Interaction of tungsten in dry sliding against steel under high density electric current

2019 ◽  
pp. 101-109 ◽  
Author(s):  
M. I. Aleutdinova ◽  
V. V. Fadin ◽  
Yu. P. Mironov
Keyword(s):  
Electrical Contact ◽  
Analysis Data ◽  
Dry Sliding ◽  
Sliding Surface ◽  
X Ray ◽  
Sliding Surfaces ◽  
Quenched Steel ◽  
Sliding Electrical Contact ◽  
A Current ◽  
Tungsten Steel

The possibility of creating a wear-resistant dry sliding electrical contact tungsten/steel was studied. It was shown that tungsten caused severe wear of the quenched steel counterbody due to unlimited plastic flow of its surface layer at a current density up to 150 A/cm2 . This indicated the impossibility of achieving satisfactory characteristics of such a contact. Low electrical conductivity and wear resistance of the contact tungsten/steel were presented in comparison with the known high copper/steel contact characteristics under the same conditions. X-ray phase analysis data of the steel sliding surfaces made it possible to state that the cause of the unsatisfactory sliding of tungsten was the absence of the necessary concentration of FeO oxide on the sliding surface of the steel. 

On self-organization of the surface layer of structural steel in dry sliding against quenched steel under electric current

2021 ◽  
pp. 29-37
Author(s):  
M. I. Aleutdinova
Keyword(s):  
Structural Steel ◽  
Electric Current ◽  
Hardened Steel ◽  
Self Organization ◽  
Confocal Laser ◽  
Dry Sliding ◽  
Surface Layers ◽  
X Ray ◽  
Quenched Steel ◽  
Two Sectors

Using optical and confocal laser microscopes it was shown that dry sliding of structural steel against hardened steel under electric current of density higher 250 A/cm2 was accompanied by the formation of composite tribolayers. By X-ray phase analysis of the surface layers of the sample and counterbody was shown that they contain α-Fe, γ-Fe, and FeO. It is noted that the self-organization of the tribosystem under conditions of dry sliding under electric current can be represented as a hierarchy of structural states of the surface layers of contacting materials. It was found that the nominal sample area had two sectors. The character of the contact interaction in the sectors differs from each other.

Wear behaviour of metals in dry sliding against molybdenum with current collection

2020 ◽  
pp. 118-125
Author(s):  
M. I. Aleutdinova ◽  
V. V. Fadin
Keyword(s):  
Electrical Conductivity ◽  
Electrical Contact ◽  
Wear Behaviour ◽  
High Wear Resistance ◽  
Dry Sliding ◽  
High Electrical Conductivity ◽  
Current Collection ◽  
Ferrous Metals ◽  
Non Ferrous Metals ◽  
Sliding Electrical Contact

The possibility of high electrical conductivity of dry sliding electrical contact against molybdenum counterbody was studied. It was found that metals W and Cu were not able to form a sliding electrical contact with high wear resistance at current density higher 100 A/cm2 . The characteristics of the contacts of iron containing metals were slightly better than the contact characteristics of non-ferrous metals due to weaker adhesion. Using X-ray phase analysis, it was shown the absence of oxides in the sliding zone of non-ferrous metals. This led to their strong wear and contact’s low electrical conductivity. In the contact zone of iron containing samples the formation of FeO was observed that made it possible to reduce wear. This means that high electrical conductivity is unattainable in sliding with current collection against molybdenum.

Robust sliding mode control for a class of underactuated systems with mismatched uncertainties

2009 ◽  
Vol 223 (6) ◽  
pp. 785-795 ◽  
Author(s):  
D W Qian ◽  
X J Liu ◽  
J Q Yi
Keyword(s):  
Robust Control ◽  
Sliding Mode Control ◽  
Control Method ◽  
Sliding Mode ◽  
Underactuated Systems ◽  
Sliding Surface ◽  
Nominal System ◽  
Sliding Surfaces ◽  
Mode Control ◽  
Mismatched Uncertainties

Based on the sliding mode control methodology, this paper presents a robust control strategy for underactuated systems with mismatched uncertainties. The system consists of a nominal system and the mismatched uncertainties. Since the nominal system can be considered to be made up of several subsystems, a hierarchical structure for the sliding surfaces is designed. This is achieved by taking the sliding surface of one of the subsystems as the first-layer sliding surface and using this sliding surface and the sliding surface of another subsystem to construct the second-layer sliding surface. This process continues till the sliding surfaces of all the subsystems are included. A lumped sliding mode compensator is designed at the last-layer sliding surface. The asymptotic stability of all of the layer sliding surfaces and the sliding surface of each subsystem is proven. Simulation results show the validity of this robust control method through stabilization control of a system consisting of two inverted pendulums and mismatched uncertainties.

Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Analysis Data ◽  
Water Stability ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Solvothermal Conditions

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.

Effect of Synthesis Conditions on the Structure and Electrochemical Properties of LiNi1/2Mn1/2O2 by Sol Gel Method

2011 ◽  
Vol 399-401 ◽  
pp. 1447-1450
Author(s):  
Zhi Yong Yu ◽  
Han Xing Liu
Keyword(s):  
Electrochemical Properties ◽  
Sol Gel ◽  
Electrochemical Analysis ◽  
X Ray Diffraction ◽  
Capacity Fading ◽  
Gel Method ◽  
X Ray ◽  
Sol Gel Method ◽  
Synthesis Conditions ◽  
A Current

The layered LiNi1/2Mn1/2O2 cathode materials were synthesized by a sol gel method. The effects of calcination temperature and time on the structural and electrochemical properties of the LiNi1/2Mn1/2O2 were investigated. The prepared samples were characterized by X-ray diffraction (XRD) and electrochemical analysis. The results revealed that the layered LiNi1/2Mn1/2O2 material could be optimal synthesized at temperature of 900°C for 10h. The sample prepared under the above conditions has the highest initial discharge capacity of 151 mAh/g and showed no dramatic capacity fading during 20 cycles between 2.5-4.5V at a current rate of 20mA/g.

An analytical solution and an experimental procedure for thermal field at the interface of dry sliding surfaces

Meccanica ◽  
2010 ◽  
Vol 46 (3) ◽  
pp. 589-595 ◽  
Author(s):  
Gennaro Cuccurullo ◽  
Vincenzo D’Agostino ◽  
Roberta Di Giuda ◽  
Adolfo Senatore
Keyword(s):  
Analytical Solution ◽  
Thermal Field ◽  
Dry Sliding ◽  
Experimental Procedure ◽  
Sliding Surfaces

Сrystalline structure and dielectric properties of ceramic materials based on AgNbO3

2020 ◽  
Vol 63 (7) ◽  
pp. 75-78
Author(s):  
Polina A. Bezborodova ◽  
◽  
Elena M. Filonenko ◽  
Kseniya R. Erager ◽  
Anatoly V. Butakov ◽  
...  
Keyword(s):  
Rietveld Method ◽  
Average Particle Size ◽  
Ceramic Materials ◽  
Analysis Data ◽  
Molar Ratio ◽  
Average Particle ◽  
Dielectric Parameters ◽  
Low Frequencies ◽  
X Ray ◽  
Substitution Degree

Using the data of qualitative X-ray phase analysis, it was shown that in a wide concentration range at 1223 K compounds based on silver niobate are formed in the condition of the heterovalent substitution of tungsten(VI) ions for niobium(V) ions. These compounds are isomorphic to a perovskite-type structure. Microprobe analysis data allows to determine the homogeneity of the analyzed samples and the correspondence of their experimental compositions to the theoretical ones for the formula Ag1-xNb1-xWxO3. Using the data of X-ray diffraction analysis (Rietveld method) in the Crystallography Data Analysis Software – GSAS, the crystal structure of the obtained compounds was refined. The surface morphology of samples having been obtained at 1373 K was investigated by scanning electron microscopy (SEM). It was shown that with an increase of Nb5+ to W6+ substitution degree for Ag1-xNb1-xWxO3 ceramic samples in the range of the (0.2≤x≤0.8) molar ratio, the average particle size for the studied compositions grows from 1.3 to 5.2 μm, respectively. For the obtained ceramic compounds based on silver niobate with a perovskite-like structure (tetragonal distortion), the temperature-frequency dependences of dielectric parameters in the range 300-900 K were studied. It was found that samples slowly cooled from 1373 K are characterized by low values of (ε ~ 10) and loss (tgδ ~ 0.004 at f = 1 kHz) at room temperature. The ceramics obtained are characterized by relatively high values of dielectric permittivity ε at low frequencies and/or high temperatures. The dielectric parameters of the obtained ceramics are similar to the characteristics of so-called "colossal" dielectric constant materials. The revealed features of the dielectric characteristics of quenched ceramics apparently result from Maxwell-Wagner relaxation at intercrystalline contacts.

Morphology and I-V Characteristics of Electrochemically Deposited Zinc Oxide on Silicon

2021 ◽  
Vol 20 (3) ◽  
pp. 32-36
Author(s):  
Ahmad Bukhairi Md Rashid ◽  
Mastura Shafinaz Zainal Abidin ◽  
Shaharin Fadzli Abd Rahman ◽  
Amirjan Nawabjan
Keyword(s):  
Zinc Oxide ◽  
Electrochemical Deposition ◽  
Dark Current ◽  
Room Temperature ◽  
Volume Ratio ◽  
Deposition Process ◽  
X Ray ◽  
Current Voltage ◽  
Electrochemically Deposited ◽  
A Current

This paper reported on the electrochemical deposition of zinc oxide (ZnO) on p-silicon (p-Si) (100) substrate in the mixture of 0.1 M of zinc chloride (ZnCl2) and potassium chloride (KCl) electrolyte at a volume ratio of 1:1, 3:1 and 5:1 namely Sample A, B and C. The deposition process was done in room temperature with a current density of 10 mA/cm2 for 30 minutes. Prior to the experiment, all samples were treated by RCA cleaning steps. All samples were characterized using scanning electron microscopy (SEM) and energy dispersive X-ray (EDX). The results show that all samples have the same morphology of a flake-like structure with different Zn:O ratio that were 2.81, 2.35 and 2.49 for samples A, B and C. The current-voltage (I-V) characteristic graph was obtained by dark current measurement using Keithley SMU 2400 and the threshold voltage (Vth) values were determined at 2.21 V, 0.85 V and 1.22 V for sample A, B and C respectively which correspond with the Zn:O ratio where the highest value of Zn:O ratio can be found in sample A and the lowest in sample B. Based on these results, it shows that electrochemical deposition technique is capable of being used to deposit the flake-like structure ZnO on semiconductor material to form the p-n junction which behaves like a diode. The value of Vth seems to be depended on the ratio between Zn and O. Higher ratio of Zn and O will cause the higher value of intrinsic carrier concentration and built in potential which will increase the Vth value.

Preparation and Electrochemical Performance of Mn3O4/GR Composites Electrode Material in Supercapacitors

2019 ◽  
Vol 807 ◽  
pp. 50-56
Author(s):  
Yun Long Zhou ◽  
Zhi Biao Hu ◽  
Li Mei Wu ◽  
Jiao Hao Wu
Keyword(s):  
Room Temperature ◽  
Raw Materials ◽  
Precipitation Method ◽  
Electrochemical Performances ◽  
Manganese Sulfate ◽  
X Ray Diffraction ◽  
X Ray ◽  
Co Precipitation ◽  
A Current ◽  
Discharge Test

Using hydrated manganese sulfate and general type graphene (GR) as raw materials, Mn3O4/GR composite has been successfully prepared by the liquid phase chemical co-precipitation method at room temperature. X-ray diffraction (XRD) was used to investigate the phase structure of Mn3O4powder and Mn3O4/GR composite; The electrochemical performances of the samples were elucidated by cyclic voltammetry and galvanostatic charge-discharge test in 0.5 mol/L Na2SO4electrolyte. The results show that the Mn3O4/GR composite possesses graphene phase and good reversibility; the composite also displays a specific capacitance of 318.8 F/g at a current density of 1 A/g.

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