scholarly journals A model for coupled electro-hydro-mechanical processes in fine grained soils accounting for gas generation and transport

2010 ◽  
Vol 82 (1) ◽  
pp. 169-193 ◽  
Author(s):  
Claudio Tamagnini ◽  
Cristina Jommi ◽  
Fabio Cattaneo

A theoretical and numerical model is developed for the quantitative analysis of coupled processes taking place in active waste containment systems, such as electrokinetic barriers or fences, in which alow intensity DC current is circulated across the clay barrier to move polar and non-polar contaminants. A novel feature of the proposed approach is the allowance for the presence of air in the pore space. Under unsaturated conditions, all transport coefficients involved in the electrokinetic process are strongly dependent on the degree of saturation of pore liquid. In order to assess the predictive capability of the proposed theory and to appreciate the impact of gas production at the electrodes, a series of numerical simulations of simple onedimensional electrokinetic tests have been performed. The results of the simulations compare reasonably well with data obtained from laboratory experiments performed on an illitic clayey silt. The numerical results indicate that the impact of gas production at the electrodes can be significant, even in low-intensity and short-duration treatments.

2020 ◽  
Vol 195 ◽  
pp. 05003
Author(s):  
Elizabeth G. Stallings Young ◽  
Claudia E. Zapata ◽  
Leon van Paassen

The use of microorganisms to induce desaturation of granular soils via denitrification results in nitrogen and carbon dioxide gas generation, which in turn lowers the degree of saturation of the soil matrix. Given sufficient substrates, the stimulated bacteria will produce enough gas to develop a continuous gas phase. Introducing gas into the soil to reduce the degree of saturation is shown to increase the soil resistance to dynamic loading and helps to mitigate liquefaction. The impact of desaturation on liquefaction hazard mitigation has comparative value to the calcite precipitation phase of the process. Meso-scale tests have been performed on a relatively thin tank of soil to simulate planar flow through a granular soil treated with MIDP.


Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4570
Author(s):  
Aman Turakhanov ◽  
Albina Tsyshkova ◽  
Elena Mukhina ◽  
Evgeny Popov ◽  
Darya Kalacheva ◽  
...  

In situ shale or kerogen oil production is a promising approach to developing vast oil shale resources and increasing world energy demand. In this study, cyclic subcritical water injection in oil shale was investigated in laboratory conditions as a method for in situ oil shale retorting. Fifteen non-extracted oil shale samples from Bazhenov Formation in Russia (98 °C and 23.5 MPa reservoir conditions) were hydrothermally treated at 350 °C and in a 25 MPa semi-open system during 50 h in the cyclic regime. The influence of the artificial maturation on geochemical parameters, elastic and microstructural properties was studied. Rock-Eval pyrolysis of non-extracted and extracted oil shale samples before and after hydrothermal exposure and SARA analysis were employed to analyze bitumen and kerogen transformation to mobile hydrocarbons and immobile char. X-ray computed microtomography (XMT) was performed to characterize the microstructural properties of pore space. The results demonstrated significant porosity, specific pore surface area increase, and the appearance of microfractures in organic-rich layers. Acoustic measurements were carried out to estimate the alteration of elastic properties due to hydrothermal treatment. Both Young’s modulus and Poisson’s ratio decreased due to kerogen transformation to heavy oil and bitumen, which remain trapped before further oil and gas generation, and expulsion occurs. Ultimately, a developed kinetic model was applied to match kerogen and bitumen transformation with liquid and gas hydrocarbons production. The nonlinear least-squares optimization problem was solved during the integration of the system of differential equations to match produced hydrocarbons with pyrolysis derived kerogen and bitumen decomposition.


2021 ◽  
Vol 80 (3) ◽  
pp. 1963-1980
Author(s):  
Solomon Adomako ◽  
Christian John Engelsen ◽  
Rein Terje Thorstensen ◽  
Diego Maria Barbieri

AbstractRock aggregates constitute the enormous volume of inert construction material used around the globe. The petrologic description as igneous, sedimentary, and metamorphic types establishes the intrinsic formation pattern of the parent rock. The engineering properties of these rocks vary due to the differences in the transformation process (e.g. hydrothermal deposits) and weathering effect. The two most common mechanical tests used to investigate the performance of aggregates are the Los Angeles (LA) and micro-Deval (MD) tests. This study reviewed the geological parameters (including mineralogy, grain and crystal size, grain shape, and porosity) and the relationship to Los Angeles and micro-Deval tests. It was found that high content of primary minerals in rocks (e.g. quartz and feldspar) is a significant parameter for performance evaluation. Traces of secondary and accessory minerals also affect the performance of rocks, although in many cases it is based on the percentage. Furthermore, some studies showed that the effect of mineralogic composition on mechanical strength is not sufficient to draw final conclusions of mechanical performance; therefore, the impact of other textural characteristics should be considered. The disposition of grain size and crystal size (e.g. as result of lithification) showed that rocks composed of fine-grain textural composition of ≤ 1 mm enhanced fragmentation and wear resistance than medium and coarse grained (≥ 1 mm). The effect of grain shape was based on convex and concave shapes and flat and elongated apexes of tested samples. The equidimensional form descriptor of rocks somehow improved resistance to impact from LA than highly flat and elongated particles. Lastly, the distribution of pore space investigated by means of the saturation method mostly showed moderate (R = 0.50) to strong (R = 0.90) and positive correlations to LA and MD tests.


Water ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 219 ◽  
Author(s):  
Antonio-Juan Collados-Lara ◽  
David Pulido-Velazquez ◽  
Rosa María Mateos ◽  
Pablo Ezquerro

In this work, we developed a new method to assess the impact of climate change (CC) scenarios on land subsidence related to groundwater level depletion in detrital aquifers. The main goal of this work was to propose a parsimonious approach that could be applied for any case study. We also evaluated the methodology in a case study, the Vega de Granada aquifer (southern Spain). Historical subsidence rates were estimated using remote sensing techniques (differential interferometric synthetic aperture radar, DInSAR). Local CC scenarios were generated by applying a bias correction approach. An equifeasible ensemble of the generated projections from different climatic models was also proposed. A simple water balance approach was applied to assess CC impacts on lumped global drawdowns due to future potential rainfall recharge and pumping. CC impacts were propagated to drawdowns within piezometers by applying the global delta change observed with the lumped assessment. Regression models were employed to estimate the impacts of these drawdowns in terms of land subsidence, as well as to analyze the influence of the fine-grained material in the aquifer. The results showed that a more linear behavior was observed for the cases with lower percentage of fine-grained material. The mean increase of the maximum subsidence rates in the considered wells for the future horizon (2016–2045) and the Representative Concentration Pathway (RCP) scenario 8.5 was 54%. The main advantage of the proposed method is its applicability in cases with limited information. It is also appropriate for the study of wide areas to identify potential hot spots where more exhaustive analyses should be performed. The method will allow sustainable adaptation strategies in vulnerable areas during drought-critical periods to be assessed.


Ceramics ◽  
2021 ◽  
Vol 4 (2) ◽  
pp. 331-363
Author(s):  
Eugeniy Lantcev ◽  
Aleksey Nokhrin ◽  
Nataliya Malekhonova ◽  
Maksim Boldin ◽  
Vladimir Chuvil'deev ◽  
...  

This study investigates the impact of carbon on the kinetics of the spark plasma sintering (SPS) of nano- and submicron powders WC-10wt.%Co. Carbon, in the form of graphite, was introduced into powders by mixing. The activation energy of solid-phase sintering was determined for the conditions of isothermal and continuous heating. It has been demonstrated that increasing the carbon content leads to a decrease in the fraction of η-phase particles and a shift of the shrinkage curve towards lower heating temperatures. It has been established that increasing the graphite content in nano- and submicron powders has no significant effect on the SPS activation energy for “mid-range” heating temperatures, QS(I). The value of QS(I) is close to the activation energy of grain-boundary diffusion in cobalt. It has been demonstrated that increasing the content of graphite leads to a significant decrease in the SPS activation energy, QS(II), for “higher-range” heating temperatures due to lower concentration of tungsten atoms in cobalt-based γ-phase. It has been established that the sintering kinetics of fine-grained WC-Co hard alloys is limited by the intensity of diffusion creep of cobalt (Coble creep).


Author(s):  
A. J. Cooper

AbstractThick and predictable deposits of fine grained Quaternary materials have been used for the siting of waste management facilities in Ontario. The search for such sites is founded on the application of techniques in Quaternary geology and hydrogeology. Two examples are presented. Oxford County is located southwest of Toronto in an area of parallel morainic ridges separated by flat till plains. Conventional wisdom would focus on the till plains for thick, consistent fine grained Quaternary Sediments. However, the careful analysis of the Quaternary stratigraphy and glacial history revealed that better sites are located along the moraines. A site on the Ingersoll Moraine was studied in detail and defended at a public hearing. Concerns about the geology of the materials were allayed by the confirmation of homogeneous clayey silt materials exposed when the site opened in late 1986. A much wider ranging search was undertaken for a major hazardous and liquid industrial waste treatment and disposal facility for the Province of Ontario. Progressively more detailed investigations of the Quaternary geology were used to assist a multi-disciplinary site selection team. Initial interpretations covered an area of 75 000 km2 at a scale of 1:250 000. Eight candidate sites were then selected for further investigation with five continuously sampled stratigraphic boreholes. The chosen site is located in a depression in the bedrock filled with 40 m of glaciolacustrine clayey silt. Site specific hydrogeological and geotechnical studies were integrated with a detailed geological investigation.


2007 ◽  
Vol 208 (2-4) ◽  
pp. 295-306 ◽  
Author(s):  
K. Kuka ◽  
U. Franko ◽  
J. Rühlmann

2010 ◽  
Vol 104 (7) ◽  
pp. 1007-1017 ◽  
Author(s):  
Adele Costabile ◽  
Sofia Kolida ◽  
Annett Klinder ◽  
Eva Gietl ◽  
Michael Bäuerlein ◽  
...  

There is growing interest in the use of inulins as substrates for the selective growth of beneficial gut bacteria such as bifidobacteria and lactobacilli because recent studies have established that their prebiotic effect is linked to several health benefits. In the present study, the impact of a very-long-chain inulin (VLCI), derived from globe artichoke (Cynara scolymus), on the human intestinal microbiota compared with maltodextrin was determined. A double-blind, cross-over study was carried out in thirty-two healthy adults who were randomised into two groups and consumed 10 g/d of either VLCI or maltodextrin, for two 3-week study periods, separated by a 3-week washout period. Numbers of faecal bifidobacteria and lactobacilli were significantly higher upon VLCI ingestion compared with the placebo. Additionally, levels ofAtopobiumgroup significantly increased, whileBacteroides–Prevotellanumbers were significantly reduced. No significant changes in faecal SCFA concentrations were observed. There were no adverse gastrointestinal symptoms apart from a significant increase in mild and moderate bloating upon VLCI ingestion. These observations were also confirmed byin vitrogas production measurements. In conclusion, daily consumption of VLCI extracted from globe artichoke exerted a pronounced prebiotic effect on the human faecal microbiota composition and was well tolerated by all volunteers.


2021 ◽  
Author(s):  
Sviatoslav Iuras ◽  
Samira Ahmad ◽  
Chiara Cavalleri ◽  
Yernur Akashev

Abstract Ukraine ranks the third largest gas reserves in Europe. Gas production is carried out mainly from the Dnieper-Donets Basin (DDB). A gradual decline in reserves is forcing Ukraine to actively search for possible sources to increase reserves by finding bypassed gas intervals in existing wells or exploration of new prospects. This paper describes 3 case studies, where advanced pulsed neutron logging technology has shown exceptional value in gas-bearing layer identification in different scenarios. The logging technology was applied for formation evaluation. The technology is based on the neutron interaction with the minerals and the fluids contained in the pore space. The logging tool combines measurements from multiple detectors and spacing for self-compensated neutron cross-capture section (sigma) and hydrogen index (HI), and the Fast Neutron Cross Section (FNXS) high-energy neutron elastic cross section rock property. Comprehensive capture and inelastic elemental spectroscopy are simultaneously recorded and processed to describe the elemental composition and the matrix properties, reducing the uncertainties related to drilling cuttings analysis, and overall, the petrophysical evaluation combined with other log outputs. The proposed methodology was tested in several wells, both in open hole and behind casing. In the study we present its application in three wells from different fields of the DDB. The log data acquisition and analysis were performed across several sandstone beds and carbonates formation with low porosities (<10%), in various combinations of casing and holes sizes. The results showed the robustness and effectiveness of using the advanced pulsed neutron logging (PNL) technologies in multiple cases: Case Study A: Enabling a standalone cased hole evaluation and highlighting new potential reservoir zones otherwise overlooked due to absence of open hole logs. Case Study B: Finding by-passed hydrocarbon intervals that were missed from log analysis based on conventional open hole logs for current field operator. Case Study C: Identifying gas saturated reservoirs and providing solid lithology identification that previously was questioned from drilling cuttings in an unconventional reservoir.


2021 ◽  
Author(s):  
Mohamed El Sgher ◽  
Kashy Aminian ◽  
Ameri Samuel

Abstract The objective of this study was to investigate the impact of the hydraulic fracturing treatment design, including cluster spacing and fracturing fluid volume on the hydraulic fracture properties and consequently, the productivity of a horizontal Marcellus Shale well with multi-stage fractures. The availability of a significant amount of advanced technical information from the Marcellus Shale Energy and Environment Laboratory (MSEEL) provided an opportunity to perform an integrated analysis to gain valuable insight into optimizing fracturing treatment and the gas recovery from Marcellus shale. The available technical information from a horizontal well at MSEEL includes well logs, image logs (both vertical and lateral), diagnostic fracture injection test (DFIT), fracturing treatment data, microseismic recording during the fracturing treatment, production logging data, and production data. The analysis of core data, image logs, and DFIT provided the necessary data for accurate prediction of the hydraulic fracture properties and confirmed the presence and distribution of natural fractures (fissures) in the formation. Furthermore, the results of the microseismic interpretation were utilized to adjust the stress conditions in the adjacent layers. The predicted hydraulic fracture properties were then imported into a reservoir simulation model, developed based on the Marcellus Shale properties, to predict the production performance of the well. Marcellus Shale properties, including porosity, permeability, adsorption characteristics, were obtained from the measurements on the core plugs and the well log data. The Quanta Geo borehole image log from the lateral section of the well was utilized to estimate the fissure distribution s in the shale. The measured and published data were utilized to develop the geomechnical factors to account for the hydraulic fracture conductivity and the formation (matrix and fissure) permeability impairments caused by the reservoir pressure depletion during the production. Stress shadowing and the geomechanical factors were found to play major roles in production performance. Their inclusion in the reservoir model provided a close agreement with the actual production performance of the well. The impact of stress shadowing is significant for Marcellus shale because of the low in-situ stress contrast between the pay zone and the adjacent zones. Stress shadowing appears to have a significant impact on hydraulic fracture properties and as result on the production during the early stages. The geomechanical factors, caused by the net stress changes have a more significant impact on the production during later stages. The cumulative gas production was found to increase as the cluster spacing was decreased (larger number of clusters). At the same time, the stress shadowing caused by the closer cluster spacing resulted in a lower fracture conductivity which in turn diminished the increase in gas production. However, the total fracture volume has more of an impact than the fracture conductivity on gas recovery. The analysis provided valuable insight for optimizing the cluster spacing and the gas recovery from Marcellus shale.


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