scholarly journals Preparation and Properties of Alkali Activated Coarse Aggregates Using Fly Ash and Slag

Author(s):  
Rugma Sunil ◽  
Parvathy Panicker L ◽  
R. Megha ◽  
Athira K. Vijayan ◽  
Ramaswamy K. P

Coarse aggregate is an essential component of concrete which influences the properties of concrete. Generally, natural crushed stones are being used for the concrete production. The increased demand of aggregates for concrete production can be countered by using alternate aggregates. Production of artificial aggregates from industrial wastes appear as a promising and sustainable alternative to natural aggregates as it helps in utilizing large amount of industrial byproducts in concrete, reduces environmental pollution and also relieves the issues involved in their waste disposal. Hence, this study aims at the utilization of industrial wastes (fly ash and slag) for the manufacture of synthetic aggregates which could be a potential sustainable alternative for the coarse aggregates. Cold bonded pelletized aggregates were prepared by using alkali-activated Class F fly ash and ground granulated blast furnace slag. Alkali mixture of sodium silicate (Na2SiO3) and 10M sodium hydroxide (NaOH) solution were used for the chemical activation of fly ash and slag. Two types of synthetic aggregates were prepared using the fabricated disc pelletizer; mix containing only slag and another mix with equal proportion of fly ash and slag, and the aggregates were heat cured for 24 hours. Tests were done to determine properties such as aggregate surface texture and shape, particle size distribution, bulk density and specific gravity, and the results were compared with the properties of normal aggregates (natural crushed stones). The results indicate that synthetic aggregates made by alkali activation of fly ash and slag could be a potential alternative to the crushed stones.

2019 ◽  
Vol 9 (3) ◽  
pp. 4213-4217 ◽  
Author(s):  
A. H. Buller ◽  
M. Oad ◽  
B. A. Memon ◽  
S. Sohu

In this article, the effect of prolonged fire (24-hour duration) on reinforced concrete beams made with recycled aggregates from demolished concrete was experimentally investigated. Demolished concrete was used recycled coarse aggregates in equal proportion with natural coarse aggregates. Normal and rich mix concrete with water-cement ratio equal to 0.54 were used. As a control specimen, beams with all-natural aggregates were also cast to compare with the results of the proposed beams. All beams were cured for 28 days and exposed to fire at 1000°C in an oven for 24 hours. After the elapse of this fire period, the beams were allowed to air cool, followed by testing till failure in a universal load testing machine. Comparison of the test results shows that rich mix concrete beams more reduction in flexural strength, more increase in maximum load carrying capacity and deflection than normal mix beams. The maximum reduction in flexural strength was 32.41% for beams cast with 50% RCA and rich mix. Although the fire duration used in this study is rare, yet the outcome provides guidelines for taking proper decisions for retrofitting/strengthening of the fire affected structure before putting it back in service.


2020 ◽  
Vol 10 (3) ◽  
pp. 5728-5731 ◽  
Author(s):  
S. A. Chandio ◽  
B. A. Memon ◽  
M. Oad ◽  
F. A. Chandio ◽  
M. U. Memon

This research paper aims at investigating the effects of fly ash as cement replacement in green concrete made with partial replacement of conventional coarse aggregates with coarse aggregates from demolishing waste. Green concrete developed with waste materials is an active area of research as it helps in reducing the waste management issues and protecting the environment. Six concrete mixes were prepared using 1:2:4 ratio and demolishing waste was used in equal proportion with conventional aggregates, whereas fly ash was used from 0%-10% with an increment of 2.5%. The water-cement ratio used was equal to 0.5. Out of these mixes, one mix was prepared with all conventional aggregates and was used as the control, and one mix with 0% fly ash had only conventional and recycled aggregates. The slump test of all mixes was determined. A total of 18 cylinders of standard size were prepared and cured for 28 days. After curing the compressive strength of the specimens was evaluated under gradually increasing load until failure. It is observed that 5% replacement of cement with fly ash and 50% recycled aggregates gives better results. With this level of dosage of two waste materials, the reduction in compressive strength is about 11%.


2021 ◽  
Vol 25 (1) ◽  
pp. 931-943
Author(s):  
Girts Bumanis ◽  
Danute Vaiciukyniene

Abstract The search for alternative alumosilicates source for production of alkali activated materials (AAM) is intensively researched. Wide spread of natural materials such as clays and waste materials are one of potential alternatives. In this research AAM was made from local waste brick made of red clay and calcined low-carbonate illite clay precursor and its properties evaluated. Waste silica gel containing amorphous silica from fertilizer production plant was proposed as additional raw material. 6 M and 7 M NaOH alkali activation solutions were used to obtain AAM. Raw materials were characterized by X-ray diffraction, laser particle size analyser, DTA/TG. Raw illite clay was calcined at a temperature of 700 to 800 °C. Waste brick was ground similar as raw clay and powder was obtained. Replacement of red clay with silica gel from 2–50 wt.% in mixture composition was evaluated. Results indicate that the most effective activator was 6 M NaOH solution and AAM with strength up to 13 MPa was obtained. Ground brick had the highest strength results and compressive strength of AAM reached 25 MPa. Silica gel in small quantities had little effect of AAM strength while significant strength reduction was observed with the increase silica gel content. The efflorescence was observed for samples with silica gel.


2018 ◽  
Vol 761 ◽  
pp. 3-6 ◽  
Author(s):  
Violeta Nikolić ◽  
Miroslav Komljenović ◽  
Nataša Džunuzović ◽  
Tijana Ivanovic

This paper investigates the influence of mechanical activation of fly ash on the toxic metals immobilization by fly ash-based geopolymers. Fly ash was firstly mechanically and then alkali-activated. Mechanical activation of fly ash was conducted in a planetary ball mill. Alkali activation of fly ash was carried out at room temperature by use of sodium silicate solution as an activator. Toxic metals (Pb and Cr) were added in the form of water soluble salts during the synthesis of geopolymers. The immobilization process was assessed via investigation of the mechanical and leaching properties of geopolymers. Structural changes of geopolymers during the toxic metals immobilization were assessed by means of gas adsorption and SEM analyses. Mechanical activation of fly ash led to a significant increase in geopolymer strength and to a reduced leaching of toxic metals from geopolymers.


2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Fotini Kesikidou ◽  
Stavroula Konopisi ◽  
Eleftherios K. Anastasiou

This study investigated the use of concrete sludge, a by-product of the ready-mix concrete industry, in combination with high-calcium fly ash in binary cementless binders. Concrete sludge was used in substitution rates ranging from 0% to 60% in test fly ash-based mortars to determine potential synergy. The mortars were tested for fresh and hardened properties; workability, viscosity, strength development, open porosity, early-age shrinkage, and analytical tests were carried out. A mortar with 50% fly ash and 50% limestone filler as binders was used for comparison purposes. Furthermore, a series of mortars with fly ash and concrete sludge were alkali-activated in order to determine potential strength gain. In the activated mortars, two fractions of concrete sludge were used, under 75 μm and 200 μm, due to different silicon oxide contents, while one mortar was cured at 40°C to investigate the effect of heating on alkali activation. Results show that sludge contributes to the formation of C-S-H and strength development when used in combination with high-calcium fly ash even at high replacement rates. The alkali activation of fly ash-concrete sludge system contributed to early-age strength development and to early-age shrinkage reduction.


In the present scenario, the production of green and sustainable concrete has become a must to substitute the ordinary Portland cement (OPC) concrete. It is an eminent fact that the manufacture of OPC requires burning of its raw materials which lead to a huge amount of carbon dioxide liberation; thus it requires a large amount of energy dissipation. The concrete produced using alkali activation has become renowned methods to replace the conventional OPC, which gives an answer to find a way to produce environmentally friendly concrete. In the current study, the alkaline activator used to activate the binder was sodium hydroxide solution dispersed in liquid sodium silicate. The utilization of industrial dissipate materials such as GGBS, fly ash, and waste glass powder was used as the binding ingredients, and stone crusher dust was used as fine aggregates. The experimental investigation showed that a quality concrete can be easily produced using alkali activation of industrial wastes satisfying its strength requirements. The statistical models developed shown that there is a significant relationship between various cube and cylinder strengths. Thus alkali-activated concrete(AAC) can effectively reduce the environmental hazards associated with OPC concrete, which also provides an effective way of utilizing major industrial byproducts


2021 ◽  
pp. 252-261

The combustion of fossil fuels results in creating a lot of solid wastes such as fly ash and slag. However, these environmentally unfriendly materials can be used as a raw material for alkali activation – geopolymerization. Although these wastes have been successfully used in industrial production for several decades, its use does not achieve the level of its potential. Today, to achieve a sustainable construction industry, alternative cement has been extensively investigated. Geopolymer (GP) is a kind of material that is obtained from the alkaline activator, and it can be produced from industrial wastes or by-products. The aim of this work was to describe the improvement of mechanical properties of alkali-activated binders – geopolymers made of fly ash and blast furnace slag. The effect of the addition of waste glass in three different values feed into fly ash or GGBFS, and its impact on mechanical properties (compressive and flexural strengths) of geopolymers was examined. The highest value of compressive strength was achieved with 20% waste glass addition to a fly ash sample on 90th day 58,9 MPa. The waste glass was added in the form of broken and crushed glass particles.


PLoS ONE ◽  
2020 ◽  
Vol 15 (11) ◽  
pp. e0242462
Author(s):  
Tero Luukkonen ◽  
Juho Yliniemi ◽  
Paivo Kinnunen ◽  
Mirja Illikainen

Concrete production is globally a major water consumer, and in general, drinking-quality water is mixed in the binder. In the present study, simulated sea water and reverse osmosis reject water were used as batching water for one-part (dry-mix) alkali-activated blast furnace slag mortar. Alkali-activated materials are low-CO2 alternative binders gaining world-wide acceptance in construction. However, their production requires approximately similar amount of water as regular Portland cement concrete. The results of the present study revealed that the use of saline water did not hinder strength development, increased setting time, and did not affect workability. The salts incorporated in the binder decreased the total porosity of mortar, but they did not form separate phases detectable with X-ray diffraction or scanning electron microscopy. Leaching tests for monolithic materials revealed only minimal leaching. Furthermore, results for crushed mortars (by a standard two-stage leaching test) were within the limits of non-hazardous waste. Thus, the results indicated that high-salinity waters can be used safely in one-part alkali-activated slag to prepare high-strength mortars. Moreover, alkali-activation technology could be used as a novel stabilization/solidification method for reverse osmosis reject waters, which frequently pose disposal problems.


Author(s):  
Barkha Verma

Abstract: Aggregates provide volume at low cost, comprising 66% to 78% of the concrete. With increasing concern over the excessive exploitation of natural and quality aggregates, the aggregate produced from industrial wastes and agricultural wastes is the viable new source for building material. This study was carried out to determine the possibilities of using coconut shells as aggregate in concrete. Utilizing coconut shells as aggregate in concrete production not only solves the problem of disposing of this solid waste but also helps conserve natural resources. In this paper, the physical properties of crushed coconut shell aggregate were presented. The fresh concrete properties such as the density and slump and 28 days compressive strength of lightweight concrete made with coconut shell as coarse aggregate were also presented. The findings indicate that water absorption of the coconut shell aggregate was high about 24% but crushing value and impact value were comparable to that of other lightweight aggregates. The average fresh concrete density and 28days cube compressive strength of the concrete using coconut shell aggregate 1975kg/m3 and 19.1 N/mm2 respectively. It is concluded that crushed coconut shell is suitable when it is used as a substitute for conventional aggregates in lightweight concrete production. Keywords: Coarse Aggregate, Cement, Concrete, Fly Ash, Coconut shell Aggregate, Water, Compressive Strength, Workability, Fine Aggregate.


Minerals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 40 ◽  
Author(s):  
Vytautas Bocullo ◽  
Danutė Vaičiukynienė ◽  
Ramūnas Gečys ◽  
Mindaugas Daukšys

This research presents the influence of ordinary Portland cement (OPC) and/or water glass addition on fly ash alkali-activated mortar and concrete. The results show that fly ash (FA) concrete activated with a NaOH solution and water glass mixture had better resistance to freeze and thaw, carbonation, alkali-silica reaction (ASR) and developed higher compressive strength and static elastic modulus compared with the FA concrete activated only with an NaOH solution. The addition of OPC contributes to the development of a denser microstructure of alkali activated concrete (AAC) samples. In the presence of water glass and OPC, the compressive strength (52.60 MPa) of the samples increased more than two times as compared with the reference sample (21.36 MPa) without OPC and water glass. The combination of OPC and water glass showed the increased strength and enhanced durability of AAC. The samples were more resistant to freeze and thaw, ASR, and carbonation.


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