scholarly journals Determination of Heavy Metals in Surface Water, Sediments and Planktons at the Junction of Multiple Rivers (Punjnad Headworks) and Their Impact on Human Health

Author(s):  
Saima Naz ◽  
Borhan Mansouri ◽  
Ahmad Manan Mustafa Chatha ◽  
Qudrat Ullah ◽  
Zain Ul Abadeen ◽  
...  

Abstract This study was conducted to calculate the burden of heavy metals i.e., aluminium (Al), arsenic (As), barium (Ba) and lead (Pb) in the river water of Punjnad Headworks, Bahawalpur, Pakistan. For this purpose, samples were collected from surface water, bed sediments and planktons during autumn, winter and spring seasons (September 2018 to May 2019). The results showed that in surface water Pb concentration was highest (453.87 mg L-1), while in sediments and plankton, Al concentration was highest (370.24 µg g-1 and 315.05 µg g-1, respectively). A significant difference (p < 0.000) in metal concentrations was found among surface water, bed sediments and plankton at different sampling stations during various seasons. However, findings of this study showed no adverse effects of heavy metal concentrations on human health. This study provided better understanding of various pollutants and their concentrations in water sources at the studied location.

2018 ◽  
Vol 3 (1) ◽  
pp. 32-37 ◽  
Author(s):  
Mohammad Kazem Souri ◽  
Neda Alipanahi ◽  
Mansoure Hatamian ◽  
Mohammad Ahmadi ◽  
Tsehaye Tesfamariam

Abstract Heavy metal accumulation in vegetable tissues often poses a great risk for human health. In the present study, accumulation of heavy metal in green leafy vegetable crops of coriander, garden cress, lettuce and spinach were evaluated under waste water irrigation in fields located in Kahrizak, on the southern edge of the metropolitan city of Tehran, Iran. Atomic absorption spectrophotometery was used for determination of heavy metal concentrations in leaf tissue. The results showed that heavy metal concentrations in soil and irrigation water were significantly high than allowable levels. Analysis of plant leaf tissue showed that spinach and garden cress accumulated higher concentrations of heavy metals compared to coriander and lettuce plants. Central leaves of lettuce showed the lowest heavy metal concentration compared to outer leaves or leaves of other vegetable crops, and can be the safer product for fresh consumption. The results indicate that the vegetables produced in the region are not suitable for fresh consumption and the agricultural activities should change towards ornamental or industrial crops production.


2021 ◽  
Vol 24 (1) ◽  
pp. 93-101
Author(s):  
Rahmat Januar Noor ◽  
Arnold Kabangnga ◽  
Fathuddin Fathuddin

The presence of heavy metals in coastal waters is a threat to the wealth of coastal ecosystems because they are toxic. The people activities of Makassar City are centered in the coastal area so that they have the potential to produce heavy metal pollutants that can escape into coastal waters. This study aimed to determine the distribution of heavy metal concentrations in the sediment and water column and to determine the contamination factor. The research location is along the coast of Makassar City by determining the location of the observation based on potential sources of input, namely ports, river estuaries, and tourism activities. The research method used survey methods with in-situ measurements (oceanographic parameters) and ex-situ (heavy metal concentrations) and data presentation using tables, graphs, and analysis of variance test results. The concentration of heavy metals Pb, Cd, and Zn in the sediment were higher and significantly different (p <0.05) compared to the water column, while Cu not different. There was no significant difference in the concentration of heavy metals (p> 0.05) spatially (ports, river estuaries, tourist sites). Heavy metals in the sediments did not exceed the quality standard, while several heavy metals in the water column exceeded the quality standards, namely Pb and Cd. The contamination level of heavy metal pollutants studied in the coastal waters of Makassar City was low (CF <1), and if sorted, a pattern of heavy metal was Cd> Zn> Pb> Cu. Keberadaan logam berat di perairan pesisir merupakan ancaman bagi kekayaan ekosistem pesisir sebab bersifat toksik. Aktivitas masyarakat Kota Makassar berpusat di daerah pesisir sehingga berpotensi menghasilkan bahan pencemar logam berat yang dapat lepas ke perairan pesisir. Penelitian ini bertujuan untuk mengetahui distribusi konsentrasi logam berat di sedimen dan kolom air serta menentukan faktor kontaminasi. Lokasi penelitian di sepanjang pesisir Kota Makassar dengan penentuan lokasi pengamatan berdasarkan potensi sumber masukan yaitu pelabuhan, muara sungai, dan aktivitas wisata. Metode penelitian menggunakan metode survey dengan pengukuran secara insitu (parameter oseanografi) dan exsitu (konsentrasi logam berat) serta penyajian data menggunakan tabel, grafik, dan hasil pengujian analisis varians. Konsentrasi logam berat Pb, Cd, dan Zn pada sedimen lebih tinggi serta berbeda secara signifikan (p<0,05) dibandingkan dengan kolom air sedangkan Cu tidak berbeda. Tidak terdapat perbedaan konsentrasi logam berat yang nyata (p>0,05) secara spasial (pelabuhan, muara sungai, lokasi wisata) Logam berat pada sedimen tidak melampaui baku mutu sedangkan pada kolom air terdapat beberapa logam berat yang melampaui baku mutu yaitu Pb dan Cd. Tingkat kontaminasi bahan pencemar logam berat yang diteliti di perairan pesisir Kota Makassar termasuk rendah (CF<1) dan bila diurutkan maka ditemui pola Cd>Zn>Pb>Cu. 


2021 ◽  
Vol 14 (1) ◽  
pp. 207-213
Author(s):  
M.Z. Karkarna ◽  
Z.M. Dabo

An assessment of selected heavy metal concentrations for fishing purposes was conducted at Mairua Reservoir, Funtua, Katsina State, Nigeria. This study aimed at assessing the selected heavy metal concentrations to enable the and sustainable use of the reservoir. Fishing is the major activity of the dwellers throughout the year, but there is less attention in considering the water quality in the reservoir. Eating fish harvested from polluted aquatic habitats could endanger the health Eating fish harvested from polluted aquatic habitats could endanger the health of the consumer. As such, there is the need of this research now if not continuously.Water samples were taken in five sampling points and the procedural plan was the monthly sampling of the water from February-April and June-August 2020. The heavy metals include Zinc (Zn), Iron (Fe), Nickel (Ni), Manganese (Mn), Cadmium (Cd) and Lead (Pb). Laboratory procedures include sample digestions in preparation for spectrophotometric analysis using Atomic Absorption Spectrometer (AAS).  Data were analysed using Analysis of Variance (ANOVA) and independent t-test and related with FAO standard for fishing. The finding shows that most of the parameters like Cd, Zn and Pb are more in concentration at SPIII (downstream), i.e. the outlet of the water in the reservoir. It can also be seen that two parameters Fe and Ni are more concentrated at SPIV (middle towards east) and only Mn is higher at SPI (upstream). Furthermore, the analysis of variance revealed no significant difference (p >0.05) in the values of all the parameters across the five sampled collection points. The results of this study show that with the exception of cadmium (Cd) and lead (Pb), the heavy metal concentrations in water did not exceed FAO (2006) standards. However, Cd and Pb exceeded the FAO standard.  The level of heavy metal concentrations was compared based on seasons (wet and dry) using independent t-test at the 0.05 level of significance. The result shows no significant difference at 0.05 between the wet and dry season values of Fe (P value 0.106), Cd (P value 0.614) Zn (P value 0.700), Mn (P value 0.950), and Ni (P value 0.937). Study on Pb concentrations revealed that the metal was affected by seasonal variation (P value 0.047). Dumping waste very close to the reservoir should be discouraged. Farmers around the reservoir should be enlightened on the negative effects of their activities into the body of the water. More studies should be carried out on physico-chemical, microbial and other heavy metal concentrations in order to provide baseline information on the ecological status of the reservoir. In line with the finding, it is recommended that for effective fishing activities in the reservoir, the use of agrochemicals and dumping municipal waste very close to the reservoir, which could be the possible sources of Cd and Pb, should be discouraged.


2021 ◽  
Vol 298 ◽  
pp. 05001
Author(s):  
Halima Jounaid ◽  
El Mehdi El Hachimi ◽  
Nihad Chakri ◽  
Toufik Remmal ◽  
Btissam Elamrani ◽  
...  

Assessing heavy metal concentrations in wetlands and identifying sources of metal contamination are critical steps in protecting wetlands. Using seven sampling stations, we evaluated the spatial variation of some heavy metal concentrations in surface waters of the Mohammedia wetland and a selected segment of the El Maleh wadi that feeds the wetland. Field observations made it possible to identify and map the pollution discharged into El Maleh wadi, carrying heavy metals into the wetland. The analyses showed that the concentrations of lead, manganese, and cadmium far exceed the thresholds relating to fish life in 100% of sampling stations. All the evidence points to heavy metals contamination of surface water in Mohammedia wetland, generated by industrial activities, wastewater discharges, and leachate from the old landfill located upstream.


2013 ◽  
Vol 10 (3) ◽  
pp. 320-325

Agrochemicals, geochemical structure and industrial wastes create a potential source of heavy metal pollution in the aquatic environment. The porpuse of this study was to investigate the seasonal variations in five heavy metals (Cu, Zn, Cd, Pb and Cr) in the surface water of the Keritis river, one of the most important rivers in Chania, Greece. The surface water samples were colloected at 8 sampling sites in the Keritis river system. Seven sampling campaigns were carried out in each site in a 1-year period, during August 2004 to July 2005. Heavy metals were determined by using flame and furnace Atomic Absorption Spectrometry. Ancillary data included water temperature, pH and electric conductivity. Significant variations were observed between the warm period (May to September) and the wet period (October to April), for the studied metals. Heavy metal concentrations were sufficiently higher in warm period than in wet period. The average concentrations in wet and warm period were: Cu (0.88 μg l-1; 6.62 μg l-1), Cd (0.005 μg l-1; 0.019 μg l-1), Pb (0.28 μg l-1; 2.59 μg l-1), Cr (1.44 μg l-1; 3.25 μg l-1), and Zn (4 μg l-1; 39 μg l-1), respectively. The relative variability followed the order: Zn>Pb>Cu>Cd>Cr. The seasonal variations may be due to either anthropogenic causes, such as agricultural practices, especially the use of fertilizers and biocides or wastewater discharge, or natural causes, such as water temperature, pH, redox condition, or river flow. The water pH was lower in warm period than in wet period. The concentrations of Cu, Zn, Cd, Pb and Cr were found to be positively related to the water pH in both periods. The water temperature was higher in the warm period and no strong, but remarkable correlations were found between the heavy metal concentrations and the temperature values for the warm and the wet period. Also, there was found no correlation between the heavy metal concentrations and the electrical conductivity.


2002 ◽  
Vol 11 (4) ◽  
pp. 285-300 ◽  
Author(s):  
V. MÄNTYLAHTI ◽  
P. LAAKSO

Increasing concentrations of arsenic and heavy metals in agricultural soils are becoming a growing problem in industrialized countries. These harmful elements represent the basis of a range of problems in the food chain, and are a potential hazard for animal and human health. It is therefore important to gauge their absolute and relative concentrations in soils that are used for crop production. In this study the arsenic and heavy metal concentrations in 274 mineral soil samples and 38 organogenic soil samples taken from South Savo province in 2000 were determined using the aqua regia extraction technique. The soil samples were collected from 23 farms.The elements analyzed were arsenic, cadmium, chromium, copper, mercury, nickel, lead and zinc. The median concentrations in the mineral soils were:As 2.90 mg kg –1, Cd 0.084 mg kg –1, Cr 17.0 mg kg –1, Cu 13.0 mg kg –1, Hg 0.060 mg kg –1, Ni 5.4 mg kg –1, Pb 7.7 mg kg –1, Zn 36.5 mg kg –1. The corresponding values in the organogenic soils were:As 2.80 mg kg –1, Cd 0.265 mg kg –1, Cr 15.0 mg kg –1, Cu 29.0 mg kg –1, Hg 0.200 mg kg –1, Ni 5.9 mg kg –1, Pb 11.0 mg kg –1, Zn 25.5 mg kg –1. The results indicated that cadmium and mercury concentrations in the mineral and organogenic soils differed. Some of the arsenic, cadmium and mercury concentrations exceeded the normative values but did not exceed limit values. Most of the agricultural fields in South Savo province contained only small amounts of arsenic and heavy metals and could be classified as “Clean Soil”. A draft for the target values of arsenic and heavy metal concentrations in “Clean Soil” is presented.;


Author(s):  
Mojtaba Arjomandi ◽  
*Hamid Shirkhanloo

Heavy metals are vital and necessary in our daily lives. Moreover, if the amounts of heavy metals are more than the acceptable amounts (mentioned by WHO) in soil, water, and air, indeed, they cause a lot of diseases in human bodies. Therefore, monitoring and measuring the amounts of heavy metals that are arduous and difficult are so important. In this review paper, a lot of studies that have been carried out on the determination and quantification of heavy metals in human bodies, soil, and water are considered. Moreover, the effect of toxicity of each heavy metal on human health is assessed. According to WHO, EPA, NIOSH, ACGIH, and clinical chemistry, the determination of heavy metals such as Cd, Pb, Zn, Hg, Cu, Mn is very important in the human body and Environmental matrixes. 


2021 ◽  
Vol 2 (5) ◽  
pp. 24-28
Author(s):  
Nnamdi Michael Ahiamadu ◽  
Ify L. Nwaogazie ◽  
Yusuf O. L. Momoh

The study assessed the concentration of heavy metals in three oil spill sites in Emohua local government area in Rivers State, Nigeria. Soil samples were collected at depth 0-30cm for surface soil samples and up to 10m for sub-surface soil samples depending on the depth of borehole. Groundwater samples were collected from drilled boreholes while the surface water samples were collected from fishponds or water bodies (rivers) close to the oil spill sites. The samples taken from the oil spill sites were analysed to determine the level of concentration of 10 Department of Petroleum Resource (DPR) specified heavy metals (Cd, Zn, Cu, Pb, Cr, Ba, Ni, Hg, As, and Co). BUCK Scientific Atomic Absorption Spectrophotometer (AAS) was used in detecting the concentration of the heavy metals. For the surface soil, Pb concentration in site A and B were significantly higher than what was obtained at site C, with a mean concentration of 219.70, 130.01 and 3.41mg/kg respectively for the three sites. The mean lead (Pb) concentration obtained in the surface soil was within DPR and United State Environmental Protection Agency (USEPA) acceptable limits. Barium also has significant concentration in both the surface soil and sub-surface soil. Kruskal Wallis test indicated significant difference in the Pb, Cd, Zn, Cu, Cr and Ba concentration in surface/topsoil among the three sites and also indicated significant difference in the concentrations of Pb, Cd, Cr, Ni, Ba and As in sub-surface soil among the sites. Little heavy metal concentration was found in both the groundwater and surface water. The study showed that even if some heavy metals were detected at the oil spill sites, they do not pose any serious health risk, as all the heavy metals in the four environmental media at the three sampling sites were below the national limit stipulated by the Department of Petroleum Resource (DPR), Nigeria.


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