scholarly journals A salt-free, zero-discharge and dyebath-recyclable circular coloration technology based on cationic polyelectrolyte complex for cotton fabric dyeing

2021 ◽  
Author(s):  
Wen-Yi Wang ◽  
Jia-Chi Chiou ◽  
Wan-Xue Chen ◽  
Jia-Li Yu ◽  
Chi-wai Kan
Keyword(s):  
Textile Industry ◽  
Polyelectrolyte Complex ◽  
Cationic Polyelectrolyte ◽  
Cotton Fabrics ◽  
Acid Dyes ◽  
Anionic Dyes ◽  
Colour Measurements ◽  
Grade 3 ◽  
Dyed Fabrics ◽  
Dyed Fabric

Abstract Textile industry is one of the most polluting industries due to the large quantities of dyeing wastewater it generates and discharges. Herein, we report an eco-friendly and sustainable circular coloration technology based on cationic polyelectrolyte complex to realise salt-free, zero-effluent-discharge circular dyeing for cotton fabrics with a recyclable dyebath by using a typical cationic polyelectrolyte polyhexamethylene biguanide (PHMB) bonded with anionic dyes. The cotton fabrics were first treated with PHMB and then dyed with three commercial acid dyes. Colour measurements show that the colour strength is controllable by adjustment of concentrations of both PHMB and the dyebath. The dyed fabric samples were found to have good/excellent colour levelness (< 0.49), and the colour fastness (Grade 3 ~ 5) was basically satisfactory and acceptable. The dyebath was proved to be recyclable for circular dyeing occurring at room temperature, which greatly reduces consumption of both water and heat energy for textile dyeing. Meanwhile, the dyed fabrics showed antimicrobial activity, particularly for the gram-positive S. aureus, which may help reduce the healthcare-associated infections that transmit through textiles. These results suggest that cationic polyelectrolyte-based circular dyeing could provide a promising and practicable strategy to address the pollution issue caused by wastewater generated in dyeing process in the textile industry.

scholarly journals Durable Antipilling Modification of Cotton Fabric with Chloropyrimidine Compounds

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1697
Author(s):  
Xue Dong ◽  
Tieling Xing ◽  
Guoqiang Chen
Keyword(s):  
Heat Release ◽  
Cotton Fabric ◽  
Textile Industry ◽  
Cotton Fabrics ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cellulose Material ◽  
Functional Textiles ◽  
Natural Cellulose ◽  
Grade 3

Cotton fabric, a natural cellulose material, is widely used in the textile industry for its excellent properties. However, its application in some fields are seriously restricted because of its poor antipilling behavior. In this study, cotton fabrics were modified with 2,4,6-trichloropyrimidine (TLP), 2,4-dichloro-5-methoxypyrimidine (DMP), and 2-amino-4,6-dichloropyridine (ADP). The surface morphology and chemical structure of the modified cotton fabric were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). Furthermore, the antipilling behavior, dyeing properties, thermal properties, and mechanical properties of modified cotton fabric were evaluated. The results showed that chloropyrimidine compounds were successfully grafted onto the surface of the cotton fabric, leading to excellent and durable antipilling activity of grade 3–4 even after 10 washes. Moreover, compared with control cotton fabric, the heat release rate (HRR) and total heat release (THR) of TLP-modified cotton fabric decreased to 173.2 W/g (42.3% reduction) and 11.3 KJ/g (13.7% reduction), respectively. In addition, the increased K/S value of modified cotton fabrics dyed with reactive dyes indicated that the modification can enhance the dyability of cotton fabric. This technique provides a simple and versatile method for improving the antipilling behavior of cellulosic materials and supports further preparation of functional textiles.

scholarly journals Preparation of Chitosan Nanoparticles and its Utilization as Novel Powerful Enhancer for Both Dyeing Properties and Antimicrobial Activity of Cotton Fabrics

2021 ◽  
Vol 11 (5) ◽  
pp. 13652-13666
Keyword(s):  
Antimicrobial Activity ◽  
Chitosan Nanoparticles ◽  
Cotton Fabrics ◽  
Diffusion Method ◽  
Acid Dyes ◽  
Disk Diffusion Method ◽  
Morphological Studies ◽  
Colorimetric Data ◽  
Ft Ir ◽  
Dyed Fabrics

Replacement of conventional chemicals with modern fewer hazards one has great attention via green chemistry. Chitosan nanoparticles (CSNPs) were prepared from the reaction of chitosan (0.2 g/100 ml) with tripolyphosphate (o.1 g/100 ml) through the ionotropic gelation method. CSNPs with different concentrations were used for cotton fabrics to impart antimicrobial activity and enhance their dyeing affinity towards acid dyes. FT-IR spectroscopy and TEM imaging were used to characterized CSNPs. SEM and TGA. Effect of CSNPs concentrations on cotton fabric dyeing affinity was recorded from colorimetric data. The antimicrobial activity of treated dyed fabrics was evaluated via disk diffusion method against S. aureus, E. coli, Candida, and Aspergillus Niger. Results have shown that cotton fabrics treated with 0.3 g/100 ml record the highest K/S values, Corresponding to the highest dyeing affinity towards acid dyes. In addition, treated dyed cotton fabrics were showed higher antimicrobial activity towards tested microorganisms because of the presence of CSNPs. Morphological studies on the untreated, treated, and treated dyed cotton fabrics via SEM imaging confirmed that CSNPs coated cotton fabrics. In addition, the light and washing fastness properties of these fabrics confirmed their durability. Therefore, CSNPs were used to impart cotton fabrics' antibacterial activity and improve their dyeability with acid dye.

Environmentally Friendly Multifunctional Treatments of Textiles with Photo-Active Colorants

2012 ◽  
Vol 441 ◽  
pp. 780-780
Author(s):  
Ning Liu ◽  
Gang Sun
Keyword(s):  
Thermal Properties ◽  
Light Exposure ◽  
Environmentally Friendly ◽  
Cotton Fabrics ◽  
Fluorescent Light ◽  
Oxidation Reactions ◽  
Acid Dyes ◽  
Chemical Structures ◽  
Wool Fibers ◽  
Dyed Fabrics

As an effort to develop environmentally friendly light-induced functional treatments for fabrics, certain acid dyes were incorporated onto different fabrics. The treated fabrics demonstrated powerful and durable antimicrobial and oxidative detoxifying functions after light exposure. In this presentation, we will report the latest progresses in using certain anthraquinone compounds in treatments of wool, nylon, silk and cotton fabrics. The dyed fabrics could demonstrate antimicrobial functions upon exposed to UVA (365 nm) and fluorescent light. However, it was more interesting to observe that the surfaces of the dyed wool fibers became polished with scales removed after being exposed to UV or day light for certain time. The chemical structures and thermal properties of the dyed fabrics were investigated by using different instrumentation such as SEM, FTIR, and other instruments, and the results verified the proposed oxidation reactions of the fibers. This research proves that dyeing fabrics with photo-active dyes could be a new green functional treatment on textiles.

scholarly journals Modification of cotton fabrics with 2-diethylaminoethyl chloride for salt-free dyeing with anionic dyes

Cellulose ◽  
2021 ◽  
Author(s):  
Peixin Tang ◽  
Leilah-Marie E. Lockett ◽  
Mengxiao Zhang ◽  
Gang Sun
Keyword(s):  
Electrostatic Interactions ◽  
Light Exposure ◽  
Dye Adsorption ◽  
Cost Effective ◽  
Cotton Fabrics ◽  
Cotton Cellulose ◽  
Hydroxyl Groups ◽  
Anionic Dyes ◽  
Free System ◽  
Untreated Cotton

AbstractA chemical modification of cotton fabrics by 2-diethylaminoethyl chloride (DEAE-Cl) was achieved, and the resulted cotton fabrics demonstrated salt-free dyeing properties with anionic dyes. Nucleophilic property of hydroxyl groups in cotton cellulose was enhanced under alkaline conditions and could react with DEAE-Cl, a chemical possessing both nucleophilic and electrophilic sites. The monolayered DEAE-grafted cotton cellulose could further react with DEAE-Cl to form multiple cationic quaternary ammonium salts (denoted as DEAE@Cotton), which are highly interactive with anionic dye molecules. The strong electrostatic interactions between the DEAE@Cotton and the dyes eliminated the use of inorganic salts in cotton dyeing process. The chemical structure and property of DEAE@Cotton were characterized and compared with untreated cotton. The DEAE@Cotton can be dyed in a salt-free system, and the dye exhaustion was faster than the conventional dyeing method due to the robust electrostatic interactions of the fabrics with anionic dyes. The dyed fabrics demonstrated outstanding color fastness under repeated washing, light exposure, and crocking. The dye adsorption process on DEAE@Cotton follows Langmuir isotherm model (R2 = 0.9667). The mechanism of enhanced dyeability was experimentally proved by treating the fabric with other anionic dyes in a salt-free system, proving the process to be environmentally friendly and cost-effective. Graphic abstract

Influence of Nano Silica Coating on the Functional Properties of Cotton Fabrics

2009 ◽  
Vol 67 ◽  
pp. 149-154
Author(s):  
K. Sasipriya ◽  
N. Gobi ◽  
R. Palanivelu ◽  
T.V. Ramachandran ◽  
V. Rajendran
Keyword(s):  
Textile Industry ◽  
Silica Coating ◽  
Cotton Fabrics ◽  
Air Permeability ◽  
Wall Material ◽  
Nano Silica ◽  
Chemical Route ◽  
Wrinkle Resistance ◽  
Potential Applications ◽  
Nanosilica Particles

Coating of nanoparticles on fabrics provides huge potential applications in textile industry. The microencapsulation process is used to encapsulate the nanosilica particles which is used to coat on the surface of fabrics and to observe the special properties such as anti-bacterial, wrinkle resistance, etc. The amorphous nano silica particles were prepared from the natural resources through chemical route. The encapsulated nano silica was prepared using sodium alginate as a wall material by the coacervation method. The prepared sample was coated on the surface of the fabrics by pad-dry-cure method. The anti-bacterial studies were carried out for the nano silica coated and uncoated fabrics and the results would demonstrate the antibacterial effectiveness of treated cotton fabrics. The basic properties like tensile strength, tear strength, air permeability, crease recovery and whiteness index have been analysed for the coated and uncoated fabrics.

Synthesis, Application and Antimicrobial activity of New Acid Dyes based on 3-Amino-2-thioxo-4-thiazolidinone nucleus on Wool and Silk fabrics

2021 ◽  
Vol 18 ◽  
Author(s):  
Fatma A. Mohamed ◽  
Shaban Elkhabiry ◽  
Ismail A. Ismail ◽  
Attia O. Attia
Keyword(s):  
Antimicrobial Activity ◽  
Fastness Properties ◽  
Acid Dyes ◽  
Light Fastness ◽  
Gram Positive ◽  
Gram Negative ◽  
Wool Fabrics ◽  
Infra Red ◽  
Dyed Fabrics ◽  
Silk Fabrics

: The dyes are synthesized by 3-Amino-2-thioxo-4thiazolidinone (N-Amino rhodanine) with glutaraldehyde or Terephthalaldehyde by 2:1 mole to form a and b then coupled with diazonium salts p-Amino benzenesulfonic acid and 4-Amino 3,4 disulfoazobenzeneazobenzene by 2:1 to form new different bis monoazo a1, b1 and diazo a2 and b2 acid dyes. Therefore, the synthesized dyes were applied to both silk and wool fabric materials. We also evaluated the antimicrobial activity for these dyed fabrics against two model gram-negative and gram-positive bacteria. Further, the chemical composition of these dyes is emphasized by elemental analysis Aims: This paper aims to synthesize, apply dye and antimicrobial to four new acid dyes based on derivatives of N-Amino rodanine as a chromophoric group. These dyes are used in dyeing silk and wool with the good lightfastness and are also excellent for washing, rubbing, and sweating fastness. Also, we measure antimicrobial activity for silk and wool fabrics toward Gram-negative, Gram-positive. Background: The search for a synthesis of new acid dyes has antimicrobial for gram-negative and gram-positive. These dyes are mainly used on silk and wool fabrics which have excellent for light fastness, washing, rubbing, and sweating fastness. Objective: The present studies were aimed at synthesis, characterization and antimicrobial toward gram- negative and gram-positive. Methods: The infra-red spectrum was recorded using an Infra-red spectrometer, Perkin Elmer/1650 FT-IR. The 1H-NMR spectra were recorded using a Varian 400MHz spectrometer. The absorbance of the dyes was measured in the ultraviolet-visible region between 300 and 700 nm by a UNICAM UV spectrophotometer. The dye uptake by wool and silk fabrics was measured using a Shimadzu UV-2401PC (UV/V is spectrophotometer at λmax) before and after dyeing. The produced dyes were found to have good antimicrobial activity against a variety of bacteria. Results and Discussion: The compounds a1, b1, a2 &b2 shows good antimicrobial activity toward gram-negative (E. coli), gram-positive (S. aurous). The data showed that exhaustion and the fastness properties of silk and wool dyed fabrics were both very high. Conclusion: This work prepares newly synthesized acid dyes based on 3-Amino-2-thioxo-4thiazolidinone derivatives and uses them for dyeing wool and silk fabrics. Both synthetic dyes have good light fastness and fastness properties. Also, all dyes have a good antimicrobial effect.

Automatic Defect Detection of Yarn-Dyed Fabrics Based on Energy Fusion and Local Binary Patterns

2012 ◽  
Vol 472-475 ◽  
pp. 3039-3042 ◽  
Author(s):  
Wen Yu Li ◽  
Long Di Cheng ◽  
Wen Liang Xue
Keyword(s):  
Defect Detection ◽  
Color Space ◽  
Local Binary Patterns ◽  
High Detection Rate ◽  
Energy Feature ◽  
Dyed Fabrics ◽  
Dyed Fabric ◽  
True Color ◽  
Real Time Application ◽  
Log Gabor

For the purpose of realizing fast and effective detection of defects of yarn-dyed fabric, and in consideration of the inherent characteristics of texture, i.e., color and structure, an approach for automatic defect detection is proposed in this paper. The image of yarn-dyed fabric to be enhanced is first converted from RGB true color space to L*a*b* color space. Then Log-gabor filters filter chromatic and brightness channels, and energy feature images are acquired after energy is fused between chromatic and brightness. Finally defects of yarn-dyed fabrics can be detected on the energy feature images using local binary patterns. The proposed method can detect colored and structural flaws. Experimental results for the defect detection from six kinds of yarn-dyed fabrics indicate that a high detection rate is achieved for the proposed method. It is fast enough to be possible for real-time application.

Multi-scale density detection for yarn-dyed fabrics with deformed repeat patterns

2016 ◽  
Vol 87 (20) ◽  
pp. 2524-2540 ◽  
Author(s):  
Dejun Zheng ◽  
Lingheng Wang
Keyword(s):  
Computation Time ◽  
Registration Method ◽  
Decomposition Approach ◽  
Micro Scale ◽  
Detection Model ◽  
Multi Scale ◽  
Fabric Density ◽  
Macro Scale ◽  
Dyed Fabrics ◽  
Dyed Fabric

A new method combining the characteristics of macro-scale texture repeat patterns and micro-scale interwoven yarns of fabric images was proposed for yarn-dyed fabric density detection. The method was formulated in a research framework of multi-scale image processing and analysis. Firstly, a structure–texture decomposition approach was used to extract texture information and woven pattern details from the macro-scale fabric image. Secondly, a texture unit detection model was proposed to extract the texture units and to detect the yarn skewness in these texture units. Thirdly, a simple yet effective image registration method and a lightness gradient projection method were adopted to analyze the micro-scale fabric image and obtain the yarn locations in a texture unit. Finally, the average fabric density was calculated by coupling the near-regular features of texture units and yarn locations. The experiments showed that the proposed method was effective in detecting hundreds of yarns in the fabric samples and the computation time was very reasonable.

scholarly journals Use of aminated hulls of sunflower seeds for the removal of anionic dyes from aqueous solutions

2019 ◽  
Vol 17 (3) ◽  
pp. 1211-1224 ◽  
Author(s):  
T. Jóźwiak ◽  
U. Filipkowska ◽  
S. Brym ◽  
L. Kopeć
Keyword(s):  
Sorption Capacity ◽  
Textile Industry ◽  
Sunflower Seed ◽  
Freundlich Isotherm ◽  
Sorption Kinetics ◽  
Reactive Black 5 ◽  
Anionic Dyes ◽  
Maximum Sorption Capacity ◽  
Maximum Sorption

Abstract In this study, we analyzed the effectiveness of sorption of dyes popular in the textile industry (Reactive Black 5, Reactive Yellow 84, Acid Yellow 23, and Acid Red 18) on aminated and non-aminated seed hulls of common sunflower (Helianthus annuus L.). The scope of the study included: determination of the effect of pH on dye sorption effectiveness, sorption kinetics analyses (sorption equilibrium time, pseudo-first-order/pseudo-second-order model, intramolecular diffusion model), and determination of the maximum sorption capacity against dyes (Langmuir/Freundlich isotherm). The sorbent was subjected to the FTIR analysis. The sorption capacity of the aminated sunflower seed hulls against reactive dyes RB5 and RY84 accounted for 51.02 mg/g and 63.27 mg/g, respectively, and was higher by 1665% (17.6 times higher) and 1425% (15.3 times higher) compared to that of non-modified hulls. In the case of acidic dyes, Acid Yellow 23 and Acid Red 18, the sorption capacity of the aminated sunflower seed hulls reached 44.78 mg/g and 42.19 mg/g, respectively, and was higher by 1881% (19.8 times higher) and 2284% (23.8 times higher), respectively, compared to the non-modified hulls.

scholarly journals Color and fastness properties of mordanted Bridelia ferruginea B dyed cellulosic fabric

2020 ◽  
Vol 7 (1) ◽  
Author(s):  
Jamiu Mosebolatan Jabar ◽  
Ademola Israel Ogunmokun ◽  
Tella Adewale Akanni Taleat
Keyword(s):  
Calcium Chloride ◽  
Metal Ion ◽  
Color Space ◽  
Fastness Properties ◽  
Color Strength ◽  
Bridelia Ferruginea ◽  
Yellow Color ◽  
Dyed Fabrics ◽  
Cellulosic Fabric ◽  
Dyed Fabric

AbstractBridelia ferruginea B dye was extracted from the bark of the tree using aqueous extraction method. Extracted dye was used to dye cellulosic (cotton) fabric in presence of 5% calcium chloride (CaCl2) or 5% alum (KAl(SO4)2·12H2O) of weight of fabric (o.w.f) as mordant. Fabric dyed without mordant was lighter in hue than metal ion mordanted dyed fabrics. The fabrics dyed in presence of calcium chloride as mordant are of deeper hue than those dyed with alum as mordant. Hence, their dye-uptake and color strength (K/S) are in the same order. K/S value of fabric dyed with alum is 43.71% higher than that without mordant and fabric dyed with calcium chloride has K/S value 51.09% higher than dyed with alum as mordant. CIEL*a*b* coordinate indicator and color space quadrant showed that those dyed fabrics without mordant and with alum as mordant are closer to yellow than red color. Those cellulosic fabrics dyed with calcium chloride as mordant are closer to red than yellow color as confirmed in colour space quadrant. Pre-mordanted dyed fabrics are of deeper color than post-mordanted dyed fabrics than meta-mordanted dyed fabrics than unmordant dyed fabric. Fastness properties of B. ferruginea B dyed cellulosic fabrics ranged from good (3) to excellent (5).

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