Land application technique for the treatment and disposal of sewage sludge

2002 ◽  
Vol 46 (9) ◽  
pp. 303-308 ◽  
Author(s):  
S.M. Zain ◽  
H. Basri ◽  
F. Suja' ◽  
O. Jaafar
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Chemical Properties ◽  
Potential Effect ◽  
Application Rate ◽  
Exchange Capacity ◽  
Land Application ◽  
Treated Soil

Some of the major concerns when applying sewage sludge to land include the potential effect on pH and cation exchange capacity; the mobility and the accumulation of heavy metals in sludge treated soil; the potential of applying too much nutrients and the problems associated with odors and insects. The main objective of this study is to identify the effects of sewage sludge application on the physical and chemical properties of sludge treated soil. Sewage sludge was applied to soil at various rates ranging from 0 L/m2 to 341 L/m2. In order to simulate the natural environment, the study was carried out at a pilot treatment site (5.2 m × 6.7 m) in an open area, covered with transparent roofing material to allow natural sunlight to pass through. Simulated rain was applied by means of a sprinkler system. Data obtained from sludge treated soil showed that the pH values decreased when the application rates were increased and the application period prolonged. The effect of sewage sludge on cation exchange capacity was not so clear; the values obtained for every application rate of sewage sludge did not indicate any consistent behaviour. The mobility of heavy metals in soils treated with sludge were described by observing the changes in the concentration of the heavy metals. The study showed that Cd has the highest mobility in sludge treated soil followed by Cu, Cr, Zn, Ni and Pb.

scholarly journals Bioavailability and leaching of Cd and Pb from contaminated soil amended with different sizes of biochar

2018 ◽  
Vol 5 (11) ◽  
pp. 181328 ◽  
Author(s):  
Alaa Hasan Fahmi ◽  
Abd Wahid Samsuri ◽  
Hamdan Jol ◽  
Daljit Singh
Keyword(s):  
Heavy Metals ◽  
Particle Size ◽  
Contaminated Soil ◽  
Contaminated Soils ◽  
Cation Exchange Capacity ◽  
Application Rate ◽  
Exchange Capacity ◽  
Particle Sizes ◽  
Empty Fruit Bunch ◽  
Treated Soil

Biochars have been successfully used to reduce bioavailability and leaching of heavy metals in contaminated soils. The efficiency of biochar to immobilize heavy metals can be increased by reducing the particle size, which can increase the surface area and the cation exchange capacity (CEC). In this study, the empty fruit bunch biochar (EFBB) of oil palm was separated into two particle sizes, namely, fine (F-EFBB < 50 µm) and coarse (C-EFBB > 2 mm), to treat the contaminated soil with Cd and Pb. Results revealed that the addition of C-EFBB and F-EFBB increased the pH, electrical conductivity and CEC of the contaminated soil. The amounts of synthetic rainwater extractable and leachable Cd and Pb significantly decreased with the EFBB application. The lowest extractable and leachable Cd and Pb were observed from 1% F-EFBB-treated soil. The amount of extractable and leachable Cd and Pb decreased with increasing incubation times and leaching cycles. The application of F-EFBB to Cd and Pb-contaminated soil can immobilize the heavy metals more than that of C-EFBB. Therefore, the EFBB can be recommended for the remediation of heavy metal-contaminated soils, and a finer particle size can be applied at a lower application rate than the coarser biochar to achieve these goals.

scholarly journals Attributes of the soil fertilized with sewage sludge and calcium and magnesium silicate

2015 ◽  
Vol 19 (11) ◽  
pp. 1107-1113 ◽  
Author(s):  
Geraldo R. Zuba Junio ◽  
Regynaldo A. Sampaio ◽  
Altina L. Nascimento ◽  
Luiz A. Fernandes ◽  
Natália N. de Lima ◽  
...  
Keyword(s):  
Sewage Sludge ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Ricinus Communis ◽  
Block Design ◽  
Magnesium Silicate ◽  
Exchange Capacity ◽  
Sludge Compost ◽  
Sewage Sludge Compost ◽  
Randomized Block Design

ABSTRACTThis study aimed to evaluate the chemical attributes of an Inceptisol cultivated with castor bean (Ricinus communis L.), variety ‘BRS Energia’, fertilized with sewage sludge compost and calcium (Ca) and magnesium (Mg) silicate. The experiment was conducted at the ICA/UFMG, in a randomized block design, using a 2 x 4 factorial scheme with three replicates, and the treatments consisted of two doses of Ca-Mg silicate (0 and 1 t ha-1) and four doses of sewage sludge compost (0, 23.81, 47.62 and 71.43 t ha-1, on dry basis). Soil organic matter (OM), pH, sum of bases (SB), effective cation exchange capacity (CEC(t)), total cation exchange capacity (CEC(T)), base saturation (V%) and potential acidity (H + Al) were evaluated. There were no significant interactions between doses of sewage sludge compost and doses of Ca-Mg silicate on soil attributes, and no effect of silicate fertilization on these attributes. However, fertilization with sewage sludge compost promoted reduction in pH and increase in H + Al, OM and CEC. The dose of 71.43 t ha-1 of sewage sludge compost promoted the best soil chemical conditions.

scholarly journals Eosin Removal by Cetyl Trimethylammonium-Cloisites: Influence of the Surfactant Solution Type and Regeneration Properties

Molecules ◽  
2019 ◽  
Vol 24 (16) ◽  
pp. 3015
Author(s):  
Fethi Kooli ◽  
Souad Rakass ◽  
Yan Liu ◽  
Mostafa Abboudi ◽  
Hicham Oudghiri Hassani ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Clay Mineral ◽  
Salt Solution ◽  
Cation Exchange Capacity ◽  
Chemical Properties ◽  
Surfactant Solution ◽  
Exchange Capacity ◽  
Maximum Temperature ◽  
Basal Spacing ◽  
Xrd Techniques

The effect of the counteranion of hexadecyltrimethylammonium salts on the physico-chemical properties of organoclays was investigated, using a selected natural clay mineral with a cation exchange capacity of 95 meq/100 g. The uptake amount of C16 cations was dependent on the hexadecyltrimethylammonium (C16) salt solution used, the organoclay prepared from C16Br salt solution exhibited a value of 1. 05 mmole/g higher than those prepared from C16Cl and C16OH salt solutions. The basal spacing of these organoclays was in the range of 1.81 nm to 2.10 nm, indicating a similar orientation of the intercalated surfactants, and could indicated that the excess amount of surfactants, above the cation exchange capacity of 0.95 meq/g could be adsorbed on the external surface of the clay mineral sheets. These organoclays were found to be stable in neutral, acidic, and basic media. The thermal stability of these organoclays was carried out using thermogravimetric analysis and in-situ X-ray diffraction (XRD) techniques. The decomposition of the surfactant occurred at a maximum temperature of 240 °C, accompanied with a decrease of the basal spacing value close to 1.42 nm. The application of these organoclays was investigated to remove an acidic dye, eosin. The removal amount was related to the initial used concentrations, the amount of the surfactants contents, and to the preheated temperatures of the organoclays. The removal was found to be endothermic process with a maximum amount of 55 mg of eosin/g of organoclay. The value decreased to 25 mg/g, when the intercalated surfactants were decomposed. The reuse of these organoclays was limited to four regeneration recycles with a reduction of 20 to 30%. However, noticeable reduction between 35% to 50% of the initial efficiency, was achieved after the fifth cycle, depending of the used organoclays.

Co-composting of distillery and winery wastes with sewage sludge

2007 ◽  
Vol 56 (2) ◽  
pp. 187-192 ◽  
Author(s):  
M.A. Bustamante ◽  
C. Paredes ◽  
R. Moral ◽  
J. Moreno-Caselles ◽  
M.D. Pérez-Murcia ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Sewage Sludge ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Total N ◽  
Organic C ◽  
Mediterranean Countries ◽  
Feasible Option ◽  
Total Organic C

The winery and distillery wastes (grape stalk and marc (GS and GM, respectively), wine lees (WL) and exhausted grape marc (EGM)) are produced in great amounts in the Mediterranean countries, where their treatment and disposal are becoming an important environmental problem, mainly due to their seasonal character and some characteristics that make their management difficult and which are not optimised yet. Composting is a treatment widely used for organic wastes, which could be a feasible option to treat and recycle the winery and distillery wastes. In this experiment, two different piles (pile 1 and 2) were prepared with mixtures of GS, GM, EG and sewage sludge (SS) and composted in a pilot plant by the Rutgers static pile composting system. Initially, GS, GM and EGM were mixed, the pile 1 being watered with fresh collected vinasse (V). After 17 days, SS was added to both piles as a nitrogen and microorganisms source. During composting, the evolution of temperature, pH, electrical conductivity, total organic C, total N, humic acid-like C and fulvic acid-like C contents, C/N ratio, cation exchange capacity and germination index of the mixtures were studied. The addition of V in pile 1 produced higher values of temperature, a greater degradation of the total organic C, higher electrical conductivity values and similar pH values and total N contents than in pile 2. The addition of this effluent also increased the cation exchange capacity and produced a longer persistence of phytotoxicity. However, both piles showed a stabilised organic matter and a reduction of the phytotoxicity at the end of the composting process.

Soil pH and Cation Exchange Capacity Affects Sunflower Tolerance to Sulfentrazone

2004 ◽  
Vol 18 (2) ◽  
pp. 243-247 ◽  
Author(s):  
Gregory W. Kerr ◽  
Phillip W. Stahlman ◽  
J. Anita Dille
Keyword(s):  
Cation Exchange ◽  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Dry Matter ◽  
Exchange Capacity ◽  
Treated Soil ◽  
Sunflower Plant ◽  
Greenhouse Study ◽  
Leaf Chlorosis ◽  
Over Time

Effects of soil pH and cation exchange capacity (CEC) on sunflower tolerance to sulfentrazone were investigated in a greenhouse study. Variables were soil pH (7.0, 7.3, 7.5, and 7.8), soil CEC (8.2, 13.7, 18.4, and 23.3 cmol/kg), and sulfentrazone rate (0, 105, 158, and 184 g ai/ha). Sulfentrazone-induced leaf chlorosis was affected by soil pH at 12 d after planting (DAP), but plants recovered, and earlier differences were not visible 9 d later. At 12 DAP, leaf chlorosis was 3 or 4% more severe in soils with pH 7.3 or higher compared with soils with pH 7.0 when averaged over both sulfentrazone rate and soil CEC. Leaf chlorosis resulting from sulfentrazone rates of 105, 158, and 184 g/ha was 17, 25, and 35% less at 23 cmol/kg than at 8.2 cmol/kg, respectively. Differences in chlorosis among sulfentrazone rates were greatest in soil with low CEC and lessened as soil CEC increased. Plants regained normal color over time, and newly emerging leaves were not affected. However, plant dry weights were reduced when sulfentrazone rate was ≥158 g/ha. Averaged over sulfentrazone rate and soil pH, sunflower dry weights were less when soil CEC was 8.2 compared with a CEC of 13.7 cmol/kg or higher, indicating a greater response at low CEC. Sunflower plant dry matter was not different in sulfentrazone-treated soil with a CEC above 13.7 cmol/kg. At the ranges tested, soil CEC had a considerably greater effect than did pH on sunflower tolerance to sulfentrazone.

scholarly journals THE EFFECTIVENESS OF COMPOST, HUMIC ACID AND PURE FULVATE ON IMPROVEMENT OF ULTISOL SOIL CHEMICAL PROPERTIES

2021 ◽  
pp. 247-254
Author(s):  
Resman ◽  
Sahta Ginting ◽  
Muhammad Tufaila ◽  
Fransiscus Suramas Rembon ◽  
Halim
Keyword(s):  
Humic Acid ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Chemical Properties ◽  
Fulvic Acids ◽  
Exchange Capacity ◽  
Humic And Fulvic Acids ◽  
Total N ◽  
Organic C ◽  
Exchangeable Al

The research aimed to determine the effectiveness of compost containing humic and fulvic acids, and pure humic and fulvic acids in increasing of Ultisol soil chemical properties. The research design used a randomized block design (RBD), consisting of 10 treatments, namely K0: 0 g polybag-1, KO1: 500 g polybag-1, KO2: 500 g polybag-1, KO3: 500 g polybag-1, KO4: 500 g polybag-1, KO5: 500 g polybag-1, KO6: 500 g polybag-1, KO7: 500 g of polybags-1, H: 50 g of polybag-1, A: 500 g polybag-1. Each treatment was repeated three times and obtained 30 treatment units. The results showed that pH H2O (K0: 4.49, KO1: 5.64, KO2: 5.47, KO3: 5.43, KO4: 5.51, KO5: 5.39, KO6: 5.48, KO7: 6.17, H: 5.06, F: 5.15), total-N (%) (K0: 0.13, KO1: 0.17, KO2: 0.18, KO3: 0.30, KO4: 0.25, KO5: 0.24, KO6: 0.29, KO7: 0.36, H: 0.16, F: 0.14), organic-C (%) (K0: 1.85, KO1; 2.30, KO2: 2.24, KO3: 2.33, KO4: 2.62, KO5: 2.25, KO6: 2.27, KO7: 2.95, H: 2.32, F: 2.26) , available-P (%) (K0: 2.75, KO1: 3.24, KO2: 3.16, KO3: 3.27, KO4: 3.57, KO5: 3.31, KO6: 3.37, KO7: 3.89, H: 3.10, F: 3.12), exchangeable-Al (me100g-1) (K0: 2.51, KO1: 2.11, KO2: 2.13, KO3: 2.15, KO4: 1.88, KO5: 2.14, KO6: 2.12, KO7: 1.75, H: 2.16, F: 2.17), base saturation (%) (K0: 30.91, KO1: 63.48, KO2: 52.63, KO3: 53.76, KO4: 56.13, KO5: 54.96, KO6: 56.71, KO7: 65.53, H: 39.11, F: 42.76), cation exchange capacity (me100g-1) (K0: 12.76, KO1: 15.64, KO2: 14.86, KO3: 14.35, KO4: 14.13, KO5: 15.01, KO6: 15.50, KO7: 17.94, H: 14.19, F: 13.73). The combined compost treatment of three types of organic matter (Imperata cylindrica + Rice straw + Glincidia sepium) is more effective in increasing the pH, H2O as 37.42%, total-N as 176.92%, Organic-C as 59.46%, available-P as 41.45%, base saturation as 65.53%, cation exchange capacity as 17.94% and exchangeable -Al, Alreduction as 30.28% of ultisol soil. KEY WORDS: compost, humic acid, fulvate, soil chemical, ultisol

scholarly journals Chemical properties of long-term irrigated Fluvisols of the Beli Drim river valley in the Klina region (Serbia)

2021 ◽  
Vol 70 (1) ◽  
pp. 13-26
Author(s):  
Miodrag Tolimir ◽  
Branka Kresović ◽  
Borivoj Pejić ◽  
Katarina Gajić ◽  
Angelina Tapanarova ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Humus Content ◽  
Chemical Properties ◽  
Base Cations ◽  
Exchange Capacity ◽  
Base Saturation ◽  
Basic Cations ◽  
Hydrolytic Acidity

The impact of long-term (> 100 yr) irrigation on soil chemical properties was studied on eight plots in the Beli Drim river valley in Kosovo and Metohija near Klina, Serbia. For these studies, soil samples from shallow profiles were collected from only one or two depth zones of the Ah horizon; and from moderately deep and deep profiles, from two to three depth zones for the purpose of comparing irrigated field and non-irrigated meadow lands. Water from the Beli Drim River and surface gravity systems (irrigation furrows or border strip irrigation) were used for irrigation. Chemical variables included determination of pH-H2O, content of CaCO3, content of humus, hydrolytic acidity, sum of basic cations, cation exchange capacity, and base saturation. On irrigated soils, the results of chemical analysis showed on average a small increase in pH-H2O (0.07 pH units), as well as a significant decrease in humus content (2.00-4.75%), sum of basic cations (4.98-12.98%) and cation exchange capacity (12.8%) compared to the non-irrigated land of the study area. Long-term irrigation had no effect on hydrolytic acidity and base saturation in the Ah horizon of the investigated lands. Namely, the mentioned variations in the chemical properties of the investigated soils show that slight processes of reduction in the humus content and reduction of the content of base cations occured. Data on the chemical properties of the investigated soils indicate that the destructive processes of reduction in the humus content and leaching of base cations must be controlled in order to achieve a stable sustainable system of high productivity and prevent their further deterioration.

scholarly journals Physicochemical Parameters and Heavy Metals Content of Soil Samples from Farms in Minna

2015 ◽  
Vol 58 ◽  
pp. 154-163
Author(s):  
Z. Abdulhamid ◽  
E.B. Agbaji ◽  
C.E. Gimba ◽  
A.S. Agbaji
Keyword(s):  
Heavy Metals ◽  
Cation Exchange Capacity ◽  
Physicochemical Parameters ◽  
Chemical Properties ◽  
Absorption Spectrometry ◽  
Exchange Capacity ◽  
Average Concentration ◽  
Soil Samples ◽  
Ph Values ◽  
Physico Chemical

Physico-chemical properties and heavy metals content of soils were determined from seven farms in Minna, central Nigeria. Conventional analytical methods were employed to determine the physico-chemical properties and the heavy metals were analysed by atomic absorption spectrometry. The result showed that pH values ranged from 6.64 - 7.70 indicating slight acidity to slight alkalinity of the soils. The total organic carbon values ranged from 0.95-2.25 % resulting in the presence of organic matter (1.63-3.87). The electrical conductivity values ranged from 17-37 μS/cm. The cation exchange capacity of the soil samples ranged from 3.68-5.15 cmol/kg. The heavy metals levels were in the following range: Cd (0.00018-0.00134 mg/g), Cu (0.0069-0.0476 mg/g), Fe (1.942-2.2059 mg/g), Mn (0.1825-0.3696 mg/g), Ni (0.0065-0.0069 mg/g) and Zn (0.0157-0.2252 mg/g). The concentration of the metals in the soil samples varied according to the following trend: Fe>Mn>Zn> Cu>Ni>Cd. The average concentration of all the metals in each farm also gave the trend Farm B>Farm G>Farm E>Farm C>Farm F>Farm D>Farm A. The findings indicate the presence of heavy metals in all the farms but only Fe was above the FAO/WHO standards.

scholarly journals Characteristics of Soils Developing from Gabbro, Phyllite and Chert Parent Rock in Karangsambung District

2019 ◽  
Vol 4 (3) ◽  
pp. 131
Author(s):  
Ratna Taher ◽  
Makruf Nurudin ◽  
Eko Hanudin
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Particle Density ◽  
Chemical Properties ◽  
Clay Content ◽  
Exchange Capacity ◽  
Parent Rock ◽  
Soil Morphology ◽  
Total N ◽  
Organic C

Understanding the nature of the soil is very important to know the potential and the proper management of the soil. This study aimed to determine the differences in morphological, physical, and chemical properties of the soils developing from gabbro, phylitte and chert parent materials. The soil profile was made to represent each parent rock of gabbro, phyllite and chert located on the upper and middle slopes with pine-dominated vegetation and mixed gardens. Observation in the field is a professional description to observe soil morphology. Soil samples were taken at each horizon to analyze soil physical properties (bulk density, particle density, and texture), soil chemical properties (pH, exchanged cations, cation exchange capacity, available P, organic C, and total N). Texture analysis results showed that clay content of the soil developing from parent rock of Gabro 1 is the highest, followed by the soil clay content from  Chert 1, Phyllite 1, Chert 2, Phyllite 2, and Gabbro 2, respectively. The order of soil acidity level (pH) is Gabbro 2 > Gabbro 1> Chert 1 ~ Chert 2 > Phyllite 1 ~ Phyllite 2. Meanwhile, the order of the cation exchange capacity is Gabbro 1> Gabbro 2> Phyllite 1> Chert 1> Phyllite 2> Chert 2, and the order of the base saturation is Chert 2> Gabbro 2> Chert 1> Phyllite 2 > Phyllite1> Gabbro 1.

scholarly journals Chemical, Mineralogical, and Rheological Characterization of Regional Clays for Potential Use in Cosmetics and Pharmaceutical Products

2021 ◽  
Author(s):  
Cochiran Pereira dos Santos ◽  
Adriana de Jesus Santos
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Chemical Properties ◽  
Pharmaceutical Products ◽  
Exchange Capacity ◽  
Added Value ◽  
Rheological Characterization ◽  
X Ray ◽  
Physical And Chemical ◽  
Potential Use

Four clay samples from different deposits in the state of Sergipe, Brazil, were fractionated by dispersion and centrifugation for comparative tests with a standard commercial clay used for cosmetic and pharmaceutical purposes. For this, they were characterized by X-ray diffraction, X-ray fluorescence spectroscopy, measurements of cation exchange capacity, oil absorption and viscosity, in addition to particle sizes and plasticity indexes. The objective was to determine the physical and chemical properties of raw clays and the consequent granulometric fractions to evaluate their potential use in products with high added value. After fractionation, the samples showed significant amounts of smectite and kaolinite, which combined with the size, particle distribution, chemical composition, and high adsorption capacity, especially in the PDL and PV samples, make them potentially interesting for applications in pharmaceutical and cosmetic products, they can also be used in spas and esthetic centers for therapeutic purposes based on their softness and cation exchange capacity.

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