HEAT-RESISTANT CONCRETE BASED ON ORTHOPHOSPHORIC ACID, WASTE OF NON-FERROUS METALLURGY AND CHEMICAL INDUSTRY

2021 ◽  
Vol 12 (1) ◽  
pp. 72-85
Author(s):  
V. Z Abdrakhimov ◽  
E. S Abdrakhimov

Currently, as numerous studies show, raw natural resources are running out, so it is necessary to involve in the production turnover of industrial waste for the manufacture of heat-resistant concrete. At the same time, the costs of geological exploration, construction and operation of quarries are excluded, and significant land plots are freed from the impact of negative anthropogenic factors. Multi-tonnage waste of non-ferrous metallurgy-ferrite-calcium slag containing 50-51 % Fe2O3, was used as an iron-containing filler for the production of heat-resistant concretes. Ferrite-calcium slag is a man-made raw material (production waste) of processing copper-zinc concentrates, obtained by slow cooling of the material to complete scattering, light yellow in color and resembling fine sand. The trivalent iron oxide Fe2O3 contained in the slag reacts very slowly with orthophosphoric acid H3PO4 at normal temperature; therefore, it is necessary to heat the mixture to 70 °C, since its own heat is not released by the reaction. A, the ferrous iron oxide FeO contained in the slag, as well as Fe(OH)3 hydroxide, on the contrary, reacts with the acid vigorously, releasing a significant amount of heat, so the binder dough begins to set after 2 minutes at a temperature of 20 °C due to significant heat release. Chemical industry waste - the spent IM-2201 catalyst was used as an aluminum-containing raw material and is a fine powder with a specific surface area of up to 8000 cm2/g and a fire resistance of up to 2000 oС. Studies have shown that due to the use of orthophosphoric acid as a binder, it is possible to dispose of up to 80-90 % of non-ferrous metallurgy and chemical industry waste and at the same time obtain heat-resistant concretes with high physical and mechanical properties.

2011 ◽  
Vol 479 ◽  
pp. 8-12 ◽  
Author(s):  
Gang Yang ◽  
Zheng Dong Liu ◽  
Shi Chang Cheng ◽  
Mu Xin Yang

The mechanism of brittleness due to slow cooling during quenching was experimentally investigated in 12% Cr martensitic heat resistant steel. The mechanical property tests and microstructural characterization by SEM、TEM and XRD were conducted. The results showed the impact toughness would decrease with the slowing of cooling rate during quenching, and the low cooling rate within the temperature range from 820 to 660 °C played a significant effect on the impact toughness . Different from the mechanism of temper brittleness, the main causes of embrittlement due to the slow cooling upon quenching were both the continuous precipitation of M23C6 along prior austenite grain boundaries during the process of slow cooling and that of M2C along prior residual austenite film during tempering, and this kind of quench brittleness was nonreversal.


2018 ◽  
Vol 196 ◽  
pp. 04010
Author(s):  
Aleksey Khlystov ◽  
Vladimir Shirokov ◽  
Elena Vlasova

The article provides information on industrial waste generation at enterprises of the Samara region, suitable for use as raw materials components of such heat-resistant composites as solutions, concretes, gun mixes, coatings. The research indicates rational ways of some heat-resistant binders application for utilization of mineral high-melting and heat-resistant industrial wastes. It proves that the enrichment of certain types of industrial waste, i.e. bringing the chemical composition of their components to the required state, allowed to expand the raw material base for the synthesis of heat-resistant binders and concrete in general. The use of sludge waste in the processes of synthesizing liquid phosphate binders allowed to obtain such effective binders as aluminophosphates and aluminocalciumphosphates. The research proves that application of technogenic wastes of non-ferrous metallurgy enterprises allows to receive heat-resistant materials solutions, concretes, coatings, gun mixes which characteristics are similar to their industrial analogues.


2010 ◽  
Vol 160-162 ◽  
pp. 373-378
Author(s):  
Jing Lan Hong ◽  
Xiang Zhi Li

A life cycle assessment was carried out to estimate the environmental impact of industry waste as aggregate in cement production. To confirm and add credibility to the study, an uncertainty analysis was also carried out. Results showed the impact seen from climate change, human toxicity, marine eutrophication, marine ecotoxicity, and freshwater eutrophication categories had an important contribution to overall environmental impact, due to energy use and direct emissions from clinker and limestone production stages. The most significant substances contribute to the climate change is CO2 to air; for the human toxicity, it is Hg to air and Mn to water; for the marine eutrophication and marine ecotoxicity, it is nitrate and Ni to water, respectively; for the freshwater eutrophication, it is phosphorus to water. Increasing electricity recovery rate, optimizing the raw material consumption for clinker production are highly recommended to reduce the adverse impact on the environment, and therefore reduce the pressure on the environment from dramatically increased hazardous industry waste disposal.


2021 ◽  
Vol 93 (1) ◽  
pp. 96-105
Author(s):  
B.Z. ABDRAKHIMOV ◽  
◽  
E.S. ABDRAKHIMOVA ◽  

In this work, using waste from the chemical industry — aluminum-containing nanotechnogenic raw materials and a fuel and energy complex — coal enrichment based on phosphate binders, heat-resistant concrete with high physical and mechanical properties is obtained. Thanks to the use of orthophosphoric acid as a binder, it was possible to utilize 80-90% of chemical industry waste and coal preparation, which helps to reduce the anthropogenic load on the environment and humans. Studies show that as the grain size decreases, the total size of the interface is increased, the average radius of curvature of the convex sections decreases, their excess surface energy grows, and the distances between the sources and absorbers of vacancies in the system decrease. Experimental studies and rich practical experience in ceramic industries confirm the crucial role of the degree of grinding (or the use of nanoscale raw materials). Due to the action of this factor alone, it is possible in some cases to reduce the required sintering temperature by 50-100 °C or more. The use of industrial wastes in the production of building materials contributes to: a) the utilization of industrial wastes; b) environmental protection; b) the expansion of the raw material base for heat-resistant concrete based on phosphate binders.


2020 ◽  
pp. 109-130
Author(s):  
Elizaveta Rastyannikova ◽  

Since the beginning of the XXI century, the raw material of non-ferrous metallurgy began to acquire new outlines. First, due to the growing demand for resources from the rapidly developing countries of Asia (China, India, South Korea), the volume of world production and international flows of both raw ore and ore dressing – concentrates have increased. Secondly, the concentration of countries that produce raw materials on the one hand and consume them on the other has increased. The article is devoted to comparative statistical analysis of international flows of raw materials of non-ferrous metals. The leading countries in the world exporting non-ferrous metal ores and countries importing them have been identified. The impact of new applications of non-ferrous metals on increasing international trade, such as the expansion of the production of batteries for electromobile and consumer electronics, the development of nuclear energy, etc., is highlighted.


2018 ◽  
Vol 6 (10) ◽  
Author(s):  
Hosam Zaghloul ◽  
Doaa A. Shahin ◽  
Ibrahim El- Dosoky ◽  
Mahmoud E. El-awady ◽  
Fardous F. El-Senduny ◽  
...  

Antisense oligonucleotides (ASO) represent an attractive trend as specific targeting molecules but sustain poor cellular uptake meanwhile superparamagnetic iron oxide nanoparticles (SPIONs) offer stability of ASO and improved cellular uptake. In the present work we aimed to functionalize SPIONs with ASO targeting the mRNA of Cyclin B1 which represents a potential cancer target and to explore its anticancer activity. For that purpose, four different SPIONs-ASO conjugates, S-M (1–4), were designated depending on the sequence of ASO and constructed by crosslinking carboxylated SPIONs to amino labeled ASO. The impact of S-M (1–4) on the level of Cyclin B1, cell cycle, ROS and viability of the cells were assessed by flowcytometry. The results showed that S-M3 and S-M4 reduced the level of Cyclin B1 by 35 and 36%, respectively. As a consequence to downregulation of Cyclin B1, MCF7 cells were shown to be arrested at G2/M phase (60.7%). S-M (1–4) led to the induction of ROS formation in comparison to the untreated control cells. Furthermore, S-M (1–4) resulted in an increase in dead cells compared to the untreated cells and SPIONs-treated cells. In conclusion, targeting Cyclin B1 with ASO-coated SPIONs may represent a specific biocompatible anticancer strategy.


2015 ◽  
Vol 26 (3-4) ◽  
pp. 116-123
Author(s):  
A. P. Korzh ◽  
T. V. Zahovalko

Recently, the number of published works devoted to the processes of synanthropization of fauna, is growing like an avalanche, which indicates the extreme urgency of this theme. In our view, the process of forming devices to coexist with human and the results of his life reflects the general tandency of the modern nature evolution. Urbanization is characteristic for such a specific group of animals like amphibians, the evidence of which are numerous literature data. Many researchers use this group to assess the bioindicative quality of the environment. For this aim a variety of indicators are used: from the cellular level of life of organization up to the species composition of the group in different territories. At the same time, the interpretation of the results is not always comparable for different areas and often have significantly different interpretations by experts. Urban environment, primarily due to the contamination is extremely aggressive to amphibians. As a consequence, the urban populations of amphibians may be a change in the demographic structure, affecting the reproductive ability of the population, the disappearance of the most sensitive species or individuals, resizing animals, the appearance of abnormalities in the development, etc. At the same time play an important amphibians in the ecosystems of cities, and some species in these conditions even feel relatively comfortable. Therefore, it is interesting to understand the mechanisms of self-sustaining populations of amphibians in urban environments. To assess the impact of natural and anthropogenic factors on the development of amphibian populations were used cognitive modeling using the program Vensim PLE. Cognitive map of the model for urban and suburban habitat conditions were the same. The differences concerned the strength of connections between individual factors (migration, fertility, pollution) and their orientation. In general, factors like pollution, parasites, predators had negative impact on the population, reducing its number. The birth rate, food and migration contributed to raising number of individuals. Some of the factors affected on the strength to of each other as well: the majority of the factors affected the structure of the population, had an influence on the fertility. Thanks to it the model reflects the additive effect of complex of factors on the subsequent status of the population. Proposed and analyzed four scenarios differing strength and duration of exposure. In the first scenario, a one-time contamination occurs and not subsequently repeated. The second and third scenario assumes half board contamination, 1 year (2 scenario) and two years (scenario 3). In the fourth scenario, the pollution affected the population of amphibians constantly. In accordance with the results of simulation, much weaker than the natural populations respond to pollution - have them as an intensive population growth and its disappearance at constant pollution is slow. Changes to other parameters of the model showed that this pollution is the decisive factor -only the constant action leads to a lethal outcome for the populations. All other components of the model have a corrective effect on the population dynamics, without changing its underlying trand. In urban areas due to the heavy impact of pollution maintaining the population is only possible thanks to the migration process – the constant replenishment of diminishing micropopulations of natural reserves. This confirms the assumption that the form of existence metapopulations lake frog in the city. In order to maintain the number of amphibians in urban areas at a high level it is necessary to maintain existing migration routes and the creation of new ones. Insular nature of the placement of suitable habitats in urban areas causes the metapopulation structure of the types of urbanists. Therefore, the process of urbanization is much easier for those species whicht are capable of migration in conditions of city. In the initial stages of settling the city micropopulationis formed by selective mortality of the most susceptible individuals to adverse effects. In future, maintaining the categories of individuals is provided mainly due to migration processes metapopulisation form of the species of existence is supported). It should be noted that the changes in the previous levels are always saved in future. In the case of reorganizations of individuals we of morphology can assume the existence of extremely adverse environmental conditions that threaten the extinction of the micropopulations. 


2020 ◽  
Vol 8 (8) ◽  
pp. 1527-1544
Author(s):  
I.L. Ryabkov ◽  
N.N. Yashalova

Subject. The article focuses on market strategies of the Russian enterprises operating in the ferrous metallurgy. Objectives. The study is to analyze corporate strategies the leading ferrous metal manufacturers use in the Russian Federation, such as NLMK Group, Severstal, Magnitogorsk Iron & Steel Works, EVRAZ Group. Methods. The study interprets public financial statements and methods of the logic, intuitive and comparative analysis. Results. We analyze market strategies of the Russian metal manufacturers, determine their development priorities and competitive advantages and weaknesses. We describe the impact of various threats and measures metallurgical companies undertake to eliminate them. Conclusions and Relevance. We sorted out possible threats and exposures of the Russian metallurgic companies' economic security and traced the dynamics of their significance for 2015 to 2019. Key threats relate to policies, economy, external and internal market, regulations and laws, production, distribution and financial management, consumption, IT, social welfare and environment.


Author(s):  
I. Saakian ◽  
Aleksandr, Grigor’ev ◽  
E. Kravets ◽  
E. Rudakov ◽  
A. Faddeev ◽  
...  

Выполнен анализ действующей редакции Методики разработки нормативов допустимых сбросов веществ и микроорганизмов в водные объекты для водопользователей , утвержденной приказом Минприроды России от 17 декабря 2007 г. 333, на предмет непротиворечивости и соответствия нормам водоохранного законодательства. Выявлена неопределенность применения Методики в условиях воздействия на качество воды природных и антропогенных факторов, не зависящих от конкретного водопользователя. Положения Методики противоречат принципам нормирования воздействия на водные объекты на основе наилучших доступных технологий, что было показано на примерах утвержденных технологических показателей содержания загрязняющих веществ в сточных водах различных отраслей промышленности. Анализ системы нормирования допустимых воздействий на водные объекты и географической дифференциации нормативов качества воды в пределах Российской Федерации вместе с системой целевых показателей качества воды также показал несоответствие Методики основным принципам водоохранного законодательства.The analysis of the current edition of the Methods of developing standards for permissible discharges of substances and microorganisms into water bodies for water users , approved by the Order of the Ministry of Natural Resources of Russia dated December 17, 2007 No. 333 for consilience and compliance with the regulations of the water protection legislation, is carried out. Uncertainty of the application of the Methods in the conditions of the impact of natural and anthropogenic factors that are independent of a specific water user on the quality of water has been identified. The provisions of the Methods contradict the principles of regulating the impact on water bodies based on the best available technologies shown on the examples of approved process indicators of the concentrations of various industrial pollutants in wastewater. An analysis of the system of regulating the permissible impact on water bodies and the geographical differentiation of water quality standards within the boundaries of the Russian Federation, together with the system of water quality targets, also showed that the Methods do not comply with the basic principles of the water protection legislation.


Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 779
Author(s):  
Mohamed Gomah ◽  
Guichen Li ◽  
Salah Bader ◽  
Mohamed Elkarmoty ◽  
Mohamed Ismael

The awareness of the impact of high temperatures on rock properties is essential to the design of deep geotechnical applications. The purpose of this research is to assess the influence of heating and cooling treatments on the physical and mechanical properties of Egyptian granodiorite as a degrading factor. The samples were heated to various temperatures (200, 400, 600, and 800 °C) and then cooled at different rates, either slowly cooled in the oven and air or quickly cooled in water. The porosity, water absorption, P-wave velocity, tensile strength, failure mode, and associated microstructural alterations due to thermal effect have been studied. The study revealed that the granodiorite has a slight drop in tensile strength, up to 400 °C, for slow cooling routes and that most of the physical attributes are comparable to natural rock. Despite this, granodiorite thermal deterioration is substantially higher for quick cooling than for slow cooling. Between 400:600 °C is ‘the transitional stage’, where the physical and mechanical characteristics degraded exponentially for all cooling pathways. Independent of the cooling method, the granodiorite showed a ductile failure mode associated with reduced peak tensile strengths. Additionally, the microstructure altered from predominantly intergranular cracking to more trans-granular cracking at 600 °C. The integrity of the granodiorite structure was compromised at 800 °C, the physical parameters deteriorated, and the rock tensile strength was negligible. In this research, the temperatures of 400, 600, and 800 °C were remarked to be typical of three divergent phases of granodiorite mechanical and physical properties evolution. Furthermore, 400 °C could be considered as the threshold limit for Egyptian granodiorite physical and mechanical properties for typical thermal underground applications.


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