scholarly journals Use of combined UASB + eMBR treatment for removal of emerging micropollutants and reduction of fouling

Author(s):  
Karen Mora-Cabrera ◽  
Carlos Peña-Guzmán ◽  
Arturo Trapote ◽  
Daniel Prats

Abstract This study employs a novel combined pilot plant consisting of an anaerobic reactor followed by a membrane electro-bioreactor (eMBR) to treat domestic water containing selected micro-pollutants of emerging concern (CECs) [ibuprofen (IB), carbamazepine, diclofenac (DCF) and 17α-ethinylestradiol (EE2)]. The first phase operated as a conventional membrane bioreactor to achieve the removal of organic matter [chemical oxygen demand (COD)], the CECs and phosphorus. A removal rate of 96.3% for COD, 94.5% for IB, 37.1% for CMZ, 87.1% for DCF and 96% for EE2 was obtained. In the three subsequent phases, current density (CD) of 5, 10 and 15 A/m2 was applied successively in the eMBR with the aim of investigating the effects on the removal of the former components and the fouling of the membrane. After the application of 5 and 10 A/m2 CD, the removal rate of COD decreased. Regarding phosphorus, a CD of 5 A/m2 was enough to achieve the rate of 97% and the membrane fouling suffered a substantial reduction too. Finally, the experimental results were subject to statistical analysis using the Kruskal–Wallis and Wilcoxon tests to validate the influence of each DC.

Membranes ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 420
Author(s):  
Chunyan Huang ◽  
Hongju Liu ◽  
Shujuan Meng ◽  
Dawei Liang

Recently, dynamic membrane bioreactor (DMBR) has gradually gained the interest of researchers for the development of membrane technology. In this paper, we set up parallel experiments to investigate the effect of powder activated carbon (PAC) on organic matter removal, transmembrane pressure, and filter cake layer characterization to make an overall performance assessment of DMBR. The results showed that DMBR has a good removal effect on organic matter removal, and with a chemical oxygen demand removal rate over 85%. Protein was found to be the main membrane fouling substance. Due to the electric double-layer effect, membrane fouling tended to be alleviated when the PN/PS value was low. Using a filtration model under constant current conditions, the filtration process through the cake layer was observed to be consistent with cake-intermediate model.


2011 ◽  
Vol 365 ◽  
pp. 354-360 ◽  
Author(s):  
Shuo Liu ◽  
Ji Fu Wang ◽  
Bao Zhen Wang ◽  
Bing Wang ◽  
Wei Wan

To solve the problem of eutrophication in receiving water, a novel Membrane Bioreactor (MBR) with combined configuration was designed for municipal wastewater treatment and reclamation. By dividing bioreactor into three zones, the combined MBR operated under anoxic, anaerobic and aerobic conditions. It provided optimum conditions for nitrification, denitrifying and phosphate accumulating bacterial growth which resulted in high biological nutrient removal rate directly. The operational performance of combined MBR pilot plant showed that it exhibited high nutrient removal rate on Chemical oxygen demand (CODcr), total nitrogen (TN) and total phosphorus (TP). The mean value of effluent CODcr, TN and TP removal rate was 90.63%, 63.05% and 60.51% respectively during 180 days of operation. In order to obtain stable membrane flux, the combined MBR packed with fibrous bio-film carrier and added diatomite. Furthermore, it could alleviate membrane fouling effectively. As a result, the combined MBR improved effluent water quality significantly and alleviated membrane fouling remarkably.


2011 ◽  
Vol 63 (4) ◽  
pp. 733-740 ◽  
Author(s):  
E. Sahar ◽  
M. Ernst ◽  
M. Godehardt ◽  
A. Hein ◽  
J. Herr ◽  
...  

The potential of membrane bioreactor (MBR) systems to remove organic micropollutants was investigated at different scales, operational conditions, and locations. The effluent quality of the MBR system was compared with that of a plant combining conventional activated sludge (CAS) followed by ultrafiltration (UF). The MBR and CAS-UF systems were operated and tested in parallel. An MBR pilot plant in Israel was operated for over a year at a mixed liquor suspended solids (MLSS) range of 2.8–10.6 g/L. The MBR achieved removal rates comparable to those of a CAS-UF plant at the Tel-Aviv wastewater treatment plant (WWTP) for macrolide antibiotics such as roxythromycin, clarithromycin, and erythromycin and slightly higher removal rates than the CAS-UF for sulfonamides. A laboratory scale MBR unit in Berlin – at an MLSS of 6–9 g/L – showed better removal rates for macrolide antibiotics, trimethoprim, and 5-tolyltriazole compared to the CAS process of the Ruhleben sewage treatment plant (STP) in Berlin when both were fed with identical quality raw wastewater. The Berlin CAS exhibited significantly better benzotriazole removal and slightly better sulfamethoxazole and 4-tolyltriazole removal than its MBR counterpart. Pilot MBR tests (MLSS of 12 g/L) in Aachen, Germany, showed that operating flux significantly affected the resulting membrane fouling rate, but the removal rates of dissolved organic matter and of bisphenol A were not affected.


RSC Advances ◽  
2021 ◽  
Vol 11 (50) ◽  
pp. 31364-31372
Author(s):  
Mengjing Cao ◽  
Yongxiang Zhang ◽  
Yan Zhang

A novel and amplifying anaerobic electrochemical membrane bioreactor was constructed and operated for a long time (204 days) with synthetic glucose solution having an average chemical oxygen demand (COD) of 315 mg L−1, at different applied voltages and room temperatures.


Water ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1803 ◽  
Author(s):  
Yuko Goto ◽  
Naoko Yoshida

Conventional aerobic treatment of swine wastewater, which generally contains 4500–8200 mg L−1 of organic matter, is energy-consuming. The aim of this study was to assess the application of scaled-up microbial fuel cells (MFCs) with different capacities (i.e., 1.5 L, 12 L, and 100 L) for removing organic matter from swine wastewater. The MFCs were single-chambered, consisting of an anode of microbially reduced graphene oxide (rGO) and an air-cathode of platinum-coated carbon cloth. The MFCs were polarized via an external resistance of 3–10 Ω for 40 days for the 1.5 L-MFC and 120 days for the 12L- and 100 L-MFC. The MFCs were operated in continuous flow mode (hydraulic retention time: 3–5 days). The 100 L-MFC achieved an average chemical oxygen demand (COD) removal efficiency of 52%, which corresponded to a COD removal rate of 530 mg L−1 d−1. Moreover, the 100 L-MFC showed an average and maximum electricity generation of 0.6 and 2.2 Wh m−3, respectively. Our findings suggest that MFCs can effectively be used for swine wastewater treatment coupled with the simultaneous generation of electricity.


2017 ◽  
Vol 30 (1) ◽  
pp. 1-10 ◽  
Author(s):  
Thi Thu Nga Vu ◽  
Manon Montaner ◽  
Christelle Guigui

Wastewater effluents can be treated by an integrated membrane system combining membrane bioreactor (MBR) and reverse osmosis (RO) for effective removal of micropollutants in the field of high-quality water reuse. However, discharging the RO concentrate waste stream directly into the natural environment could lead to serious problems due to the toxic components contained in the concentrates (micropollutants, salts, organic matter). A possible solution could be the recirculation of RO concentrate waste to the MBR. However, such an operation should be studied in detail since the recirculation of non-biodegradable organic matter or high concentrations of salts and micropollutants could directly or indirectly contribute to MBR membrane fouling and modification of the biodegradation activity. In this context, the work reported here focused on the recirculation of such concentrates in an MBR, paying specific attention to MBR membrane fouling. Lab-scale experiments were performed on a continuous MBR-RO treatment line with RO concentrate recirculation. The main goal was to determine the recovery of the RO unit and of the global process that maintained good process performance in terms of biodegradation and MBR fouling. The results demonstrate that the impact of the toxic flow on activated sludge depends on the recovery of the RO step but the same trends were observed regardless of the organic matter and salt contents of the concentrates: the concentration of proteins increased slightly. Size-exclusion high performance liquid chromatography (HPLC-SEC) was employed to study the effects of RO concentrate on the production of protein-like soluble microbial products (SMPs) and demonstrated a significant peak of protein-like substances corresponding to 10-100 kDa and 100-1 000 kDa molecules in the supernatant. Thus a significant increase in the propensity for sludge fouling was observed, which could be attributed to the increased quantity of protein-like substances. Finally, the effect of the concentrate on sludge activity was studied and no significant effect was observed on biodegradation, indicating that the return of the concentrate to the MBR could be a good alternative.


2012 ◽  
Vol 66 (12) ◽  
pp. 2546-2555 ◽  
Author(s):  
Miyoung Choi ◽  
Dong Whan Choi ◽  
Jung Yeol Lee ◽  
Young Suk Kim ◽  
Bun Su Kim ◽  
...  

Growing attention is given to pharmaceutical residue in the water environment. It is known that pharmaceuticals are able to survive from a series of wastewater treatment processes. Concerns regarding pharmaceutical residues are attributed to the fact that they are being detected in water and sediment environment ubiquitously. Pharmaceutical treatment using a series of wastewater treatment processes of the DAF (dissolved air flotation)–MBR (membrane bioreactor)–ozone oxidation was conducted in the study. DAF, without addition of coagulant, could remove CODcr (chemical oxygen demand by Cr) up to over 70%, BOD 73%, SS 83%, T-N 55%, NH4+ 23%, and T-P 65% in influent of municipal wastewater. Average removal rates of water quality parameters by the DAF–MBR system were very high, e.g. CODcr 95.88%, BOD5 99.66%, CODmn (chemical oxygen demand by Mn) 93.63%, T-N 69.75%, NH4-N 98.46%, T-P 78.23%, and SS 99.51%, which satisfy effluent water quality standards. Despite the high removal rate of the wastewater treatment system, pharmaceuticals were eliminated to be about 50–99% by the MBR system, depending on specific pharmaceuticals. Ibuprofen was well removed by MBR system up to over 95%, while removal rate of bezafibrate ranged between 50 and 90%. With over 5 mg/l of ozone oxidation, most pharmaceuticals which survived the DAF–MBR process were removed completely or resulted in very low survival rate within the range of few micrograms per litre. However, some pharmaceuticals such as bezafibrate and naproxen tended to be resistant to ozone oxidation.


2012 ◽  
Vol 66 (8) ◽  
pp. 1774-1780 ◽  
Author(s):  
V. Boonyaroj ◽  
C. Chiemchaisri ◽  
W. Chiemchaisri ◽  
K. Yamamoto

Two-stage membrane bioreactor (MBR) system was applied to the treatment of landfill leachate from a solid waste disposal site in Thailand. The first stage anoxic reactor was equipped with an inclined tube module for sludge separation. It was followed by an aerobic stage with a hollow fiber membrane module for solid liquid separation. Mixed liquor sludge from the aerobic reactor was re-circulated back to anoxic reactor in order to maintain constant mixed liquor suspended solids (MLSS) concentration in the aerobic reactor. The removal of micro-pollutants from landfill leachate along the treatment period of 300 days was monitored. The results indicated that two-stage MBRs could remove biochemical oxygen demand (BOD), chemical oxygen demand (COD) and NH4+ by 97, 87 and 91% at steady operating condition. Meanwhile organic micro-pollutant removals were 50–76%. The removal efficiencies varied according to the hydrophobic characteristic of compounds but they were improved during long-term MBR operation without sludge discharge.


2017 ◽  
Vol 8 (1) ◽  
Author(s):  
C–Y. Chang ◽  
Roger Ben Aim ◽  
S. Vigneswaran ◽  
J–S. Chang ◽  
S–L. Chen

A laboratory scale membrane bioreactor (MBR) fed on real septic tank effluent was studied at different levels of alkalinity (0, 250 and 500 mg NaHCO3/L addition) and sludge retention time (SRT, complete sludge retention, 10 and 20 days). A long–term operation of 267 days was divided into 5 stages to examine the SRT and alkalinity influences on parameters related to nitrification, chemical oxygen demand (COD) removal, extracellular polymeric substances (EPS) production and membrane cleaning. The results of the study showed that the removals of TCOD, SCOD and NH4+–N varied between 86–94%, 71–86%, and 70–94%, respectively. Appropriate alkalinity supplement and SRT control can enhance the COD removal and nitrification. Irreversible membrane fouling occurred fast and water cleaning for the improvement of filtration capacity was ineffective. The results also revealed that the rejection of EPS played a major role both in the enhancement of removal efficiency as well as the increase of filtration resistance during the operation.


Archaea ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Yue Li ◽  
Qi Hu ◽  
Da-Wen Gao

An integrated anaerobic fluidized-bed membrane bioreactor (IAFMBR) was investigated to treat synthetic high-strength benzothiazole wastewater (50 mg/L) at a hydraulic retention time (HRT) of 24, 18, and 12 h. The chemical oxygen demand (COD) removal efficiency (from 93.6% to 90.9%), the methane percentage (from 70.9% to 69.27%), and the methane yield (from 0.309 m3 CH4/kg·CODremoved to 0.316 m3 CH4/kg·CODremoved) were not affected by decreasing HRTs. However, it had an adverse effect on membrane fouling (decreasing service period from 5.3 d to 3.2 d) and benzothiazole removal efficiency (reducing it from 97.5% to 82.3%). Three sludge samples that were collected on day 185, day 240, and day 297 were analyzed using an Illumina® MiSeq platform. It is striking that the dominant genus of archaea was always Methanosaeta despite of HRTs. The proportions of Methanosaeta were 80.6% (HRT 24), 91.9% (HRT 18), and 91.2% (HRT 12). The dominant bacterial genera were Clostridium in proportions of 23.9% (HRT 24), 16.4% (HRT 18), and 15.3% (HRT 12), respectively.


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