scholarly journals Heavy Metals in Tobacco Smoke II: Trace Metals Cadmium, Lead, Copper, Cobaltand Nickel in Austrian Cigarettesand in Particle Phase and Smoke Gas - Schwermetalle in Tabaken und in Tabakrauch ll: Spurenelemente Cadmium, Blei, Kupfer, Kobalt und Nickel in oesterreichischen Zigaretten und deren Rauchkondensaten und Rauchgasen

Author(s):  
A Nitsch ◽  
K Kalcher ◽  
H Greschonig ◽  
R Pietsch

AbstractThe trace metals cadmium, lead, copper, cobalt and nickel have been analysed in 14 different Austrian filter cigarettes. The results show a good conformity thus allowing the calculation of a characteristic mean value. The same metals were analysed separately in the gas and particle phase. From this data and the results obtained from butt and ash analysis, the sidestream concentrations and the transfer rates for both fractions could be evaluated. A classification into light and heavy cigarettes on the basis of heavy metal contents could not be made due to the similarity of the results.

Author(s):  
Kouadio Kan Rodrigue ◽  
Biego Henri ◽  
Nyamien Yves ◽  
Konan Ysidor ◽  
Konan Constant ◽  
...  

Aims: The current study targets the achievement of a reliable process for the determination of heavy metal contents in kola nuts, namely cadmium, mercury, and lead, for better appreciation of the risks incurred from the consumption of such food products. Study Design: kola nuts collected from different stakeholders (planters, collectors, stores and centers) were analyzed after the validation of the proposed analytical method. Place and Duration of Study: Central Laboratory for Food Hygiene and Agro-Industry, LANADA in Abidjan, Côte d’Ivoire, running 2018. Methodology: Two references were used for the validation of the analytical method, namely the French standard NF V 03-110 and the European directive 2001/22/EC. The assays were achieved with an flame Atomic Absorption Spectrophotometer (AAS). The heavy metal contents of some samples collected from different sampling place were then determined Results: From the data, a significant regression chart was recorded for the heavy metals detection graphs, with significant correlation coefficients (R²˃ 0.99). The linearity domain was validated between 0.5 μg/L and 1.5 μg/L for cadmium, 15 μg/L and 45 μg/L for lead and from 10 μg/L to 100 μg/L for mercury. In addition, the LOD were 0.03 μg/L, 1.85 μg/L and 2.92 μg/L, while the LOQ were 0.07 μg/L, 6.52 μg/L and 3.32 μg/L for cadmium, lead and mercury, respectively. The relative standard deviations of the repeatability and reproducibility assays are below 4%, whereas standard additions of heavy metals are fully recovered, with percentages close to 100%. Contents of cadmium, lead and mercury in kola nuts are respectively valued at 22.97±9.01 μg/kg, 1065.57±613.76 μg/kg and 33.88±31.58 μg/kg from the farmers and 24.99±7.79 μg/kg, 296.51±98.18 μg/kg and 39.74±34.66 μg/kg from the storage centres. Conclusion: This analytical method could help in ensuring effective sanitary control at different critical points of kola nut distribution channel for promoting a good management of the toxicity concerns in such products.


2021 ◽  
pp. 38-47
Author(s):  
L. C. Okoro ◽  
M. O. Nwachukwu ◽  
S. G. I. Ikeh

This assessment of some heavy metal contents in different land used soils in Ohaji/Egbema, Imo State was conducted between June, 2019 and May, 2020. Three land used soils namely; the grass land, continuously cropped and forest land were studied. Soil profile representations were established in each of the physiographic units and soil samples collected from the pedogenetic horizons for the analysis of some heavy metals like Lead (Pb), Copper (Cu), Manganese (Mn), Zinc (Zn), and Iron (Fe). The heavy metals observed in this study were Cu, Mn, Zn and Fe while Pb was not detected in this study. The results of this study showed that the grass land, continuously cropped and forest land had no Pb detected. The heavy metal contents(Cu, Mn, Zn and Fe) detected decreases with depth from 0.15cm depth to 60-90 cm depth in grass land and continuously cropped and forested land respectively. The occurrence of Fe was high in forested land which ranges from 7.8-6.3Mg/Kg with mean value of 7.0Mg/Kg than continuous cropped land and grass land with lower values. The forest land had high sodium content with mean value of 0.74 and high electrical conductivity with a mean 4.91 dsm-1. The results showed low to moderate heavy metal load in forest land and high to moderate load of heavy metals in the grass land and continuously cropped land.


Author(s):  
Ngo The Cuong ◽  
Tran Hoan Quoc ◽  
Svetlana Vasilievna Zolotokopova

The article focuses on the study of change of containing heavy metals (zinc, copper, iron, cadmium, lead, arsenic) in the abiotic and biotic components of the Serepok river (Vietman) influenced by wastewater discharge from industrial areas. Heavy metal content was determined in the river water and bottom sediments in the four zones: above and within the boundaries of industrial regions Xoa Phu and Tam Thang and in two water reservoirs situated below the boundaries of those industrial areas. Tilapia Galilean ( Sarotherodon galilaeus ), Hemibagrus ( Hemibagrus ), and sazan ( Cyprinus carpio ) caught in these areas were the hydrobionts under study in which liver, gills, skeleton and muscles accumulation of heavy metals was detected. In the organs of fish caught in the river within industrial region, heavy metals concentration was 3-7 times higher. The greatest concentration of heavy metals was found in the liver and gills of fish caught in the boundaries of industrial regions, the least concentration was in the muscles. In most cases, significant correlation between heavy metal concentration in organs of fishes and in river water, bottom sediments has been revealed.


2019 ◽  
Author(s):  
Chem Int

A significant flux of heavy metals, among other toxins, reaches the lungs through smoking. This study reports Cd, Pb, Cu and Zn contents in tobacco of 11 brands of cigarette commonly sold in Ethiopia. The heavy metals were determined by atomic absorption spectrophotometry after wet digestion of cigarette tobacco using HNO3 and H2O2. The concentration of trace metals in the cigarettes ranged (mean) (μg/g), Cd: 1.3−7.6 (2.48±0.32), Pb: 0.50−12.50 (6.24±2.2), Cu: 2.89−25.35 (13.70±4.12) and Zn: 24.40−62.55 (36.22±7.50) while Ni was not detected in all the eleven brands of cigarettes. Comparable levels of trace metals were obtained in the tobacco of both imported and Ethiopian cigarettes. The average trace metal contents of cigarettes available in Ethiopia were Cd 1.82±0.39, Pb 4.23±0.97, Cu 10.2±3.1 and Zn 28.2±7.8 μg/cigarette and a person who smokes 20 cigarettes per day is estimated to increase his/her daily Cd, Pb, Cu and Zn retention by approximately 0.036, 0.085, 0.204, 0.564 mg/day, respectively. The results indicate that smoking and exposure to cigarette smoke is a serious problem to be taken into account when carrying out epidemiological studies on human exposure to trace metals.


Foods ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1310
Author(s):  
Matúš Várady ◽  
Sylwester Ślusarczyk ◽  
Jana Boržíkova ◽  
Katarína Hanková ◽  
Michaela Vieriková ◽  
...  

The aim of this study was to determine the effect of roasting on the contents of polyphenols (PPH), acrylamide (AA), and caffeine (CAF) and to analyze heavy metals in specialty coffee beans from Colombia (COL) and Nicaragua (NIC). Samples of NIC were naturally processed and COL was fermented anaerobically. Green beans from COL (COL-GR) and NIC (NIC-GR) were roasted at two levels, light roasting (COL-LIGHT and NIC-LIGHT) and darker roasting (COL-DARK and NIC-DARK), at final temperatures of 210 °C (10 min) and 215 °C (12 min), respectively. Quantitative analyses of PPH identified caffeoylquinic acids (CQA), feruloylquinic acids, and dicaffeoylquinic acids. Isomer 5-CQA was present at the highest levels and reached 60.8 and 57.7% in COL-GR and NIC-GR, 23.4 and 29.3% in COL-LIGHT and NIC-LIGHT, and 18 and 24.2% in COL-DARK and NIC-DARK, respectively, of the total PPH. The total PPH contents were highest in COL-GR (59.76 mg/g dry matter, DM). Roasting affected the contents of PPH, CAF, and AA (p < 0.001, p < 0.011 and p < 0.001, respectively). Nickel and cadmium contents were significantly higher in the COL-GR than in the NIC-GR beans. Darker roasting decreased AA content, but light roasting maintained similar amounts of CAF and total PPH.


2011 ◽  
Vol 138-139 ◽  
pp. 1149-1155 ◽  
Author(s):  
Yi Dong Guan ◽  
Ye Hong Du ◽  
Zhen Dong Li ◽  
An Cheng Luo

This paper reports the concentration of heavy metals (Cr, Cu, Zn, Cd and Pb) in the soils and rices surrounding the abandoned rural waste dumping sites in Ningbo. Igeo (geoaccumulation index) was calculated to assess the contamination degree of heavy metals in soils. The mean contents of Cr, Cu, Cd, Zn and Pb of soils were 33.3, 24.1, 1.5, 118.9 and 45.6 mg/(kg DW) (dry weight), respectively. All of them were much higher than that of the reference value (i.e. CK), but there were no coherent trend of the metal contents within 1-120m distance from the dumping site. Igeo of heavy metals reveals the order of Cd>Cu>Cr>Pb>Zn, and the contamination assessment of soils using Igeo indicate the moderate Cd pollution, while the soils were unpolluted-moderately overall by Cr, Cu, Zn as well as Pb. The heavy metal contents in root, stem & leaf and rice grains were all remarkable higher than that of the CK at 20-120 m distances, and the heavy metal contents in root were evidently much higher than other plant parts, while those in rice grain were lowest, indicating the great bioaccumulation trend of heavy metals. Although the metal contents in the rice grain were within the legislation limit, its bioaccumulation trend of heavy metals was remarkable, whose contents were 4.38-fold for Cr, 1.76-fold for Cu, 1.28-fold for Zn, 2.67-fold for Cd and 3.03-fold for Pb higher than that of reference value, respectively. Finally, we proposed a decentralized in-situ restoration approach for the dumping sites.


2022 ◽  
Vol 12 (2) ◽  
pp. 595
Author(s):  
Collin J. Weber ◽  
Jens Hahn ◽  
Christian Opp

Soils contain an increasing number of different pollutants, which are often released into the environment by human activity. Among the “new” potential pollutants are plastics and microplastics. “Recognized” pollutants such as heavy metals, of geogenic and anthropogenic origin, now meet purely anthropogenic contaminants such as plastic particles. Those can meet especially in floodplain landscapes and floodplain soils, because of their function as a temporary sink for sediments, nutrients, and pollutants. Based on a geospatial sampling approach, we analyzed the soil properties and heavy metal contents (ICP-MS) in soil material and macroplastic particles, and calculated total plastic concentrations (Ptot) from preliminary studies. Those data were used to investigate spatial connections between both groups of pollutants. Our results from the example of the Lahn river catchment show a low-to-moderate contamination of the floodplain soils with heavy metals and a wide distribution of plastic contents up to a depth of two meters. Furthermore, we were able to document heavy metal contents in macroplastic particles. Spatial and statistical correlations between both pollutants were found. Those correlations are mainly expressed by a comparable variability in concentrations across the catchment and in a common accumulation in topsoil and upper soil or sediment layers (0–50 cm). The results indicate comparable deposition conditions of both pollutants in the floodplain system.


Author(s):  
Özgür Canpolat ◽  
Ece Vanlı

Industries, as a source of pollution, have a considerable impact on aquatic ecosystems due to the diversity in the composition of their wastewater. In this study, it is aimed to determine the heavy metal pollution caused by the wastewater of milk products factory, paint factory and textile factory in the Organized Industrial Zone of Kahramanmaraş province. For this purpose, seasonal concentrations of some heavy metals (Fe, Cu, Zn, Cr, Ni, Cd, As and Hg) have been determined in wastewaters of milk products factory, paint factory and textile factory and in the region where these wastewaters discharge in the Erkenez Stream. The seasonal variation of heavy metals in all stations, generally the lowest concentrations of all elements were determined in winter and the highest concentrations were determined in summer. When the heavy metal contents of milk products factory, paint factory and textile factory wastewaters were compared, the highest values were found in textile factory wastewater. When all stations are taken into consideration, according to USEPA and water quality criteria, it is determined that the wastewaters of milk products factory, paint factory and textile factory and the area of the Erkenez Stream, where these wastewaters are discharged, were very dirty in term of heavy metals. When these results are taken into consideration, it is clear that the wastewater of these factories causes serious heavy metal pollution in the Erkenez Stream.


2005 ◽  
pp. 55-67 ◽  
Author(s):  
Ratko Kadovic ◽  
Olivera Kosanin ◽  
Snezana Belanovic ◽  
Milan Knezevic

During the last decades, forest ecosystems have been strongly exposed to the effect of different harmful pollutants, especially from the atmosphere. Harmful substances from the air, in addition to the direct effect on forest trees, also deposit in the soil, and have an adverse effect on soil chemistry and pedogenetic processes. The results of previous studies in Serbia (Kadovic, Knezevic, 2002, 2004) show some specificities regarding the accumulation and migration of heavy metals in the soil. The highest concentrations were found in the layers of forest litter and in the surface organo-mineral horizons. This paper presents the results of the study of heavy metal contents (Zn, Mn, Cu, Fe, Cd, Pb, Ni and Cr) in the organic horizon (forest litter) of beech forests in Serbia. The study of the heavy metal content in the organic horizon (forest litter) is very significant primarily in the aim of monitoring the trend of their migration through the soil profile and the effect on the soil properties and genesis. The soil quality in beech forests in Serbia was assessed within the Project ICP Forest, Level I, by the methodology UN/ECE-EC, 2000.


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