scholarly journals INVESTIGATION OF THE NEUTRALIZATION PROCESS OF SULFATION PRODUCTS IN THE SURFACTANTS PRODUCTION

Author(s):  
Oleksandr Dzevochko ◽  
Mykhaylo Podustov ◽  
Ihor Lysachenko ◽  
Alona Dzevochko ◽  
Roman Vorozhbiian

The process of sulfation products neutralization in the production of surfactants is not basic, but at this stage the positive effects obtained at the stage of sulfation of organic matter with sulfur trioxide gas are fixed. To preserve the degree of sulfation obtained, it is necessary to carry out the neutralization process under conditions precluding the occurrence of hydrolysis in an acidic medium. The neutralization reaction takes place with a high heat release of about 40 kJ / mol. Analysis of the literature data showed that the neutralization process is not well covered. Little data and hardware and technological design of the process. The process of neutralization in industrial conditions is carried out in apparatus with mechanical turbine mixers, to remove the heat of the exothermic reaction, the paste from the neutralizer is fed into a water-borne heat exchanger and returns to the neutralizer again. The purpose of this study is to determine the optimal technological parameters of the process of neutralization of sulfate products and the development of a mathematical model of this process. The results of experimental studies of the process of sulfation products neutralization with an aqueous solution of sodium hydroxide are presented. During the research, the influence of technological parameters on the quality indicators of neutralization products was determined, the main of which is the degree of sulfation. The optimal technological parameters for carrying out this process in a reactor with a stirrer under laboratory conditions were found. Based on the data obtained in the basis of this process, the use of a continuous-action reactor with a turbine mixer and with a combined heat exchanger. For the transition to an industrial reactor-neutralizer, a mathematical model has been developed, which makes it possible, by means of mathematical modeling, to correct technological parameters in industrial conditions.

2018 ◽  
Vol 212 ◽  
pp. 01032 ◽  
Author(s):  
Amur Fiapshev ◽  
Olesya Kilchukova ◽  
Yuriy Shekikhachev ◽  
Marat Khamokov ◽  
Luan Khazhmetov

One of the promising areas of processing poultry and livestock waste is anaerobic digestion, which helps to prevent pollution of the natural environment, as well as to receive processing products such as gaseous fuel, biogas and highly effective biofertilizer. The use of plants for the production of biological gas as alternative sources of energy is largely determined by its design characteristics and the worked out technological regimes. The study was conducted with the aim of obtaining data on the effect of the main parameters of the biogas plant and the heat exchanger-agitator on the quality of its operation. This paper considers the thermal processes taking place in the biogas plant in which the mixing device and the heating element are combined into one unit, which allows heating and maintaining the given temperature regime more evenly due to the rotation of the heat exchanger and the transfer of biomass heat throughout the whole volume of the methane. As a result of theoretical studies of the processes of heat exchange and heat transfer taking place in the biogas plant, a mathematical model has been obtained that allows determining the distribution of the temperature of the biomass throughout the entire volume of the methane. It is established that the theoretical temperature homogeneity of the stirred medium is achieved by combining the heat exchanger and the mixing device into one unit, the design and technological parameters of which characterize the intensity of the forced motion of fermentable manure, while changing the value of thermal conductivity.


Author(s):  
Samuel Mariano do Nascimento ◽  
Gustavo Galdi Heidinger ◽  
Pedro Dinis Gaspar ◽  
Pedro Dinho Silva

This chapter reports an overview about experimental studies concerning the thermal performance of air curtains and heat exchangers installed in vertical open refrigerated display cases. The air curtain analysis shows the influence on the thermal performance by varying the width of the discharge air grille and the perforation density of the back panel by a mathematical model. The variation on the perforation density of the back panel and the width of discharge air grille alter significantly the thermal entrainment factor and the energy consumption of the equipment. Focusing the influence of environmental conditions on the performance of the heat exchanger, a second mathematical model was developed to evaluate the total heat load, its partial components and the condensate water mass. This analysis provides valuable information to the design of the air curtain and heat exchanger based on in-store environmental conditions and airflow efficiency.


Energies ◽  
2020 ◽  
Vol 13 (13) ◽  
pp. 3399
Author(s):  
Dawid Taler ◽  
Jan Taler ◽  
Marcin Trojan

The paper presents an analytical mathematical model of a car radiator, which takes into account various heat transfer coefficients (HTCs) on each row of pipes. The air-side HTCs in a specific row of pipes in the first and second passes were calculated using equations for the Nusselt number, which were determined by CFD simulation by the ANSYS program (Version 19.1, Ansys Inc., Canonsburg, PA, USA). The liquid flow in the pipes can be laminar, transition, or turbulent. When changing the flow form from laminar to transition and from transition to turbulent, the HTC continuity is maintained. Mathematical models of two radiators were developed, one of which was made of round tubes and the other of oval tubes. The model allows for the calculation of the thermal output of every row of pipes in both passes of the heat exchangers. Small relative differences between the total heat flow transferred in the heat exchanger from hot water to cool air exist for different and uniform HTCs. However, the heat flow rate in the first row is much higher than the heat flow in the second row if the air-side HTCs are different for each row compared to a situation where the HTC is constant throughout the heat exchanger. The thermal capacities of both radiators calculated using the developed mathematical model were compared with the results of experimental studies. The plate-fin and tube heat exchanger (PFTHE) modeling procedure developed in the article does not require the use of empirical correlations to calculate HTCs on both sides of the pipes. The suggested method of calculating plate-fin and tube heat exchangers, taking into account the different air-side HTCs estimated using CFD modelling, may significantly reduce the cost of experimental research for a new design of heat exchangers implemented in manufacturing.


Author(s):  
Bratishko, V. ◽  
Rebenko, V. ◽  
Milko, D. ◽  
Khmelovska, A.

Purpose. Set the nature of the distribution of bulk material in the working chamber of a batch grinder with a steady state of its operation. Methods. Theoretical principles of classical mechanics, mechanics of liquids and gases. Results. A general mathematical model of the material distribution in the chamber batch grinder is obtained. This model allows determining the height of the material layer at an each point in the working chamber of the batch grinder at a certain distance from the axis rotation of the working bodies and interconnects the physical and mechanical properties of the crushed raw material, technological parameters of the grinder and its mode of operation. The character of the obtained model indicates that it corresponds to the well-established ideas about the distribution of loose media in the working chamber of the batch grinder. Conclusions. As a result of theoretical studies, a mathematical model of the distribution of bulk material in a cylindrical working chamber of a batch grinder with a steady state of operation was obtained in general terms. Assumptions made in the course of research prove the feasibility of conducting experimental studies to verify the adequacy and refinement of the model. Keywords: grinding, bulk material, batch grinder, character of distribution, surface shape.


Author(s):  
O. Yu. Kichigina

At production of stainless steel expensive alloying elements, containing nickel, are used. To decrease the steel cost, substitution of nickel during steel alloying process by its oxides is an actual task. Results of analysis of thermodynamic and experimental studies of nickel reducing from its oxide presented, as well as methods of nickel oxide obtaining at manganese bearing complex raw materials enrichment and practice of its application during steel alloying. Technology of comprehensive processing of complex manganese-containing raw materials considered, including leaching and selective extraction out of the solution valuable components: manganese, nickel, iron, cobalt and copper. Based on theoretical and experiment studies, a possibility of substitution of metal nickel by concentrates, obtained as a result of hydrometallurgical enrichment, was confirmed. Optimal technological parameters, ensuring high degree of nickel recovery out of the initial raw materials were determined. It was established, that for direct steel alloying it is reasonable to add into the charge pellets, consisting of nickel concentrate and coke fines, that enables to reach the through nickel recovery at a level of 90%. The proposed method of alloying steel by nickel gives a possibility to decrease considerably steel cost at the expense of application of nickel concentrate, obtained out of tails of hydrometallurgical enrichment of manganese-bearing raw materials, which is much cheaper comparing with the metal nickel.


Author(s):  
Oleksii Timkov ◽  
Dmytro Yashchenko ◽  
Volodymyr Bosenko

The article deals with the development of a physical model of a car equipped with measuring, recording and remote control equipment for experimental study of car properties. A detailed description of the design of the physical model and of the electronic modules used is given, links to application libraries and the code of the first part of the program for remote control of the model are given. Atmega microcontroller on the Arduino Uno platform was used to manage the model and register the parameters. When moving the car on the memory card saved such parameters as speed, voltage on the motor, current on the motor, the angle of the steered wheel, acceleration along three coordinate axes are recorded. Use of more powerful microcontrollers will allow to expand the list of the registered parameters of movement of the car. It is possible to measure the forces acting on the elements of the car and other parameters. In the future, it is planned to develop a mathematical model of motion of the car and check its adequacy in conducting experimental studies on maneuverability on the physical model. In addition, it is possible to conduct studies of stability and consumption of electrical energy. The physical model allows to quickly change geometric dimensions and mass parameters. In the study of highway trains, this approach will allow to investigate the various layout schemes of highway trains in the short term. It is possible to make two-axle road trains and saddle towed trains, three-way hitched trains of different layout. The results obtained will allow us to improve not only the mathematical model, but also the experimental physical model, and move on to further study the properties of hybrid road trains with an active trailer link. This approach allows to reduce material and time costs when researching the properties of cars and road trains. Keywords: car, physical model, experiment, road trains, sensor, remote control, maneuverability, stability.


Author(s):  
Petar Kazakov ◽  
Atanas Iliev ◽  
Emil Marinov

Over the decades, more attention has been paid to emissions from the means of transport and the use of different fuels and combustion fuels for the operation of internal combustion engines than on fuel consumption. This, in turn, enables research into products that are said to reduce fuel consumption. The report summarizes four studies of fuel-related innovation products. The studies covered by this report are conducted with diesel fuel and usually contain diesel fuel and three additives for it. Manufacturers of additives are based on already existing studies showing a 10-30% reduction in fuel consumption. Comparative experimental studies related to the use of commercially available diesel fuel with and without the use of additives have been performed in laboratory conditions. The studies were carried out on a stationary diesel engine СМД-17КН equipped with brake КИ1368В. Repeated results were recorded, but they did not confirm the significant positive effect of additives on specific fuel consumption. In some cases, the factors affecting errors in this type of research on the effectiveness of fuel additives for commercial purposes are considered. The reasons for the positive effects of such use of additives in certain engine operating modes are also clarified.


Author(s):  
S.N. Larin S.N. ◽  
V.I. Tregubov ◽  
A.N. Isaeva

Combined extrusion processes can be in demand in the production of body products with jumper in the central part and thin walls. Often, their industrial implementation requires theoretical justifi cation of power regimes. Mathematical model of combined extrusion created on the basis of the upper estimates method is presented. The effect of technological parameters on extrusion force is established based on the obtained expressions for pressure estimation.


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