scholarly journals Equilibrium of ion exchange of calcium, magnesium and potassium for proton on fibrous carboxylic ion exchanger

2021 ◽  
Vol 57 (2) ◽  
pp. 135-143
Author(s):  
V. S. Soldatov ◽  
N. V. Vonsovich ◽  
T. A. Korshunova
Keyword(s):  
Ion Exchange ◽  
Ion Exchanger ◽  
Hydrogen Ion ◽  
Ionic Form ◽  
Potassium Ions ◽  
Titration Curves ◽  
Wide Range ◽  
Calcium Magnesium ◽  
Calcium And Magnesium ◽  
Low Solubility

By the method of potentiometric titration of a fibrous aminocarboxylic polyampholyte with a predominant content of carboxyl groups, the equilibrium of the cation exchange of calcium, magnesium, and potassium ions for a hydrogen ion was studied. Due to the low solubility of calcium and magnesium hydroxides in these cases, titration was carried out by Ca(OH)2 and Mg(OH)2, which are formed in solution upon contact with the H-form of the ion exchanger оf increasing portions of solid CaO and MgO. This made it possible to obtain titration curves in a wide range of pH and calcium and magnesium chlorides concentration (0–0.1 eq./L). The dependences of the swelling of ion exchangers on the neutralization degree with the bases of the studied cations are obtained. The coefficients of ion-exchange equilibria are calculated. It was found that the swelling of the ion exchanger is relatively little dependent on its ionic form. The ion exchanger has a higher affinity for calcium than magnesium ion.

scholarly journals CHANGE IN THERMODYNAMIC CHARACTERISTICS OF HYDRATION OF CARBOXYL FIBER SORBENT IN EXCHANGE OF MAGNESIUM AND CALCIUM CATION

2020 ◽  
Vol 63 (4) ◽  
pp. 42-48
Author(s):  
Yuriy S. Peregudov ◽  
Sabukhi I. Niftaliev ◽  
Anna V. Timkova ◽  
Larisa P. Bondareva ◽  
Aleksey V. Astapov
Keyword(s):  
Ion Exchange ◽  
Gibbs Energy ◽  
Phase Transfer ◽  
Thermodynamic Characteristics ◽  
Ion Exchanger ◽  
Isopiestic Method ◽  
Ionic Form ◽  
Magnesium Ions ◽  
Calcium And Magnesium ◽  
Sodium Form

The relationship between the characteristics of hydration and the selectivity of the fibrous carboxyl sorbent is established. Using the isopiestic method and thermal analysis, the hydration of the carboxyl fiber ion exchanger VION KN-1 in sodium, calcium and magnesium forms was studied. The quantity of absorbed water was determined, including the ratio of kinetically unequal water in the sorbent phase. The amount of water absorbed form of magnesium ion exchanger is greater than calcium, the molar proportion of water distribution varying in the degree of hydration of the magnesium and calcium forms fibers substantially equally. The changes in Gibbs energy of hydration and enthalpy of dehydration of ion-exchange fiber are calculated. The increase in Gibbs energy is due to the absorption of near- hydration water, and water farthest hydration is adsorbed at a constant value of the energy. Its highest values are determined for the magnesium form of the sorbent, and the least-for calcium, which corresponds to the ratio of the absorbed solvent of both forms in the first step of hydration. The exchange isotherms of calcium and magnesium ions on the sodium form of VION KN-1 fiber were obtained. The Gibbs energy of solvent interface transfer was calculated, which represents the difference between the Gibbs energies of ion exchange sorption and the direct exchange of cations, and describes the contribution of the change in sorbent hydration during the transition from one ionic form to another. It is found that the selectivity of extractable fiber ion exchanger to metal cations depending on the change in the sorbent during the hydration of ion exchange, which is energetically favorable process and promotes ion-exchange sorption. Carboxyl cation exchanger is more selective for magnesium ions than calcium ions, as confirmed by phase transfer energy high values solvent and less water released during the transition from the sodium form to the magnesium than during the transition to the calcium.

Maize Stalk as Natural Ion Exchanger for Hazardous Pollutants

2017 ◽  
Vol 68 (8) ◽  
pp. 1726-1731
Author(s):  
Nicoleta Mirela Marin ◽  
Luoana Florentina Pascu ◽  
Ioana Stanculescu ◽  
Ovidiu Iordache ◽  
Denisa Jianu ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Kinetic Models ◽  
High Selectivity ◽  
Ion Exchanger ◽  
Exchange Equilibrium ◽  
Waste Waters ◽  
Cationic Species ◽  
Hazardous Pollutants ◽  
Tailing Ponds

This paper recommends maize stalk as a cheap natural ion exchanger. Ion exchange equilibrium was studied using thermodynamic and kinetic models. The results showed a high selectivity towards cationic species of antimony (III), molybdenum (VI), lead (II) and arsenium (III). Waste waters and sediments from tailing ponds samples were analysed.

SERUM BIOCHEMICAL CHANGES IN KETOTIC BUFFALOES ( BUBALUS BUBALIS)

2016 ◽  
Vol 12 (1) ◽  
Author(s):  
Usha Choudhary ◽  
Meenaxi Sareen ◽  
Anil Moolchandani
Keyword(s):  
Serum Calcium ◽  
Bubalus Bubalis ◽  
Biochemical Changes ◽  
Blood Analysis ◽  
Serum Phosphorus ◽  
Serum Minerals ◽  
Calcium Magnesium ◽  
Serum Biochemical ◽  
Calcium And Magnesium

The present study was carried out to evaluate the variations in serum minerals ( viz. calcium, magnesium and phosphorus) and transaminases in ketotic buffaloes. Results of blood analysis revealed a significant (P<0.05) reduction in serum phosphorus in ketotic buffaloes whereas nonsignificant (P>0.05) difference occur in serum calcium and magnesium in ketotic buffaloes as compared to control. At the same time significant increase in transaminases GPT, GOT and GGT have been observed .

scholarly journals Towards a Glass New World: The Role of Ion-Exchange in Modern Technology

2021 ◽  
Vol 11 (10) ◽  
pp. 4610
Author(s):  
Simone Berneschi ◽  
Giancarlo C. Righini ◽  
Stefano Pelli
Keyword(s):  
Ion Exchange ◽  
Communication Networks ◽  
High Speed ◽  
High Performance ◽  
Low Cost ◽  
Modern Technology ◽  
Historical Background ◽  
Wide Range ◽  
Happy Marriage

Glasses, in their different forms and compositions, have special properties that are not found in other materials. The combination of transparency and hardness at room temperature, combined with a suitable mechanical strength and excellent chemical durability, makes this material indispensable for many applications in different technological fields (as, for instance, the optical fibres which constitute the physical carrier for high-speed communication networks as well as the transducer for a wide range of high-performance sensors). For its part, ion-exchange from molten salts is a well-established, low-cost technology capable of modifying the chemical-physical properties of glass. The synergy between ion-exchange and glass has always been a happy marriage, from its ancient historical background for the realisation of wonderful artefacts, to the discovery of novel and fascinating solutions for modern technology (e.g., integrated optics). Getting inspiration from some hot topics related to the application context of this technique, the goal of this critical review is to show how ion-exchange in glass, far from being an obsolete process, can still have an important impact in everyday life, both at a merely commercial level as well as at that of frontier research.

The Nutritive Value of Marine Products: XIII. Mineral Constituents of the Flesh, Skin, Bone and Free Liquor in Canned British Columbia Coho (Blueback) Salmon

1936 ◽  
Vol 2 (5) ◽  
pp. 473-475
Author(s):  
W. A. Riddell
Keyword(s):  
British Columbia ◽  
Nutritive Value ◽  
Calcium Orthophosphate ◽  
Marine Products ◽  
Calcium Magnesium ◽  
Calcium And Magnesium ◽  
Mineral Constituents

Determinations of the Ca, Mg, Na, K, P and Cl content were made and the ratios of calcium, magnesium and phosphorus oxides suggest the presence of calcium and magnesium metaphosphates in the ash of the flesh, calcium metaphosphate in that from the skin and tribasic calcium orthophosphate in that from the bone.

PREPARATION AND HEAT DENATURATION OF THE GLUTEN PROTEINS

1931 ◽  
Vol 5 (4) ◽  
pp. 389-406 ◽  
Author(s):  
W. H. Cook
Keyword(s):  
Elevated Temperatures ◽  
Marked Decrease ◽  
Hydrogen Ion ◽  
Ion Concentration ◽  
Heat Denaturation ◽  
Hydrogen Ion Concentration ◽  
Gluten Proteins ◽  
Buffer Solutions ◽  
Natural Moisture Content ◽  
Low Solubility

Gliadin prepared by several different methods had the same nitrogen content and distribution. The critical peptization temperature (C.P.T.) in 60% alcohol and viscosity in 30% urea-buffer solutions, however, showed considerable variation, preparations of high C.P.T. (low solubility) being more viscous. This variation in the physical properties is explained by fractionation or denaturation incidental to the method of preparation.Gluten precipitated from 30% urea solutions at salt concentrations varying from 0.1 to 0.5 of saturation, yielded fractions that varied continuously in their gliadin and glutenin content, as judged from their percentage of arginine nitrogen.Gluten dispersed in buffered 30% urea solutions showed no change in viscosity during 101 hr. after the gluten was completely dispersed. A variation of hydrogen ion concentration between pH 6.0 and 6.95 had little effect on its viscosity. Heating at 70 °C. caused a marked decrease in the viscosity of this dispersion during the first hour. When gliadin dispersions are heated as above only samples having a high initial viscosity and C.P.T. become less viscous. Heating gliadin of natural moisture content (12 to 14%) at 70 °C. for varying periods of time did not change significantly its subsequent C.P.T. and viscosity in 60% alcohol. More severe heat treatments at higher moisture contents rendered the gliadin insoluble in 60% alcohol. Dilute alcoholic extracts of heated flours contained less protein than those of unheated controls. However, the C.P.T. of the former was lower than that of the latter. It is concluded from these experiments that when the gluten proteins are subjected to elevated temperatures, the glutenin fraction is first affected, next the gliadin fractions of low solubility, and finally, under severe conditions, all of the gliadin is denatured.

scholarly journals Platelet sodium/hydrogen ion exchange in normal pregnancy and non-proteinuric pre-eclampsia

1997 ◽  
Vol 11 (7) ◽  
pp. 453-458 ◽  
Author(s):  
D Graham ◽  
JCP Kingdom ◽  
J McDonald ◽  
DL Davies ◽  
CJ Kenyon
Keyword(s):  
Ion Exchange ◽  
Normal Pregnancy ◽  
Hydrogen Ion ◽  
Sodium Hydrogen

scholarly journals Nutritional factors in milk from Brazilian mothers delivering small for gestational age neonates

1993 ◽  
Vol 27 (6) ◽  
pp. 455-462 ◽  
Author(s):  
Anete S. Grumach ◽  
Solange E.I. Jerônimo ◽  
Marcia Hage ◽  
Magda M.S. Carneiro-Sampaio
Keyword(s):  
Breast Milk ◽  
Low Birthweight ◽  
Total Proteins ◽  
Sodium Potassium ◽  
Nutritional Factors ◽  
High Sodium ◽  
Milk Samples ◽  
Calcium Magnesium ◽  
Preterm Babies ◽  
Calcium And Magnesium

The composition of breast milk from brazilian mothers delivering low birthweight infants and its adequacy as a source of nutrients for this group has not yet been fully elucidated. A total of 209 milk samples from 66 women were analysed. The mothers were divided into three groups: G1, mothers delivering term babies of low birthweight (TSGA, n=16); G2, mothers delivering preterm babies of appropriate birthweight (PTAGA, n=20); G3, mothers delivering term babies of appropriate birthweight (TAGA, n=30). The following factors were analysed: osmolarity, total proteins and protein fractions, creamatocrit, sodium, potassium, calcium and magnesium. Milk samples were collected 48 h and 7, 15, 30 and 60 days after delivery. The groups did not differ significantly in terms of osmolarity, total proteins and fractions, creamatocrit, calcium, magnesium or potassium throughout the study period. Sodium levels were higher in all samples from mothers of TSGA infants and in samples from mothers of PTAGA infants on the 7th, 15th and 30th days than in milk from the TAGA group. The authors consider the needs of the low birthweight and TAGA infants and that these high sodium levels may be necessary for growth of low birthweight infants.

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