale. Large-scale leach tests integrate these and other possible waste form characteristics that are not represented in typical small samples.The facility, equipment, test method and results of one year leach test- ing are discussed. These results substantiate the applicability of small scale test data which precede this work, and the use of small scale tests to simulate leaching of the Defense Waste Processing Facility's borosilicate glass product. Exceptionally good sampling statistics make the large scale data particularly well suited for verification of models of leachability rates.

Comparison of 200 Liter and 40 Milliliter Leach Tests

1982 ◽  
Vol 15 ◽  
Author(s):  
J. H. Westsik ◽  
C. O. Harvey ◽  
F. P. Roberts ◽  
W. A. Ross ◽  
R. E. Thornhill
Keyword(s):  
Large Scale ◽  
Deionized Water ◽  
Waste Form ◽  
Small Scale ◽  
Matrix Elements ◽  
Elemental Concentrations ◽  
The Past ◽  
Leach Test ◽  
The Matrix ◽  
Scale Test

ABSTRACTDuring the past year we have conducted a modified MCC-1 leach test on a 145 kg block of a cast cement waste form. The leach vessel was a 200 liter Teflon®-lined drum and contained 97.5 liters of deionized water. The results of this large-scale leach test were compared with the results of standard MCC-1 tests (40 ml) on smaller samples of the same waste form. The ratio of leachate volumes between the large and small scale tests was 2500 and the ratio of sample masses was 150,000. The cast cement samples for both tests contained plutonium-doped incinerator ash.The leachates from these tests were analyzed for both plutonium and the matrix elements. Evaluation of plutonium plateout in the large-scale test indicated that the majority of the plutonium leached from the samples deposits onto vessel walls and little (<3 × 10−12M) remains in solution. Comparison of elemental concentrations in the leachates indicates some differences up to 5X in the concentration in the large- and small-scale tests. The differences are attributed to differences in the solubilities of Ca, Si, and Fe at pH ˜11.5 and at pH ˜12.5. The higher pH observed for the large-scale test is a result of the larger quantities of sodium in the large block of cement.

scholarly journals Combined measurement of velocity and temperature in liquid metal convection

2019 ◽  
Vol 876 ◽  
pp. 1108-1128 ◽  
Author(s):  
Till Zürner ◽  
Felix Schindler ◽  
Tobias Vogt ◽  
Sven Eckert ◽  
Jörg Schumacher
Keyword(s):  
Reynolds Number ◽  
Liquid Metal ◽  
Large Scale ◽  
Scale Up ◽  
Convection Cell ◽  
Small Scale ◽  
Convection Flow ◽  
Large Scale Circulation ◽  
Large Scale Flow ◽  
The Impact

Combined measurements of velocity components and temperature in a turbulent Rayleigh–Bénard convection flow at a low Prandtl number of $Pr=0.029$ and Rayleigh numbers of $10^{6}\leqslant Ra\leqslant 6\times 10^{7}$ are conducted in a series of experiments with durations of more than a thousand free-fall time units. Multiple crossing ultrasound beam lines and an array of thermocouples at mid-height allow for a detailed analysis and characterization of the complex three-dimensional dynamics of the single large-scale circulation roll in a cylindrical convection cell of unit aspect ratio which is filled with the liquid metal alloy GaInSn. We measure the internal temporal correlations of the complex large-scale flow and distinguish between short-term oscillations associated with a sloshing motion in the mid-plane as well as varying orientation angles of the velocity close to the top/bottom plates and the slow azimuthal drift of the mean orientation of the roll as a whole that proceeds on a time scale up to a hundred times slower. The coherent large-scale circulation drives a vigorous turbulence in the whole cell that is quantified by direct Reynolds number measurements at different locations in the cell. The velocity increment statistics in the bulk of the cell displays characteristic properties of intermittent small-scale fluid turbulence. We also show that the impact of the symmetry-breaking large-scale flow persists to small-scale velocity fluctuations thus preventing the establishment of fully isotropic turbulence in the cell centre. Reynolds number amplitudes depend sensitively on beam-line position in the cell such that different definitions have to be compared. The global momentum and heat transfer scalings with Rayleigh number are found to agree with those of direct numerical simulations and other laboratory experiments.

Solar Upgrading of Fuels for Generation of Electricity

2001 ◽  
Vol 123 (2) ◽  
pp. 160-163 ◽  
Author(s):  
Rainer Tamme ◽  
Reiner Buck ◽  
Michael Epstein ◽  
Uriyel Fisher ◽  
Chemi Sugarmen
Keyword(s):  
Gas Turbines ◽  
Large Scale ◽  
Fossil Fuels ◽  
High Efficiency ◽  
Combined Cycle ◽  
Test Facility ◽  
Small Scale ◽  
Start Up ◽  
Efficiency Conversion ◽  
Solar Field

This paper presents a novel process comprising solar upgrading of hydrocarbons by steam reforming in solar specific receiver-reactors and utilizing the upgraded, hydrogen-rich fuel in high efficiency conversion systems, such as gas turbines or fuel cells. In comparison to conventionally heated processes about 30% of fuel can be saved with respect to the same specific output. Such processes can be used in small scale as a stand-alone system for off-grid markets as well as in large scale to be operated in connection with conventional combined-cycle plants. The complete reforming process will be demonstrated in the SOLASYS project, supported by the European Commission in the JOULE/THERMIE framework. The project has been started in June 1998. The SOLASYS plant is designed for 300 kWel output, it consists of the solar field, the solar reformer and a gas turbine, adjusted to operate with the reformed gas. The SOLASYS plant will be operated at the experimental solar test facility of the Weizmann Institute of Science in Israel. Start-up of the pilot plant is scheduled in April 2001. The midterm goal is to replace fossil fuels by renewable or non-conventional feedstock in order to increase the share of renewable energy and to establish processes with only minor or no CO2 emission. Examples might be upgrading of bio-gas from municipal solid waste as well as upgrading of weak gas resources.

Radial Profiles of Particle Velocity in a Large Scale CFB Downer

2004 ◽  
Vol 2 (1) ◽  
Author(s):  
Zhen Qian ◽  
Minghui Zhang ◽  
Hao Yu ◽  
Fei Wei
Keyword(s):  
Particle Velocity ◽  
Large Scale ◽  
Circulating Fluidized Bed ◽  
Scale Up ◽  
Radial Profile ◽  
Small Scale ◽  
Wall Region ◽  
Radial Profiles ◽  
Peak Value ◽  
Near Wall

Radial profiles of particle velocity in a large scale (418 mm I.D.) downward Circulating Fluidized Bed (CFB downer) were obtained via a Laser Doppler Velocimetry (LDV) system. Results show that particle velocity is gradually increasing along the radial direction and there exists a peak value in the near wall region. Such unique radial profile shape can be explained by the solids accumulating trend in the near wall region of the downer. Experiment results in this large scale downer are also compared with those obtained by other researchers in small scale units so as to investigate the scale-up effect on the radial particle velocity distribution in the downer.

scholarly journals European Project ATLAS+: Small and Large Scale Ductile Tearing Experiments on Ferritic Steel WB36 to Study Transferability of Material Ductile Properties

2019 ◽  
Author(s):  
Anna Dahl ◽  
Dominique Moinereau ◽  
Patrick Le Delliou ◽  
Willy Vincent
Keyword(s):  
Ferritic Steel ◽  
Large Scale ◽  
Structural Integrity ◽  
Assessment Tools ◽  
Test Facility ◽  
Small Scale ◽  
Feed Water ◽  
Ductile Tearing ◽  
Integrity Assessment ◽  
European Project

Abstract The 4-years European project ATLAS+ (Advanced Structural Integrity Assessment Tools for Safe long Term Operation) has been launched in June 2017. One of its objectives is to study the transferability of material ductile properties from small scale specimens to large scale components and validate some advanced tools for structural integrity assessment. The study of properties transferability is based on a wide experimental programme which includes a full set of fracture experiments conducted on conventional fracture specimens and large scale components (mainly pipes). Three materials are considered in the programme : a ferritic steel WB36 typical from secondary feed water line in German PWR reactors, an aged stainless steel austenitic weld representative of EPR design and a typical VVER austenitic dissimilar weld (DMW). This paper describes the experimental work conducted on the ferritic steel WB 36 (15NiCuMoNb5) and summarizes the experimental results available after 2 years of work. Numerous mechanical tests have been conducted on a wide panel of fracture mechanics specimens for a full characterization of the ferritic steel: Tensile properties, Hardness, Charpy Energy, pre-cracked Charpy PCC, Master curve on CT and SENT specimens, ductile tearing properties on CT and SENT specimens. In parallel, it is planned to test three 4PB large scale tests on pipings (FP1, FP2 and FP3) at room temperature on the EDF test facility with 3 configurations (shape, size and location) of cracks: through wall crack (TWC), internal and external ½ elliptical cracks. Progress of these large scale experiments is described including first results.

scholarly journals A MODIFIED TWO-SCALE MICROWAVE SCATTERING MODEL FOR A GAUSSIAN-DISTRIBUTED CONDUCTING ROUGH SURFACE

2018 ◽  
Vol XLII-3 ◽  
pp. 2141-2146
Author(s):  
F. Yu ◽  
H. Wang ◽  
Z. Y. Chen
Keyword(s):  
Surface Roughness ◽  
Rough Surface ◽  
Large Scale ◽  
Incident Angle ◽  
Wavelet Packet ◽  
Small Scale ◽  
Backscattering Coefficient ◽  
Microwave Scattering ◽  
Scattering Model ◽  
Scale Roughness

A modified two-scale microwave scattering model (MTSM) was presented to describe the scattering coefficient of natural rough surface in this paper. In the model, the surface roughness was assumed to be Gaussian so that the surface height <i>z(x, y)</i> can be split into large-scale and small-scale components relative to the electromagnetic wavelength by the wavelet packet transform. Then, the Kirchhoff Model (KM) and Small Perturbation Method (SPM) were used to estimate the backscattering coefficient of the large-scale and small-scale roughness respectively. Moreover, the ‘tilting effect’ caused by the slope of large-scale roughness should be corrected when we calculated the backscattering contribution of the small-scale roughness. Backscattering coefficient of the MTSM was the sum of backscattering contribution of both scale roughness surface. The MTSM was tested and validated by the advanced integral equation model (AIEM) for dielectric randomly rough surface, the results indicated that, the MTSM accuracy were in good agreement with AIEM when incident angle was less than 30&amp;deg; (<i>&amp;theta;<sub>i</sub></i>&amp;thinsp;&amp;lt;30&amp;deg;) and the surface roughness was small (<i>ks</i>&amp;thinsp;=&amp;thinsp;0.354).

Large-Scale Rig for the Characterization of DCC at Sub-Atmospheric Pressure

2020 ◽  
Author(s):  
R. Lo Frano ◽  
A. Pesetti ◽  
D. Aquaro ◽  
M. Olcese
Keyword(s):  
Atmospheric Pressure ◽  
Large Scale ◽  
Fusion Reactor ◽  
Scale Up ◽  
Small Scale ◽  
Vacuum Vessel ◽  
Steam Condensation ◽  
Main Components ◽  
Under Construction ◽  
Experimental Rig

Abstract The Direct Contact Condensation (DCC) is the main phenomenon characterizing the steam condensation. It plays an important role for the operation of Vacuum Vessel Pressure Suppression System (VVPSS) tanks, particularly for managing the Ingress of Coolant Event (determining fusion reactor overpressurization). It is safety relevant (key) system of the fusion reactor because by condensing the steam generated during such accident event allows to damp the overpressure. This paper deals with experimental and theoretical analyses of the DCC at sub-atmospheric pressure. The similitude analysis was elaborated to scale up the experimental results obtained in the reduced scale facility: similitude laws are used for the design of large experimental rig. Correlations are defined starting from the water temperature and pressure variation already obtained in the small-scale rig. Furthermore, the experimental rig and its main components accordingly designed (and under construction at the University of Pisa) allow to study at large scale the steam condensation. The testing conditions are presented and discussed.

scholarly journals Scaling the INGO: What the Development and Expansion of Canadian INGOs Tells Us

2020 ◽  
Vol 9 (8) ◽  
pp. 140
Author(s):  
Logan Cochrane ◽  
John-Michael Davis
Keyword(s):  
Large Scale ◽  
Scale Up ◽  
Critical Factor ◽  
Individual Case ◽  
Government Funding ◽  
Future Research ◽  
Small Scale ◽  
Non Governmental Organizations ◽  
Original Dataset ◽  
Organizational Age

The literature on international non-governmental organizations (INGOs) has focused primarily on large INGOs, which capture the majority of total INGO spending but represent a small number of total INGOs. Over the past two decades, the number of INGOs has more than tripled throughout the global North, which has ushered in a decentralization of the sector as an emerging class of small- and medium-sized INGOs increasingly share the same space once occupied solely by large INGOs. This study focuses on these INGOs in transition to explore how they differ from large INGOs that receive significant government funding and their pathways to scale. Using an original dataset of 1371 Canadian INGOs, we explored comparative differences related to funding sources, overhead, organizational age, country coverage, staff, and religion between the transitioning and small-scale INGOs. Our results identified several general insights for how INGOs transition: (1) Large INGOs are less likely to articulate a religious motivation, which may impede government funding; (2) INGOs are more likely to be headquartered in Ontario, which is closer to federal government offices; (3) low overhead expenditures inhibit small-scale INGOs from transitioning to medium- and large-scale INGOs; (4) organizational age plays a critical factor to scale-up as INGOs increase their experience and expertise; (5) generous compensation to attract talented staff offers an under-valued pathway to scale. Finally, our results demonstrate the diversity among INGOs in Canada and problematizes singular scale-up pathways, while underscoring the necessity of future research to explore scaling strategies through individual case studies.

scholarly journals Modeling surface-roughness/solar-ablation feedback: application to small-scale surface channels and crevasses of the Greenland ice sheet

2011 ◽  
Vol 52 (59) ◽  
pp. 99-108 ◽  
Author(s):  
L. Maclagan Cathles ◽  
Dorian S. Abbot ◽  
Jeremy N. Bassis ◽  
Douglas R. MacAyeal
Keyword(s):  
Surface Roughness ◽  
Solar Radiation ◽  
Solar Energy ◽  
Large Scale ◽  
Ice Sheet ◽  
Greenland Ice Sheet ◽  
Ablation Rate ◽  
Small Scale ◽  
Universal Curve ◽  
Roughness Effects

AbstractSurface roughness enhances the net ablation rate associated with direct solar radiation relative to smooth surfaces, because roughness allows solar energy reflected from one part of the surface to be absorbed by another part. In this study we examine the feedback between solar-radiation-driven ablation and growth of surface roughness on the Greenland ice sheet, using a numerical model of radiative transfer. Our experiments extend previous work by examining: (1) the effects of diurnal and seasonal variation of solar zenith angle and azimuth relative to incipient roughness features, (2) the evolution of roughness geometry in response to radiatively driven ablation and (3) the relative solar energy collection efficiencies of various roughness geometries and geographic locations and orientations. A notable result of this examination is that the time evolution of the aspect ratio of surface features under solar-driven ablation collapses onto a roughly universal curve that depends only on latitude, not the detailed shape of the feature. The total enhancement of surface melt relative to a smooth surface over a full ablation season varies with this ratio, and this dependence suggests a way to parameterize roughness effects in large-scale models that cannot treat individual roughness features. Overall, our model results suggest that surface roughness at the latitudes spanned by the Greenland ice sheet tends to dissipate as the ablation season progresses.

scholarly journals STUDY THE GROWTH KINETICS OF PEDIOCOCCUS ACIDILACTICI WITH ESTIMATION OF KINETIC PARAMETERS AND APPLIED IN LARGE SCALE PEDIOCIN PRODUCTION

2016 ◽  
Vol 9 (5) ◽  
pp. 130
Author(s):  
Barnali Mandal
Keyword(s):  
Experimental Data ◽  
Lactic Acid ◽  
Kinetic Parameters ◽  
Growth Kinetics ◽  
Large Scale ◽  
Scale Up ◽  
Small Scale ◽  
Pediococcus Acidilactici ◽  
Monod Model ◽  
Kinetics Of

ABSTRACTObjectives: The aim of the study was to determine the growth kinetics of Pediococcus acidilactici using a mathematical model for large scale pediocinproduction.Methods: Growth kinetics of P. acidilactici has been studied for pediocin production in small scale batch fermenter (Erlenmeyer flask) using meatprocessing waste medium. The experiments have been conducted with varying the concentrations of glucose, protein, and lactic acid. A mathematicalmodel has been developed to describe growth rate, products (pediocin and lactic acid) formation rate, and substrates (glucose and protein) utilizationrate. Monod model for dual substrates (glucose and protein) has been used with considering lactic acid inhibition. Luedeking-Piret model has beenintroduced to describe the production of pediocin and lactic acid.Results: The values of kinetic parameters have been determined using experimental data and model equations. The model prediction has beencompared satisfactorily with the experimental data for the validation of the model.Conclusions: The developed model was satisfactorily validated to scale up the production of pediocin.Keywords: Pediococcus acidilactici, Pediocin, Meat processing waste, Monod model, Luedeking-Piret model, Kinetic parameters.

Sign in / Sign up

Export Citation Format

Share Document