scholarly journals Correlations between TDS and electrical conductivity for high-salinity formation brines characteristic of South Atlantic pre-salt basins

Water SA ◽  
2020 ◽  
Vol 46 (4 October) ◽  
Author(s):  
Lucas Rego Barros Rebello ◽  
Thauara Siepman ◽  
Santiago Drexler
Keyword(s):  
Electrical Conductivity ◽  
Ionic Strength ◽  
Natural Waters ◽  
High Salinity ◽  
Petroleum Industry ◽  
Gravimetric Method ◽  
Salinity Range ◽  
Chemical Complexity ◽  
Monovalent Ions ◽  
Exponential Equations

Total dissolved solids (TDS) is an important property in the characterization of natural waters for diversified applications, such as in geochemistry and the petroleum industry. Under appropriate circumstances, the determination of this parameter through correlations with the electrical conductivity (EC) of aqueous systems yields considerable advantages over the gravimetric method. However, the development of empirical equations correlating TDS and EC is still required due to the physical-chemical complexity of charge transport in multicomponent natural waters. Most existing correlations were built considering systems in the lower or medium salinity range. In this context, this research aims to provide experimental correlations between TDS and EC in a broad concentration range for high salinity formation brines characteristic of the pre-salt reservoirs. It contributes to filling a gap in the literature for geochemical systems of this nature. Moreover, correlations were also obtained for a concentrated desulphated seawater and an aqueous sodium chloride solution in the same salinity range. For all aqueous solutions, the polynomial fittings of degree greater than one fit the experimental data better compared to both linear and exponential equations. In addition, the solutions with higher concentration of divalent ions had lower EC than the solutions dominated by monovalent ions with the same ionic strength. This evidences the effect of ion pairing on the EC, particularly in solutions of high ionic strength. Therefore, the use of a general correlation to represent solutions with dramatic variations in chemical composition carries substantial error, particularly in the high salinity range. Thus, a specific correlation must be developed to represent brines with similar composition.

Growth and Mineral Nutrition in Salt Stressed Guava ( Psidium guajava L.) cv . Allahabad Safeda

2016 ◽  
Vol 3 (1) ◽  
Author(s):  
ANSHUMAN SINGH ◽  
ASHWANI KUMAR ◽  
R.K. YADAV ◽  
ASHIM DUTTA ◽  
D.K. SHARMA
Keyword(s):  
Electrical Conductivity ◽  
Chemical Composition ◽  
Plant Height ◽  
Salinity Tolerance ◽  
Soil Ph ◽  
High Salinity ◽  
Psidium Guajava ◽  
Sodium Adsorption Ratio ◽  
Saline Soils ◽  
Experimental Soil

Guav a cv . Allahabad Safeda w as grown in saline soils and irrigated with the best av ailable w ater -1 -1 + -1 (EC 2.8 dS m ). Based on chemical composition (pH- 7.1, EC - 2.8 dS m , Na - 20.04 meq l and IW IW sodium adsorption ratio- 4.86), irrigation w ater w as categorized as marginally saline. The soil pH 2 -1 w as mostly below 8.5 but mean electrical conductivity (EC ) v alues ranged from 0.5-2 dS m 2 indicating moderate to high salinity in the experimental soil. After one-y ear of experimentation, fiv e plants randomly selected from each treatment and the data w ere recorded. Plant height -1 -1 significantly increased (LSD 5%) with increase in salinity from 0.5 dS m to 1.4 dS m . A similar -1 trend w as noted with respect to stem girth. The av erage plant height at 0.5, 0.9 and 1.4 dS m salinity lev els w as 98.3 cm, 108.3 cm and 123 cm, respectiv ely whereas the corresponding stem girth v alues -1 w ere 2.24 cm, 2.28 cm and 2.46 cm. At 2 dS m salinity ,how ev er , both av erage plant height (94.6 cm) and stem girth (2.24 cm) significantly decreased and w ere found to be comparable to control (0.5 dS -1 + -1 m ) v alues. Plants show ed negligible Na accumulation in leav es up to 1.4 dS m salinity , but -1 + exposure to elev ated salinity (2 dS m ) significantly increased leaf Na (0.16% DW). These data -1 indicated a salinity tolerance (EC )threshold of about 1.5 dS m inguav a cultiv ar Allahabad Safeda.

scholarly journals Performance of Hydroponically Cultivated Geranium and Common Verbena under Salinity and High Electrical Conductivity Levels

Agronomy ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1237
Author(s):  
Antonios Chrysargyris ◽  
Spyridon A. Petropoulos ◽  
Dejan Prvulovic ◽  
Nikolaos Tzortzakis
Keyword(s):  
Electrical Conductivity ◽  
Chlorophyll Fluorescence ◽  
Nutrient Solution ◽  
High Salinity ◽  
Stomatal Resistance ◽  
Water Sources ◽  
Total Flavonoid ◽  
Control Treatment ◽  
Total Phenolic ◽  
High Electrical Conductivity

Abiotic factors in nutrient solutions (NSs), such as salinity and high electrical conductivity (EC), may adversely alter plant growth and crop performance. However, there are medicinal/aromatic plants which can not only withstand these adverse conditions, but which can also increase their productivity or even enhance their quality in such conditions. As fresh water sources suitable for irrigation are becoming more and more limited, the use of low-quality water sources and hydroponic growing systems have been suggested as the main alternatives. Towards that direction, this study aims to evaluate the effect of high EC levels in NSs on geranium (Pelargonium graveolens L’Hér.) and common verbena (Verbena officinallis L.) plants cultivated in a soilless (perlite) hydroponics system. Plants were irrigated with a full nutrient solution of EC 2.1 dS m−1 and pH 5.8 until they reached a uniform size. Then, three treatments were applied, namely: (a) a control treatment with an EC of 2.1 dS m−1 in the NS, (b) a high-salinity NS created by adding 75 mM of NaCl (EC under 8.5 dS m−1) and (c) a concentrated NS with an EC of 8.5 dS m−1. In pelargonium, high salinity decreased the total phenolic and total flavonoid contents; antioxidant capacity; N, K, Mg and P content; as well as chlorophyll fluorescence, compared to the control treatment. On the other hand, increased salinity levels increased the Na and Ca content and stomatal resistance. In common verbena, salinity decreased total phenolic content and chlorophyll fluorescence but increased total flavonoid content; antioxidants; leaf K, P, Na, Cu and Zn content; and stomatal resistance, compared to the control. In both species, high EC did not affect polyphenols, flavonoids or antioxidants, whereas it increased stomatal resistance and nutrient accumulation in the leaves, and decreased chlorophyll fluorescence compared to the control treatment. Damage indices, indicated by lipid peroxidation, hydrogen peroxide production and the elevation of enzymes’ antioxidant activities, were evidenced in both saline- and high-EC-treated plants. In conclusion, despite having the same EC levels in the nutrient solution, it seems that ionic stress caused by high mineral concentrations in the nutrient solution had less severe effects on the tested plants than the relevant osmotic stress caused by high salinity due to the addition of NaCl in the nutrient solution.

scholarly journals Analysis Methods for Characterizing Salinity Variability from Multivariate Time Series Applied to the Apalachicola Bay Estuary

2012 ◽  
Vol 29 (4) ◽  
pp. 613-628 ◽  
Author(s):  
Steven L. Morey ◽  
Dmitry S. Dukhovskoy
Keyword(s):  
Time Series ◽  
Time Scales ◽  
River Discharge ◽  
River Flow ◽  
High Salinity ◽  
Multivariate Time Series ◽  
Salinity Range ◽  
Apalachicola Bay ◽  
Analysis Methods ◽  
Salinity Variability

Abstract Statistical analysis methods are developed to quantify the impacts of multiple forcing variables on the hydrographic variability within an estuary instrumented with an enduring observational system. The methods are applied to characterize the salinity variability within Apalachicola Bay, a shallow multiple-inlet estuary along the northeastern Gulf of Mexico coast. The 13-yr multivariate time series collected by the National Estuary Research Reserve at three locations within the bay are analyzed to determine how the estuary responds to variations in external forcing mechanisms, such as freshwater discharge, precipitation, tides, and local winds at multiple time scales. The analysis methods are used to characterize the estuarine variability under differing flow regimes of the Apalachicola River, a managed waterway, with particular focus on extreme events and scales of variability that are critical to local ecosystems. Multivariate statistical models are applied that describe the salinity response to winds from multiple directions, river flow, and precipitation at daily, weekly, and monthly time scales to understand the response of the estuary under different climate regimes. Results show that the salinity is particularly sensitive to river discharge and wind magnitude and direction, with local precipitation being largely unimportant. Applying statistical analyses with conditional sampling quantifies how the likelihoods of high-salinity and long-duration high-salinity events, conditions of critical importance to estuarine organisms, change given the state of the river flow. Intraday salinity range is shown to be negatively correlated with the salinity, and correlated with river discharge rate.

scholarly journals SPACE DEPENDENCE OF SOIL MOISTURE AND SOIL ELECTRICAL CONDUCTIVITY IN ALUVIAL REGION1

Irriga ◽  
2019 ◽  
Vol 24 (1) ◽  
pp. 1-15
Author(s):  
Iug Lopes ◽  
Abelardo A. A. Montenegro
Keyword(s):  
Electrical Conductivity ◽  
Soil Moisture ◽  
Precision Agriculture ◽  
Spatial Dependence ◽  
Spatial Information ◽  
Gravimetric Method ◽  
Research Unit ◽  
Soil Electrical Conductivity ◽  
Agricultural Engineering ◽  
Space Dependence

SPACE DEPENDENCE OF SOIL MOISTURE AND SOIL ELECTRICAL CONDUCTIVITY IN ALUVIAL REGION1     IUG LOPES2 E ABELARDO ANTONIO DE ASSUNÇÃO MONTENEGRO3   1Paper extracted from the doctoral thesis of the first author. 2Department of Agronomy, Instituto Federal de Educação, Ciência e Tecnologia Baiano, BR 349, Km 14 - Zona Rural, CEP: 47600-000, Bom Jesus da Lapa - BA, Brazil; [email protected] - ORCID: 0000-0003-0592-4774. 3Department of Agricultural Engineering, Universidade Federal Rural de Pernambuco, Rua Dom Manoel de Medeiros, Dois Irmão, CEP: 52171-900, Recife - PE, Brazil; [email protected] -ORCID: 0000-0002-5746-8574.     1 ABSTRACT   Spatial information on soil characteristics is essential to proper decision-making regarding to the environment and land use management. The objective of this work was the investigation of cross - variance between soil moisture and apparent soil electrical conductivity (CEa), under different land uses in an alluvial valley of Pernambuco. The study was developed at the Advanced Research Unit of Universidade Federal Rural de Pernambuco (UFRPE), located at  Brígida River Basin, municipality of Panamirim-PE. Soil samples were collected in a regular mesh of 20 x 10 m, for soil moisture by gravimetric method and, following a regular 10 x 10 m mesh, CEa measurements were performed using EM38® device. Cross-semivariograms were assessed and spatial dependence was verified by geostatistical procedures. It was verified in geostatistical procedures  low variation for soil moisture and intermediate variation for CEa. The use of geostatistics allowed identification of covariance between soil moisture and ECa, as well as spatial dependence for both variables, for agricultural areas. It was verified that soil moisture, even at levels close to residual, constitutes a relevant secondary component for increasing soil salinity maps precision, and hence to precision agriculture.   Keywords: geostatistics, semi-arid, precision agriculture     LOPES, I. E MONTENEGRO, A. A. DE A. DEPENDÊNCIA ESPACIAL DA UMIDADE DO SOLO E CONDUTIVIDADE ELÉTRICA EM REGIÃO ALUVIAL     2 RESUMO   Informações espaciais sobre as características do solo são essenciais para uma tomada de decisão adequada em relação ao meio ambiente e ao gerenciamento do uso do solo. O objetivo deste trabalho foi investigar a variância cruzada entre a umidade do solo e a condutividade elétrica aparente do solo (CEa), sob diferentes usos do solo em um vale aluvial de Pernambuco. O estudo foi desenvolvido na Unidade de Pesquisa Avançada da Universidade Federal Rural de Pernambuco (UFRPE), localizada na bacia do rio Brígida, município de Panamirim-PE. As amostras de solo foram coletadas em uma malha regular de 20 x 10 m, para a umidade do solo pelo método gravimétrico e, seguindo uma malha regular de 10 x 10 m, as medidas de CEa foram realizadas usando o dispositivo EM38®. Os semivariogramas cruzados foram avaliados e a dependência espacial foi verificada por procedimentos geoestatísticos. Verificou-se procedimentos geoestatísticos, uma baixa variação da umidade do solo e variação intermediária para CEa. O uso da geoestatística permitiu identificar a covariância entre a umidade do solo e o CEa, bem como a dependência espacial para ambas as variáveis, para as áreas agrícolas. Verificou-se que a umidade do solo, mesmo em níveis próximos ao residual, constitui um componente secundário relevante para o aumento da precisão do mapeamento da salinidade do solo e, consequentemente, para a agricultura de precisão.   Palavras-chave: geoestatística, semiárido, agricultura de precisão

scholarly journals Ammonia/ammonium dissociation coefficient in seawater: A significant numerical correction

2007 ◽  
Vol 4 (3) ◽  
pp. 183 ◽  
Author(s):  
Thomas G. Bell ◽  
Martin T. Johnson ◽  
Timothy D. Jickells ◽  
Peter S. Liss
Keyword(s):  
Ionic Strength ◽  
Natural Waters ◽  
Ammonia Toxicity ◽  
Acid Dissociation ◽  
Gaseous Ammonia ◽  
Accurate Estimation ◽  
Environmental Processes ◽  
Climate Regulation ◽  
Natural Temperature ◽  
Ammonia Exchange

Environmental context. Quantifying ammonia concentrations in natural waters is important for our understanding of environmental processes that relate, in particular, to aquaculture toxicity and to the transfer of gaseous ammonia into the atmosphere where it plays a role in new particle formation and climate regulation. The proportion of ammonia present in natural waters is determined in part by variations in temperature and salinity. This work identifies that a previous equation for predicting ammonia concentrations over natural temperature and salinity ranges is incorrect and suggests alternative, more appropriate equations. A more accurate estimation of environmental ammonia concentrations is essential if improved estimates are to be made of the flux of ammonia into the atmosphere and the level of ammonia toxicity within aquacultures. Abstract. The equilibrium between ammonia (NH3) and ammonium (NH4+) in aqueous solution is a function of temperature, pH and the ionic strength of the solution. Here we reveal a 30-year-old error in published work on the thermodynamics of ammonium dissociation in seawater, which has propagated throughout the literature. The work in question[1] [K. H. Khoo, C. H. Culberson, R. G. Bates, J. Solution Chem. 1977, 6, 281] presents an incorrect expression for the variation of the acid dissociation coefficient (Ka) of ammonium with temperature and ionic strength. We detail the error and reveal that it can lead to as much as a 500% overestimation in calculated NH3 concentration under environmental conditions. This finding is highly relevant, particularly for studies of ammonia toxicity and air–sea ammonia exchange. In addition, we recommend two expressions that better reproduce previous experimental work: (i) taken from the work of Johansson and Wedborg,[2] and (ii) our own derivation using the dataset of Khoo et al.[1]

scholarly journals The Influence of Non-Engineered Municipal Landfills on Groundwater Chemistry and Quality in Bloemfontein, South Africa

Molecules ◽  
2020 ◽  
Vol 25 (23) ◽  
pp. 5599
Author(s):  
Rinae Makhadi ◽  
Saheed A. Oke ◽  
Olusola O. Ololade
Keyword(s):  
South Africa ◽  
Water Quality ◽  
Electrical Conductivity ◽  
High Salinity ◽  
Total Coliform ◽  
Landfill Site ◽  
Water Type ◽  
Permissible Limits ◽  
Salinity Hazard ◽  
Landfill Sites

This study assessed the groundwater quality around two municipal solid waste landfill sites, in the city of Bloemfontein, Free State Province, South Africa. The two landfill sites are located in two contrasting geological terrains, with both lacking some basic facilities found in a well-designed landfill. A total of eight groundwater samples were collected from pollution monitoring boreholes near the two landfill sites, with five samples representing the northern landfill site and three samples representing the southern landfill site. The samples were collected in the autumn and winter seasons to assess any possible seasonal variations. They were analysed for physicochemical (pH, electrical conductivity (EC), total dissolve solids (TDS), chemical oxygen demand (COD) and total organic carbon (TOC)) and microbiological parameters (Escherichia coli, total coliform). The results of the analysis showed that the waters from both landfills were generally dominated by Ca, Mg, SO4, and HCO3 ions. Some of the major anions and cations in the water samples were above the South African National Standard (SANS241:2015) and World Health Organisation (WHO) permissible limits for drinking water. Majority of the boreholes had total dissolved solids and electrical conductivity values exceeding the SANS 241:2015 and WHO permissible limits. Piper trilinear plots for the two landfill sites showed that Ca(Mg)HCO3 water type predominates, but Ca(Mg)SO4 and Ca(Mg)Cl were also found. These water types were further confirmed with expanded Durov diagrams, indicating that that the boreholes represented a water type that is seldom found which is undergoing ion exchange, typical of sulphate contamination. From the SAR diagrams, boreholes in the northern landfill site had a high salinity hazard with only one borehole in the southern landfill site having a high salinity hazard. The geology was found to play a significant role in the distribution of contaminants into the groundwater systems in the study area. The study concluded that the northern landfill site had a poorer water quality in comparison to the southern landfill site based on the analysed physicochemical parameters. However, the southern landfill site showed significant microbial contamination, due to the elevated amount of E. coli and total coliform concentrations. The high permeability of the weathered dolerites in the northern landfill site might have enabled the percolation of contaminants into the groundwater resulting in the poorer water quality.

scholarly journals Deoxyribonuclease from Salmon Testes

1962 ◽  
Vol 45 (4) ◽  
pp. 77-92 ◽  
Author(s):  
Margaret R. McDonald
Keyword(s):  
Ionic Strength ◽  
Maximal Activity ◽  
Optimum Concentration ◽  
Heat Denaturation ◽  
Acid Extraction ◽  
Fractional Precipitation ◽  
Temperature Optimum ◽  
Monovalent Ions ◽  
Ph Range ◽  
Deoxyribonuclease Activity

A procedure is described for the purification of salmon testis deoxyribonuclease II by means of acid extraction, fractional precipitation with ammonium sulfate, heat denaturation of extraneous proteins, and ethanol fractionation. This process separates the deoxyribonuclease activity from that of ribonuclease, phosphatase, phosphodiesterase, and protease. Over 50 per cent of the activity is retained with an over-all enrichment of 20,000-fold. The enzyme degrades both native and heat-denatured DNA, but the rate of degradation of the latter is only one-tenth that of the former. It does not hydrolyze apurinic acid. The enzyme is most stable in the pH range 4 to 5. Electrolytes are essential for the expression of its activity: monovalent ions satisfy the requirement, but divalent ones are much more effective. Above a certain optimum concentration, each electrolyte is inhibitory. The pH of maximal activity, under conditions of optimal ionic strength, is 4.8; the temperature optimum is near to 55°C.

Effect of Humic Substances on Americium (III) Retention onto Silica

1988 ◽  
Vol 127 ◽  
Author(s):  
Valerie Moulin ◽  
Denise Stammose
Keyword(s):  
Ionic Strength ◽  
Humic Substances ◽  
Safety Assessment ◽  
Natural Waters ◽  
Major Influence ◽  
Liquid Interfaces ◽  
Aquifer Systems ◽  
Humic Materials ◽  
Solid Liquid ◽  
Influence Of Ph

ABSTRACTThe migration/retention phenomena of radionuclides in geological systems are of great interest for the safety assessment of a nuclear disposal. Interactions at solid/liquid interfaces play a significant role in the speculation and transport of radionuclides in aquifer systems. Oxide surfaces and humic substances which occur in natural waters in large concentration ranges (from few mg/1 to several hundred mg/1) may have a major influence on radionuclides behaviour. For this purpose, studies have been carried out on a ternary system: oxide-humic substances-americium (III). The influence of pH, ionic strength and humic concentration on the adsorption of americium onto silica has been investigated. The ionic strength of the solution (0.1 and 0.01) has little effect on the americium adsorption. In the presence of humic materials, the fixation of americium is enhanced at low pH (pH<5) whereas, at higher pH (pH>5), the adsorption is lowered and dependent of humic concentration.

scholarly journals Effect of ionic strength on the ion exchange equilibrium between AMX membrane and electrolyte solutions

2015 ◽  
Vol 51 (1) ◽  
pp. 60-68 ◽  
Author(s):  
Islem Louati ◽  
Fatma Guesmi ◽  
Akram Chaabouni ◽  
Chiraz Hannachi ◽  
Béchir Hamrouni
Keyword(s):  
Ionic Strength ◽  
Ion Exchange ◽  
Anion Exchange ◽  
Natural Waters ◽  
Electrolyte Solutions ◽  
Anion Exchange Membrane ◽  
Exchange Equilibrium ◽  
Thermodynamic Constants ◽  
Separation Factors ◽  
Exchange Membrane

The effect of ionic strength variation on the ion exchange equilibrium between AMX anion exchange membrane and electrolyte solutions containing the most dominant anions on natural waters (Cl−, NO3−, and SO42−) was studied. All experiments were carried out at a constant temperature of 25 °C. Ion exchange isotherms were established, at different ionic strengths from 0.1 to 0.5 M, for the systems (Cl−/NO3−), (Cl−/SO42−) and (NO3−/SO42−). Obtained results showed that for I = 0.1 M the affinity order is SO42 −&gt;NO3−&gt;Cl−. For I = 0.2 M this order is NO3−&gt;SO42−&gt;Cl−. For 0.3 and 0.5 M the AMX membrane becomes more selective for chloride than for nitrate or sulfate. Selectivity coefficients KNO3−Cl−, K2Cl−SO42− and K2NO3−SO42−, thermodynamic constants, and separation factors were calculated and decreased with the increase of ionic strength.

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