scholarly journals Preparation Of Melt Spun Electroconductive Fine Fibres Containing Carbon Nanotubes

2015 ◽  
Vol 15 (2) ◽  
pp. 87-92 ◽  
Author(s):  
Mohammad Mirjalili ◽  
Loghman Karimi

AbstractPreparation of electroconductive fine fibres containing carbon nanotubes (CNTs) by melt spinning was the main goal of the present study. In this regard, the influence of the main operating parameters such as type of polymer used (polyester, polypropylene and polyamide), type and concentration of the CNTs on conductivity, and mechanical and thermal properties of the melt spun fibres was studied. The conductivity of melt spun fibres was measured based on the method developed by Morton and Hearl. The morphologies of the CNTs–polymer composite fibres were studied by scanning electron microscopy. Thermal behaviours and mechanical properties of the CNTs–polymer composite fibres were investigated using differential scanning calorimetry and tearing tester, respectively. The results reveal that using CNTs had tangible effect on electrical, thermal and mechanical properties of the melt spun fibres. Also, polyamide had a better dispersion of CNTs and correspondingly lower surface resistivity.

Holzforschung ◽  
2015 ◽  
Vol 69 (2) ◽  
pp. 199-205 ◽  
Author(s):  
Anuj Kumar ◽  
Arun Gupta ◽  
Korada Viswanathan Sharma

AbstractThe effect of multiwalled carbon nanotubes (MWCNT) as reinforcement on the properties of urea-formaldehyde (UF) resin and medium-density fiberboards was investigated. MWCNT was added to UF in two concentrations, and the effects were studied by means of differential scanning calorimetry and dynamic mechanical thermal analysis in terms of the curing and viscoelastic properties of the resins. In the presence of MWCNT, the activation energy of the resins was lowered, and their storage modulus and thermal conductivity were enhanced. The formaldehyde emission decreased and mechanical properties increased after addition of MWCNT to UF resin.


2007 ◽  
Vol 539-543 ◽  
pp. 1926-1931 ◽  
Author(s):  
T.H. Hung ◽  
Y.C. Chang ◽  
H.M. Chen ◽  
Y.L. Tsai ◽  
J.C. Huang ◽  
...  

The thermal and mechanical characteristics of various Mg-Cu(Ni)-Y(Gd) metallic glassy alloys prepared by melt spinning are examined using differential scanning calorimetry (DSC), thermomechanical analyzer (TMA), and instrumental nanoindenter. The replacement of Y by Gd appears to benefit both the thermal and mechanical properties, while the replacement of Cu by Ni improves only the hardness and modulus, with the sacrifice of thermal characteristics. The amorphous Mg-Cu-Gd based alloys can be fabricated into rods with a diameter greater than 6 mm, with minimum porosity and reasonable toughness.


2016 ◽  
Vol 7 (6) ◽  
pp. 762-772 ◽  
Author(s):  
Stavros C. Anagnou ◽  
Eleni G. Milioni ◽  
Costas S. Mpalias ◽  
Ioannis A. Kartsonakis ◽  
Elias P. Koumoulos ◽  
...  

Purpose The purpose of this paper is to focus on the investigation of mechanical and thermal properties of lignin/poly (ethylene oxide) (PEO) blends, intended to be used as carbon fiber precursor. Design/methodology/approach Softwood kraft lignin was modified via esterification using phthalic anhydride and then blended with PEO. The final lignin/PEO ratios blends were (w/w) 20/80, 50/50 and 80/20 for both unmodified and modified lignin. The structural, thermal and mechanical properties of the blends were investigated by Fourier transform infrared, differential scanning calorimetry and tensile tests, respectively. Findings The results revealed that modified lignin/PEO blend (20/80) exhibited enhanced elongation. Originality/value The structural analysis as well as thermal and mechanical properties of the produced blends are clearly demonstrated.


2016 ◽  
Vol 61 (2) ◽  
pp. 1215-1219 ◽  
Author(s):  
T. Kozieł ◽  
J. Latuch ◽  
G. Cios ◽  
P. Bała

AbstractThe effect of oxygen content in zirconium on the structure and mechanical properties of the Cu46Zr42Al7Y5alloy, in the form of melt-spun ribbons and suction-cast rods, was investigated. Two types of Zr, rod and crystal bar of different nominal purities and oxygen contents, were used to synthesize the alloy by arc melting. Rapidly solidified ribbons were produced by melt spinning and their amorphous structures were confirmed by X-ray diffractometry (XRD) and differential scanning calorimetry (DSC). Bulk samples in the form of rods were cast using a special water-cooled suction casting unit attached to the arc melting system. XRD and DSC studies proved the amorphous structure of the bulk alloy synthesized from low-oxygen Zr and partial crystallization of the same alloy for high-oxygen Zr. In both bulk samples, uniformly distributed crystalline particles were identified as yttrium oxides. Higher mean compressive strength of amorphous alloy was observed. The hardness of amorphous phase was close to 500 HV1 in both bulk alloys, while the hardness of crystalline dendritic areas, observed in the alloy synthesized from high oxygen Zr, was lower by about 50 HV1.


2021 ◽  
pp. 095400832199676
Author(s):  
Yuting Ouyang ◽  
Qiu Zhang ◽  
Xiukun Liu ◽  
Ruan Hong ◽  
Xu Xu ◽  
...  

Different ionic liquid modified graphene nanosheets (IG) were induced into polyimide (PI) to improve the tribological, thermal, and mechanical properties of shape memory IG/PI composites. The results demonstrated that when using 1-aminoethyl-3-methylimidazole bromide to modify graphene nanosheets (IG-1), the laser-driven shape recovery rate of IG-1/PI composites (IGPI-1) reached 73.02%, which was 49.36% higher than that of pure PI. In addition, the IGPI-1 composite materials reached the maximum shape recovery rate within 15 s. Additionally, under dry sliding, the addition of IG can significantly improve the tribological properties of composite materials. IGPI-1 exhibited the best self-lubricating properties. Compared with pure PI, the friction coefficient (0.19) and wear rate (2.62 × 10–5) mm3/Nm) were reduced by 44.1% and 24.2%, respectively, and the T10% of IGPI-1 increased by 32.2°C. The Tg of IGPI-1 reached 256.5°C, which was 8.4°C higher than that of pure PI. In addition, the tensile strength and modulus of IGPI-1 reached 82.3 MPa and 1.18 GPa, which were significantly increased by 33.6% and 29.8%, respectively, compared with pure PI. We hope that this work will be helpful for the preparation of shape memory materials with excellent tribological, thermal, and mechanical properties.


2007 ◽  
Vol 49 (6) ◽  
pp. 702-707 ◽  
Author(s):  
A. V. Okotrub ◽  
N. F. Yudanov ◽  
V. M. Aleksashin ◽  
L. G. Bulusheva ◽  
O. A. Komarova ◽  
...  

2021 ◽  
Vol 891 ◽  
pp. 150-163
Author(s):  
Jorge Mauricio Fuentes ◽  
Omar Flor Unda ◽  
Santiago Ferrandiz ◽  
Franyelit Suarez

In this article presents evidence about performance of mechanical properties of polycarbonate and nylon materials, which are used in the additive manufacturing by deposition of molten material and that have been subjected to sterilization processes by moist heat at 121°C and dry heat at 140°C. This study provides useful information to consider the use of these materials in sanitary and sterile settings. Mechanical tests of tensile, flex, hardness, Izod impact, thermal tests in Differential Scanning Calorimetry DSC, Thermomechanical analysis TMA and Scanning Electron Microscopy SEM were performed. It is concluded that the mechanical and thermal properties have not been altered through the effect of temperature in sterilization processes.


2018 ◽  
Vol 33 (4) ◽  
pp. 435-450 ◽  
Author(s):  
Patrycja Bazan ◽  
Stanisław Kuciel ◽  
Mariola Sądej

The work has evaluated the possibility of the potential reinforcing of poly(oxymethylene) (POM) by basalt fibers (BFs) and influence of BFs addition on thermal properties. Two types of composites were produced by injection molding. There were 20 and 40 wt% long BFs content with an average length of 1 mm. The samples were made without using a compatibilizer. In the experimental part, the basic mechanical properties (tensile strength, modulus of elasticity, strain at break, flexural modulus, flexural strength, and deflection at 3.5% strain) of composites based on POM were determined. Tensile properties were also evaluated at three temperatures −20°C, 20°C, and 80°C. The density and Charpy impact of the produced composites were also examined. The influence of water absorption on mechanical properties was investigated. Thermal properties were conducted by the differential scanning calorimetry, thermal gravimetric analysis, and fourier transform infrared (FTIR)-attenuation total reflection (ATR) spectroscopy analysis. In order to make reference to the effects of reinforcement and determine the structure characteristics, scanning electron microscopy images were taken. The addition of 20 and 40 wt% by weight of fibers increases the strength and the stiffness of such composites by more than 30–70% in the range scale of temperature. Manufactured composites show higher thermal and dimensional stability in relation to neat POM.


2011 ◽  
Vol 6 (3) ◽  
pp. 155892501100600 ◽  
Author(s):  
Eric Devaux ◽  
Carole Aubry ◽  
Christine Campagne ◽  
Maryline Rochery

Polylactide (PLA) was mixed with 4 wt.% of carbon nanotubes (CNTs) to produce electrical conductive multifilament yarns by melt spinning process for humidity detection. Thanks to a variation of electrical conductivity, this flexible sensor could detect the moisture presence. The introduction of plasticizer was necessary to ensure higher fluidity and drawability of the blend during the spinning process. The plasticizer modifies the crystallinity and the mechanical properties of the yarns. The effectiveness of this sensor (PLA/4 wt.% CNTs fibres) sensitive to humidity, is optimal when the spinning conditions are adapted. In this way, the temperature and the rate of the drawing roll were reduced. The influence of these parameters on the crystallinity, the mechanical properties and the sensitivity of the yarns were studied. Once the appropriate spinning conditions found, one humidity sensitive yarn was processed and the repeatability and efficient reversibility of its sensitivity were highlighted.


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