scholarly journals Mixing and Compaction Temperature of Nanosilica Composite Polymer Modified Asphalt

2020 ◽  
Vol 8 (2) ◽  
pp. 27-36
Author(s):  
Esraa J Al-mousawi ◽  
Rashaa H Al-Rubaee ◽  
Ammar A Shubber
Keyword(s):  
Surface Area ◽  
High Temperatures ◽  
Storage Stability ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Compaction Temperature ◽  
Modified Asphalt ◽  
Modified Binders ◽  
Polymer Modified Asphalt ◽  
Waste Polypropylene

Recently, polymer -nanocomposites were used to manufacture durable asphalt mixtures to replace the polymer modified binder, because of the remarkable properties and unique features of nanomaterials compared to conventional materials, such as their wide surface area and small dimensions, making it possible to be utilized as an additive for asphalt paving. Nanosilica particles (NS) are one of the latest minerals which likely integrate useful characteristics, such as huge surface area, good distributions, high absorption levels, high stability, and a high level of purity. Therefore, this paper is interested in studying the characteristics of nanocomposite-polymer modified asphalt. In laboratory work, a pure asphalt 60-70 penetration grade, has been modified separately with waste polypropylene polymer (WPP), and nanosillica composite polypropylene (NS/WPP) at different concentrations. As a result, two modified binders: waste polypropylene polymer- modified asphalt (WPP-MA), and nanosillica composite polypropylene modified asphalt (NSCPMA) were obtained. Traditional asphalt binder tests were performed for pure and modified binders such as penetration, ductility, flash and fire point test, softening point, and rotational viscosity. Also, storage stability test has been conducted to ensure the storage stability of binders at high temperatures. The results showed an improvement in physical properties and increase in mixing and compaction temperature due to the increase in stiffness of (NSCPMA). The results also indicated that the nanosillica composite polypropylene modified asphalt binders have good storage stability at high temperatures.

scholarly journals Characterization of thermal storage stability of waste plastic pyrolytic char modified asphalt binders with sulfur

PLoS ONE ◽  
2021 ◽  
Vol 16 (3) ◽  
pp. e0248465
Author(s):  
Abhinay Kumar ◽  
Rajan Choudhary ◽  
Ankush Kumar
Keyword(s):  
Storage Stability ◽  
Asphalt Binder ◽  
Principal Component ◽  
Thermal Storage ◽  
Asphalt Binders ◽  
Waste Plastic ◽  
Modified Asphalt ◽  
Modified Binders ◽  
Pyrolytic Char

Pyrolysis has gained a strong interest in recent times for sustainable treatment and recovery of energy-rich products from different wastes including plastic. Waste plastic pyrolytic char (PPC) generated as a carbonaceous by-product in the pyrolysis process, is gaining attention as an asphalt binder modifier. Adequate thermal storage stability is an essential requirement for a modified asphalt binder to ensure that the composite offers integrity and homogeneous properties during its storage, handling and transportation in the field. The objective of this study was to evaluate and characterize the thermal storage stability properties of PPC modified binders. PPC modified asphalt binders were fabricated and evaluated at multiple dosages of sulfur as a cross-linking agent. In addition to the conventionally used softening point difference (SPD), characterization of thermal storage stability was attempted using rheology-based separation indices (SIs) derived through temperature sweep, frequency sweep, and multiple stress creep and recovery (MSCR) tests. These rheological SIs were based on complex modulus (G*), Superpave rutting parameter (G*/sin δ), Shenoy rutting parameter (SRP), zero shear viscosity (ZSV), and MSCR Jnr (at three stress levels 0.1, 3.2 and 10 kPa). Two formulations of each rheology-based separation index were studied: (1) ratio, and (2) maximum-average difference formulations. The temperature and frequency dependencies of rheological SIs were also evaluated. Further, the Fourier transform infrared spectroscopy (FTIR) was used to characterize storage stability by comparing the chemical functionalities of the PPC modified binders. A 0.3% dosage of sulfur was found to produce the best results considering all SPD, rheology-based SIs and FTIR. Principal component analysis showed that the ratio and maximum-average formulations had similar contributions to the first principal component accounting for more than 99% of the variability.

scholarly journals Impact of Graphene Oxide on Zero Shear Viscosity, Fatigue Life and Low-Temperature Properties of Asphalt Binder

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3073
Author(s):  
Abbas Mukhtar Adnan ◽  
Chaofeng Lü ◽  
Xue Luo ◽  
Jinchang Wang
Keyword(s):  
Graphene Oxide ◽  
Fatigue Life ◽  
Low Temperature ◽  
Shear Viscosity ◽  
Storage Stability ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Test Results ◽  
Zero Shear Viscosity ◽  
Modified Asphalt

This study has investigated the impact of graphene oxide (GO) in enhancing the performance properties of an asphalt binder. The control asphalt binder (60/70 PEN) was blended with GO in contents of 0%, 0.5%, 1%, 1.5%, 2%, and 2.5%. The permanent deformation behavior of the modified asphalt binders was evaluated based on the zero shear viscosity (ZSV) parameter through a steady shear test approach. Superpave fatigue test and the linear amplitude sweep (LAS) method were used to evaluate the fatigue behavior of the binders. A bending beam rheometer (BBR) test was conducted to evaluate the low-temperature cracking behavior. Furthermore, the storage stability of the binders was investigated using a separation test. The results of the ZSV test showed that GO considerably enhanced the steady shear viscosity and ZSV value, showing a significant contribution of the GO to the deformation resistance; moreover, GO modification changed the asphalt binder’s behavior from Newtonian to shear-thinning flow. A notable improvement in fatigue life was observed with the addition of GO to the binder based on the LAS test results and Superpave fatigue parameter. The BBR test results revealed that compared to the control asphalt, the GO-modified binders showed lower creep stiffness (S) and higher creep rate (m-value), indicating increased cracking resistance at low temperatures. Finally, the GO-modified asphalt binders exhibited good storage stability under high temperatures.

scholarly journals High-Temperature Performance Evaluation of Asphaltenes-Modified Asphalt Binders

Molecules ◽  
2020 ◽  
Vol 25 (15) ◽  
pp. 3326
Author(s):  
Amirhossein Ghasemirad ◽  
Nura Bala ◽  
Leila Hashemian
Keyword(s):  
High Temperatures ◽  
High Performance ◽  
Asphalt Binder ◽  
Viscoelastic Behavior ◽  
Asphalt Binders ◽  
Performance Grade ◽  
Modified Binders ◽  
Linear Viscoelastic Behavior ◽  
Linear Viscoelastic ◽  
Gravity Driven

Asphalt binder comprises four main fractions—asphaltenes (A), saturates (S), aromatics (A), and resins (R)—referred to as “SARA”. Asphaltenes plays an important role in determining the linear viscoelastic behavior of asphalt binders. In this research, asphaltenes are added as a distinct modifier to improve the performance properties of asphalt binder. The modified binders are aged using a rolling thin film oven. A dynamic shear rheometer is then used to measure the rheological properties of the binders at high temperatures. Changes in the chemical composition of the modified binders are also studied through the determination of SARA fractions, using precipitation and gravity-driven chromatography methods. The rheological results show that asphaltenes improve the stiffness and elasticity of asphalt binder. It is also shown that the addition of asphaltenes raises the high Performance grade (PG) temperature of the asphalt binder, with every 6% of asphaltenes added resulting in a one-interval increase in high PG temperature grade. SARA analysis shows that the increase in polar fraction content due to the addition of asphaltenes causes the stiffness, elasticity, and viscosity of asphalt binders to increase. The results indicate that asphaltenes are an effective yet inexpensive additive to improve asphalt binder properties at high temperatures.

Nonlinear Viscoelastic Response of Crumb Rubber Modified Asphalt Binder Under Large Strains

2020 ◽  
Vol 2674 (3) ◽  
pp. 139-149
Author(s):  
Saqib Gulzar ◽  
B. Shane Underwood
Keyword(s):  
Asphalt Binder ◽  
Crumb Rubber ◽  
Oscillatory Shear ◽  
Asphalt Binders ◽  
Large Strains ◽  
Viscoelastic Response ◽  
Modified Asphalt ◽  
Nonlinear Viscoelastic ◽  
Modified Asphalt Binder ◽  
Polymer Modified Asphalt

Agencies have been increasing their use of polymer modified asphalt binders in recent years to address performance issues and lengthen the useful life of their pavements. When deployed these materials likely experience strain levels exceeding their linear viscoelastic (LVE) limits. The same situation exists in non-polymer modified asphalt binders as well, but the effect may be more pronounced in polymer modified systems because of their bi-phasic nature. In this study, terminally blended crumb rubber (CR-TB) modified asphalt is studied to understand and quantify the nonlinear viscoelastic response under large strains. The CR-TB binders are extensively used in pavements subjected to high vehicular loads and extreme climatic conditions; thereby, their response under large strains becomes more critical. The current standard characterization techniques are based on LVE response using small amplitude oscillatory shear rheology only and do not consider the behavior of binders under large strains. In this study, large amplitude oscillatory shear (LAOS) rheology is used as a framework to more thoroughly investigate the complete response of the CR-TB modified asphalt binder under large strains at 30°C, 40°C, 50°C, and 60°C and at the frequencies of 0.5, 1, and 5 Hz. The LAOS response is analyzed using Fourier-transform rheology and the orthogonal stress decomposition method involving Chebyshev polynomial representation. It is found that nonlinearity manifests greatly in this study material as strain levels increase and frequencies decrease. The relative nonlinearity increases with increasing strain amplitude and is more significant towards lower end of the tested temperature range. The CR-TB binder shows strain-stiffening/softening and shear-thinning/thickening behavior depending upon a specific temperature, strain level, and frequency.

scholarly journals Mechanistic-empirical evaluation of specific polymer-modified asphalt binders effect on the rheological performance

2020 ◽  
Vol 103 (4) ◽  
pp. 003685042095987
Author(s):  
Ghazi G Al-Khateeb ◽  
Waleed Zeiada ◽  
Mohammed Ismail ◽  
Ahmad Shabib ◽  
Adel Tayara
Keyword(s):  
Rheological Properties ◽  
Laboratory Tests ◽  
Complex Modulus ◽  
Heavy Traffic ◽  
Asphalt Binder ◽  
Empirical Evaluation ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Pavement Structures ◽  
Polymer Modified Asphalt

Major distresses such as rutting, fatigue, and thermal cracking are facing asphalt pavement structures due to continuous heavy traffic loading and climate change. The modification of asphalt binders (one of the main components of the asphalt paving mix) has the potential to mitigate distresses through using different additives. Polymer modified asphalt (PMA) binders showed a noticeable resistance to pavement distresses as reported in previous studies. The present study aims to evaluate the effect of polymer modification on the rheological properties of asphalt binders through laboratory tests. The polymers included styrene-butadiene-styrene (SBS) and epolene emulsifiable (EE2) types. The 60/70 binder was used as a control for comparison. The Mechanistic-Empirical Pavement Design Guide (MEPDG) was also utilized to simulate the effect of PMA binders on the rheological properties under different climatic conditions and structural capacities. Additionally, the MEPDG was further utilized to compare the effect of asphalt binders on rheological properties using four different binder input levels. Findings of the study showed that laboratory tests experienced varying outcomes regarding the most efficient asphalt binder by means of distresses resistance. However, the MEPDG evaluation showed that the overall ranking of asphalt binders positively impacting the rheological properties was as following: (1) 4.5% EE2 PMA, (2) 4% EE2 PMA, (3) 60/70 binder, (4) 5% SBS PMA, and (5) 4% SBS PMA binders. Furthermore, statistical analysis illustrated that the effect of using different binder input levels on the performance of pavement varied relatively to the evaluated distresses. The analysis showed that using different binder input levels would affect, to a certain extent, the asphalt binder influence on rheological properties only when evaluating rutting and fatigue distresses. Therefore, it is recommended that precise asphalt binder inputs, that is, shear complex modulus (G*) and phase angle (δ) are used when designing pavement structures in regions with hot and mild climate conditions.

PHYSICAL PROPERTIES AND STORAGE STABILITY OF GEOPOLYMER MODIFIED ASPHALT BINDER

2016 ◽  
Vol 78 (7-2) ◽  
Author(s):  
Ahmad Nazrul Hakimi Ibrahim ◽  
Nur Izzi Md. Yusoff ◽  
Norliza Mohd Akhir ◽  
Muhamad Nazri Borhan
Keyword(s):  
Physical Properties ◽  
Storage Stability ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Potential Alternative ◽  
Modified Binder ◽  
And Storage

This study was conducted to investigate the physical properties and storage stability of the 80/100 penetration grade asphalt modified with geopolymer. In this research, fly ash and alkali activators, namely sodium silicate (Na2SiO3) and sodium hydroxide (NaOH), were used as geopolymer components. The penetration, Ring and Ball softening point, ductility, and viscosity tests were conducted to determine the physical properties of geopolymer modified asphalt (GMA). Five samples of asphalt binders with varying percentages of geopolymer, namely 0, 3, 5, 7 and 9%, by weight of asphalt binder were studied. Results show that geopolymer has good compatibility with asphalt binder. The addition of geopolymer into asphalt binder resulted in improved permanent deformation resistance of the modified binder compared to that of the conventional asphalt. In conclusion, geopolymer could be considered as a potential alternative in the modification of the properties of asphalt binder.

Creep Compliance of Polymer-Modified Asphalt, Asphalt Mastic, and Hot-Mix Asphalt

2003 ◽  
Vol 1829 (1) ◽  
pp. 33-38 ◽  
Author(s):  
Ota Vacin ◽  
Jiri Stastna ◽  
Ludo Zanzotto
Keyword(s):  
Creep Compliance ◽  
Superposition Principle ◽  
Asphalt Binder ◽  
Tensile Creep ◽  
Asphalt Binders ◽  
Simple Relationship ◽  
Modified Asphalt ◽  
Asphalt Mastic ◽  
Polymer Modified Asphalt ◽  
Time Temperature Superposition Principle

The possibility of using commercial rheometers for comprehensive testing of asphalt binders, asphalt mastics, and hot-mix asphalts (HMA) is explored. Samples of one polymer-modified asphalt, its mix with fine mineral filler (mastic), and one HMA prepared with the same modified asphalt as binders were tested in the dynamic shear rheometer (DSR) and the bending beam rheometer (BBR). All tested materials can be characterized by their discrete relaxation and retardation spectra (under the condition of small deformations). DSR testing was performed in the plate–plate and the torsion bar geometry. From the obtained relaxation and retardation spectra, the shear compliance, J(t), was calculated and compared with the tensile creep compliance, D(t), measured in BBR (both creep and recovery experiments were run). A simple relationship between J(t) and D(t) was found for the asphalt binder and the asphalt mastic. In the case of HMA, the bulk compliance, B(t), contributes to D(t) at short and long times. Both the Boltzmann superposition principle and the time–temperature superposition principle hold very well for all tested materials at low temperatures. There are qualitative differences, in the rheological behavior, of the asphalt binder and asphalt mastic on one side and the HMA on the other. These differences can be seen in dynamic (DSR) as well as in transient (BBR) experiments.

scholarly journals Evaluation of High-Performance Asphalt Binders Modified with SBS, SIS, and GTR

2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
Hyun Hwan Kim ◽  
Mithil Mazumder ◽  
Moon-Sup Lee ◽  
Soon-Jae Lee
Keyword(s):  
High Performance ◽  
Asphalt Binder ◽  
Microstructural Analysis ◽  
Asphalt Binders ◽  
Creep Recovery ◽  
Rotational Viscometer ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Polymer Modified Asphalt ◽  
Styrene Butadiene

In this study, performance properties of polymer-modified asphalt (PMA) binders are evaluated depending on ground tire rubber (GTR) and styrene-isoprene-styrene (SIS). Styrene-butadiene-styrene- (SBS-) modified asphalt binder of PG 76-22 is used as a base binder to manufacture the rubberized PMA binder. The rubberized PMA binders are blended using SIS modifier. The binders were artificially short-term and long-term aged using rolling thin-film oven (RTFO) and pressure aging vessel (PAV) procedures. Superpave binder tests were conducted on the binders through rotational viscometer (RV), dynamic shear rheometer (DSR), and bending beam rheometer (BBR). Furthermore, multiple stress creep recovery (MSCR) test and atomic force microscopy (AFM) microstructural analysis were performed. The results of this study indicated that (1) the viscosity properties seem to be highly dependent on GTR and SIS contents, (2) the addition of SIS is observed to have a significant effect on improving the rutting performances of rubberized PMA binders, (3) the cracking properties are considered to be improved significantly through SIS modification, and (4) in general, the rubberized PMA binders with SIS showed the best performance for rutting and cracking among all the binders used in this study.

Evaluation of Stability, Nature of Modifier, and Short-Term Aging of Modified Binders Using New Tests: LAST, PAT, and Modified RTFO

1998 ◽  
Vol 1638 (1) ◽  
pp. 64-71 ◽  
Author(s):  
Hussain U. Bahia ◽  
Huachun Zhai ◽  
Andres Rangel
Keyword(s):  
Storage Stability ◽  
Data Interpretation ◽  
Test Methods ◽  
Asphalt Binders ◽  
Short Term ◽  
Testing Procedures ◽  
Modified Asphalt ◽  
Typical Data ◽  
Modified Binders ◽  
Modified Binder

In a recent survey of users and producers of modified asphalts, stability and short-term aging were two of the main concerns regarding the use of modified asphalts. In an NCHRP project, a concentrated effort was put into development of revised or new testing procedures to better characterize the nature of modified asphalt and to solve some of the difficulties with using existing aging procedures developed for neat asphalts and modified asphalts. Three main procedures have been proposed to complement the existing Superpave procedures: the laboratory asphalt stability test, for measuring the storage stability of asphalt binders; the particulate additive test, for separation of particulate additives; and the modified rolling thin film oven test for short-term aging. The background behind the development of these test methods is explained, and typical data collected for a number of modified asphalts are presented. The results indicate that these tests show high promise in covering characteristics not covered by the current Superpave binder specifications and in solving some of the problems with the existing aging methods. The results also indicate that the behavior of modified binder can be very complex and that the method of data interpretation is very critical.

scholarly journals Evaluation of Rutting and Fatigue Behaviors of Asphalt Binders Modified with Calcium Lignosulfonate

2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Saeed Fatemi ◽  
Jafar Bolouri Bazaz ◽  
Seyed Ali Ziaee
Keyword(s):  
Storage Stability ◽  
Asphalt Binder ◽  
Thermal Storage ◽  
Fatigue Performance ◽  
Stability Test ◽  
Asphalt Binders ◽  
Test Results ◽  
Asphalt Mixes ◽  
Modified Asphalt ◽  
The Impact

Asphalt mixes encounter different distress during the life cycle of asphalt pavements, among which rutting and fatigue failure are prominent. Moreover, the addition of environmentally friendly modifiers into the asphalt binder to increase the performance of asphalt mixes has been a challenging phenomenon for researchers. Calcium lignosulfonate (CL) is a waste material that is a by-product of the wood industry. In this paper, the impact of the calcium lignosulfonate on the rutting and fatigue performance of the asphalt binder was investigated. For this purpose, the Dynamic Shear Rheometer (DSR) was utilized to run the Multiple Stress Creep Recovery (MSCR) test and evaluate G ∗ /sinδ and G ∗ ·sinδ indices for the asphalt binder containing different percentages of CL. The elastic recovery test was also conducted on the asphalt binder. In order to analyze the thermal storage stability of CL-modified asphalt binders, the storage stability test was considered. The Field Emission Scanning Electron Microscope test showed that using CL as a binder modifier makes the texture of the asphalt binder spongy and porous. The conventional test results indicated that increasing the CL amount in the asphalt binder led to an increase in the stiffness of the asphalt binder. The rheological test results showed that the rutting resistance of the asphalt binder improved by adding up to 15% of the CL powder; however, the fatigue performance and the elasticity of the asphalt binder declined by increasing the CL content in the asphalt binder. The storage stability test revealed that the dispersion of CL in the asphalt binder was uniform; moreover, the presence of CL in the asphalt binder could not adversely affect the thermal storage stability of the modified asphalt binder.

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