scholarly journals Ecological Indices of the Heavy Metals in the Soil of Shewasoor Sub-Basin, Kirkuk NE Iraq

2018 ◽  
Vol 3 (1) ◽  
Author(s):  
Mustafa Jamal Akbar ◽  
Omer Sabah Al-Tamimi
Keyword(s):  
Heavy Metals ◽  
Cancer Risk ◽  
Risk Index ◽  
Sediment Quality ◽  
Hazard Index ◽  
Soil Samples ◽  
Geochemical Background ◽  
Ecological Indices ◽  
Distribution Maps ◽  
Contamination Levels

The current research aimed to assess contamination levels in the soil of study area by heavy metals. Eight sites were selected for the collection of soil samples. The eight heavy metals namely As, Pb, Cd, Cr, Co, Cu, Ni, and Zn were analyzed in each soil samples by using ICP-MS technology. The measured concentrations of heavy metals were compared with Geochemical Background values, EPA Sediment Quality Guidelines, Ecological Screening values, and WHO Guidelines. The spatial distribution maps of ecological indices were performed using ArcGIS software (version 10.2), which provides an idea of the geographical distribution of heavy metals contamination levels in the soil of Shewasoor sub-basin. The soil contamination by heavy metals assessed using Potential Ecological Risk Index (RI), Nemerow Pollution Index (P_N), Hazard Index (HI), and Cancer Risk. The RI showed there are high risk of heavy metals in soil and according to P_N the soil has been moderate to severely contaminated by heavy metals. The hazard index of all soil samples was within acceptable range for adults and showed unacceptable risk for children. While the total cancer risk values of As and Cr were within acceptable limits, whereas of Pb, Cd, Co, and Ni were lower than acceptable risk range at all sites for adults and children. Ecological indices which are used to assess the contamination levels in the soil by heavy metals refers to the soil of study area was contaminated moderate to heavily by heavy metals, this attributed to the natural and anthropogenic pollution sources around and within the study area.

scholarly journals Heavy Metals in Urban Street Dust: Health Risk Assessment (Lublin City, E Poland)

2021 ◽  
Vol 11 (9) ◽  
pp. 4092
Author(s):  
Wojciech Zgłobicki ◽  
Małgorzata Telecka
Keyword(s):  
Heavy Metals ◽  
Cancer Risk ◽  
Health Risk ◽  
Road Traffic ◽  
Hazard Index ◽  
Street Dust ◽  
Geochemical Background ◽  
Large Cities ◽  
Urban Street Dust ◽  
The Individual

Various pollutants, including heavy metals, present in street dust can pose a threat to the health of city dwellers. So far, studies on levels of this threat have been carried out mainly in large cities, characterised by considerable road traffic and industrial activity. This paper assesses the levels of hazard index and cancer risk for Cd, Cr, Cu, Ni, Pb and Zn contained in street dust collected in 2013 and 2018 at 62 points located in different parts of a small/medium-sized city (Lublin, E Poland). Heavy metals contents were analysed by means of XRF spectrometry (in the fraction <63 µm). Despite the fact that the concentrations of some elements (Zn, Cd and Cu) in street dust are 6–7 times higher than the geochemical background, this does not pose a risk of non-carcinogenic effects. The average hazard index (HI) for the individual elements reaches very low levels (<0.01). Cancer risk (CR) for adults is below the less strict limit of 10−4, and in the case of Pb, it is even lower than values of the order of 10−6, whereas for children, CR levels exceed the standards and are of the order of 10−4, except for Pb. For all metals except Cr, the health risk was higher in 2013 than in 2018.

scholarly journals Estimation of Risk to the Eco-Environment and Human Health of Using Heavy Metals in the Uttarakhand Himalaya, India

2020 ◽  
Vol 10 (20) ◽  
pp. 7078 ◽  
Author(s):  
Amit Kumar ◽  
Marina Cabral-Pinto ◽  
Amit Kumar ◽  
Munesh Kumar ◽  
Pedro A. Dinis
Keyword(s):  
Heavy Metals ◽  
Cancer Risk ◽  
Ecological Risk ◽  
Risk Index ◽  
Hazard Index ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Mitigation Measures ◽  
Sampling Locations ◽  
Modern Era

In the modern era, due to the rapid increase in urbanization and industrialization in the vicinity of the Himalayas, heavy metals contamination in soil has become a key priority for researchers working globally; however, evaluation of the human and ecological risks mainly in hilly areas remains limited. In this study, we analyzed indices like the contamination factor (CF), degree of contamination (DC), enrichment factor (EF), geochemical index (Igeo), pollution ecological risk index (PERI), and pollution load index (PLI), along with cancer risk (CR) and hazard indices (HI), to ascertain the eco-environmental and human risks of using heavy metals in datasets collected from 168 sampling locations in Uttarakhand, India. The evaluation calculated of Igeo, EF, and CF suggests that represented soil samples were moderately contaminated and highly augmented with Rb, while PERI (75.56) advocates a low ecological risk. Further, PLI and DC (PLI: 1.26; DC: 36.66) show a possible health risk for the native population in the vicinity of the studied catchment. The hazard index (HI) is estimated greater than 1 (HI > 1) for Cr and Mn, representing a possible risk for cancer. However, adults are free from cancer risk, and other studied elements have been reported as noncarcinogenic. This assessment gives important information to policymakers, environmentalists, and foresters for taking mitigation measures in advance to mitigate the potential future risk of soil pollution on humans, ecology, and the environment.

scholarly journals Geoaccumulation and Ecological Risk Indexes in Papaya Cultivation Due to the Presence of Trace Metals

Agronomy ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 301
Author(s):  
Isabel Araceli Amaro-Espejo ◽  
María del Refugio Castañeda-Chávez ◽  
Joaquín Murguía-González ◽  
Fabiola Lango-Reynoso ◽  
Karina Patricia Bañuelos-Hernández ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Soil Texture ◽  
Geoaccumulation Index ◽  
Sandy Loam ◽  
Risk Index ◽  
Soil Samples ◽  
Silt Loam ◽  
Clay Loam ◽  
Contamination Levels ◽  
The Impact

The aim of this research was to evaluate the impact of heavy metals on Maradol papaya cultivation soil, through the geoaccumulation index (Igeo) and the ecological potential risk index (RI). Soil samples from 15 locations in the Cotaxtla municipality of Veracruz, Mexico were tested for pH, soil texture, and concentrations of lead (Pb), chromium (Cr), cadmium (Cd), zinc (Zn), copper (Cu), and organic matter (MO). The pH varied between values of 5.5 ± 0.10 and 7.7 ± 0.22, while the MO varied from 1.57% ± 0.97% to 13.1% ± 1.342%. The type of soil texture represented 48% sandy loam, 40% loam, 8% clay loam, and 4% silt-loam. For heavy metals, average levels were found in the following order Cr (0.695 ± 0.018) > Zn (0.615 ± 0.016) > Pb (0.323 ± 0.012) > Cu (0.983 ± 0.011) > Cd (0.196 ± 0.011) mg kg−1. The Igeo values from 96% of the analyzed sampling points were below zero and were considered uncontaminated. The other 4% of samples, from the Potrerillo1 (PT) site, had Igeo values of 1.13, where the highest concentration of Cd was found, which indicates moderate contamination levels. The RI index at the PT site was in the category of moderate contamination, and the rest of the points correspond to the category of low pollution.

scholarly journals Assessment of heavy metals contamination and associated risks in shallow groundwater sources from three different residential areas within Ibadan metropolis, southwest Nigeria

2021 ◽  
Vol 11 (5) ◽  
Author(s):  
Saheed Adekunle Ganiyu ◽  
Abimbola Temitope Oyadeyi ◽  
Azeem Adedeji Adeyemi
Keyword(s):  
Heavy Metals ◽  
Cancer Risk ◽  
Urban Area ◽  
Ecological Risk ◽  
Water Samples ◽  
Risk Index ◽  
Shallow Groundwater ◽  
World Health ◽  
Southwest Nigeria ◽  
The Mean

AbstractThis study has been conducted to appraise the concentrations of selected heavy metals and total dissolved solids (TDSs) in the drinking water from shallow wells in parts of Ibadan metropolis, southwest Nigeria. Fifteen (15) water samples were collected from three representative residential locations [traditional core area (TCA), peri-urban area (PUA), and urban area (UA)] for geochemical analysis. Heavy metals and TDS were analyzed with the aid of atomic absorption spectrophotometer and calibrated meter, respectively. The mean concentration (mg/L) of Zn, Pb Mn, Fe, and Cd has been 3.930, 0.658, 0.0304, 1.698, and 0.501, respectively, and as a consequence, the order of abundance of studied metals was Zn > Fe > Pb > Cd > Mn. Concentrations of Zn, Fe, Pb, and Cd were higher than recommended standards in 60%, 86.7%, 100%, and 100% of groundwater samples, respectively. However, at all points tested, the mean concentrations of Mn and TDS in water samples lie within the safe limits set by World Health Organization. The evaluation of geoaccumulation index (Igeo), enrichment factor (EF), and contamination factor suggests that representative water samples were low-to-moderate contamination. The potential ecological risk index advocates low-to-moderate ecological risk in TCA and PUA, while it demonstrated exclusive “moderate” risk in UA. Further, the range of pollution load index (PLI) (0.55–1.32) in both TCA and PUA shows nil-to-moderate pollution status, while PLI values > 1 in UA indicate moderate contaminated state. The degree of contamination in groundwater showed the following trends: UA > TCA > PUA in the study area. Moreover, the results of EF and quantification of contamination of analyzed metals in water samples indicate geogenic and anthropogenic inputs. The contribution of studied metals to the incidence of non-cancer risk via oral intake within the residential sites follows the order: cadmium > lead > zinc > iron > manganese. The hazard index as a result of ingested heavy metals for the three population classes surpasses the acceptable range in the order of infant < child < adult. Cadmium and lead made considerable impact to the estimation of cancer risk in the study area for the three human population categories. Factor analysis extracted only one component that explained 94.64% of the entire variance, while cluster analysis identified three distinct groups based on similar water quality characteristics. Based on the findings of the study, awareness programs toward protecting the shallow groundwater sources should be launched, encouraged, and sustained. Moreover, the study suggests better hygienic practices and pre-treatment of contaminated water before consumption.

scholarly journals Trace Metal Contamination Characteristics and Health Risks Assessment ofCommelina africanaL. and Psammitic Sandflats in the Niger Delta, Nigeria

2016 ◽  
Vol 2016 ◽  
pp. 1-14 ◽  
Author(s):  
Nsikak U. Benson ◽  
Paul A. Enyong ◽  
Omowunmi H. Fred-Ahmadu
Keyword(s):  
Trace Metal ◽  
Niger Delta ◽  
Anthropogenic Activities ◽  
Hazard Quotient ◽  
Risk Index ◽  
Sediment Quality ◽  
Hazard Index ◽  
Adult Males ◽  
Metal Concentrations ◽  
Metal Levels

The purpose of this study was to investigate and quantify trace metal concentrations inCommelina africanaL. and psammitic sandflats from an intertidal coastal ecosystem in Niger Delta, Nigeria, and to evaluate their spatial distribution, degree of contamination, and source apportionment. The environmental risks associated with soil contamination were elaborately assessed using potential ecological risk index, sediment quality guidelines, and enrichment relative to background levels. The mean concentrations of Cd, Cr, Ni, Pb, and Zn in sandflat soil samples are0.76±9.0×10-2,7.39±8.7×10-1,2.28±0.35,0.024±4.0×10-3, and74.51±2.55 mg/kg, respectively. Metal levels indicate strong variability with sampling sites. The order of trace metal concentrations in theCommelina africanaL. samples isZn>Ni>Cr>Pb>Cd. The concentrations varied with the sample locations; and the levels of Pb (0.05 to 0.08 mg/kg) at all locations are found to be significantly below permissible level of 0.3 mg/kg. Potential sources of metal loadings may be associated with localised or diffused anthropogenic activities. The average carcinogenic risks are below1.0×10-6threshold values, and the sandflat soils are not considered to pose significant health effects to children and adult males and females. However, the carcinogenicity and noncarcinogenicity risks ranking decrease following the orderchildren>adult  males>adult  females. Comparatively, the hazard quotient and hazard index indicate that the psammitic sandflats might pose a health risk to children in future.

X-ray fluorescence spectrometric determination of heavy metals in selected rice samples sold on the Liberian market: a case study conducted in Paynesville City, Greater Monrovia

2020 ◽  
Vol 9 (3) ◽  
pp. 1
Author(s):  
McClain James ◽  
PAYE Plenseh Diana ◽  
N’debewillie Kokolo ◽  
CHEA Sampson K. P. ◽  
Kiazolu J. Boima
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Cancer Risk ◽  
Hazard Index ◽  
Rice Sample ◽  
X Ray ◽  
Total Cancer Risk ◽  
Total Cancer ◽  
Rice Consumption ◽  
The Mean

Background: Environmental pollution with toxic heavy metals can be lead to the possible contamination of rice. Rice is a staple food widely consumed in the urban and rural parts of Liberia daily. Rice is cultivated in approximately 113 countries and a fundamental source for energy and protein. Objective: The study assesses selected heavy metals (As, Pb, Cd, Se, and Cr) concentration in selected imported rice and traditionally grown rice and bulgur wheat in Liberia. Methods: Six grade of imported rice, Bulgar wheat, and traditionally grown rice were purchased from the Duport Road and Red-Light markets in Greater Monrovia and analyze using X-ray Fluorescence Spectrometer. All data were analyzed using XLSTAT, and data was used to calculate the risk factor of each rice sample. Results: The mean concentration of heavy metal found in the rice as follow: As, 1.31ppm; Cd, 9.42ppm; Cr. 12.3ppm; Se, 5.73ppm; and Pb, 1.75ppm. The estimated daily intakes (EDIs) were calculated in combination with the rice consumption data. The mean intakes of As, Cd, Cr, Se, and Pb through rice were estimated to be 1.32, 9.42. 12.4. 5.74, and 1.75 mg/kg BW/day. Chromium has the average estimated daily intake. The combined hazard index for the heavy metals in each sample and the total cancer risk for each sample contributed most significantly to a cancer risk of rice consumption during adult life expectancy.Conclusion: The selected heavy metal concentration from the rice sample was above the FAO/WHO reference Standard but was within the range of the contaminant level except for chromium, which is above the accepted range. However, the hazard index and the total cancer risk indicate a potential non-carcinogenic and carcinogenic risk.  

scholarly journals Data Analysis of Beach Sands’ Chemical Analysis Using Multivariate Statistical Methods and Heavy Metal Distribution Maps: The Case of Moonlight Beach Sands, Kemer, Antalya, Turkey

Symmetry ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 1538 ◽  
Author(s):  
Fusun Yalcin
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Data Analysis ◽  
Chemical Analysis ◽  
Statistical Methods ◽  
Risk Index ◽  
Multivariate Statistical Methods ◽  
Multivariate Statistical ◽  
Distribution Maps ◽  
Beach Sands

Multivariate statistical methods are widely used in several disciplines of fundamental sciences. In the present study, the data analysis of the chemical analysis of the sands of Moonlight Beach in the Kemer region was examined using multivariate statistical methods. This study consists of three parts. The multivariate statistical analysis tests were described in the first part, then the pollution indexes were studied in the second part. Finally, the distribution maps of the chemical analyses and pollution indexes were generated using the obtained data. The heavy metals were mostly observed in location K1, while they were sorted as follows based on their concentrations: Mg > Fe > Al > Ti > Sr > Mn > Cr > Ni > Zn > Zr > Cu > Rb. Also, strong positive correlations were found between Si, Fe, Al, K, Ti, P. According to the results of factor analysis, it was found that four factors explained 83.5% of the total variance. On the other hand, the coefficient of determination (R2) was calculated as 63.6% in the regression model. Each unit increase in the value of Ti leads to an increase of 0.022 units in the value of Si. Potential Ecological Risk Index analysis results (RI < 150) revealed that the study area had no risk. However, the locations around Moonlight Beach are under risk in terms of Enrichment Factor and Contamination Factor values. The index values of heavy metals in the anomaly maps and their densities were found to be successful; and higher densities were observed based on heavy metal anomalies.

scholarly journals Geochemistry pollution status and ecotoxicological risk assessment of heavy metals in the Pahang River sediment after the high magnitude of flood event

2020 ◽  
Author(s):  
K. Y. Lim ◽  
N. A. Zakaria ◽  
K. Y. Foo
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
River Sediment ◽  
Risk Index ◽  
River Sediments ◽  
Sediment Quality ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Flood Event ◽  
Pollution Status

Abstract The present work is aimed at assessing the aftermath effects of the 2014 flood tragedy on the distribution, pollution status and ecological risks of the heavy metals deposited in the surface river sediment. A series of environmental pollution indexes, specifically the enrichment factor (EF), geo-accumulation index (Igeo), contamination factor (CF), modified degree of contamination (mCd), pollution load index (PLI), potential ecological risk index (PERI) and sediment quality guidelines (SQGs) have been adopted. Results revealed that the freshly deposited sediments collected soon after the flood event were dominated by Cu, Fe, Pb, Ni, Zn, Cr and Cd, with the average concentrations of 38.74, 16,892, 17.71, 4.65, 29.22, 42.36 and 0.29 mg/kg, respectively. According to the heavy metal pollution indexes, Pahang River sediments were moderately to severely contaminated with Pb, Ni, Cu, Zn and Cr, while Cd with the highest risk of 91.09 was the predominant element that illustrated an aesthetic ecological risk to the water body after the tragic flood event. The findings highlighted a critical deterioration of the heavy metals content, driven by the catastrophic flood event, which has drastically altered their geochemical cycles, sedimentary pollution status and biochemical balance of the river's environment.

scholarly journals Human Health Risk Assessment of Heavy Metals in Onion Bulbs Cultivated in Katsina State, North West Nigeria

2020 ◽  
pp. 30-39
Author(s):  
A.I. Yaradua ◽  
A. J. Alhassan ◽  
A. Nasir ◽  
S. S. Matazu ◽  
A. Usman ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Cancer Risk ◽  
Health Risk ◽  
Health Risk Assessment ◽  
Human Health Risk ◽  
Hazard Index ◽  
The United States ◽  
Potential Health ◽  
North West

Vegetable fields in Katsina State are increasingly being loaded with heavy metals through various pollution sources such as agricultural activities mining and traffic. Onion bulb samples from the three senatorial zones that constitute to make up Katsina state in the North West of Nigeria were collected and the concentrations of seven heavy metals (Pb, Cd, Cr, Fe, Zn, Mn and Ni) in all the samples were determined by atomic absorption spectrometry. The health risk assessment methods developed by the United States Environmental Protection Agency (US EPA) were employed to explore the potential health hazards of heavy metals in the samples on the children and adult population. The highest mean concentration (mg/kg) was observed for Fe, followed by Pb, Zn and Mn. While Cd has the lowest concentration with the heavy metals Cr and Ni being below detection level (BDL). Overall hazard index (Hi) for the heavy metals were within the safety limit. The overall cancer risk to the adults based on pseudo-total metal concentrations exceeded the target value, mainly contributed by Pb.  Mn and Zn were the primary heavy metals posing non-cancer risks while Pb caused the greatest cancer risk. It was concluded that consumption of the onion samples from Katsina State may contribute to the population cancer burden.

scholarly journals Ecological and Health Risk Studies of Heavy Metals in Soils around an Abandoned Battery Factory in Ibadan, Southwestern Nigeria

2020 ◽  
Vol 1 (4) ◽  
Author(s):  
Romanus A. Obasi ◽  
Henry Y. Madukwe
Keyword(s):  
Heavy Metals ◽  
Health Risk ◽  
Enrichment Factor ◽  
Health Risks ◽  
Ecological Risk ◽  
Risk Index ◽  
Hazard Index ◽  
Contamination Factor ◽  
Southwestern Nigeria ◽  
High Enrichment

Heavy metals on the soil around an abandoned battery site at Wofun, Ibadan, Southwestern, Nigeria were studied for their ecological and health risks. Ten soil samples collected from the soil around the abandoned battery sites were analyzed using Inductively Coupled Plasma –Mass spectrometry (ICP-MS). The data were evaluated using indices such as contamination factor, enrichment factor, geo-accumulation index and pollution index to determine the ecological and health risks posed by the heavy metals. The results showed an average concentration of Pb (7274.4), V (190.63), Cu (77.52), Zn (53.08) and Co (53) in a decreasing order. The enrichment factor revealed high enrichment for Co (12.30) at site one (S1), and extreme enrichment of Pb (61.12). Zn, Rb and Mo showed no enrichment in the soil. All the sites exhibited extremely high enrichment of Pb except at S10 where the enrichment of Pb was only severe. The results of Igeo indicated that all the sites were strongly to extremely polluted by Pb while S6 is moderately polluted by Co. The rest of the metals do not constitute any pollution threats. An evaluation of the ecological risk index (RI) revealed that the mean Er for Co (13.95), Cu (8.61), and Zn (0.56) indicate low ecological risk as they are less than 40 (Er <40).  Lead (Pb) with Er value of 1818.60 has a very high ecological risk and accounts for most of the ecological risks in the study area. Lead (Pb) being the most toxic and abundant of all the heavy metals analyzed in the study areas was used to evaluate the potential  non-carcinogenic health risk for both children and adults. The hazard index which is the sum of the hazard quotients for children is 26.64 suggesting that non-carcinogenic health risk may occur if there is any form of exposure to the soil. The hazard index for the adult (2.87) indicated a significant potential non-carcinogenic health risk in the study area.

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