scholarly journals Preparation and Study of some Electrical Properties of PVA-Ni(NO3)2 Composites

Author(s):  
Sabah A. Salman ◽  
Nabeel A. Bakr ◽  
Mohammed H. Mahmood

The aim of this paper is to prepare and study the (D.C.) electrical conductivity of (PVA-Ni (NO3)2) composites at different temperatures. For that purpose, PVA films with Ni (NO3)2 salt additive were prepared with different concentrations‎ 2, 4, 6, 8 and 10 wt. % and with thickness of 45μm by using casting technique. The experimental results for PVA-Ni (NO3)2) ‎films show that the (D.C.) electrical‏ ‏conductivity increased with increasing ‎the filler content and the‏ ‏temperature, and the activation energy was ‎decreased with increasing the filler content‎.

2011 ◽  
Vol 8 (1) ◽  
pp. 168-174
Author(s):  
Baghdad Science Journal

The present studies are focused on the modification of the properties of epoxy resin with different additives namely aluminum, copper by preparing of composites systems with percentage (20%, 40% and 50%) of the above additives. The experimental results show that the D.C of conductivity on wt% filler content at ( 293-413 ) K electrical conductivity of all above composites increased with temperature for composites with filler contact and find the excellent electrical conductivity of copper and lie between (2.6*10-10 - 2.1*10-10)?.cm . The activation energy of the electrical conductivity is determined and found to decrease with increasing the filler concentration.


2019 ◽  
Vol 11 (22) ◽  
pp. 56-63
Author(s):  
Hussein Neama Najeeb

                The electrical characteristics of polyvinyl alcohol PVA doped with different concentrations (0, 1, 2, 3 and 4wt%) of sodium  iodide NaI powder were studied. The films are prepared using solution casting technique, in order to investigate the effect of sodium iodide NaI additions on the electrical properties of PVA host. The D.C conductivity measured by measuring the D.C electrical resistance using the Keithly Electrometer type 616C, and for different temperatures ranging from 30 – 70oC.           The dielectric properties measured by measuring the capacitor and the loss angle tangent as a function of the alternating electric field frequency using the Agilent impedance analyzer 4294A, within the frequency range 50 – 6 ×106 Hz at room temperature.  The experimental results showed that the dielectric constant is decrease with increase frequency of applied electrical field and increase with increasing concentrations, dielectric loss is increase with increasing frequency of applied electrical field to be 1MHz after this it was decreasing, A.C electrical conductivity are increasing with increasing frequency of applied electrical field, also, the results showed that the D.C electrical conductivity are increasing with increase concentration of NaI and temperature, activation energy are decreasing with increase concentration of additive salt.     


2010 ◽  
Vol 145 ◽  
pp. 177-180 ◽  
Author(s):  
Hai Bin Li ◽  
Qing Xue Huang ◽  
Jian Mei Wang ◽  
Qin Ma

In this paper, the diffusion quantity of different temperatures and unit time have been investigated basing on experimental results and theoretical analysis. The diffusing parameters of molten tin in the reaction process is investigated according to diffusing formula. The results within the range of 260~350°C indicates that the diffusing activation energy is increased with the time until the reaction ceases and it is decreased with the increasing of the temperature and substrate vacancy, but the average diffusing constant of tin increased with the temperature.


2016 ◽  
Vol 34 (2) ◽  
pp. 386-392 ◽  
Author(s):  
H.A.M. Ali ◽  
Magdy A. Ibrahim

AbstractThe crystal structure of (4E)-2-amino-3-cyanobenzo[b]oxocin-6-one, denoted as 4(E)-ACBO, was analyzed using X-ray diffraction technique. The dielectric and AC electrical conductivity measurements of the bulk 4(E)-ACBO in the form of pellet were studied in the range of frequency 42 Hz to 5 MHz and the temperature range of 303 K to 373 K. The temperature and frequency dependence of dielectric constant (∊1), dielectric loss (∊2) and AC electrical conductivity (σAC) were investigated. The relaxation time (τ) for electrons to hop over a barrier of height WH was calculated at different temperatures. The AC activation energy was determined from the temperature dependence of σAC at different frequencies.


MRS Bulletin ◽  
1987 ◽  
Vol 12 (5) ◽  
pp. 36-39 ◽  
Author(s):  
P. Craig Taylor

Although there are some significant exceptions, most important glass-forming systems contain elements from the sixth, or chalcogenide, column of the periodic table (oxygen, sulfur, selenium, or tellurium). The glasses which contain oxygen are typically insulators, while those which contain the heavier chalcogen elements are usually semiconductors. Even though oxygen is technically a chalcogen element, the term “chalcogenide glass” is commonly used to denote those largely covalent, semiconducting glasses which contain sulfur, selenium, or tellurium as one of the constituents.The chalcogenide glasses are called semiconducting glasses because of their electrical properties. The electrical conductivity in these glasses depends exponentially on the temperature with an activation energy which is approximately one half of the optical gap. In this sense these glasses exhibit electrical properties similar to those in intrinsic crystalline semiconductors. The analogy is by no means perfect. The mobilities for the charge carriers in these glasses are very low (< 10 cm2/V-s) compared to crystalline semiconductors, and there are even discrepancies in determining the sign of the charge carriers from measurements of the Hall effect and the Seebeck effect.The first detailed studies of the chalcogenide glasses were performed about 30 years ago. For many years the prototype compositions have been selenium (Se), arsenic triselenide (As2Se3) or arsenic trisulfide (As2S3), and germanium diselenide (GeSe2) or germanium disulfide (GeS2).


2015 ◽  
Vol 230 ◽  
pp. 233-237 ◽  
Author(s):  
Aleksandr V. Yatsenko ◽  
A.S. Pritulenko ◽  
S.V. Yevdokimov ◽  
Dmytro Yu. Sugak ◽  
I.I. Syvorotka ◽  
...  

The temperature dependence of the dark electrical conductivity of the LiNbO3(LN) crystals annealed in saturated H2O and D2O vapor in the range 293...400 K is investigated. It is found that the activation energy of the electrical conductivity is equal to (0.71 ± 0.02) eV and is close this value of LN samples, reduced in hydrogen. Annealing in ampoules with H2O vapor also lead to LN optical spectra changes such annealing in H2. The nature of this phenomenon is discussed.


2004 ◽  
Vol 835 ◽  
Author(s):  
C. Delacourt ◽  
C. Wurm ◽  
L. Laffont ◽  
F. Sauvage ◽  
J.-B. Leriche ◽  
...  

AbstractLiFePO4-based powders prepared through various synthesis conditions are presented. Depending on whether the precursors contain carbon or not, LiFePO4-based composites obtained contain significant amounts of carbon as well. We did not succeed in doping LiFePO4 with Nb and produced, instead, crystalline β-NbOPO4 and/or an amorphous (Nb, Fe, C, O, P) matrix around LiFePO4 particles. The total electrical conductivity is of ∼10−9 S.cm−1 at 25°C with an activation energy of ca. 0.65 eV for pure LiFePO4 and LiFePO4/β-NbOPO4 composite. C-containing LiFePO4 samples, including those that had been tentatively doped with Nb, are much more conductive (up to 1.6.10−1 S.cm−1) with an activation energy ΔE ∼ 0.08 eV.


2020 ◽  
Vol 8 (1) ◽  
pp. 130-134
Author(s):  
Rasha Hamid Ahmed

"In this study, nickel oxide (NPs) films were produced by doping each element with 2% zinc, tin, iron, cobalt and magnesium. pulsed laser deposition was used to deposit them on glass substrates , and we used a pulsed Nd-YAG laser with a wavelength of 1064nm. All the films were annealed with one temperature (573k). The electrical properties of the prepared films were studied, such as the continuous electrical conductivity and activation energy, and we found that increasing the temperature increases the electrical conductivity values Also, the value of the electrical conductivity and the activation energy change according to the type of added doping. We also discovered many activation energy values in the temperature ranges of (308K-428K) , and observed the conduct of nanoparticle oxide doping with various metals at these temperatures.


Author(s):  
Balqyz Lovelila Hermansyah Azari ◽  
Totok Wicaksono ◽  
Jihan Febryan Damayanti ◽  
Dheananda Fyora Hermansyah Azari

Conductive Polymers are one of the interesting topics to be developed in recent years. Conductive polymers can combine the properties of polymers and the electrical properties of metals. Research related to the electrical properties of conductive polymers, including electrical conductivity measurements and determination of activation energy has been carried out. This study aims to determine the effect of addition mass fraction of activated carbon into the nylon polymer on the conductive polymer material based on the electrical conductivity and activation energy. The variations of activated carbon used are 0%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10% (wt/V). The conductive polymer from nylon polymer and activated carbon is made by casting solution method. The electrical conductivity measurement of the conductive polymer and the activation energy was carried out using the parallel plate method. The value of electrical conductivity increased from 5.62×10-9 ± 1.89×10-10 S/cm for the pure nylon to 2.51×10-8 ± 2.87×10-10 S/cm for the addition of mass fraction of activated carbon 8% wt/V. Meanwhile, there was a decrease in the addition of 9% wt/V and 10% wt/V of mass fraction of activated carbon, which were 2.36×10-8 ± 3.47×10-10 S/cm and 2.28×10-8 ± 4.01×10-10 S/cm. The activation energy of conductive polymer obtained decreased with increasing in the mass fraction of the activated carbon into the nylon polymer. The activation energy for the pure nylon was 0.0189 eV and 0.0127 eV for the addition of 8% wt/V mass fraction of activated carbon. Meanwhile, there was an increase in the addition of 9% wt/V and 10% wt/V mass fractions of activated carbon of 0.0145 eV and 0.0150 eV, respectively.


2020 ◽  
Vol 1 (1) ◽  
pp. 13-25
Author(s):  
Salama A. H.

Electrical properties of some new cyclopentenone derivatives have been studied. The structures of prepared samples were characterized by (UV), (XRD) and (SEM). The dependence of electrical properties such as σdc , σac , ɛ' and ɛ'' on frequency and temperature were studied at frequency range from 50 Hz to 5 MHz and the temperature range from 25oC to 140oC. It was found that, ɛ' decreased with increasing frequency while it increases with increasing temperatures within the used ranges. Moreover, dielectric constant is structural dependent which is obvious from the variation of dielectric constant for each sample. Ac-electrical conductivity increased with increasing frequency which was attributed to the polarization of the charge carriers. The temperature dependence of dc-electrical conductivity show typical Arrhenius relation for the three prepared samples. The activation energy calculated from Arrhenius equation and the results are discussed in detailed.


Sign in / Sign up

Export Citation Format

Share Document