scholarly journals Estimation of the energy of detonation initiation in a hydrogen-oxygen mixture by a high-velocity projectile

2021 ◽  
pp. 180-180
Author(s):  
Igor Bedarev ◽  
Valentin Temerbekov
Keyword(s):  
Experimental Data ◽  
High Velocity ◽  
Numerical Study ◽  
Initial Pressure ◽  
Theoretical Models ◽  
Detonation Initiation ◽  
Oxygen Mixture ◽  
Initiation Energy ◽  
Detonation Cell ◽  
Detonation Cell Size

The paper presents the results of a numerical study of the initiation of oblique detonation modes by a high-velocity projectile moving in an argon-diluted hydrogen?oxygen mixture. The simulation of oblique detonation wave modes showed that calculated and experimental flow patterns agree. The calculated detonation cell size agreed with experimental data. For the initial pressure Pst = 121 kPa and Pst = 141 a series of calculations were carried out for a different projectile diameters. The detonation initiation energy was estimated, and the results were compared with theoretical models.

scholarly journals Experimental Research on Detonation Cell Size of a Purified Biogas-Oxygen Mixture

Energies ◽  
2021 ◽  
Vol 14 (20) ◽  
pp. 6605
Author(s):  
Stanislaw Siatkowski ◽  
Krzysztof Wacko ◽  
Jan Kindracki
Keyword(s):  
Cell Size ◽  
Cellular Structure ◽  
Renewable Energy Sources ◽  
Initial Pressure ◽  
Oxygen Mixture ◽  
Average Cell Size ◽  
Detonation Cell ◽  
Average Cell ◽  
Promising Alternative ◽  
Detonation Cell Size

Interest in alternative and renewable energy sources has risen significantly in recent years. Biogas is a prime example of a promising, alternative fuel that might be a possible replacement for fossil fuels. It is a mixture consisting mainly of CH4 and CO2 with various additions. Biogas is easily storable and as such is a more reliable and stable source of energy than solar and wind sources, which suffer from unreliability due to their dependence on weather conditions. In this paper, the authors report experimental results of detonation of a biogas-oxygen mixture. The composition of the biogas was 70% CH4 + 30% CO2 and the experiments were carried out for a range of equivalence ratios (Φ = 0.5 ÷ 1.5) and initial pressures (0.6 ÷ 1.6 bar). The aim of the research was to analyze the cellular structure of detonation. The soot foil technique was used to determine the width of the detonation cells (λ). The conducted experiments and subsequent analysis of the detonation cell size confirm that both the increase in the initial pressure of the mixture or move away from stoichiometric (Φ = 1) composition is accompanied by a decrease in the width of the detonation cell. The authors also argue that due to the unstable cellular structure of the detonation, it is insufficient to report only the average cell size. Instead, the researchers propose more detailed statistical description assured values.

TEMPERATURE DEPENDENCE BEHAVIOR OF ELECTRICAL RESISTIVITY IN NOBLE METALS AT LOW TEMPERATURES

2014 ◽  
Vol 5 (3) ◽  
pp. 982-992 ◽  
Author(s):  
M AL-Jalali
Keyword(s):  
Experimental Data ◽  
Electrical Resistivity ◽  
Temperature Dependence ◽  
Concentration Dependence ◽  
Low Temperatures ◽  
Noble Metals ◽  
Phonon Scattering ◽  
Theoretical Models ◽  
Residual Resistivity ◽  
Electron Phonon Scattering

Resistivity temperature – dependence and residual resistivity concentration-dependence in pure noble metals(Cu, Ag, Au) have been studied at low temperatures. Dominations of electron – dislocation and impurity, electron-electron, and electron-phonon scattering were analyzed, contribution of these mechanisms to resistivity were discussed, taking into consideration existing theoretical models and available experimental data, where some new results and ideas were investigated.

Simple theoretical models of elimination reactions on polar catalysts; Dehydration reactivity of secondary alcohols on acidic and basic catalysts

1985 ◽  
Vol 50 (4) ◽  
pp. 920-929 ◽  
Author(s):  
Jiří Sedláček
Keyword(s):  
Experimental Data ◽  
Quantum Chemical ◽  
Theoretical Models ◽  
Aliphatic Alcohols ◽  
Secondary Alcohols ◽  
Carbonium Ion ◽  
Dehydration Reactions ◽  
Aromatic Alcohols ◽  
Basic Catalysts ◽  
Simple Models

CNDO/2 calculations for simple models of adsorption and dehydration reactions of secondary aliphatic and aromatic alcohols on polar catalysts are presented. The models involve selected stages of elimination mechanisms of various types (E1, E2 and E1cB elimination). Calculated quantum chemical quantities were correlated with reported experimental data. It is shown that reactivities for the series of substituted phenylethanols correlate very well with the ease of carbonium ion formation. In the case of aliphatic alcohols, calculated quantities correlate generally with the reactivities on SiO2 and are in anticorrelation with the reactivities on Al2O3.NaOH.

scholarly journals Detonation initiation by shock focusing at elevated pressure conditions in a pulse detonation combustor

2020 ◽  
Vol 12 ◽  
pp. 175682772092171
Author(s):  
Fabian E Habicht ◽  
Fatma C Yücel ◽  
Joshua AT Gray ◽  
Christian O Paschereit
Keyword(s):  
Success Rate ◽  
Mass Flow Rate ◽  
Mass Flow ◽  
Flow Rate ◽  
Initial Pressure ◽  
Detonation Initiation ◽  
Major Influence ◽  
Mean Flow ◽  
Shock Focusing ◽  
Pulse Detonation

This work contains experimental investigations on the correlation of the detonation initiation process via a shock-focusing device with various initial pressures and mass flow rates. A pulse detonation combustor is operated with stoichiometric hydrogen--air--oxygen mixtures in single cycle operation. A rotationally symmetric shock-focusing geometry evokes the onset of a detonation by the focusing of the reflected leading shock wave, while a blockage plate at the rear end of the test rig is applied to induce an elevated initial pressure. The results show that the reactivity has a major influence on the success rate of detonation initiation. However, measurements with different blockage plates suggest that the mass flow rate has to be considered as well when predicting the success rate. Three main statements can be drawn from the results. (1) An increase in the mean flow velocity induces higher velocity fluctuations which result in a stronger leading shock ahead of the accelerating deflagration front. (2) An increase in the initial static pressure reduces the critical shock strength that must be exceeded to ensure successful detonation initiation by shock focusing. (3) Since the initial pressure is directly linked to the mass flow rate, these contrary trends can cancel each other out, which could be observed for 40% vol. of oxygen in the oxidizer. High-speed images were taken, which confirm that the detonation is initiated in the center of the converging--diverging nozzle due to focusing of the leading shock.

Oscillatory Heat Transfer in a Pipe Subjected to a Laminar Reciprocating Flow

1996 ◽  
Vol 118 (3) ◽  
pp. 592-597 ◽  
Author(s):  
T. S. Zhao ◽  
P. Cheng
Keyword(s):  
Heat Transfer ◽  
Experimental Data ◽  
Heat Flux ◽  
Nusselt Number ◽  
Numerical Study ◽  
Temperature Cycle ◽  
Uniform Heat Flux ◽  
Fluid Temperature ◽  
Cycle Space ◽  
Reciprocating Flow

An experimental and numerical study has been carried out for laminar forced convection in a long pipe heated by uniform heat flux and subjected to a reciprocating flow of air. Transient fluid temperature variations in the two mixing chambers connected to both ends of the heated section were measured. These measurements were used as the thermal boundary conditions for the numerical simulation of the hydrodynamically and thermally developing reciprocating flow in the heated pipe. The coupled governing equations for time-dependent convective heat transfer in the fluid flow and conduction in the wall of the heated tube were solved numerically. The numerical results for time-resolved centerline fuid temperature, cycle-averaged wall temperature, and the space-cycle averaged Nusselt number are shown to be in good agreement with the experimental data. Based on the experimental data, a correlation equation is obtained for the cycle-space averaged Nusselt number in terms of appropriate dimensionless parameters for a laminar reciprocating flow of air in a long pipe with constant heat flux.

Modeling and Experimental Validation of the Effective Bulk Modulus of a Mixture of Hydraulic Oil and Air

2014 ◽  
Vol 136 (5) ◽  
Author(s):  
Hossein Gholizadeh ◽  
Doug Bitner ◽  
Richard Burton ◽  
Greg Schoenau
Keyword(s):  
Experimental Data ◽  
Bulk Modulus ◽  
Theoretical Models ◽  
Operating Conditions ◽  
Air Bubbles ◽  
Pressure Sensitivity ◽  
Hydraulic Oil ◽  
Effective Bulk Modulus ◽  
Experimental Apparatus ◽  
Major Factors

It is well known that the presence of entrained air bubbles in hydraulic oil can significantly reduce the effective bulk modulus of hydraulic oil. The effective bulk modulus of a mixture of oil and air as pressure changes is considerably different than when the oil and air are not mixed. Theoretical models have been proposed in the literature to simulate the pressure sensitivity of the effective bulk modulus of this mixture. However, limited amounts of experimental data are available to prove the validity of the models under various operating conditions. The major factors that affect pressure sensitivity of the effective bulk modulus of the mixture are the amount of air bubbles, their size and the distribution, and rate of compression of the mixture. An experimental apparatus was designed to investigate the effect of these variables on the effective bulk modulus of the mixture. The experimental results were compared with existing theoretical models, and it was found that the theoretical models only matched the experimental data under specific conditions. The purpose of this paper is to specify the conditions in which the current theoretical models can be used to represent the real behavior of the pressure sensitivity of the effective bulk modulus of the mixture. Additionally, a new theoretical model is proposed for situations where the current models fail to truly represent the experimental data.

Numerical Simulation of Detonation Propagation in Flame Arrestor Applications

2020 ◽  
Author(s):  
Hoden A. Farah ◽  
Frank K. Lu ◽  
Jim L. Griffin
Keyword(s):  
Heat Transfer ◽  
Experimental Data ◽  
Numerical Study ◽  
Forchheimer Equation ◽  
Detonation Propagation ◽  
Simulation Domain ◽  
Shock Transmission ◽  
Propagation Parameters ◽  
Porous Zone ◽  
Viscous Solutions

Abstract A detail numerical study of detonation propagation and interaction with a flame arrestor product was conducted. The simulation domain was based on the detonation flame arrestor validation test setup. The flame arrestor element was modeled as a porous zone using the Forchheimer equation. The coefficients of the Forchheimer equation were determined using experimental data. The Forchheimer equation was incorporated into the governing equations for axisymmetric reactive turbulent flow as a momentum sink. A 21-step elementary reaction mechanism with 10 species was used to model the stoichiometric oxyhydrogen detonation. Different cases of detonation propagation including inviscid, viscous adiabatic, and viscous with heat transfer and a porous zone were studied. A detail discussion of the detonation propagation and effect of the arrestor geometry, the heat transfer and the porous zone are presented. The inviscid numerical model solutions of the detonation propagation parameters are compared to one-dimensional analytical solution for verification. The viscous solutions are qualitatively compared to historical experimental data which shows very similar trend. The effect of the porous media parameters on shock transmission and re-initiation of detonation is presented.

Validation of Film Evaporation Model in GASFLOW-MPI

2018 ◽  
Author(s):  
Li Yabing ◽  
Zhang Han ◽  
Xiao Jianjun
Keyword(s):  
Experimental Data ◽  
Wall Temperature ◽  
Cooling System ◽  
Numerical Study ◽  
Thermal Power ◽  
Heat Removal ◽  
Air Velocity ◽  
Evaporation Model ◽  
Film Evaporation ◽  
Test Region

A dynamic film model is developed in the parallel CFD code GASFLOW-MPI for passive containment cooling system (PCCS) utilized in nuclear power plant like AP1000 and CAP1400. GASFLOW-MPI is a widely validated parallel CDF code and has been applied to containment thermal hydraulics safety analysis for different types of reactors. The essential issue for PCCS is the heat removal capability. Research shows that film evaporation contributes most to the heat removal capability for PCCS. In this study, the film evaporation model is validated with separate effect test conducted on the EFFE facility by Pisa University. The test region is a rectangle gap with 0.1m width, 2m length, and 0.6m depth. The water film flowing from the top of the gap is heated by a heating plate with constant temperature and cooled by countercurrent air flow at the same time. The test region model is built and analyzed, through which the total thermal power and evaporation rate are obtained to compare with experimental data. Numerical result shows good agreement with the experimental data. Besides, the influence of air velocity, wall temperature and gap widths are discussed in our study. Result shows that, the film evaporation has a positive correlation with air velocity, wall temperature and gap width. This study can be fundamental for our further numerical study on PCCS.

Combustion Simulation of Propane/Oxygen (With Nitrogen/Argon) Mixtures Using Rate-Controlled Constrained-Equilibrium

2018 ◽  
Vol 141 (2) ◽  
Author(s):  
Guangying Yu ◽  
Hameed Metghalchi ◽  
Omid Askari ◽  
Ziyu Wang
Keyword(s):  
Experimental Data ◽  
Energy System ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Oxygen Mixture ◽  
Free Valence ◽  
Wide Range ◽  
Constrained Equilibrium ◽  
Rate Controlled ◽  
Good Agreement

The rate-controlled constrained-equilibrium (RCCE), a model order reduction method, has been further developed to simulate the combustion of propane/oxygen mixture diluted with nitrogen or argon. The RCCE method assumes that the nonequilibrium states of a system can be described by a sequence of constrained-equilibrium states subject to a small number of constraints. The developed new RCCE approach is applied to the oxidation of propane in a constant volume, constant internal energy system over a wide range of initial temperatures and pressures. The USC-Mech II (109 species and 781 reactions, without nitrogen chemistry) is chosen as chemical kinetic mechanism for propane oxidation for both detailed kinetic model (DKM) and RCCE method. The derivation for constraints of propane/oxygen mixture starts from the eight universal constraints for carbon-fuel oxidation. The universal constraints are the elements (C, H, O), number of moles, free valence, free oxygen, fuel, and fuel radicals. The full set of constraints contains eight universal constraints and seven additional constraints. The results of RCCE method are compared with the results of DKM to verify the effectiveness of constraints and the efficiency of RCCE. The RCCE results show good agreement with DKM results under different initial temperature and pressures, and RCCE also reduces at least 60% CPU time. Further validation is made by comparing the experimental data; RCCE shows good agreement with shock tube experimental data.

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