scholarly journals Mechanical properties and X-ray diffraction analyses of clay/sand pellets for CO2 adsorption: the effects of sand content and humidity

Author(s):  
Isaac Iglesias ◽  
Mayra Jiménez ◽  
Andrea M. Gallardo ◽  
Edward E. Ávila ◽  
Vivian Morera ◽  
...  

In this work, we report the mechanical properties of an alternative material based on a mixture of natural clay and ferruginous sand in pellet form for CO2 capture. These raw materials were collected from Ecuador, and they contain iron and titanium oxides from volcanic origin. To evaluate the effect of the sand content on the mechanical properties of pellets, the samples were manually prepared with 0 (control sample), 15, and 25 wt.% sand contents and analyzed using free-fall drop impact and uniaxial compression tests. The uniaxial compression test was carried out under three conditions: using sieved sand, using sand without sieving, and under wet conditions. The sand contents caused the drop number to decrease in the free-fall drop impact test. From the uniaxial compression test, the compressive strength, elastic modulus, and toughness were calculated. The elastic modulus showed a better performance for samples with lower porosity. The compressive strength demonstrated higher values for samples with 15 wt.% sand contents than for samples with the other sand contents. The toughness values did not significantly change. It was evidenced that the porosity, mineral composition, and humidity exerted an influence during the mechanical tests. The mineral phases were analyzed by X-ray diffraction, and quantitative analysis based on whole-powder-pattern fitting revealed that the iron and titanium oxide contents increased as the concentration of sand in the pellets increased.

2012 ◽  
Vol 594-597 ◽  
pp. 816-819
Author(s):  
Zhi Hao Liu ◽  
Chuan Xiao Liu ◽  
Dong Chen Huang ◽  
Long Wang

Through the uniaxial compression test, the mechanical properties of different placements of iron wire cement mortar, e.g. compressive strength and elastic modulus, were studied, and the mass ratios of cement, sands and water influencing the mechanical properties were put forward, which provided the experimental results for reference for the wide use of the iron wire cement mortar material. From the study it is gained that: (1) The best placement of the iron wires in cement mortar is horizontal. (2) The best mass ratio of the cement, sands and water is 1:4.70:0.81.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-9
Author(s):  
Man Lei ◽  
Fa-ning Dang ◽  
Haibin Xue ◽  
Mingming He

In order to study the mechanical properties of granite at the micro- and nanoscale, the load-displacement curve, residual indentation information, and component information of the quartz, feldspar, and mica in granite were obtained using a nanoindentation test, a scanning electron microscope (SEM), and X-ray diffraction (XRD). The elastic modulus and the hardness of each component of the granite were obtained through statistical analysis. Treating rock as a composite material, the relation between the macro- and microscopic mechanical properties of rock was established through the theory of micromechanical homogenization. The transition from micromechanical parameters to macromechanical parameters was realized. The equivalent elastic modulus and Poisson’s ratio of the granite were obtained by the Self-consistent method, the Dilute method, and the Mori-Tanaka method. Compared with the elastic modulus and the Poisson ratio of granites measured by a uniaxial compression test and the available data, the applicability of the three methods were analyzed. The results show that the elastic modulus and hardness of the quartz in the granite is the largest, the feldspar is the second, the mica is the smallest. The main mineral contents in granite were analyzed using the semiquantitative method by XRD and the rock slice identification test. The elastic modulus and the Poisson ratio of granite calculated by three linear homogenization methods are consistent with those of the uniaxial compression test. After comparing the calculation results of the three methods, it is found that the Mori-Tanaka method is more suitable for studying the mechanical properties of rock materials. This method has an important theoretical significance and practical value for studying the quantitative relationship between macro- and micromechanical indexes of brittle materials. The research results provide a new method and an important reference for studying the macro-, micro-, and nanomechanical properties of rock.


Author(s):  
Muhammad Armaghan Siffat ◽  
Muhammad Ishfaq ◽  
Afaq Ahmad ◽  
Khalil Ur Rehman ◽  
Fawad Ahmad

This study is supervised to assess the characteristics of the locally available wheat straw ash (WSA) to consume as a substitute to the cement and support in enhancing the mechanical properties of concrete. Initially, after incineration at optimum temperature of 800°C for 0.5, the ash of wheat straw was made up to the desirable level of fineness by passing through it to the several grinding cycles. Subsequently, the X-ray fluorescence (XRF) along with X-ray diffraction (XRD) testing conducted on ash of wheat straw for the evaluation its pozzolanic potential. Finally, the specimens of concrete were made by consuming 10% and 20% percentages of wheat straw ash as a replacement in concrete to conclude its impact on the compressive strength of high strength concrete. The cylinders of steel of dimensions 10cm diameter x 20cm depth were acquired to evaluate the compressive strength of high strength concrete. The relative outcomes of cylinders made of wheat straw ash substitution presented the slight increase in strength values of the concrete. Ultimately, the C-100 blends and WSA aided cement blends were inspected for the rheology of WSA through FTIR spectroscopy along with Thermogravimetric technique. The conclusions authenticate the WSA potential to replace cement in the manufacturing of the high strength concrete.


2017 ◽  
Vol 12 (1) ◽  
pp. 63-77 ◽  
Author(s):  
Siriporn Sirikingkaew ◽  
Nuta Supakata

This study presents the development of geopolymer bricks synthetized from industrial waste, including fly ash mixed with concrete residue containing aluminosilicate compound. The above two ingredients are mixed according to five ratios: 100:0, 95:5, 90:10, 85:15, and 80:20. The mixture's physico-mechanical properties, in terms of water absorption and the compressive strength of the geopolymer bricks, are investigated according to the TIS 168-2546 standard. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses are used to investigate the microstructure and the elemental and phase composition of the brick specimens. The results indicate that the combination of fly ash and concrete residue represents a suitable approach to brick production, as required by the TIS 168–2546 standard.


2021 ◽  
Vol 10 (2) ◽  
pp. 129-138
Author(s):  
. Fatma ◽  
. Desnelli ◽  
Fahma Riyanti ◽  
Mustafa Kamal ◽  
Muhammad Ramdan Abdul Mannan ◽  
...  

Eggshell is a solid waste that is available in abundance but is being left unused. Eggshell containing calcium in a high amount. Calcium can be used as a precursor for hydroxyapatite (HAp). Modification of HAp with SiO2 is expected to improve its low mechanical properties for biomedical applications. In this study, HAp is synthesized from the eggshell. Then, it was modified by adding SiO2 utilizing the coprecipitation method with concentrations of 10%, 20%, 30%, and 40%, respectively. The HAp and HAp/SiO2 were characterized using; X-ray diffraction and Fourier transform infrared spectroscopy. The analysis HAp and HAp/SiO2 were density, compressive strength, and hardness. The best mechanical properties of HAp/SiO2 were characterized using SEM-EDS. The HAp were prepared successfully with a ratio of Ca/P was 1.673, close to the theoretical 1.67. The addition of SiO2 caused a decrease in crystallite size and density but increased compressive strength and hardness. The best mechanical properties of HAp/SiO2 were obtained with SiO2 of 30% and 40% with similar values.


2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Xin Liu ◽  
Yu-Zhou Zheng ◽  
Qin Fang ◽  
Heng-Bo Xiang ◽  
Hai-Chun Yan

To explore the influence of microexpansive concrete self-stress on the performance of steel pipe concrete, the expansion rate test of microexpansive concrete confined by steel tube was carried out with different expansion rates. Then, the mechanical properties of high-strength steel tube-confined microexpansive concrete (HSTCMC) short columns were conducted by the uniaxial compression test. The length-to-diameter ratio, the expansion rate of the microexpansive concrete, and the steel tube thickness were investigated in the study. Furthermore, the ABAQUS software was employed to analyze the microexpansive mechanism of the concrete, and it was verified by the uniaxial compression test. The test results show that the concrete possesses a remarkable volume expansion phenomenon, which was up to 150 με after four days of maintenance time. The mechanical properties of the HSTCMC short columns were greatly improved compared to the control RC pier. The yield and ultimate strength of the HSTCMC short columns can be enhanced to 8.9% and 14.6%, and with the content of expansive agent that increased from 8% to 12%. The finite element analysis results highlighted that the end constraint at the two ends has the biggest influence on the mechanical performance of the HSTCMC short columns, followed by the thickness of the steel tube and the content of the expansive agent. It should be noted that the self-stress of microexpansive concrete will be decreased with the increase in the length-to-diameter ratio, when the length-to-diameter ratio is less than four. Furthermore, the constraint effect of the circular steel tube on the microexpansive concrete is better than that of the rectangular section steel tube.


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