Upflow Anaerobic Filtration of a Sugar Containing Wastewater

1993 ◽  
Vol 28 (2) ◽  
pp. 125-134 ◽  
Author(s):  
M. A. Boller ◽  
J. Eugster
Keyword(s):  
Pore Space ◽  
Gas Production ◽  
Operating Conditions ◽  
Cod Removal ◽  
Process Conditions ◽  
Processing Plant ◽  
Biomass Distribution ◽  
Reactor Model ◽  
Design Considerations ◽  
Steady State Performance

Pretreatment of a sugar containing wastewater from a date processing plant was tested for COD removal in an anaerobic pilot filter over a period of eight months. The filter was operated in the upflow mode and randomly packed with a plastic pipe carrier material. Initial start and restart after a 6-week break, steady state performance on seven different COD load levels ranging from 1.6 to 25 kg COD/m3·d, and filter behavior during reactor acidification were observed. In all examined experimental cases, the anaerobic filter rapidly adapted (5-7 days) to new operating conditions, thus indicating its high process flexibility. Below COD loads of 20 kg COD/m3·d, a COD removal of 90% or more was achieved. The specific CH4 gas production was measured at 0.40 - 0.53 m3 CH4/kg COD removed, and the specific sludge production was quantified at 0.1 kg paniculate COD/kg COD removed throughout the experimental periods. Biomass distribution revealed that 60% was attached to the packing media and 40% was suspended in the pore space. Based on COD profiles along the filter height, conclusions on the reactor flow pattern could be drawn. With the help of a simple reactor model, the experimental results could be used to simulate other process conditions for design considerations.

The use of a thermophilic anaerobic system for pretreatment of textile dye wastewater

2000 ◽  
Vol 42 (5-6) ◽  
pp. 309-316 ◽  
Author(s):  
J.R.M. Willetts ◽  
N.J. Ashbolt ◽  
R.E. Moosbrugger ◽  
M.R. Aslam
Keyword(s):  
Textile Wastewater ◽  
Gas Production ◽  
Operating Conditions ◽  
Cod Removal ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Textile Dye ◽  
Anaerobic Sludge Blanket ◽  
Selection Of ◽  
Anaerobic System

A thermophilic up-flow anaerobic sludge blanket (UASB) reactor was investigated for the decolouration of a synthetic textile wastewater. Textile wastewater is produced at high temperature and dyes are amenable to decolourisation under anaerobic conditions, however this is the first report of the use of such a thermophilic system to aid in the treatment of this wastewater. The decolouration efficiency and robustness of the thermophilic system were compared with a corresponding mesophilic anaerobic system to study the reduction of a selection of reactive dyes, the toxic effect of increasing influent dye concentration (up to 0.64 g.L-1), and the response during acclimation to high salinity conditions (up to 20 g.L-1 as sodium chloride) in three separate stages of experimentation. It was shown that compared with the mesophilic system, the thermophilic UASB treatment gave considerably higher dye decolouration with all the dyes tested, and under all operating conditions investigated. No loss in decolourisation potential was observed during an increase in influent dye concentration. However, toxicity effects were evident, noted by a decrease in COD removal and methane gas production. Acclimation to high salt concentrations also showed an adverse effect upon COD removal and gas production, however dye removal again remained virtually 100 % efficient.

scholarly journals Modeling of a Real-Life Industrial Reactor for Hydrogenation of Benzene Process

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 412
Author(s):  
Mirosław K. Szukiewicz ◽  
Krzysztof Kaczmarski
Keyword(s):  
Catalyst Activity ◽  
Real Life ◽  
Operating Conditions ◽  
Reactor Operation ◽  
Reactor Model ◽  
High Scale ◽  
Industrial Reactor ◽  
Knowledge Based ◽  
Operation Conditions ◽  
Insight Into

A dynamic model of the hydrogenation of benzene to cyclohexane reaction in a real-life industrial reactor is elaborated. Transformations of the model leading to satisfactory results are presented and discussed. Operating conditions accepted in the simulations are identical to those observed in the chemical plant. Under those conditions, some components of the reaction mixture vanish, and the diffusion coefficients of the components vary along the reactor (they are strongly concentration-dependent). We came up with a final reactor model predicting with reasonable accuracy the reaction mixture’s outlet composition and temperature profile throughout the process. Additionally, the model enables the anticipation of catalyst activity and the remaining deactivated catalyst lifetime. Conclusions concerning reactor operation conditions resulting from the simulations are presented as well. Since the model provides deep insight into the process of simulating, it allows us to make knowledge-based decisions. It should be pointed out that improvements in the process run, related to operating conditions, or catalyst application, or both on account of the high scale of the process and its expected growth, will remarkably influence both the profits and environmental protection.

Dynamic Modeling of CATOFIN® Fixed-Bed Iso-Butane Dehydrogenation Reactor for Operational Optimization

2016 ◽  
Vol 14 (1) ◽  
pp. 491-515 ◽  
Author(s):  
Zeeshan Nawaz
Keyword(s):  
Coke Formation ◽  
Fixed Bed ◽  
Process Intensification ◽  
Operating Conditions ◽  
Catalytic Dehydrogenation ◽  
Heating Rates ◽  
Reactor Model ◽  
Fuel Gas ◽  
Bed Temperature ◽  
Operational Optimization

AbstractThe catalytic dehydrogenation of iso-butane to iso-butylene is an equilibrium limited endothermic reaction and requires high temperature. The catalyst deactivates quickly, due to deposition of carbonaceous species and countered by periodic regeneration. The reaction-engineering constraints are tied up with operation and/or technology design features. CATOFIN® is a sophisticated commercialized technology for propane/iso-butane dehydrogenation using multiple adiabatic fixed-bed reactors having Cr2O3/Al2O3 as catalyst, that undergo cyclic operations (~18–30m); dehydrogenation, regeneration, evacuation, purging and reduction. It is always a concern, how to maintain CATOFIN® reactor at an optimum production, while overcoming gradual decrease of heat in catalyst bed and deactivation. A homogeneous one-dimensional dynamic reactor model for a commercial CATOFIN® fixed-bed iso-butane dehydrogenation reactor is developed in an equation oriented (EO) platform Aspen Custom Modeler (ACM), for operational optimization and process intensification. Both reaction and regeneration steps were modeled and results were validated. The model predicts the dynamic behavior and demonstrates the extent of catalyst utilization with operating conditions and time, coke formation and removal, etc. The model computes optimum catalyst bed temperature profiles, feed rate, pre-heating, rates for reaction and regeneration, fuel gas requirement, optimum catalyst amount, overall cycle time optimization, and suggest best operational philosophy.

scholarly journals Application of Ozone and Oxygen to Reduce Chemical Oxygen Demand and Hydrogen Sulfide from a Recovered Paper Processing Plant

2010 ◽  
Vol 2010 ◽  
pp. 1-6 ◽  
Author(s):  
Patricia A. Terry
Keyword(s):  
Hydrogen Sulfide ◽  
Chemical Oxygen Demand ◽  
Contact Time ◽  
Oxygen Demand ◽  
Gas Production ◽  
Injection System ◽  
Processing Plant ◽  
Short Contact Time ◽  
Production Of Hydrogen ◽  
Fox River

A pilot study was performed at the Fox River Fiber recovered paper processing company in DePere, Wisconsin, to determine the extent to which injection of oxygen and ozone could reduce the high chemical oxygen demand, COD, in the effluent and the effectiveness of the ozone/oxygen stream in suppressing production of hydrogen sulfide gas in downstream sewage lines. Adaptive Ozone Solutions, LLC, supplied the oxygen/ozone generation and injection system. Samples were analyzed both before and after oxygen/ozone injection. Hydrogen sulfide gas was continuously monitored at sewer stations downstream of Fox River Fiber. Results showed that with a very short contact time, effluent COD was reduced by over 15%. A simple kinetic model predicts that a contact time of fewer than 30 minutes could reduce COD by as much as 60%. In addition, downstream hydrogen sulfide gas production in the sewage mains was also better controlled, such that costly Bioxide applications could be reduced.

Logging Optimization and Data Analysis Enabling Bypass Pay Identification and Hydrocarbon Quantification with Advanced Pulsed Neutron Behind Casing

2021 ◽  
Author(s):  
Sviatoslav Iuras ◽  
Samira Ahmad ◽  
Chiara Cavalleri ◽  
Yernur Akashev
Keyword(s):  
Cross Section ◽  
Pore Space ◽  
High Energy ◽  
Elastic Cross Section ◽  
Gas Production ◽  
Donets Basin ◽  
Lithology Identification ◽  
Open Hole ◽  
Pulsed Neutron

Abstract Ukraine ranks the third largest gas reserves in Europe. Gas production is carried out mainly from the Dnieper-Donets Basin (DDB). A gradual decline in reserves is forcing Ukraine to actively search for possible sources to increase reserves by finding bypassed gas intervals in existing wells or exploration of new prospects. This paper describes 3 case studies, where advanced pulsed neutron logging technology has shown exceptional value in gas-bearing layer identification in different scenarios. The logging technology was applied for formation evaluation. The technology is based on the neutron interaction with the minerals and the fluids contained in the pore space. The logging tool combines measurements from multiple detectors and spacing for self-compensated neutron cross-capture section (sigma) and hydrogen index (HI), and the Fast Neutron Cross Section (FNXS) high-energy neutron elastic cross section rock property. Comprehensive capture and inelastic elemental spectroscopy are simultaneously recorded and processed to describe the elemental composition and the matrix properties, reducing the uncertainties related to drilling cuttings analysis, and overall, the petrophysical evaluation combined with other log outputs. The proposed methodology was tested in several wells, both in open hole and behind casing. In the study we present its application in three wells from different fields of the DDB. The log data acquisition and analysis were performed across several sandstone beds and carbonates formation with low porosities (<10%), in various combinations of casing and holes sizes. The results showed the robustness and effectiveness of using the advanced pulsed neutron logging (PNL) technologies in multiple cases: Case Study A: Enabling a standalone cased hole evaluation and highlighting new potential reservoir zones otherwise overlooked due to absence of open hole logs. Case Study B: Finding by-passed hydrocarbon intervals that were missed from log analysis based on conventional open hole logs for current field operator. Case Study C: Identifying gas saturated reservoirs and providing solid lithology identification that previously was questioned from drilling cuttings in an unconventional reservoir.

An ESP Production Optimization Algorithm Applied to Unconventional Wells

2021 ◽  
Author(s):  
Fernando Bermudez ◽  
Noor Al Nahhas ◽  
Hafsa Yazdani ◽  
Michael LeTan ◽  
Mohammed Shono
Keyword(s):  
Gas Production ◽  
Oil Wells ◽  
Production Optimization ◽  
Operating Conditions ◽  
Tight Oil ◽  
Daily Production ◽  
Free Gas ◽  
Maximum Production ◽  
Electrical Submersible Pumps ◽  
High Production

Abstract The objectives and Scope is to evaluate the feasibility of a Production Maximization algorithm for ESPs on unconventional wells using projected operating conditions instead of current ones, which authors expect will be crucial in adjusting the well deliverability to optimum frequencies on the rapidly changing conditions of tight oil wells. Actual production data for an unconventional well was used, covering from the start of Natural Flow production up to 120 days afterwards. Simulating what the production would be if a VFD running on IMP Optimization algorithms had been installed, new values for well flowing pressures were calculated, daily production scenarios were evaluated, and recommended operating frequencies were plotted. Result, observations, and conclusions: A. Using the Intelligent Maximum Production (IMP) algorithm allows maximum production from tight oil wells during the initial high production stage, and the prevention of gas-locking at later stages when gas production increases. B. The adjustment of frequency at later stages for GOR wells is key to maintaining maximum production while controlling free gas at the intake when compared against controlling the surface choke. Novel/additive information: The use of Electrical Submersible Pumps for the production of unconventional wells paired with the use of a VFD and properly designed control algorithms allows faster recovery of investment by pumping maximum allowable daily rates while constraining detrimental conditions such as free gas at the intake.

scholarly journals A model for coupled electro-hydro-mechanical processes in fine grained soils accounting for gas generation and transport

2010 ◽  
Vol 82 (1) ◽  
pp. 169-193 ◽  
Author(s):  
Claudio Tamagnini ◽  
Cristina Jommi ◽  
Fabio Cattaneo
Keyword(s):  
Pore Space ◽  
Transport Coefficients ◽  
Gas Production ◽  
Degree Of Saturation ◽  
Coupled Processes ◽  
Gas Generation ◽  
Fine Grained ◽  
Clayey Silt ◽  
Waste Containment Systems ◽  
The Impact

A theoretical and numerical model is developed for the quantitative analysis of coupled processes taking place in active waste containment systems, such as electrokinetic barriers or fences, in which alow intensity DC current is circulated across the clay barrier to move polar and non-polar contaminants. A novel feature of the proposed approach is the allowance for the presence of air in the pore space. Under unsaturated conditions, all transport coefficients involved in the electrokinetic process are strongly dependent on the degree of saturation of pore liquid. In order to assess the predictive capability of the proposed theory and to appreciate the impact of gas production at the electrodes, a series of numerical simulations of simple onedimensional electrokinetic tests have been performed. The results of the simulations compare reasonably well with data obtained from laboratory experiments performed on an illitic clayey silt. The numerical results indicate that the impact of gas production at the electrodes can be significant, even in low-intensity and short-duration treatments.

Linking Microbial Community Dynamics in BIOX® Leaching Tanks to Process Conditions: Integrating Lab and Commercial Experience

2017 ◽  
Vol 262 ◽  
pp. 38-42 ◽  
Author(s):  
Mariette Smart ◽  
Robert J. Huddy ◽  
Catherine J. Edward ◽  
Charl Fourie ◽  
Trust Shumba ◽  
...  
Keyword(s):  
South Africa ◽  
Community Structure ◽  
Microbial Community ◽  
Research University ◽  
Community Dynamics ◽  
Operating Conditions ◽  
Process Conditions ◽  
Significant Shift ◽  
Engineering Research ◽  
Microbial Community Dynamics

In the commercial BIOX® process, an acidophilic mixed bacterial and archaeal community dominated by iron and sulphur oxidising microorganisms is used to facilitate the recovery of precious metals from refractory gold-bearing sulphidic mineral concentrates. Characterisation of the microbial communities associated with commercial BIOX® reactors from four continents revealed a significant shift in the microbial community structure compared to that of the seed culture, maintained at SGS (South Africa). This has motivated more detailed study of the microbial community dynamics in the process. Microbial speciation of a subset of the BIOX® reactors at Fairview mines (Barberton, South Africa) and two laboratory maintained reactors housed at Centre for Bioprocess Engineering Research, University of Cape Town, has been performed tri-annually for three years by quantitative real-time polymerase chain reaction. The laboratory BIOX® culture maintained on Fairview concentrate was dominated by the desired iron oxidiser, Leptospirillum ferriphilum, and sulphur oxidiser, Acidithiobacillus caldus, when operated under standard BIOX® conditions. Shifts in the microbial community as a result of altered operating conditions were transient and did not result in a loss of the microbial diversity of the BIOX® culture. The community structure of the Fairview mines BIOX® reactor tanks showed archaeal dominance of these communities by organisms such as the iron oxidiser Ferroplasma acidiphilum and a Thermoplasma sp. for the period monitored. Shifts in the microbial community were observed across the monitoring period and mapped to changes in performance of the commercial process plant. Understanding the effect of changes in the plant operating conditions on the BIOX® community structure may assist in providing conditions that support the desired microbial consortium for optimal biooxidation to maximize gold recovery.

scholarly journals IMPROVE THE PYROLYTIC GAS PRODUCTION BY USING THE CO-PYROLYSIS TECHNIQUE : AN EXPERIMENTAL STUDY

2021 ◽  
Vol 21 (2) ◽  
Author(s):  
Abo . Zahra A.I ◽  
M.K. Abd El- Wahab ◽  
M.A. Tawfik
Keyword(s):  
Energy Conversion ◽  
Fluidized Bed ◽  
Conversion Efficiency ◽  
Fixed Bed ◽  
Energy Conversion Efficiency ◽  
Gas Production ◽  
Operating Conditions ◽  
Energy Unit ◽  
Heating Value ◽  
Slow Pyrolysis

The target of the biomass co-pyrolysis is improvingthe heating value of the produced bio-products of a certain type of feedstock, besides disposal of more than one residue in the same time. Thus, this work aims to operate a local fabricated fixed-bed pyrolyzer to improve the pyrolytic gas yield produced by the ground pieces of three biomass residues namely Mango trees Pruning Logs (MPL), Sugarcane bagasse (SB) and Rice straw (RS) using an affordable slow pyrolysis technique. This work was carried out under slow pyrolysis conditions represented in final pyrolysis temperature of 400 °C, vapor residence time of 4 min, heating rate of 0.01-1 °C/s in full absence of oxygen. The pyrolytic gas production was assessed under different feedstock mixing ratios of (1:2:1), (1:1:2) and (2:1:1) as ratio of (RS: SB: MPL), particle lengths of 1-5, 10-15 and 20-25 mm, with and without sandy bed at the bottom of pyrolysis chamber as a fluidized bed. The obtained results showed that, using the fluidized fixed-bed pyrolyzer under slow co-pyrolysis conditions gave the optimum results where in, the pyrolytic gas concentration, gas yield, higher heating value of pyrolytic gasand energy conversion efficiency were 55%, 1.09 Nm3 /kg, 14.97 MJ/Nm3 and 85.43%, respectively, and 53.7%, 1.08 Nm3 /kg, 13.75 MJ/Nm3 ,77.71% in case of using the pyrolyzer without fluidized bed under the same operating conditions. So, the pyrolyzer with fluidized bed achieves an increment in the higher heating value and energy conversion efficiency by about 8.15% and 9.03%, respectivly over the pyrolyzer without fluidized bed.Furthermore, the cost per energy unit of pyrolytic gas produced by the fluidized bed pyrolyzer is lower than the common two fossil gaseous fuels of natural gas and LPG costs by about 28.57% and 80%, respectively.

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