scholarly journals Distribution of nickel (Ni) in peatland situated alongside mineral soil derived from ultrabasic rocks

2021 ◽  
Vol 18 (1) ◽  
pp. 15
Author(s):  
Heru Bagus Pulunggono ◽  
Moh Zulfajrin ◽  
Fuadi Irsan
Keyword(s):  
Cation Exchange Capacity ◽  
Mineral Soil ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Water Soluble ◽  
Soil Fraction ◽  
Ni Content ◽  
Peat Surface ◽  
Central Sulawesi ◽  
Cu And Zn

<p>Detailed studies of Ni distribution in peat that is influenced by Ni-rich soil derived from ultrabasic rocks are still limited. The objective of this study was to reveal the characteristics of Ni in peat from Morowali (Central Sulawesi Province, Indonesia) at several depths and distances from the boundary of the ultrabasic mineral soil. Peat was sampled from depths of 0–30, 30–60, and 60–90 cm at distances of 100, 200, 300, 400, 500, and 600 m from the border of the ultrabasic mineral soil in March 2018. Ni characteristics were examined through their total, exchangeable, water-soluble, and adsorbed distributions. The relationships between Ni and some peat chemical properties such as pH; cation exchange capacity; macronutrient contents of K, Ca, and Mg; and micronutrient contents of Fe, Cu and Zn were also observed. The high Ni content in peat at the study transect is caused by an accumulation of Ni transported from elevated areas of mineral soil. Most Ni in peat is bonded to the soil organic exchange complexes. Accumulation of the mineral soil fraction in the peat surface is indicated at distances of 100–400 meters from the ultrabasic mineral soil. Ni distribution in peat at the study transect is mainly governed by a combination of Fe, pH, organic material, water content, peat depth, and distance from ultrabasic mineral soil.</p>

scholarly journals Root Medium Chemical Properties

1998 ◽  
Vol 8 (4) ◽  
pp. 486-494 ◽  
Author(s):  
William R. Argo
Keyword(s):  
Irrigation Water ◽  
Cation Exchange Capacity ◽  
Nutrient Management ◽  
Chemical Properties ◽  
Nutrient Supply ◽  
Exchange Capacity ◽  
Water Soluble ◽  
Nutrient Concentrations ◽  
Medium Ph ◽  
Over Time

Maintaining medium pH and nutrient concentrations at levels acceptable for growth are important for producing vigorous transplants in the shortest time. Medium chemical properties, such as cation-exchange capacity, aeration, liming materials, preplant fertilizer, irrigation-water sources, water-soluble fertilizers, and plant species, interact to affect medium pH and nutrient management. However, these chemical properties do not affect medium pH or the nutrient supply simultaneously or with equal intensity. The objective of this review is to consider key chemical properties of container media and their affects on pH and nutrient management initially and over time.

scholarly journals COMPOSITION, MICROSTRUCTURE AND PROPERTIES OF QUATERNARY CLAYS OF THE PRIKHANKAYSKAYA DEPRESSION (PRIMORYE)

2019 ◽  
Vol 14 (1) ◽  
pp. 20-34
Author(s):  
T. G. RYASHCHENKO ◽  
N. N. UKHOVA ◽  
S. I. SHTELMAKH ◽  
N. I. BELYANINA ◽  
P. S. BELYANIN
Keyword(s):  
Clay Minerals ◽  
Laboratory Data ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Climatic Conditions ◽  
Water Soluble ◽  
Laboratory Studies ◽  
Microstructural Parameters ◽  
Physical Chemical ◽  
Study Results

The article considers the study results of composition, microstructure and physical-chemical properties of the quaternary clays of the Prikhankayskaya depression in district of the lake Khanka (Primorye) on the example of air-dry samples of geological borehole 45-b in the range of 18–62 m. The objective of research was to obtain new information about the properties of widespread clay sediments in this area using geologic-lithological materials and laboratory data. The schematic geologic-lithological column was composed with the selection of various zones in the quaternary clay sediments section and the border with sediments of the Neogene System. The methodological scheme of laboratory studies of clays was proposed. This scheme includes the determination of chemical and microelement composition, clay minerals, contents of carbonates, water-soluble salts, mobile forms of aluminum oxide, humus, as well as microstructural parameters (method «Microstructure») and some physical-chemical properties. Geochemical coefficients (Kz, CIA, CIW, ICV) determined the degree of chemical maturity of clays and confirmed the results of palynological studies reflecting the fluctuations of the climatic conditions of their formation. For the group of toxic microelements for the first time the special indicator (Zc) was calculated. Which was the criterion for a degree of pollution of the clay sediments section. Clay minerals of the quaternary clays are represented by smectite and hydromica. The clear change in the mineral association was found when passing to the Neogene sediments (kaolinite prevails). The method «Microstructure» revealed the aggregated type of clays microstructure, the domination of the particles of coarse dust fraction among the primary (free) particles and the almost complete absence of the particles of fine-grained sand fraction, the participation of various fractions in the composition of aggregates. The variants of the formation of certain types of aggregates (on sizes) in the fluviolacustrine «khankayskiy» clays are presented. Solid part density, water resistance (soaking time), sedimentation volume, plasticity, relative swelling (samples-pastes) were determined using standard methods for clays. By special methods, the cation exchange capacity was measured and the calculated values of the plasticity index were obtained from forecasting formulas using the yield limit. The proposed methodological scheme of complex laboratory studies of clay sediments can be recommended for problematic geologic-lithological and engineering-geological sections.

scholarly journals Eosin Removal by Cetyl Trimethylammonium-Cloisites: Influence of the Surfactant Solution Type and Regeneration Properties

Molecules ◽  
2019 ◽  
Vol 24 (16) ◽  
pp. 3015
Author(s):  
Fethi Kooli ◽  
Souad Rakass ◽  
Yan Liu ◽  
Mostafa Abboudi ◽  
Hicham Oudghiri Hassani ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Clay Mineral ◽  
Salt Solution ◽  
Cation Exchange Capacity ◽  
Chemical Properties ◽  
Surfactant Solution ◽  
Exchange Capacity ◽  
Maximum Temperature ◽  
Basal Spacing ◽  
Xrd Techniques

The effect of the counteranion of hexadecyltrimethylammonium salts on the physico-chemical properties of organoclays was investigated, using a selected natural clay mineral with a cation exchange capacity of 95 meq/100 g. The uptake amount of C16 cations was dependent on the hexadecyltrimethylammonium (C16) salt solution used, the organoclay prepared from C16Br salt solution exhibited a value of 1. 05 mmole/g higher than those prepared from C16Cl and C16OH salt solutions. The basal spacing of these organoclays was in the range of 1.81 nm to 2.10 nm, indicating a similar orientation of the intercalated surfactants, and could indicated that the excess amount of surfactants, above the cation exchange capacity of 0.95 meq/g could be adsorbed on the external surface of the clay mineral sheets. These organoclays were found to be stable in neutral, acidic, and basic media. The thermal stability of these organoclays was carried out using thermogravimetric analysis and in-situ X-ray diffraction (XRD) techniques. The decomposition of the surfactant occurred at a maximum temperature of 240 °C, accompanied with a decrease of the basal spacing value close to 1.42 nm. The application of these organoclays was investigated to remove an acidic dye, eosin. The removal amount was related to the initial used concentrations, the amount of the surfactants contents, and to the preheated temperatures of the organoclays. The removal was found to be endothermic process with a maximum amount of 55 mg of eosin/g of organoclay. The value decreased to 25 mg/g, when the intercalated surfactants were decomposed. The reuse of these organoclays was limited to four regeneration recycles with a reduction of 20 to 30%. However, noticeable reduction between 35% to 50% of the initial efficiency, was achieved after the fifth cycle, depending of the used organoclays.

The ameliorative effects of low-grade palygorskite on acidic soil

Soil Research ◽  
2020 ◽  
Vol 58 (4) ◽  
pp. 411
Author(s):  
Jin-Hua Yuan ◽  
Sheng-Zhe E ◽  
Zong-Xian Che
Keyword(s):  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Soil Amendment ◽  
Acid Soil ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Acidic Soil ◽  
Low Grade ◽  
Incubation Experiments ◽  
Acid Neutralisation

Mineral composition and alkaline properties of palygorskite (Pal), and its ameliorative effects on chemical properties of acid soil were investigated. Dolomite was the main form of alkali in Pal and the acid neutralisation capacity of Pal was 215 cmol kg–1. Incubation experiments indicated that Pal incorporation increased soil pH, cation exchange capacity, base saturation and exchangeable K+, Na+, Ca2+ and Mg2+ contents, and decreased the levels of exchangeable H+, Al3+ and acidity, over a 1-year period. The ameliorative mechanisms were the dissolution of major alkaline matter in Pal (i.e. dolomite), and the exchange between released Ca2+ and Mg2+ with H+ in acidic soil. Hence, Pal can be used as a moderate acidic soil amendment.

Radial variations in cation exchange capacity and base saturation rate in the wood of pedunculate oak and European beech

2002 ◽  
Vol 32 (10) ◽  
pp. 1829-1837 ◽  
Author(s):  
J Herbauts ◽  
V Penninckx ◽  
W Gruber ◽  
P Meerts
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
European Beech ◽  
Base Cation ◽  
Exchange Capacity ◽  
Water Soluble ◽  
Soluble Form ◽  
Pedunculate Oak ◽  
Exchangeable Ca ◽  
Saturation Rate

In a mixed forest stand on an ochreous brown earth in the Belgian Ardennes, pedunculate oak (Quercus robur L.) and European beech (Fagus sylvatica L.) have outwardly decreasing cation concentration profiles in wood. To test if these profiles can be ascribed to endogenous factors or to decreased availability of cations in the soil, radial profiles of water-soluble, exchangeable, and total cations and of cation exchange capacity (CEC) of wood were determined. In both species, [Formula: see text]75% of K is in the water-soluble form so is of little use for dendrochemical monitoring. About 80% of Mg is adsorbed on wood exchange sites. For Ca, 30 (beech) to 60% (oak) of total content cannot be extracted by SrCl2 and is, thus, relatively immobile in wood. Wood CEC decreases from pith to bark in European beech and from pith to outer heartwood in pedunculate oak. Decreasing profiles of exchangeable Ca and Mg in pedunculate oak and exchangeable Ca in European beech are strongly constrained by CEC and, thus, are not related to environmental change. Base cation saturation rate shows no consistent radial change in either species. European beech maintained much higher base cation saturation rate than pedunculate oak, although both species had similar CEC. In conclusion, the results do not provide convincing evidence for a significant change in nutritional status of pedunculate oak and European beech in the Belgian Ardennes due to atmospheric pollution.

scholarly journals THE EFFECTIVENESS OF COMPOST, HUMIC ACID AND PURE FULVATE ON IMPROVEMENT OF ULTISOL SOIL CHEMICAL PROPERTIES

2021 ◽  
pp. 247-254
Author(s):  
Resman ◽  
Sahta Ginting ◽  
Muhammad Tufaila ◽  
Fransiscus Suramas Rembon ◽  
Halim
Keyword(s):  
Humic Acid ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Chemical Properties ◽  
Fulvic Acids ◽  
Exchange Capacity ◽  
Humic And Fulvic Acids ◽  
Total N ◽  
Organic C ◽  
Exchangeable Al

The research aimed to determine the effectiveness of compost containing humic and fulvic acids, and pure humic and fulvic acids in increasing of Ultisol soil chemical properties. The research design used a randomized block design (RBD), consisting of 10 treatments, namely K0: 0 g polybag-1, KO1: 500 g polybag-1, KO2: 500 g polybag-1, KO3: 500 g polybag-1, KO4: 500 g polybag-1, KO5: 500 g polybag-1, KO6: 500 g polybag-1, KO7: 500 g of polybags-1, H: 50 g of polybag-1, A: 500 g polybag-1. Each treatment was repeated three times and obtained 30 treatment units. The results showed that pH H2O (K0: 4.49, KO1: 5.64, KO2: 5.47, KO3: 5.43, KO4: 5.51, KO5: 5.39, KO6: 5.48, KO7: 6.17, H: 5.06, F: 5.15), total-N (%) (K0: 0.13, KO1: 0.17, KO2: 0.18, KO3: 0.30, KO4: 0.25, KO5: 0.24, KO6: 0.29, KO7: 0.36, H: 0.16, F: 0.14), organic-C (%) (K0: 1.85, KO1; 2.30, KO2: 2.24, KO3: 2.33, KO4: 2.62, KO5: 2.25, KO6: 2.27, KO7: 2.95, H: 2.32, F: 2.26) , available-P (%) (K0: 2.75, KO1: 3.24, KO2: 3.16, KO3: 3.27, KO4: 3.57, KO5: 3.31, KO6: 3.37, KO7: 3.89, H: 3.10, F: 3.12), exchangeable-Al (me100g-1) (K0: 2.51, KO1: 2.11, KO2: 2.13, KO3: 2.15, KO4: 1.88, KO5: 2.14, KO6: 2.12, KO7: 1.75, H: 2.16, F: 2.17), base saturation (%) (K0: 30.91, KO1: 63.48, KO2: 52.63, KO3: 53.76, KO4: 56.13, KO5: 54.96, KO6: 56.71, KO7: 65.53, H: 39.11, F: 42.76), cation exchange capacity (me100g-1) (K0: 12.76, KO1: 15.64, KO2: 14.86, KO3: 14.35, KO4: 14.13, KO5: 15.01, KO6: 15.50, KO7: 17.94, H: 14.19, F: 13.73). The combined compost treatment of three types of organic matter (Imperata cylindrica + Rice straw + Glincidia sepium) is more effective in increasing the pH, H2O as 37.42%, total-N as 176.92%, Organic-C as 59.46%, available-P as 41.45%, base saturation as 65.53%, cation exchange capacity as 17.94% and exchangeable -Al, Alreduction as 30.28% of ultisol soil. KEY WORDS: compost, humic acid, fulvate, soil chemical, ultisol

scholarly journals Chemical properties of long-term irrigated Fluvisols of the Beli Drim river valley in the Klina region (Serbia)

2021 ◽  
Vol 70 (1) ◽  
pp. 13-26
Author(s):  
Miodrag Tolimir ◽  
Branka Kresović ◽  
Borivoj Pejić ◽  
Katarina Gajić ◽  
Angelina Tapanarova ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Humus Content ◽  
Chemical Properties ◽  
Base Cations ◽  
Exchange Capacity ◽  
Base Saturation ◽  
Basic Cations ◽  
Hydrolytic Acidity

The impact of long-term (> 100 yr) irrigation on soil chemical properties was studied on eight plots in the Beli Drim river valley in Kosovo and Metohija near Klina, Serbia. For these studies, soil samples from shallow profiles were collected from only one or two depth zones of the Ah horizon; and from moderately deep and deep profiles, from two to three depth zones for the purpose of comparing irrigated field and non-irrigated meadow lands. Water from the Beli Drim River and surface gravity systems (irrigation furrows or border strip irrigation) were used for irrigation. Chemical variables included determination of pH-H2O, content of CaCO3, content of humus, hydrolytic acidity, sum of basic cations, cation exchange capacity, and base saturation. On irrigated soils, the results of chemical analysis showed on average a small increase in pH-H2O (0.07 pH units), as well as a significant decrease in humus content (2.00-4.75%), sum of basic cations (4.98-12.98%) and cation exchange capacity (12.8%) compared to the non-irrigated land of the study area. Long-term irrigation had no effect on hydrolytic acidity and base saturation in the Ah horizon of the investigated lands. Namely, the mentioned variations in the chemical properties of the investigated soils show that slight processes of reduction in the humus content and reduction of the content of base cations occured. Data on the chemical properties of the investigated soils indicate that the destructive processes of reduction in the humus content and leaching of base cations must be controlled in order to achieve a stable sustainable system of high productivity and prevent their further deterioration.

scholarly journals Physicochemical Parameters and Heavy Metals Content of Soil Samples from Farms in Minna

2015 ◽  
Vol 58 ◽  
pp. 154-163
Author(s):  
Z. Abdulhamid ◽  
E.B. Agbaji ◽  
C.E. Gimba ◽  
A.S. Agbaji
Keyword(s):  
Heavy Metals ◽  
Cation Exchange Capacity ◽  
Physicochemical Parameters ◽  
Chemical Properties ◽  
Absorption Spectrometry ◽  
Exchange Capacity ◽  
Average Concentration ◽  
Soil Samples ◽  
Ph Values ◽  
Physico Chemical

Physico-chemical properties and heavy metals content of soils were determined from seven farms in Minna, central Nigeria. Conventional analytical methods were employed to determine the physico-chemical properties and the heavy metals were analysed by atomic absorption spectrometry. The result showed that pH values ranged from 6.64 - 7.70 indicating slight acidity to slight alkalinity of the soils. The total organic carbon values ranged from 0.95-2.25 % resulting in the presence of organic matter (1.63-3.87). The electrical conductivity values ranged from 17-37 μS/cm. The cation exchange capacity of the soil samples ranged from 3.68-5.15 cmol/kg. The heavy metals levels were in the following range: Cd (0.00018-0.00134 mg/g), Cu (0.0069-0.0476 mg/g), Fe (1.942-2.2059 mg/g), Mn (0.1825-0.3696 mg/g), Ni (0.0065-0.0069 mg/g) and Zn (0.0157-0.2252 mg/g). The concentration of the metals in the soil samples varied according to the following trend: Fe>Mn>Zn> Cu>Ni>Cd. The average concentration of all the metals in each farm also gave the trend Farm B>Farm G>Farm E>Farm C>Farm F>Farm D>Farm A. The findings indicate the presence of heavy metals in all the farms but only Fe was above the FAO/WHO standards.

scholarly journals Cation exchange capacities of upland soils in eastern Canada

1994 ◽  
Vol 74 (4) ◽  
pp. 393-408 ◽  
Author(s):  
W. L. Meyer ◽  
P. A. Arp ◽  
M. Marsh
Keyword(s):  
Organic Carbon ◽  
New Brunswick ◽  
Cation Exchange ◽  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Mineral Soil ◽  
Exchange Capacity ◽  
Soil Horizons ◽  
Eastern Canada ◽  
Upland Soils

Relationships between cation exchange capacity (CEC), clay and organic carbon contents and soil pH were analyzed by way of multiple regressions for upland soils in eastern Canada (mostly Ontario, with additional data for New Brunswick). This was done by vegetation type in an attempt to explain some of the otherwise unexplained CEC variations. Data were taken from about 2000 soil horizons (organic L, F, and H horizons as well as A, B, and C mineral soil horizons) under broadleaves (mostly maples, beech, birch or aspen as dominant species), conifers (mostly fir, spruces and/or pines), and grass vegetation. For the organic forest floor horizons (or L, F, and H horizons), both organic carbon content (%) and pH were highly significant for predicting CEC, i.e.,CEC (L, F, and H of broadleaves) = −38 + 0.71 × org. C (%) + 10.3 × pH (R2 = 0.69), andCEC (L, F and H of conifers) = −31 + 0.34 × org. C (%) + 12.1 × pH (R2 = 0.58).For the mineral soil, clay and organic carbon contents (%) and pH were highly significant for predicting CEC. Soils with forest vegetation were found to have lower contributions of organic matter to CEC than grassland soils, i.e.,CEC (forest soils) = −7.0 + 0.29 × clay (%) + 0.82 × org. C (%) + 1.4 × pH (R2 = 0.72),CEC (wooded grasslands) = −6.0 + 0.31 × clay (%) + 1.31 × org. C (%) + 1.0 pH (R2 = 0.74), andCEC (grasslands) = −8.3 + 0.24 × clay (%) + 2.14 × org. C (%) + 1.3 × pH (R2 = 0.79).Relationships that were developed from Ontario data for specific vegetational types (maple sites, strongly podzolized conifer sites, grasslands/croplands) were tested by comparing CEC predictions with reported values for similar sites in New Brunswick and Quebec. The predictions were consistent with the general trends for maple sites and grasslands/croplands, but CEC values were strongly overpredicted for Podzolic subsoils on conifer sites.Literature information of the CEC dependency on in situ pH is sparse. Existing information that is based on buffering grassland/cropland soil samples from pH 2.5 to 8 appears to mimic this dependency quite well. Key words: Cation exchange capacity, clay, organic carbon, soil pH, forests, grasslands

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