scholarly journals Morphology and thermal properties of polypropylene-montmorillonite nanocomposite using modified bentonite of Bener Meriah Aceh

2020 ◽  
Vol 20 (3) ◽  
pp. 56-60
Author(s):  
JULINAWATI JULINAWATI ◽  
BASUKI WIRJOSENTONO ◽  
EDDIYANTO EDDIYANTO ◽  
SAHARMAN GEA ◽  
ICHWANA RAMLI

Research on the use of modified bentonite from Bener Meriah Aceh to study the morphology and thermal properties of polypropylene-montmorillonite nanocomposite (PP-MMT) was carried out. Bentonite was isolated into nano-sized montmorillonite and modified with the addition of PP-g-MA as a compatibilizer and octadecylamine as a modifier of MMT. PP-MMT nanocomposite processing was carried out in an internal mixer at 180 oC with a time of 10 minutes, and a speed of 65 rpm. Based on the results of the TGA-DTA test, the modified bentonite from Bener Meriah Aceh with PP-g-MA and octadecylamine can improve the thermal properties of PP-MMT nanocomposite in a composition comparison of  PP; PP-g-MA; MMT is 85; 10; 5. The SEM test results also showed that exfoliation and intercalation had occurred of MMT at PP-MMT nanocomposite.

2013 ◽  
Vol 812 ◽  
pp. 125-130 ◽  
Author(s):  
Siti Norasmah Surip ◽  
Z.Y. Zhang ◽  
H.N. Dhakal ◽  
N.N. Bonnia ◽  
S. H. Ahmad

The effect of preparation technique on the crystallisation behavior and thermal properties of TPNR filled nanoclay nanocomposites was investigated. The nanocomposites were prepared via melt blending method using internal mixer (Haake 600P). Two types of nanocomposites preparation technique were employed which is method A and B. In method A, the nanoclay was pre-mixed with liquid natural rubber (LNR) before it was charged into the other materials. For method B, the nanoclay was directly charged into the molten TPNR matrix. The result shows, preparation methods were significantly affect the crystallinity and thermal properties of TPNR nanocomposites. DSC thermogram revealed that nanocomposites crystallinity was increased when prepared by method A but decreased with method B. An increment in polypropylene crystallinity was attributed by the nanoclay which is believed to be as a nucleating agent. DMA thermogram suggested that the preparation method has affected the storage modulus and tan δ but not the glass transition temperature (tg).


2012 ◽  
Vol 9 (3) ◽  
pp. 450-458
Author(s):  
Baghdad Science Journal

In this study , Iraqi Bentonite clay was used as a filler for polyvinyl chloride polymer. Bentonite clay was prepared as a powder for some certain particle size ,followed by calcinations process at (300,700,900) OC ,then milled and sieved. The selected sizes were D ~75 µm and D ~150. After that polyvinyl Al-Cohool solution prepared and used as a coated layer covered the Bentonite powder before applied as a filler ,followed by drying , milling and sieving for limited recommend sizes. polyvinyl chloride solutions were prepared and adding of modified Bentonite power at certain quantities were followed .Sheet of these variables on the mechanical and thermal properties of the prepared reinforced particular polyvinyl chloride composite Experimentally, it was found that the composite prepared by adding modified Iraqi Bentonite powder , that calcined at 700 oC as a filler have an advantage in heating insulator properties by 30 from that found for PVC as it is ,and the value of stress strength exceed by three times as that for original value.


Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1493 ◽  
Author(s):  
In-Hwan Yang ◽  
Jihun Park

The thermal conductivity of concrete is a key factor for efficient energy consumption in concrete buildings because thermal conductivity plays a significant role in heat transfer through concrete walls. This study investigated the effects of replacing fine aggregates with coal bottom ash (CBA) and the influence of curing age on the thermal properties of high-strength concrete with a compressive strength exceeding 60 MPa. The different CBA aggregate contents included 25%, 50%, 75%, and 100%, and different curing ages included 28 and 56 days. For concrete containing CBA fine aggregate, the thermal and mechanical properties, including the unit weight, thermal conductivity, compressive strength, and ultrasonic velocity, were measured. The experimental results reveal that the unit weight and thermal conductivity of the CBA concrete were highly dependent on the CBA content. The unit weight, thermal conductivity, and compressive strength of the concrete decreased as the CBA content increased. Relationships between the thermal conductivity and the unit weight, thermal conductivity and compressive strength of the CBA concrete were proposed in the form of exponential functions. The equations proposed in this study provided predictions that were in good agreement with the test results. In addition, the test results show that there was an approximately linear relationship between the thermal conductivity and ultrasonic velocity of the CBA concrete.


2013 ◽  
Vol 795 ◽  
pp. 433-437 ◽  
Author(s):  
S.T. Sam ◽  
N.Z. Noriman ◽  
S. Ragunathan ◽  
O.H. Lin ◽  
H. Ismail

Soya spent powder as an inexpensive and renewable source has been used as a filler for linear-low density polyethylene (LLDPE) in this study. Linear-low density polyethylene (LLDPE)/soya spent powder composites were prepared by using Haake internal mixer. The mixing time was 10 minutes at 150°C with rotor speed 50 rpm. Epoxidised natural rubber (ENR 50) has been used as a compatibilizer in the present study. The thermal properties of the LLDPE/soya spent powder composites with and without ENR were studied with a differential scanning calorimetry (DSC). The crystallinity of the LLDPE/soya spent powder composites decreased with increasing soya spent powder content. However, the addition of ENR 50 as a compatibilizer increased the crystallinity of the LLDPE/soya spent powder composites.


2021 ◽  
Vol 15 (1) ◽  
pp. 115-126
Author(s):  
Ghina Rizqa Raihanah ◽  
Junaidi Junaidi ◽  
Fadjryani Fadjryani

Stable and adaptive superior varieties play an important role in increasing plant productivity. The technological innovation was carried out by studying the yield GEI. However, if only paying attention to yield GEI would not be enough in selecting stable and adaptive varieties, so this research used a combination of AMMI and SEM methods. Through the SEM-AMMI, GEI modeling was carried out by taking into account the physiological processes of growth and genotype development which explained the relationship between yield GEI components and how it affected yield GEI. The results of the AMMI biplot showed that genotypes were adaptable and relatively stable were planted in five planting locations, namely Biru Lancor and Tinombo. SEM test results showed that the yield component has an effect on production yield, where the tuber weight above the average will give relatively more onion yields and genotypes planted in relatively low locations, soil pH above 6 and dusty clay soil conditions will produce relatively more red onions and quality.


2011 ◽  
Vol 117-119 ◽  
pp. 1014-1017
Author(s):  
How Ji Chen ◽  
Ming Der Yang ◽  
Wen Po Tsai ◽  
Yung Hsuan Chang

In recent years, the reservoir sediments have been a disturbance to Taiwan government, and are getting worse due to the climate change. Consequently, it becomes an urgent issue for the authority to dredge and dispose reservoir sludge effectively. Material researchers in civil engineering and environmental engineering, cooperating with microbiologists and geochemists, have recently attempted the solidification of sludge granules into sandstone-like materials employing microorganisms. The aim of this study is to investigate the approach to solidify sludge or soil particle rapidly to attain strength through the growth of bacteria and apply the technique in practical. In this research, we used Bacillus pasteurii in the solidification of reservoir sludge. The sludge used in the experiment has a moisture content of 40%. The change of bacteria broth culture concentration (0%, 25%, 50%, 75%, and 100%) and CaCl2 ratio in the culturing Urea-CaCl2 medium (10%, 30% and 70%) were used as the experimental variables. The culture broth was mixed directly with reservoir sludge to form a cubic specimen (50 mm x 50 mm x 50 mm), which was then used in compressive strength, XRD and SEM test. The test results showed that being cultured in 70%-CaCl2 medium, the specimen blended with 100% bacteria broth had the highest compressive strength. Compared with the blank samples (0% bacteria broth), the compressive strength was enhanced by approximately 13.48%. Also, it was suggested that the solidification by bacteria can indeed enhance the compressive strength of the cube. The sludge solidified with bacteria cultured in 70%-CaCl2 medium has the highest compressive strength. The result also showed that the higher the content of CaCl2 used in the culturing medium is, the more CaCO3 deposit is induced by the bacteria.


2021 ◽  
Vol 109 (1) ◽  
pp. 101
Author(s):  
Fadhila Mouissa ◽  
Azzedine Benyahia ◽  
Mokhtar Djehiche ◽  
Kamel Belmokre ◽  
Nadir Deghfel ◽  
...  

This study investigates the effect of the chemical treatment of sawdust on the mechanical and thermal properties of a clay composite reinforced with sawdust in variable mass proportions: 0.5, 1, 1.5, 2 and 2.5%, intended for use as brick in rural houses in desert areas. The sawdust was chemically treated with 5 wt% NaOH and 0.01 wt% KMnO4 solutions. The mechanical test results of the reinforced composite with alkali-treated sawdust show an increase in flexural and compression strength, reaching a maximum value of 0.89 and 4.85 MPa, respectively. However, the thermal test results show a significant decrease in the thermal conductivity of the sawdust-reinforced composite. The best result recorded is that of untreated sawdust, which has a value of 0.37 (W.m−1.K−1) compared to the one reinforced with treated sawdust.


2015 ◽  
Vol 10 (2) ◽  
pp. 155892501501000 ◽  
Author(s):  
Xuechuan Wang ◽  
Xiaoqin Wang ◽  
Taotao Qiang ◽  
Longfang Ren ◽  
Peiyi Wang

Modified by the pretreated model with collagen under the crosslinking effect of glutaraldehyde, the moisture absorption of modified samples increased by 26.34% and 42.6%. The test results of SEM, AFM and DSC show that there was coating on the fibers modified with collagen, and the relative average roughness of the modified fabric decreased. Modification with collagen also affected the thermal properties of the modified sample compared with that of the non-treated sample. Modification of the base with collagen in the same way that modified the model, the result indicate that the contents of amino group on the modified base sample were 1.61 times and 8.15 times compared with that of pretreated sample and non-treated sample, water vapor permeability of collagen modified samples increased by 28.58% and 53.43% respectively.


2015 ◽  
Vol 815 ◽  
pp. 9-13
Author(s):  
P. Santhiya ◽  
S.T. Sam ◽  
H. Kamarudin ◽  
S. Ragunathan ◽  
N.Z. Noriman ◽  
...  

The effects of adding hexanedioic acid (HA) into low density polyethylene (LDPE)/jackfruit seeds (JSF) blends on the properties were investigated by using differential scanning calorimetry (DSC). The influence of the crystallinity and thermal properties of HA on LDPE at various compositions was investigated. JSF was blended with LDPE by using internal mixer (Brabender) at temperature 150°C. JSF content was varied from 0 to 20 wt%. Crystallinity of the blends was significantly reduced with increasing JSF content and further increased with the presence of HA. Therefore, the crystallinity of the blends was improved with the presence of HA.


2011 ◽  
Vol 117-119 ◽  
pp. 773-776 ◽  
Author(s):  
Wang Ren ◽  
Ying Zhang ◽  
Min Jiao Li

The electrodeposition of cobalt nanoparticles from mixture of 1-butyl-3- methylimidazolium chloride (BMIC) ionic liquid and urea was investigated. The results from the cyclic voltammetry (CV) show that the reduction of Co(II) to cobalt is an irreversible process and controlled by the diffusion of Co(II) on Pt working electrode. The cobalt nanoparticles prepared by direct current (DC) electrodeposition method at 70 °C were characterized by scanning electron microscope (SEM). Test results indicate that the Co nanoparticles are grain-like arrays and link together because of their magnetic property. The average length of these particles is about 100 nm.


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