Variation of wastewater contaminants in China and source identification using hierarchical clustering based on weighted factor scores

2019 ◽  
Vol 79 (8) ◽  
pp. 1527-1533
Author(s):  
Haoxiang Liao ◽  
Xiqian Huang ◽  
Jingjing Feng ◽  
Deming Han ◽  
Yong Zhou ◽  
...  

Abstract Human activities have huge impact on the aquatic environment. Knowledge on sources of the contaminants provides guidelines to determine the ideal location and maintenance of monitoring stations, thus advancing environmental monitoring and pollution control. Factor analysis (FA) may be the most popular method for source identification, but the results should be affirmed. Following this logic, in this research, firstly the potential sources were determined, and secondly the contaminant concentrations in the source regions and the non-source regions were compared. To identify the potential sources, 75 meteorological, economic and social indicators were used to group the study regions. FA was used to reduce dimensionality and factor scores were calculated. The grouping was based on the weighted factor scores while the weight was variance explained by each factor respectively. Each group was supposed to correspond to a factor; that is, a potential source. The results indicated that the concentrations of chemical oxygen demand (COD), ammonia nitrogen, phosphorus and arsenic in wastewater were significantly different between groups. Animal husbandry, mining and/or energy industry were the main sources of COD, ammonia nitrogen and phosphorus; animal husbandry, mining, energy industry, and/or heavy and chemical industry were the main sources of phosphorus; humid climate and/or secondary industry were the main sources of arsenic.

2011 ◽  
Vol 250-253 ◽  
pp. 3392-3396
Author(s):  
Yu Jia Song ◽  
Hui Qing Liu

The discharge of urban sewage and agricultural non-point source pollutants is the main reason causing eutrophication in gullies in most cities of northern China. Based on a careful analysis on the ecological structure and ecological characteristics of a gully, this article preliminarily studies the interception and degradation mechanisms of nitrogen pollutants by the gully. Meanwhile, to take gullies in Changchun as the object of the study, this article carries out an experiment on the interception effect of nitrogen pollutants by gullies. This experiment respectively establishes a control section in the upper and lower reaches of a gully, and takes water samples four times in each section from May to August to determine total nitrogen, total phosphorus, nitrate nitrogen, ammonia nitrogen and salinity. The result shows: the gully plays some role in the interception of pollutants; total phosphorus accounts for the largest interception in pollutants in the experimented gully section, with the relative interception rate of 27.46%, followed by ammonia nitrogen, with the interception rate of 21.80%, which is the result of the combined effects of aquatic plants, microorganisms and sediment in the gully.


Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2181 ◽  
Author(s):  
Gonghan Xia ◽  
Wenlai Xu ◽  
Qinglin Fang ◽  
Zishen Mou ◽  
Zhicheng Pan

In this work, the influence of graphene on nitrogen and phosphorus in a batch Chlorella reactor was studied. The impact of graphene on the removal performance of Chlorella was investigated in a home-built sewage treatment system with seven identical sequencing batch Chlorella reactors with graphene contents of 0 mg/L (T1), 0.05 mg/L (T2), 0.1 mg/L (T3), 0.2 mg/L (T4), 0.4 mg/L (T5), 0.8 mg/L (T6) and 10 mg/L (T7). The influence of graphene concentration and reaction time on the pollutant removal performance was studied. The malondialdehyde (MDA) and total superoxide dismutase (SOD) concentrations in each reactor were measured, and optical microscopy and scanning electron microscopy (SEM) characterizations were performed to determine the related mechanism. The results show that after 168 h, the total nitrogen (TN), ammonia nitrogen (AN) and total phosphorus (TP) removal rates of reactors T1–T7 become stable, and the TN, AN and TP removal rates were gradually reduced with increasing graphene concentration. At 96 h, the concentrations of both MDA and SOD in T1–T7 gradually increased as the graphene concentration increased. In optical microscopy and SEM measurements, it was found that graphene was adsorbed on the surface of Chlorella, and entered Chlorella cells, deforming and reducing Chlorella. Through the blood plate count method, we estimated an average Chlorella reduction of 16%. According to the water quality and microscopic experiments, it can be concluded that the addition of graphene causes oxidative damage to microalgae and destruction of the Chlorella cell wall and cell membrane, inhibiting the nitrogen and phosphorus removal in Chlorella reactors. This study provides theoretical and practical support for the safe use of graphene.


2013 ◽  
Vol 295-298 ◽  
pp. 1478-1481
Author(s):  
Feng Xun Tan ◽  
Jiu Mei Wang ◽  
Dao Ji Wu

Traditional wastewater treatment methods can no longer remove effectively nitrogen and phosphorus that are the direct murderers of water eutrophication hazard. Enhanced coagulation method was adopted to improve the treatment effect by dosing suitable coagulants and coagulant aids. The raw water was from the reclaimed water in a University. TP and ammonia nitrogen removal of the water had been researched through an enhanced coagulation process with dosing ferric chloride, aluminum sulfate, polymeric ferric chloride, and poly-aluminum chloride (PAC) in this study. The coagulants effects were estimated by determining the removal rate of ammonia nitrogen, TP, COD and turbidity. When dosing the raw water with 80 mg/L PAC, the removal rates of ammonia nitrogen, TP, COD and turbidity are respectively 6.12%, 67.79%, 26.21%, 85.41%. The experimental results can be used as a reference of water treatment in the reclaimed water station.


2004 ◽  
Vol 49 (5-6) ◽  
pp. 207-214 ◽  
Author(s):  
J.J. Lee ◽  
C.U. Choi ◽  
M.J. Lee ◽  
I.H. Chung ◽  
D.S. Kim

This research is concerned with the removal of ammonia nitrogen and phosphorus in foodwaste by crystallization. Reductions have been achieved by struvite formation after the addition of magnesium ions (Mg2+). Magnesium ions used in this study were from magnesium salts of MgCl2. The results of our analysis using scanning electron microscopy and energy dispersive X-ray analysis showed that the amount of struvite in precipitated sludge grew enough to be seen with the naked eye (600-700μm). EDX analysis also showed that the main components of the struvite were magnesium and phosphorus. NH3-N removal efficiency using MgCl2 was 67% while PO4-P removal efficiency was 73%. It was confirmed that nitrogen and phosphorus could be stabilized and removal simultaneously through anaerobic digestion by Mg, NH3 and PO4-P, which were necessary for struvite formation.


Author(s):  
Yu Li ◽  
Leigang Li ◽  
Reham Yasser Farouk ◽  
Yuanyuan Wang

Flocculation can remove large amounts of nitrogen and phosphorus from wastewater, and the resulting nitrogen- and phosphorus-rich floc can be used to produce organic fertilizer. For biogas slurries containing high levels of nitrogen and phosphorus, ordinary flocculants can no longer meet the flocculation requirements. In this study, to fully utilize the advantages of the two flocculants and achieve efficient removal rates of nitrogen and phosphorus from a biogas slurry, chitosan (CTS) and polyaluminum chloride (PAC) were used as a composite flocculation agent to flocculate pig biogas slurries. The response surface method was used to study the effect of PAC added (PACadded) to the composite flocculant (CF), composite flocculant added (CFadded) to the biogas slurry and the pH on flocculation performance, and optimize these three parameters. In the tests, when the PACadded was 6.79 g·100 mL−1CF, the CFadded was 20.05 mL·L−1 biogas slurry and the pH was 7.50, the flocculation performance was the best, with an absorbance of 0.132 at a wavelength of 420 nm. The total phosphorus (TP) concentration was reduced from 214.10 mg·L−1 to 1.38 mg·L−1 for a removal rate of 99.4%. The total ammonia nitrogen (TAN) concentration was reduced from 1568.25 mg·L−1 to 150.27 mg·L−1 for a removal rate of 90.4%. The results showed that the CF could form larger flocs, and had greater adsorption capacity and more stable flocculation performance than ordinary flocculants. Furthermore, the CF could exhibit better chelation, electrical neutralization and bridge adsorption.


2019 ◽  
Vol 60 ◽  
pp. 520-534 ◽  
Author(s):  
Fabrício Alves de Almeida ◽  
Guilherme Ferreira Gomes ◽  
Juliana Helena Daroz Gaudêncio ◽  
José Henrique de Freitas Gomes ◽  
Anderson Paulo de Paiva

2016 ◽  
Vol 74 (7) ◽  
pp. 1553-1560
Author(s):  
Kun Zhong ◽  
Yi-yong Luo ◽  
Zheng-song Wu ◽  
Qiang He ◽  
Xue-bin Hu ◽  
...  

A vertical flow constructed wetland was combined with a biological aerated filter to develop an ecological filter, and to obtain the optimal operating parameters: The hydraulic loading was 1.55 m3/(m2·d), carbon–nitrogen ratio was 10, and gas–water ratio was 6. The experimental results demonstrated considerable removal efficiency of chemical oxygen demand (COD), ammonia nitrogen (NH4+-N), total nitrogen (TN), and total phosphorus (TP) in wastewater by the ecological filter, with average removal rates of 83.79%, 93.10%, 52.90%, and 79.07%, respectively. Concentration of NH4+-N after treatment met the level-A discharge standard of GB18918-2002. Compared with non-plant filter, the ecological filter improved average removal efficiency of COD, NH4+-N, TN, and TP by 13.03%, 25.30%, 14.80%, and 2.32%, respectively: thus, plants significantly contribute to the removal of organic pollutants and nitrogen. Through microporous aeration and O2 secretion of plants, the ecological filter formed an aerobic–anaerobic–aerobic alternating environment; thus aerobic and anaerobic microbes were active and effectively removed organic pollutants. Meanwhile, nitrogen and phosphorus were directly assimilated by plants and as nutrients of microorganisms. Meanwhile, pollutants were removed through nitrification, denitrification, filtration, adsorption, and interception by the filler. High removal rates of pollutants on the ecological filter proved that it is an effective wastewater-treatment technology for decentralized wastewater of mountainous towns.


1979 ◽  
Vol 16 (1) ◽  
pp. 17-24 ◽  
Author(s):  
John D. Morris

Several advantages to the use of factor scores as independent variables in a multiple regression equation have been advocated in the literature. To provide guidance for selecting the most desirable type of factor score upon which to calculate a regression equation, computer-based Monte Carlo methods were used to compare the predictive accuracy upon replication of regression on five “complete” and four “incomplete” factor score estimation methods. For several levels of multiple correlation (R2 = .30, .50, and. 70), and for several subject-to-variable sampling ratios (3:1, 5:1, and 10:1), prediction on incomplete factor scores showed better double cross-validated prediction accuracy than on complete factor scores. Moreover, the unique unit-weighted factor score was superior among the incomplete methods.


2020 ◽  
Vol 17 (2) ◽  
pp. 946-949
Author(s):  
Samaneh Alijantabar Aghouzi ◽  
Thomas S. Y. Choong ◽  
M. I. Aida Isma

This study elucidates the performance of sequencing batch reactor for nutrient removal from municipal wastewater. The removal of COD, ammonia nitrogen and phosphorus were investigated. The SBR with a working volume of 5 L was operated for 6 hours, with 5 min fill, 30 min settle and 5 min effluent withdrawal. The remaining time in each cycle was 90 min anaerobic phase, 130 min anoxic phase and 110 min aerobic phase. The experiment was repeated with a longer aeration time of 180 min resulting to prolong the duration cycle. In the aerobic phase, dissolved oxygen was kept in the range of more than 2 mg/L. During batch operation, the system attained stability and had a removal efficiency for ammonia nitrogen, COD and phosphorus of 51.36%, 83.33% and 99.53%, respectively. Extending the aeration period improved ammonia nitrogen removal to 54.27%. It should be noted that the stability of the granular biomass agglomerates highly depending on the bacterial consortia. The particle size of sludge reduced from 60.26 μm to 39.00 μm in 60 days. It was observed that degranulation process and biomass loss was unavoidable.


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