scholarly journals Migration behaviour of fluoride in contaminated soils near ammophos production plant: laboratory studies

2020 ◽  
Vol 64 (4) ◽  
Author(s):  
Andrey Litvinovich ◽  
Olga Pavlova ◽  
Anton Lavrishchev ◽  
Vladimir Bure ◽  
Elmira Saljnikov

Fluoride contamination of irrigated alkaline soils (Irragric Anthrosols) is a common problem in the areas of vast cotton production in Uzbekistan. Large number of laboratory measurements using corresponding models allows deeper studying the fluoride mobility in contaminated soil in the vicinity of Ammophos production factory. In a series of column experiments the migration ability of fluoride was studied in Irragric Anthrosols of different particle size distribution and four different experiments using near neutral and acidic washing water in the low, moderate and highly contaminated soils. It has been established that studied soils, located in the zone of airborne emissions from the Ammophos production plants, have a weak fluoride-holding capacity. The intensity of fluoride migration was conditioned by the initial level of soil contamination. Repeated simulated irrigation of the soil didn’t result in complete removal of fluoride. At low contamination level (3.5 mg F/kg soil) on sandy-loam soil, concentration of fluoride increased with increasing of the volume of leaching moisture. With medium contamination level (6.1 mg F/kg soil) on a loamy soil, the average leaching rate was near zero throughout the measurement interval. At high contamination level (17.5 mg/kg) on heavy textured soil, the increase in the concentration of fluoride in the eluates was observed throughout the entire study interval and posed a threat of ground water contamination.

Soil Research ◽  
2019 ◽  
Vol 57 (8) ◽  
pp. 814 ◽  
Author(s):  
Arkadiusz Telesiński ◽  
Teresa Krzyśko-Łupicka ◽  
Krystyna Cybulska ◽  
Barbara Pawłowska ◽  
Robert Biczak ◽  
...  

This study used laboratory experiments to compare the effects of coal tar creosote on the activity of oxidoreductive enzymes in sandy loam, loamy sand and sandy clay loam soils. Different amounts of coal tar creosote were added to soil samples as follows: 0 (control), 2, 10 or 50 g kg–1 dry matter. The activity of soil dehydrogenases (DHAs), o-diphenol oxidase (o-DPO), catalase (CAT), nitrate reductase (NR) and peroxidases (POX) was determined. Contamination of soil with coal tar creosote affected oxidoreductase activity. Oxidoreductive enzyme activity following soil contamination with coal tar creosote was in the following order: DHAs > CAT > NR > POX > o-DPO in loamy sand and in sandy loam; and DHAs > POX > CAT > NR > o-DPO in sandy clay loam. The index of soil oxidoreductive activity (IOx) introduced in this study confirms the negative effect of coal tar creosote on oxidoreductase activity in soil. DHAs were the most sensitive to the contamination of soil with coal tar creosote. Moreover, the greatest changes in oxidoreductase activities were observed in loamy sand. Knowledge of the mechanism underlying the effects of coal tar creosote on oxidoreductive processes may enable development of a method for the bioremediation of polycyclic aromatic hydrocarbon-contaminated soils.


2009 ◽  
Vol 2009 ◽  
pp. 1-8 ◽  
Author(s):  
M. Camps Arbestain ◽  
L. Rodríguez-Lado ◽  
M. Bao ◽  
F. Macías

Mercury contamination of soils and vegetation close to an abandoned Hg-fulminate production plant was investigated. Maximum concentrations of Hg (>6.5 gkg−1soil) were found in the soils located in the area where the wastewater produced during the washing procedures carried out at the production plant used to be discharged. A few meters away from the discharge area, Hg concentrations decreased to levels ranging between 1 and 5 gkg−1, whereas about 0.5 ha of the surrounding soil to the NE (following the dominant surface flow direction) contained between 0.1 and 1 gkg−1. Mercury contamination of soils was attributed (in addition to spills from Hg containers) to (i) Hg volatilization with subsequent condensation in cooler areas of the production plant and in the surrounding forest stands, and (ii) movement of water either by lateral subsurface flow through the contaminated soils or by heavy runoff to surface waters.


Geosciences ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 332 ◽  
Author(s):  
Manar Hasan ◽  
Abdul-Sahib Al-Madhhachi

Iraqi soil contamination greatly influenced soil detachment. Previous researchers have not been able to predict the influence of crude oil soil contamination on either the mechanistic dimensional detachment parameter b0 or the threshold parameter b1 of the mechanistic detachment model (Wilson model). The aims of this research were (1) to investigate the influence of crude oil on deriving Wilson model parameters, b0 and b1, with two setups at different scales and different soil moisture contents and (2) to predict b0 and b1 in crude oil contaminated dry soils with varying levels of contamination. The “mini” JET apparatus was implemented under laboratory conditions for soil specimens packed at both a small (standard mold) and a large (in-situ soil box) scale. The results showed an inverse correlation between b0 and water content for clean soil. No correlation between b0 and soil moisture content was observed for contaminated soils. There was a huge reduction in the b0 value as the contamination time increased compared to the clean soil. This was related to the role crude oil plays in soil stabilization. Crude oil contamination significantly increased lead contamination level while slightly increasing the pH and total organic carbon. The influence of crude oil on mechanistic soil detachment can be predicted with a priori JET experiments on soils without crude oil based on crude oil parameters.


ISRN Agronomy ◽  
2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Subash Chandra Shaha ◽  
Md. Abul Kashem ◽  
Khan Towhid Osman

An experiment was conducted to investigate the effect of lime and farmyard manure on the concentration of cadmium in water spinach. Water spinach (Ipomoea aquatica cv. Kankon) was grown in sandy loam soil spiked with 5 mg Cd with lime (L) and farmyard manure (M) amendments. The treatments consisted of control, four levels of L (5, 10, 15, and 20 t ), M (5, 10, 15, and 20 t ), and their combinations (55, 1010, 1515, and 2020 t ). Growth parameters of water spinach increased significantly with the addition of lime and farmyard manure in the soil. Lime addition to soil decreased Cd concentration in both shoot and root of water spinach. In control (00), Cd concentration was 62.67 mg  in shoot, and 135.5 mg  in root. Cadmium concentration decreased by 72, 15, and 66% over the control in shoot and 82, 28, and 76% in the roots correspondingly with the highest rate of lime (20 t ), manure (20 t ), and lime plus manure combinations (20 t  20 t ). The results imply that 5 to 10 t  lime could be used in Cd-contaminated soils to reduce Cd uptake by agricultural crops.


PeerJ ◽  
2018 ◽  
Vol 6 ◽  
pp. e6076 ◽  
Author(s):  
Hadia -e- Fatima ◽  
Ambreen Ahmed

Bacteria are tiny organisms which are ubiquitously found in the environment. These microscopic living bodies are responsible for the flow of nutrients in biogeochemical cycles and fertility imparted to the soil. Release of excessive chromium in agricultural soils due to rapid growth of industries may result in minimizing the fertility of soil in future, which will lead to reduction in crop production. Plant growth promoting bacteria (PGPB) are beneficial to the environment, some of which can tolerate chromium and protect plants against heavy metal stress. The current study aims to identify such chromium-tolerant auxin-producing rhizobacteria and to investigate their inoculation effects on the growth characteristics of Lens culinaris in chromium polluted soils by using two different chromium salts i.e., K2Cr2O7 and K2CrO4 in varying concentrations (0, 50, 100, 200, 400 and 500 µgml−1). The results revealed that Bacillus species are efficient in significantly reducing the deleterious effects of Cr. These effective bacterial strains were able to stimulate the growth of metal effected plants of Lens culinaris which were grown in chromium contaminated environment. Therefore, these plant growth promoting rhizobacteria PGPRs, having both auxin production potential and chromium-resistance ability, are considered as efficient micro-factories against chromium pollution.


2020 ◽  
Vol 47 (3) ◽  
pp. 173-179
Author(s):  
M. C. Lamb ◽  
R. B. Sorensen ◽  
C. L. Butts

ABSTRACT Although the Southeast U.S. receives an average annual precipitation of 1300 mm, crop yields are often limited by erratic seasonal rainfall distributions. Studies were conducted from 2001 through 2017 at the USDA/ARS Multi-crop Irrigation Research Farm in Shellman, GA (84°36′ W, 30°44′ N) on a Greenville fine sandy loam (fine, kaolinitic, thermic Rhodic Kandiudults). The objective of this long-term study is to evaluate the effects of irrigation and crop rotation sequencing consisting of peanut, corn, and cotton on yield and net economic returns to both variable and total costs. Analysis included the entire study period and was also separated for years with below and above average rainfall. When averaged across all years, irrigation increased peanut, corn, and cotton yield and net returns compared with non-irrigation. Six different rotation sequences were addressed inclusive of continuous peanut, one year out of peanut with corn or cotton, and two years out of peanut with combinations of corn and cotton. In both irrigated and non-irrigated peanuts, the least and greatest yields were from continuous peanut and the two year out rotations, respectively. No peanut yield difference resulted with corn or cotton rotation partners for the rotation sequence. Length of rotation between peanut years did influence peanut yield and net returns. Profitability and optimal rotation sequence within any cropping system depended on irrigation, yield, crop price, and production costs for peanut, corn, and cotton.


Plants ◽  
2020 ◽  
Vol 9 (12) ◽  
pp. 1629
Author(s):  
Azhar Mahmood Aulakh ◽  
Ghulam Qadir ◽  
Fayyaz Ul Hassan ◽  
Rifat Hayat ◽  
Tariq Sultan ◽  
...  

Drought is a major constraint in drylands for crop production. Plant associated microbes can help plants in acquisition of soil nutrients to enhance productivity in stressful conditions. The current study was designed to illuminate the effectiveness of desert rhizobacterial strains on growth and net-return of chickpeas grown in pots by using sandy loam soil of Thal Pakistan desert. A total of 125 rhizobacterial strains were isolated, out of which 72 strains were inoculated with chickpeas in the growth chamber for 75 days to screen most efficient isolates. Amongst all, six bacterial strains (two rhizobia and four plant growth promoting rhizobacterial strains) significantly enhanced nodulation and shoot-root length as compared to other treatments. These promising strains were morphologically and biochemically characterized and identified through 16sRNA sequencing. Then, eight consortia of the identified isolates were formulated to evaluate the growth and development of chickpea at three moisture levels (55%, 75% and 95% of field capacity) in a glass house experiment. The trend for best performing consortia in terms of growth and development of chickpea remained T2 at moisture level 1 > T7 at moisture level 2 > T4 at moisture level 3. The present study indicates the vital role of co-inoculated bacterial strains in growth enhancement of chickpea under low moisture availability. It is concluded from the results that the consortium T2 (Mesorhizobium ciceri RZ-11 + Bacillus subtilis RP-01 + Bacillus mojavensis RS-14) can perform best in drought conditions (55% field capacity) and T4 (Mesorhizobium ciceri RZ-11 + Enterobacter Cloacae RP-08 + Providencia vermicola RS-15) can be adopted in irrigated areas (95% field capacity) for maximum productivity of chickpea.


Author(s):  
Wouter Aerts ◽  
Thomas De Bruecker ◽  
Anna Lytek

Contaminated soils form a large part of the nuclear waste arising from decommissioning activities. The storage and disposal of these large volumes of waste is costly. For this reason techniques which can decontaminate this waste stream to free release levels are economically very interesting. A feasibility study of the possibilities of soil washing to decontaminate such soils was ordered by NIRAS/ONDRAF and performed at Belgoprocess in collaboration with DEC. Initial contamination level and particle size distributions of contaminated soils from three different sources were determined. The main isotopes detected with gamma spectrometry contained in the waste were 241Am, 137Cs, 226Ra, 60Co and 232Th. The particle size distribution revealed that more than half of the mass of the quartz sand that makes up the soil has a particle size between 125 and 212μm. This fraction is less contaminated than the fractions containing smaller particles. However, separation of the fines fraction (< 125 μm) was not enough to achieve the free release limit. Soil attrition was tested as an extra decontamination step for the sand fraction. The removal efficiencies for the different radionuclides contained in the soil were measured. The process conditions were optimized to achieve maximum removal and a treatment method for the secondary waste coming from this process step was determined. The soil washing process was not only performed with water but also with nitric acid to assess the possibilities of a combination of a mechanical and a chemical decontamination process. Reduction efficiencies of 60–80% for the most relevant radionuclides were recorded.


2021 ◽  
Vol 3 (7) ◽  
Author(s):  
Abdollah Yazdi ◽  
Ebrahim Sharifi Teshnizi

AbstractLeaking tanks may lead to severe contamination of their surrounding soil. The geotechnical behavior of the soil varies with the physicochemical processes that occur between the contaminant and the soil. In this respect, studying the geochemical properties of gasoline-contaminated soils and sediments seems to be important for engineering and especially environmental purposes. In this paper, laboratory tests were carried out to examine the effects of crude gasoline contamination on some of the geotechnical properties of a silty soil sampled from the Mashhad plain, located in the northeast of Iran. Tests consisted of basic properties, Atterberg limits, compaction, direct shear, and uniaxial compression tests, which were carried out on clean and contaminated soil samples at the same densities. The contaminated samples were prepared by mixing the soils with crude gasoline in the amounts of 3%, 6%, 9%, and 12% of dry weight and curing periods of 0, 7, 15, and 30 days. Results indicated a decrease in the friction angle and an increase in the cohesion of the soil by increasing gasoline content. Besides, a reduction in the maximum dry density and optimum moisture content was observed in the compaction test. The increase in gasoline percentage up to 6% also showed a direct effect on increasing the liquid limit and plastic limit of silty soil, which decreased thereafter. Moreover, any increase in gasoline percentage had a reverse effect on the modulus of elasticity of the soil. The increase in gasoline percentage up to 3% also had a direct impact on the uniaxial compressive strength of the soil, exceeding which it started to decline. Finally, the effects of contamination duration were examined by testing contaminated samples in periods of 7, 15, and 30 days under natural conditions. The results showed a reverse relationship with all geotechnical properties due to aging and a reduction in the gasoline content due to the evaporation of volatile compounds. Also, the numerical analysis of the laboratory results indicated an increase in settling and the percentage of shear strain beneath the foundation with increasing the contamination level, confirming the laboratory results.


2021 ◽  
Vol 244 ◽  
pp. 01011
Author(s):  
Oleg Selivanov ◽  
Anton Martsev

The article presents the content determining results of heavy metals and arsenic in sod-podzolic soils of the school grounds in Vladimir, Vladimir region. According to the accumulation indicator, the accumulation intensity of heavy metals and arsenic in these areas has been determined, which is decreasing in the series of Pb→As→Cu→Zn→Ni. The calculation of the pollutants hazard coefficient showed that their MPC excess decreases in the series of As→Zn→Pb→Cu→Ni. The soil pollution level has been assessed for the school grounds and their ecological situation has been evaluated applying the cumulative indicator of soil pollution with heavy metals and soil pollution index. The values of the soil pollution cumulative indicator of school territories indicate dangerous and moderately dangerous contamination level of the studied soils, and the calculated values of the soil pollution index refer these soils to the category of “contaminated” soils, which poses potential risks for the schoolchildren health.


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