scholarly journals INFLUENCE OF THE ANIONIC COMPOSITION AND ACID GAS CONTENT IN FORMATION WATERS OF PERM KRAI FIELDS ON CORROSION INHIBITOR EFFECTIVENESS

2020 ◽  
Vol 20 (2) ◽  
pp. 192-200
Author(s):  
Aleksandr N. Ladygin ◽  
Keyword(s):  
Hydrogen Sulfide ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Phase Interface ◽  
Chloride Ions ◽  
Gas Content ◽  
Water Volume ◽  
Acid Gases ◽  
Equipment Corrosion ◽  
The Impact

In the course of hydrocarbon deposit development, formation water starts entering the wells over time. An increasing produced water volume has a negative impact on economic indicators of oilfield developments and leads to other hazardous consequences, such as equipment corrosion. Downhole equipment corrosion causes largest financial losses, since well accidents entail expensive repairs. Therefore, it is critical to prevent the equipment corrosion. The study considers main properties and composition of formation waters. Based on an overview of open literature sources, we analyzed the impact of Cl–, SO4 –2, HCO3 – anions contained in the formation waters on corrosion process kinetics at the phase interface between metal (electrode) and water (electrolyte). The study also discusses the results of researches on the influence of dissolved acid gases (H2S and CO2) on corrosion mechanisms and rates. An influence of pH value on the corrosion rate is considered. Contents of various salts in the formation waters contribute to the complexity of corrosion processes occurring in real conditions. Presence of aggressive environments can accelerate corrosion in some instances, but sometimes it can slow it down; this fact also affects the inhibitor protection effectiveness. Based on laboratory analysis data, effectiveness of using the corrosion inhibitor in the formation waters with different compositions and properties is assessed. It has been established that presence of a mix of aggressive components – chloride ions and hydrogen sulfide – in the formation waters causes hydrogen sulfide corrosion inhibition and reduction of chloride corrosion rate. Presence of dissolved salt ions and acid gases in the formation waters improves effectiveness of the corrosion inhibitors due to strong passive films formed on steel equipment surfaces.

scholarly journals Assessing the Impact of DMAs and the Use of Boosters on Chlorination in a Water Distribution Network in Greece

Water ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2141
Author(s):  
Stavroula Tsitsifli ◽  
Vasilis Kanakoudis
Keyword(s):  
Water Distribution ◽  
Distribution Network ◽  
Water Distribution Network ◽  
Assessment Process ◽  
Water Volume ◽  
Pressure Management ◽  
Water Age ◽  
Chlorination Process ◽  
Management Measures ◽  
The Impact

Disinfection is one of the most important water treatment processes as it inactivates pathogens providing safe drinking water to the consumers. A fresh-water distribution network is a complex system where constant monitoring of several parameters and related managerial decisions take place in order for the network to operate in the most efficient way. However, there are cases where some of the decisions made to improve the network’s performance level, such as reduction of water losses, may have negative impacts on other significant operational processes such as the disinfection. In particular, the division of a water distribution network into district metered areas (DMAs) and the application of various pressure management measures may impact the effectiveness of the water chlorination process. Two operational measures are assessed in this paper: (a) the use of inline chlorination boosters to achieve more efficient chlorination; and (b) how the DMAs formation impacts the chlorination process. To achieve this, the water distribution network of a Greek town is chosen as a case study where several scenarios are being thoroughly analyzed. The assessment process utilizes the network’s hydraulic simulation model, which is set up in Watergems V8i software, forming the baseline to develop the network’s water quality model. The results proved that inline chlorination boosters ensure a more efficient disinfection, especially at the most remote parts/nodes of the network, compared to conventional chlorination processes (e.g., at the water tanks), achieving 100% safe water volume and consuming almost 50% less chlorine mass. DMAs’ formation results in increased water age values up to 8.27%, especially at the remote parts/nodes of the network and require more time to achieve the necessary minimum effective chlorine concentration of 0.2 mg/L. However, DMAs formation and pressure management measures do not threaten the chlorination’s efficiency. It is important to include water age and residual chlorine as criteria when optimizing water pressure and the division of DMAs.

A New Integrated Grey Water Footprint Assessment Method

2015 ◽  
Vol 671 ◽  
pp. 412-418
Author(s):  
Lu Lu Xu ◽  
Li Zhu Chen ◽  
Hugh Gong ◽  
Xue Mei Ding
Keyword(s):  
Water Footprint ◽  
Ecological Impact ◽  
Water Environment ◽  
Assessment Method ◽  
Water Volume ◽  
Accurate Assessment ◽  
Ambient Water ◽  
Grey Water ◽  
The Impact ◽  
Comprehensive Indicator

Water footprint is a volumetric indicator of freshwater appropriation. The grey water footprint (GWF) provides a tool to assess the water volume needed to assimilate a pollutant. However, evaluating the impact on water environment cannot rely solely on volumetric consumption of freshwater. It demands accurate assessment criteria to reflect its environmental and ecological effects on ambient water resource. In this paper, a new assessment method is proposed: the effluent toxicity and the Potential Eco-toxic Effects Probe (PEEP) index of aquatic environment are taken into consideration. This method provides a comprehensive indicator for evaluating water footprint, specified in effluents’ ecological impact on ambient water sources.

Test and Study on Impact of Corrosion on Bond Force between Steel and Concrete

2010 ◽  
Vol 36 ◽  
pp. 176-181
Author(s):  
Xian Feng He ◽  
Shou Gang Zhao ◽  
Yuan Bao Leng
Keyword(s):  
Reinforced Concrete ◽  
Corrosion Rate ◽  
Concrete Structure ◽  
Steel Corrosion ◽  
Reinforced Concrete Structure ◽  
Bond Force ◽  
Steel Bars ◽  
Protection Layer ◽  
Corrosion Of Steel ◽  
The Impact

The corrosion of steel will have a bad impact on the safety of reinforced concrete structure. In severe cases, it may even be disastrous. In order to understand the impact of steel corrosion on the structure, tests are carried out to study corrosion and expansion rules of steel bars as well as the impact rules of corrosion on bond force between steel and concrete. The results show that wet and salty environment will result in steel corrosion; relatively minor corrosion will not cause expansion cracks of protection layers; when steel rust to a certain extent, it will cause cracks along the protection layer; when there exists minor corrosion in steel and the protection layer does not have expansion cracks, the bond force is still large and rapidly decreases as the corrosion rate increases.

The Application of Corrosion and Scale Inhibitor to Circulating Water

2012 ◽  
Vol 610-613 ◽  
pp. 2591-2594
Author(s):  
Jia Guo Ren ◽  
Qian Qian Wu
Keyword(s):  
Water Treatment ◽  
Power Plant ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Economic Efficiency ◽  
Concentration Ratio ◽  
Scale Inhibitor ◽  
Circulating Water

According to the requirements of the circulating water treatment, a corrosion and scale inhibitor which compounded several single corrosion inhibitor and scale inhibitor was prepared, resulting in simplifying the process of operation, improving the concentration ratio of circulating water from 2.2 to 2.8, reducing the sewage volume, and decreasing the corrosion rate and cohesion rate. Therefore, the economic efficiency of the power plant gets greatly improved.

scholarly journals In vitro anticancer activity of hydrogen sulfide and nitric oxide alongside nickel nanoparticle and novel mutations in their genes in CRC patients

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Zjwan Housein ◽  
Tayeb Sabir Kareem ◽  
Abbas Salihi
Keyword(s):  
Nitric Oxide ◽  
Cell Proliferation ◽  
Hydrogen Sulfide ◽  
Direct Sequencing ◽  
Scorpion Venom ◽  
Enos Gene ◽  
Cytotoxic Activities ◽  
No Donors ◽  
The Impact

AbstractThis study was carried out to assess the impact of nickel nanoparticles (NiNPs) as well as scorpion venom on colorectal cancer (CRC) cells in the presence and/or absence of 5-fluorouracil (5-FU), hydrogen sulfide (H2S), and nitric oxide (NO) donors and to determine alterations in endothelial NO synthase (eNOS) and cystathionine γ-lyase (CSE) enzyme-producing genes in CRC patients. The IC50 of both H2S and NO donors, along with NiNPs, were determined. The CRC cells were treated for 24hrs, and the cytotoxic activities were assessed using the MTT test. Moreover, the apoptosis was determined after 24hrs and 48hrs using TUNEL assay. Furthermore, the mutations in the eNOS gene (intron 4, -786T>C and 894 G>T) and CSE gene (1364GT) were determined using direct sequencing. The IC50 values for sodium disulfide (Na2S) and sodium nitroprusside (SNP) at 24hrs treatment were found to be 5 mM and 10−6 M, respectively, while the IC50 value for 5-FU was reached after 5-days of treatment in CRC cell line. Both black and yellow scorpion venoms showed no inhibition of cell proliferation after 24hrs treatment. Furthermore, Na2S showed a significant decrease in cell proliferation and an increase in apoptosis. Moreover, a co-treatment of SNP and 5-FU resulted in inhibition of the cytotoxic effect of 5-FU, while a combination treatment of NiNPs with Na2S, SNP, and 5-FU caused highly significant cytotoxicity. Direct sequencing reveals new mutations, mainly intronic variation in eNOS gene that has not previously been described in the database. These findings indicate that H2S promotes the anticancer efficiency of 5-FU in the presence of NiNPs while NO has antiapoptotic activity in CRC cell lines.

scholarly journals Hyaluronan and the Fascial Frontier

2021 ◽  
Vol 22 (13) ◽  
pp. 6845
Author(s):  
Rebecca L. Pratt
Keyword(s):  
Nerve Fibers ◽  
The Body ◽  
Water Volume ◽  
Cell Behavior ◽  
Connective Tissues ◽  
Wide Range ◽  
The World ◽  
Extracellular Microenvironment ◽  
The Impact ◽  
The Relationship

The buzz about hyaluronan (HA) is real. Whether found in face cream to increase water volume loss and viscoelasticity or injected into the knee to restore the properties of synovial fluid, the impact of HA can be recognized in many disciplines from dermatology to orthopedics. HA is the most abundant polysaccharide of the extracellular matrix of connective tissues. HA can impact cell behavior in specific ways by binding cellular HA receptors, which can influence signals that facilitate cell survival, proliferation, adhesion, as well as migration. Characteristics of HA, such as its abundance in a variety of tissues and its responsiveness to chemical, mechanical and hormonal modifications, has made HA an attractive molecule for a wide range of applications. Despite being discovered over 80 years ago, its properties within the world of fascia have only recently received attention. Our fascial system penetrates and envelopes all organs, muscles, bones and nerve fibers, providing the body with a functional structure and an environment that enables all bodily systems to operate in an integrated manner. Recognized interactions between cells and their HA-rich extracellular microenvironment support the importance of studying the relationship between HA and the body’s fascial system. From fasciacytes to chronic pain, this review aims to highlight the connections between HA and fascial health.

Discussion of Oxygen Threshold Level for Corrosion Management in Seawater Injection Systems

2021 ◽  
Author(s):  
Jean Vicente Ferrari
Keyword(s):  
Corrosion Rate ◽  
Oxygen Reduction ◽  
Water Injection ◽  
Steel Corrosion ◽  
Threshold Level ◽  
International Standards ◽  
Limiting Current ◽  
Order Of Magnitude ◽  
The Impact ◽  
Oxygen Concentrations

Abstract Generally, in water injection systems, oxygen levels starting from around eight ppm are deoxygenated to below 50 ppm, following international standards' guidelines. This work aims to discuss the impact of such a magnitude value of oxygen contamination on steel corrosion in seawater injection systems by analysing theoretical polarisation curves and results from published works with different approaches. Corrosion models consider mass-transfer controlled diffusion of oxygen to predict the maximum steel corrosion rate, which depends on the oxygen limiting current, which in turn is strongly influenced by flow velocity. The effect of free chlorine on corrosion in seawater injection systems has also been considered and included in an oxygen equivalent parameter. In such systems, where oxygen reduction is the key cathodic reaction, the corrosion process may be under cathodic activation control, independent of flow at higher velocities or when erosion-corrosion begins. In this work, theoretical polarisation curves were constructed by using published oxygen and chlorine cathodic limiting currents (iLc) on carbon steel and a noble metal electrode, respectively. Aerated (200 ppb and 9000 ppb of oxygen) and deaerated conditions (50 ppb of oxygen) and the presence of 300 ppb of chlorine were applied to the assumed exchange current densities (io). Neutral (pH 7) and acid (pH 4) conditions (considering the presence of CO2) were also assumed to be at room temperature and pressure. Since the corrosion rate in lower oxygen concentrations (ppb order of magnitude) may result in corrosion rates of the same order of magnitude than in higher oxygen concentrations (ppm order of magnitude) when comparing and analysing results from experimental, semi-empirical or mechanistic approaches, it is necessary to weigh up the effects of both steel surface (bare or scaled/corrosion products) and flow. At oxygen concentrations below 200 ppb and under acid conditions, the contribution of H+ reduction on corrosion rate starts to be higher than oxygen reduction, mainly in the absence of chlorine.

Application of Benzotriazole Corrosion Inhibitor in Synthetic-Based Drilling Fluid and its Overall Impact in Improving Drilling Fluid Functionality

2021 ◽  
Author(s):  
Zhao Xionghu ◽  
Saviour Bassey Egwu ◽  
Deng Jingen ◽  
Miao Liujie
Keyword(s):  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Coefficient Of Friction ◽  
Hot Rolling ◽  
Drilling Fluid ◽  
Effect Of Temperature ◽  
Fluid Loss ◽  
Fluid Composition ◽  
Fluid System ◽  
Before And After

Abstract The effect of corrosion inhibitor Benzotriazole on synthetic-based mud system was studied. Rheological performance of the benzotriazole enhanced synthetic-based fluid system was studied and compared against the base mud. To study its effect on dynamic wellbore conditions, different drilling fluid compositions were placed in a hot rolling oven for 16 hours at temperatures 150 °C and 170°C and the effect of temperature on mud properties were studied. Tests carried out include rheological test (before and after hot rolling), filtrate pH, lubricity test, and fluid loss test. The corrosion penetration rate was studied using the weight loss method. Based on experiment results, the synthetic-based mud system which comprised of benzotriazole displayed a reduction in coefficient of friction up to 95.93%. At ambient condition, optimal ratio of mineral oil:benzotriazole (M:B) which gives best lubricity performance on synthetic-based mud system is 80:20. This leads to improved corrosion inhibition and lubricity of the synthetic-based fluid by reducing the coefficient of friction up to 90.13%. Increased temperature led to further decrease in coefficient of friction with a % torque reduction of 95.93 displayed by the 80:20 ratio M:B mud composition at 170 °C. Significant alterations of the mud composition rheological and fluid loss parameters before and after exposure to high temperature in hot rolling oven were not observed. pH values were maintained ≥7 at the dynamic conditions highlighting solubility of the formulated fluid composition and absence of contaminants which can pose significant threats to the rates of corrosion in drill pipes. Increasing the concentration of Benzotriazole led to a reduction in corrosion rate. However, as the temperature effect increased, the corrosion rate elevated. Based on results from this investigation, it was concluded that Benzotriazole can be applied as a corrosion inhibitor in a synthetic-based drilling fluid system as an alternative corrosion inhibitor without significant alteration of the base mud properties. Benefits of this will be the optimization of extended reach well drilling operations due to excellent lubricity performance, corrosion rate reduction, compatibility with HPHT wellbore condition and fluid loss control.

scholarly journals The impact of rotational speed and water volume on textile translational motion in a front-loading washer

2018 ◽  
Vol 89 (16) ◽  
pp. 3401-3410 ◽  
Author(s):  
Hong Liu ◽  
R Hugh Gong ◽  
Pinghua Xu ◽  
Xuemei Ding ◽  
Xiongying Wu
Keyword(s):  
Residence Time ◽  
Rotational Speed ◽  
High Speed ◽  
Translational Motion ◽  
Processing System ◽  
Water Volume ◽  
Motion Path ◽  
Rotational Axis ◽  
Passive Region ◽  
The Impact

Textile motion in a front-loading washer has been characterized via video capturing, and a processing system developed based on image geometric moment. Textile motion significantly contributes to the mass transfer of the wash solution in porous materials, particularly in the radial direction (perpendicular to the rotational axis of the inner drum). In this paper, the velocity profiles and residence time distributions of tracer textiles have been investigated to characterize the textile dynamics in a front-loading washer. The results show that the textile motion varies significantly with the water volume and rotational speed, and that the motion path follows certain patterns. Two regions are observed in the velocity plots: a passive region where the textile moves up with low velocity and an active region where the textile falls down with relatively high speed. A stagnant area in the residence time profile is observed. This corresponds to the passive region in the velocity profile. The stagnant area affects the mechanical action, thus influencing washing efficiency and textile performance. The findings on textile dynamics will help in the development of better front-loading washers.

scholarly journals Characterizing Hydrological Connectivity of Artificial Ditches in Zoige Peatlands of Qinghai-Tibet Plateau

Water ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1364 ◽  
Author(s):  
Zhiwei Li ◽  
Peng Gao ◽  
Yuchi You
Keyword(s):  
Google Earth ◽  
Tibet Plateau ◽  
Annual Rainfall ◽  
Water Volume ◽  
Hydrological Connectivity ◽  
Total Water ◽  
Zoigê Basin ◽  
The Impact ◽  
Qinghai Tibet Plateau ◽  
Peatland Degradation

Peats have the unique ability of effectively storing water and carbon. Unfortunately, this ability has been undermined by worldwide peatland degradation. In the Zoige Basin, located in the northeastern Qinghai-Tibet Plateau, China, peatland degradation is particularly severe. Although climate change and (natural and artificial) drainage systems have been well-recognized as the main factors catalyzing this problem, little is known about the impact of the latter on peatland hydrology at larger spatial scales. To fill this gap, we examined the hydrological connectivity of artificial ditch networks using Google Earth imagery and recorded hydrological data in the Zoige Basin. After delineating from the images of 1392 ditches and 160 peatland patches in which these ditches were clustered, we calculated their lengths, widths, areas, and slopes, as well as two morphological parameters, ditch density (Dd) and drainage ability (Pa). The subsequent statistical analysis and examination of an index defined as the product Dd and Pa showed that structural hydrological connectivity, which was quantitatively represented by the value of this index, decreased when peatland patch areas increased, suggesting that ditches in small patches have higher degrees of hydrological connectivity. Using daily discharge data from three local gauging stations and Manning’s equation, we back-calculated the mean ditch water depths (Dm) during raining days of a year and estimated based on Dm the total water volume drained from ditches in each patch (V) during annual raining days. We then demonstrated that functional hydrological connectivity, which may be represented by V, generally decreased when patch areas increased, more sensitive to changes of ditch number and length in larger peatland patches. Furthermore, we found that the total water volume drained from all ditches during annual raining days only took a very small proportion of the total volume of stream flow out of the entire watershed (0.0012%) and this nature remained similar for the past 30 years, suggesting that during annual rainfall events, water drained from connected ditches is negligible. This revealed that the role of connected artificial ditches in draining peatland water mainly takes effect during the prolonged dry season of a year in the Zoige Basin.

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