Microstructural and Physical Properties of Thermoplastic Corn Starch/Polystyrene Blend Foams Affected by Different Contents and Combinations of Plasticizers
Abstract A comprehensive study was performed on thermoplastic corn starch (TPS)/polystyrene (PS) blend foam to optimize the formulation from the aspects of plasticizer content and the blend ratio. Plasticization of native starch was implemented with various contents of plasticizer (water + glycerol), 21, 23, 25 and 29%, and water/glycerol ratio of 1/2, 2/3, 3/2 and 2/1 using melt extrusion process. The influence of plasticizer loading content and also its combination on the microstructural and physical properties of the blend foam were investigated. The morphological consideration was also carried out by scanning electron microscopy (SEM) to evaluate the distribution and regularity of the foam cells. In the following, full factorial method in Minitab software was used to optimize the formulation according to the properties. Moreover, the effect of PS content on the moisture absorption and cell structure of TPS/PS blend foam was evaluated. The addition of 20% PS to TPS caused to 6 times higher expansion ration than PS and 60 % higher than TPS, while 50 % lower moisture absorption than TPS. This combination can be a good alternative candidate for warm food packing applications.