Comparative analysis of sorptive, textural, strength properties and chemical composition of commercial medical CO2 sorbents

2019 ◽  
Vol 19 (4) ◽  
pp. 258-264
Author(s):  
V. S. Derevshchikov ◽  
E. D. Kazakova

Physicochemical properties of commercial medical CO2 sorbents Amsorb Plus, Draeger 800, Draeger free, Loflosorb, Sodasorb, Sofnolime, Spherasorb, Ventisorb, as well as of the Russian adsorbent HPI were studied to determine the chemical compositions, textural characteristics, effective protection time with respect to CO2; crushing and attrition resistance of granular sorbents were measured using the SHELL SMS-1471 and ASTM D 4058 96 procedures. The best performance (a high CO2 capacitance, strength) was observed with Draeger 800. The obtained data on operating properties of commercial sorbents and recommendations can be useful for medicine, rescue works, as well as for scientific and production activities when cleaning air mixtures from carbon dioxide is necessary.

2019 ◽  
Author(s):  
Nelson K. Chepkwony ◽  
Cécile Berne ◽  
Yves V. Brun

ABSTRACTBacterial adhesion is affected by environmental factors, such as ionic strength, pH, temperature, and shear forces, and therefore marine bacteria must have developed holdfasts with different composition and structures than their freshwater counterparts to adapt to their natural environment. The dimorphic α-proteobacterium Hirschia baltica is a marine budding bacterium in the Caulobacterales clade. H. baltica uses a polar adhesin, the holdfast, located at the cell pole opposite the reproductive stalk for surface attachment and cell-cell adhesion. The holdfast adhesin has been best characterized in Caulobacter crescentus, a freshwater member of the Caulobacterales, and little is known about holdfast composition and properties in marine Caulobacterales. Here we use H. baltica as a model to characterize holdfast properties in marine Caulobacterales. We show that freshwater and marine Caulobacterales use similar genes in holdfast biogenesis and that these genes are highly conserved among the two genera. We also determine that H. baltica produces larger holdfast than C. crescentus and that those holdfasts have a different chemical composition, as they contain N-acetylglucosamine and galactose monosaccharide residues and proteins, but lack DNA. Finally, we show that H. baltica holdfasts tolerate higher ionic strength than those of C. crescentus. We conclude that marine Caulobacterales holdfasts have physicochemical properties that maximize binding in high ionic strength environments.IMPORTANCEMost bacteria spend a large amount of their lifespan attached to surfaces, forming complex multicellular communities called biofilms. Bacteria can colonize virtually any surface, therefore they have adapted to bind efficiently in very different environments. In this study, we compare the adhesive holdfasts produced by the freshwater bacterium C. crescentus and a relative, the marine bacterium H. baltica. We show that H. baltica holdfasts have a different morphology and chemical composition, and tolerate high ionic strength. Our results show that H. baltica holdfast is an excellent model to study the effect of ionic strength on adhesion and providing insights on the physicochemical properties required for adhesion in the marine environment.


Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4801
Author(s):  
Maria Tarapatskyy ◽  
Patrycja Sowa ◽  
Grzegorz Zaguła ◽  
Małgorzata Dżugan ◽  
Czesław Puchalski

Is it possible to characterize the types of honey based on their chemical composition, their content of bioactive substances, and their physicochemical properties? The objective of this study was a comparative analysis of four types of honey from the Carpathian Foothills area, located in south-east Poland, based on the content of the main phenolic acids and proline, the mineral composition, and selected physicochemical properties. Most analyses, such as those of phenolic acids, sugars, and proline content, in honey samples were performed using chromatographic methods. These experiments demonstrated that honeydew honeys were the richest in phenolic acids, minerals, as well as oligosaccharides, compared to other honeys. Dark-colored honeys were characterized by the highest proline content. The dominant elements in all types of honey were potassium and calcium. The results of the present study show that analyses of specific phenolic acids, minerals, proline, and sugar content, in combination with chemometrics analysis, may successfully differentiate between the biological origins of honey samples and allow the preliminary verification of the samples before performing time-consuming pollen analysis.


TAPPI Journal ◽  
2015 ◽  
Vol 14 (2) ◽  
pp. 73-81 ◽  
Author(s):  
GISELY SAMISTRARO ◽  
PETER W. HART ◽  
JORGE LUIZ COLODETTE ◽  
RICARDO PAIM

Eucalyptus dunii has been commercially used in southern Brazil because of its relatively good frost tolerance and adequate productivity in the winter months. More recently, interest has grown in cultivating Eucalyptus benthamii Maiden & Cambage, which presents even superior frost tolerance compared to E. dunii and is highly productive as well. The quality of E. benthamii for pulp production is not yet proven. Thus, the chemical, anatomical, and technological aspects of pulp made from E. benthamii were compared with those of E. dunii for unbleached paper production. Samples of E. benthamii chips were obtained and analyzed for their basic density, chemical composition, higher heating value, trace elemental analysis, and chip size distribution. The chips were kraft cooked using conditions that produced a 74 ± 6 kappa number. The pulps were characterized for kappa number, yield, viscosity, and morphologic characteristics (e.g., length, wall thickness, and coarseness). Black liquor was analyzed for total solids, organics, inorganics, sodium sulfide, sodium hydroxide, and sodium carbonate. Brownstocks were beaten at five different energy levels in a Valley beater, and the physical strength properties of 120 g/m² handsheets were measured to develop a beater curve. The results of this study showed differences in delignification between the two woods and lower pulp yield for E. benthamii , which are related to their chemical compositions and basic densities. The E. benthamii studied in this work exhibited higher amounts of lignin and extractives, lower carbohydrate content, and lower basic density. However, cooking a blend of the two woods afforded good results in pulping and in physical pulp properties.


2021 ◽  
Vol 13 (15) ◽  
pp. 8164
Author(s):  
Brian E. Bautista ◽  
Lessandro E. O. Garciano ◽  
Luis F. Lopez

There are limited published studies related to the mechanical properties of bamboo species in the Philippines. In this study, the shear strength properties of some economically viable bamboo species in the Philippines were properly characterized based on 220 shear test results. The rationales of selecting this mechanical property are the following: (1) Shear strength, parallel to the fiber, has the highest variability among the mechanical properties; and (2) Shear is one of the governing forces on joint connections, and such connections are the points of failure on bamboo structures when subjected to extreme loading conditions. ISO 22157-1 (2017) test protocol for shear was used for all tests. The results showed that Bambusa blumeana has the highest average shear strength, followed by Gigantochloa apus, Dendrocalamus asper, Bambusa philippinensis, and Bambusa vulgaris. However, comparative analysis, using One-way ANOVA, showed that shear strength values among these bamboo species have significant differences statistically. A linear regression model is also established to estimate the shear strength of bamboo from the physical properties. Characteristic shear strength is also determined using ISO 12122-1 (2014) for future design reference.


Agriculture ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 374
Author(s):  
Teresa Szczęsna ◽  
Ewa Waś ◽  
Piotr Semkiw ◽  
Piotr Skubida ◽  
Katarzyna Jaśkiewicz ◽  
...  

The aim of this study was to determine the influence of storage temperature and time on physicochemical parameters of starch syrups recommended for the winter feeding of bee colonies. The studies included commercially available three starch syrups and an inverted saccharose syrup that were stored at different temperatures: ca. 20 °C, 10–14 °C, and ca. 4 °C. Physicochemical parameters of fresh syrups (immediately after purchase) and syrups after 3, 6, 9, 12, 15, 18, 21, and 24 months of storage at the abovementioned temperatures were measured. It was observed that the rate of unfavorable changes in chemical composition of starch syrups and the inverted saccharose syrup, mainly the changes in the 5-hydroxymethylfurfural (HMF) content, depended on the type of a syrup and storage conditions (temperature, time). Properties of tested starch syrups intended for winter feeding of bees stored at ca. 20 °C maintained unchanged for up to 6 months, whereas the same syrups stored at lower temperatures (10–14 °C) maintained unchanged physicochemical parameters for about 12 months. In higher temperatures, the HMF content increased. To date, the influence of this compound on bees has not been thoroughly investigated.


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