Perchlorate, chlorate and bromate in water samples from the South-West coast of India

2012 ◽  
Vol 12 (5) ◽  
pp. 595-603 ◽  
Author(s):  
V. N. Anupama ◽  
K. Kannan ◽  
P. V. G. Prajeesh ◽  
S. Rugmini ◽  
B. Krishnakumar
Keyword(s):  
Surface Water ◽  
Water Samples ◽  
High Performance ◽  
Sea Water ◽  
Tap Water ◽  
Water Source ◽  
Well Water ◽  
The South ◽  
South West ◽  
South West Coast

Occurrence of perchlorate (ClO4−), chlorate (ClO3−) and bromate (BrO3−) in public drinking, open well and surface water sources at 20 locations in the South-West coastal state of Kerala (India) is reported. The analysis was performed by high performance liquid chromatography interfaced with tandem mass spectrometry (HPLC–MS/MS). Irrespective of water source (public tap water, open well water and surface water) all the analyzed samples contained high levels of ClO4−, indicating its contamination throughout the region. The highest ClO4− level found was 91.4 μg/L, which is 3.7 times higher than US EPA recommendations. ClO3− and BrO3− were also detected in the samples, with highest concentrations of 177 and 5.34 μg/L respectively in tap water samples. Regression analysis showed moderate positive correlation between ClO4− and bromide (Br−) in tap water (r2=0.659) and open well water (r2=0.485) samples, respectively. Similar correlation was also observed between ClO4− and Cl− (r2=0.591) concentrations in well water samples, indicating sea water could be one of the probable sources in addition to ClO4− manufacturing in the area. This is the first report of high levels of ClO4− and ClO3− and detectable BrO3− in water samples from anywhere in India.

scholarly journals Stable Isotope Reveals Tap Water Source under Different Water Supply Modes in the Eastern Margin of the Qinghai–Tibet Plateau

Water ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2578
Author(s):  
Mingxia Du ◽  
Mingjun Zhang ◽  
Shengjie Wang ◽  
Hongfei Meng ◽  
Cunwei Che ◽  
...  
Keyword(s):  
Surface Water ◽  
Water Supply ◽  
Water Samples ◽  
Tap Water ◽  
Water Source ◽  
Water Sources ◽  
Tibet Plateau ◽  
Water Isotopes ◽  
Source Water ◽  
Qinghai Tibet Plateau

Based on 1260 tap water samples gathered monthly and 136 surface water samples collected seasonally in the eastern margin of the Qinghai–Tibet Plateau, the local tap water line, the basic spatiotemporal characteristics of tap water isotopes, and their indication for water source under different water supply modes were discussed, linking the local tap water supply and water source information. A new tap water isotopes data set based on dense sampling sites was established, which was reliable for the analysis of tap water isotope features, tap water supply management, and tap water sources. The main conclusions are: (1) The local tap water lines in Gannan and Longnan are δ2H = (7.06 ± 0.17) δ18O + (3.24 ± 1.75) (r2 = 0.81, p < 0.01) and δ2H = (5.66 ± 0.09) δ18O + (−8.12 ± 0.82) (r2 = 0.82, p < 0.01), respectively. (2) The annual mean δ2H and δ18O in tap water show an increasing trend from southwest to northeast. The seasonal differences of δ2H and δ18O in tap water in Gannan and Longnan are small. (3) The correlation of tap water isotopes with those in main source water is high, while that of isotopes in tap water with those in non-water source is low. Under the central water supply mode by local tap water company, tap water isotopes in Gannan where groundwater is the direct water source show weak connection with those in surface water and precipitation, and those in tap water in Longnan with surface water as main source water reveal good connection with isotopes in surface water. Under mixed water supply modes, tap water isotopes indicate that surface water is the main tap water source in Gannan and Longnan with multiple water sources.

scholarly journals Stable Isotope Ratios in Tap Water of a Riverside City in a Semi-Arid Climate: An Application to Water Source Determination

Water ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1441 ◽  
Author(s):  
Mingxia Du ◽  
Mingjun Zhang ◽  
Shengjie Wang ◽  
Fenli Chen ◽  
Peipei Zhao ◽  
...  
Keyword(s):  
Surface Water ◽  
Water Supply ◽  
Water Samples ◽  
Numerical Range ◽  
Tap Water ◽  
Sampling Site ◽  
Water Source ◽  
Raw Water ◽  
Data Set ◽  
Regional Water

Stable isotopes (e.g., δ2H and δ18O) in tap water are important tools to understand the local climate or environment background, water sources and the state of regional water supply. Based on 242 tap water samples, 35 precipitation samples and 24 surface water samples gathered in the urban area of Lanzhou, the basic spatiotemporal characteristics of isotopes in tap water, their connection with isotopes in other water bodies and change during the process from raw water to tap water are discussed in detail, combining the information of local tap water supply and water source. It can provide reliable help for understanding the isotope characteristics of local tap water, regional water supply management and determination of tap water source of in a small area. Except for the establishment of a new data set of isotopes in tap water with complete time series and uniform spatial distribution of sampling sites, other results show that: (1) The Local Tap Water Line (LTWL) of Lanzhou is δ2H = (6.03 ± 0.57) δ18O + (−8.63 ± 5.44) (r2 = 0.41, p < 0.01). (2) For seasonal variations, δ2H and δ18O in tap water both are higher in autumn and lower in spring. The diurnal and daily variations of isotopes in tap water are not large. As for spatial variations, the monthly mean values of δ2H and δ18O in tap water at each sampling site show little difference. The isotopes in tap water collected from one single sampling site can be considered as a representative for isotopes in tap water in the area with a single tap water source. (3) Isotopes in tap water show weak connection with precipitation isotopes, but exhibit good connection (consistent seasonal variation, similar numerical range, small numerical difference and high correlation) with isotopes in surface water, which is the direct water source. Isotopes in water change little from raw water to tap water. Isotopic composition of tap water in Lanzhou can be used as a representative of isotopes in surface water.

scholarly journals Carbon-14 in the Southern Indian Ocean

Radiocarbon ◽  
1980 ◽  
Vol 22 (3) ◽  
pp. 684-692 ◽  
Author(s):  
Georgette Delibrias
Keyword(s):  
Surface Water ◽  
Indian Ocean ◽  
Water Samples ◽  
Sea Water ◽  
Time Lag ◽  
Vertical Profiles ◽  
Carbon 14 ◽  
Middle Latitudes ◽  
The North ◽  
The Indian Ocean

14C measurements were carried out on sea water samples collected in 1973, in the Indian ocean. The results obtained for 9 vertical profiles between 27° S and 48°S are presented. In surface water, the bomb 14C content is maximum at middle latitudes. A time lag relative to the north hemisphere bomb 14C delivery is apparent. In the more southern latitudes, 14C content remains very low.

Inter-annual and seasonal dynamics of amino acid, mineral and vitamin composition of silver belly Leiognathus splendens

2014 ◽  
Vol 95 (4) ◽  
pp. 817-828 ◽  
Author(s):  
Kajal Chakraborty ◽  
Deepu Joseph
Keyword(s):  
Amino Acids ◽  
Amino Acid ◽  
Protein Content ◽  
West Coast ◽  
Sensor Data ◽  
The South ◽  
Post Monsoon ◽  
South West ◽  
South West Coast ◽  
Protein Amino Acids

Silver bellies, Leiognathus splendens were studied for their spatial (south-west and south-east coasts of India), annual (2008–2011) and seasonal (pre-monsoon, monsoon and post-monsoon) variations of protein, amino acids, vitamins and minerals. The monthly mean Sea Viewing Wide Field-of-view Sensor data for the period from January 2008 to December 2011 were taken into account to indicate the distribution of the photosynthetic pigment chlorophyll-a to test the hypothesis that surface productivity might be related to nutritional biochemistry of this species. The four year average total protein content and chlorophyll-a showed good correlation during monsoon on the south-west coast and monsoon/post-monsoon on the south-east coast, suggesting that the protein content is prejudiced by the chlorophyll-a concentration. Amino acid scores observed monsoon maxima along the south-west and south-east coasts. Significant seasonal variations in vitamin content were observed at the study locations with high content of vitamins D3, E, K1 and C on the south-west coast. Na content was maximal during pre-monsoon on the south-west coast, while post-monsoon maxima of Ca and K content were observed. The Fe, Mn and Zn were abundant in the samples collected from the south-west coast. The concentration of Se exhibited maximum values post-monsoon along the south-west and south-east coasts. The present study demonstrated L. splendens as a valuable source of the protein, amino acids, minerals and vitamins, showing that this low-value species is a good source of well balanced proteins with high biological value to be qualified as a preferred healthy food for human consumption.

Comparison of Lipid Profile in Three Species of Myctophids from the South West Coast of Kerala, India

2014 ◽  
Vol 37 (1) ◽  
pp. 33-37 ◽  
Author(s):  
Libin Baby ◽  
Thazhakot Vasunambisan Sankar ◽  
Rangasamy Anandan
Keyword(s):  
Lipid Profile ◽  
West Coast ◽  
The South ◽  
South West ◽  
South West Coast

Seasonal and inter-annual lipid dynamics of spiny cheek grouper (Epinephelus diacanthus) in the southern coast of India

2014 ◽  
Vol 94 (8) ◽  
pp. 1677-1686 ◽  
Author(s):  
Kajal Chakraborty ◽  
Deepu Joseph ◽  
Selsa Jose Chakkalakal
Keyword(s):  
Fatty Acids ◽  
West Coast ◽  
Arabian Sea ◽  
The South ◽  
Human Diet ◽  
Post Monsoon ◽  
Lipid Dynamics ◽  
South West ◽  
Acid Ratio ◽  
South West Coast

The muscle lipid, fatty acids and total cholesterol profiles of the spiny cheek grouper, Epinephelus diacanthus, collected from south-west (Arabian Sea) and south-east coasts (Bay of Bengal) of India were evaluated over four years (2008–2011) with regard to three seasons (pre-monsoon, monsoon and post-monsoon). Fatty acids were correlated with chlorophyll-a concentration and sea surface temperature. Lipid content, total polyunsaturated, eicosapentaenoic and docosahexaenoic fatty acids of the samples from the south-west coast showed positive correlation with chlorophyll-a concentration during the monsoon (r2 = 0.93, 0.97, 0.97 and 0.99, respectively). Higher hypocholesterolaemic/hypercholesterolaemic ratio (>1.0) and low atherogenic (<1.2), thrombogenicity (≤0.6) indices make the groupers collected from the coast of the Arabian Sea a valued candidate species for human nutrition. High levels of n-3 fatty acids (>19% during post-monsoon), important in the human diet for their platelet anti-aggregating and blood pressure-reducing properties, for groupers collected from the south-west coast, with higher n-3/n-6 fatty acid ratio (>5.1) proved this species from the coast of the Arabian Sea to be a desirable item in the human diet.

scholarly journals Fast UHPLC-MS/MS for the Simultaneous Determination of Azithromycin, Erythromycin, Fluoxetine and Sotalol in Surface Water Samples

2021 ◽  
Vol 11 (18) ◽  
pp. 8316
Author(s):  
Mira Azzi ◽  
Sylvain Ravier ◽  
Assem Elkak ◽  
Bruno Coulomb ◽  
Jean-Luc Boudenne
Keyword(s):  
Surface Water ◽  
Simultaneous Determination ◽  
Surface Waters ◽  
Water Samples ◽  
High Performance ◽  
Chemical Properties ◽  
Environmental Water ◽  
Butyl Ether ◽  
Flight Mass Spectrometry

Chromatographic development for the determination of pharmaceuticals in environmental water samples is particularly challenging when the analytes have significantly different physico-chemical properties (solubility, polarity, pKa) often requiring multiple chromatographic methods for each active component. This paper presents a method for the simultaneous determination of azithromycin, erythromycin (antibiotics), fluoxetine (anti-depressant) and sotalol (b-blocker) in surface waters by ultra-high-performance liquid chromatography coupled with ultra-high-resolution time-of-flight mass spectrometry. These pharmaceuticals—presenting a broad spectrum of polarity (0.24 ≤ log Kow ≤ 4.05)—were separated on a C-18 analytical column, after a simple filtration step for freshwater samples or after a liquid–liquid extraction with Methyl-tertio-butyl ether (MTBE) for seawater samples. The optimized separation method (in terms of nature of column and eluent, elution gradient, and of mass spectrometric parameters), enable one to reach limits of detection ranging between 2 and 7 ng L−1 and limits of quantification between 7 and 23 ng L−1 for the four targeted molecules, within a three minute run. This method was validated using samples collected from three different surface waters in Lebanon (freshwater and seawater) and analytical results were compared with those obtained in surface waters sampled in a French river, equivalent in terms of human activities. Using this method, we report the highest concentration of pharmaceuticals found in surface water (up to 377 ng L−1 and 268 ng L−1, respectively, for azithromycin and erythromycin, in the Litani river, Lebanon).

scholarly journals Assessment of Fluoride in Groundwater and Surface Water in Gorakhpur District, Uttar Pradesh, India

2021 ◽  
Vol 9 (VII) ◽  
pp. 2028-2036
Author(s):  
Aseem Saxena
Keyword(s):  
Surface Water ◽  
Ground Water ◽  
Water Samples ◽  
Rural Areas ◽  
Fluoride Concentration ◽  
Uttar Pradesh ◽  
Water Source ◽  
Common Element ◽  
Daily Routine ◽  
Groundwater Source

Fluorine is the most electronegative and most reactive halogen. Fluorine is 13th most common element on earth crust found in the form of fluoride. Concentration of fluoride below 1 mg/l are believed beneficial in the prevention of dental carries or tooth decay, but above 1.5mg/l, it increases the severity of the deadly diseases fluorosis, which is incurable in India. The whole study was conducted in Gorakhpur region to know about the concentration of fluoride, mainly in rural areas of the district. We have collected 64 drinking water samples from 9 blocks of the district in which we took 6 number of ground water samples from each block so total 54 number of samples were collected from the groundwater source and 8 number of samples were taken from surface water source. Out of 54 ground water samples, 36 numbers of samples were taken from India Mark-II hand pumps and rest 18 number of samples were taken from shallow depth hand pumps and tested to determine the concentration of fluoride. From our assessment we came to know that in this region the concentration of fluoride in groundwater ranges between 0.004 to 1.42mg/l, minimum value is found in the surface water source and the maximum value is found from the ground water source.The samples collected from both ground water and as well as surface water were taken from potable sources i.e. they are used for drinking purposes in daily routine. After the testing and analyzing the samples it is come to know that surface water has quite lower levels fluoride compare to ground water. The conclusion of this work is to give information about the concentration of fluoride in groundwater and surface water of the district.

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