scholarly journals Study of the mechanism of pre-burned ash leaching by hydrochloric acid

2021 ◽  
Vol 4 (319) ◽  
pp. 72
Author(s):  
N.K. Dosmukhamedov ◽  
◽  
E.E. Zholdasbay ◽  
G.S. Daruesh ◽  
A.A. Argyn ◽  
...  
Keyword(s):  
Hydrochloric Acid ◽  
Raw Materials ◽  
Experimental Studies ◽  
Complete Separation ◽  
Metal Compounds ◽  
Acid Consumption ◽  
Aluminum Iron ◽  
Limiting Stage ◽  
Aluminum Compounds ◽  
Low Solubility

The use of hydrochloric acid for processing aluminum-containing raw materials has a number of advantages over other acids, which include: easy decomposition of aluminum compounds with the transfer of aluminum into solution; low solubility of silica in HCl, the possibility of complete separation of the solid residue without significant losses of acid, etc. The paper considers the possibility of using the method for processing ash and slag dumps accumulated in large volumes in the country. Based on the thermodynamic analysis of reactions of interaction between ash components and hydrochloric acid, the behavior of aluminum, iron and nonferrous metal compounds during leaching is studied. It was shown that the preliminary roasting of ash with calcium chloride provides a high extraction of aluminum in the solution from the cinder. Based on experimental studies, the influence of time, temperature and acid consumption on the degree of aluminum extraction into the solution has been established. At optimal conditions of leaching conducted at S:L = 1:3, T = 60 ºC, τ = 60 min extraction of aluminum in a solution as chloride amounted to 99.92 %. At the same time the extraction of silica in solid sediment due to the maximum transfer of impurities in the solution was 99.8 %. The mechanism of the leaching process is proposed. The values of activation energy and the order of the reaction, indicating the complex 3-step character of the reactions, have been calculated. It is established that the limiting stage during leaching is the dissolution of anorthite.

scholarly journals Lithosphere Protection with Hardening Phosphate-Containing Soil-Cement Technology

2018 ◽  
Vol 7 (4.7) ◽  
pp. 352
Author(s):  
Larisa Svatovskaya ◽  
Anastasia Sychovа ◽  
Maxim Sychov
Keyword(s):  
Raw Materials ◽  
Construction Material ◽  
Experimental Studies ◽  
Road Construction ◽  
Clay Material ◽  
Bonding Agents ◽  
Metal Compounds ◽  
Soil Cement ◽  
Good For ◽  
Ionic Contaminants

This research is relevant in the light of a need to protect lithosphere from pollution. A solution to this problem can be the exercise of a geoecoprotective function by using building and construction technologies. Phosphate-containing bonding agents usually have low solubility in water. They are made of aluminosilicates that occur in common clay. These minerals react with phosphoric acid to release phosphates and silica gel with absorption properties. The purpose of this research is to make fake rocks from phosphate clay material, intended for building and construction purposes, and to investigate their longevity. The material used was treated to neutralize and detoxify the mobile ionic contaminants and heavy metal compounds, as well as petroleum pollutants, so that at the end we could get construction material like fake rocks or improved aggregates that would be good for the environment. These cement systems are called the geoecoprotective systems. The leading methods that were applied were thermodynamic and experimental studies of service and geoecoprotective properties of phosphate-containing cement systems, more specifically fake landscape rocks. Selected studies lasted for more than 10 years, and were carried out in accordance with the guidelines, adopted in the Russian Federation. This research shows that phosphate-containing cement systems made from contaminated clay/sandy artificial soils have long-lasting properties like strength, frost resistance, water resistance and contaminant binding. From this perspective, they are good for building and construction. For example, they can be used to improve the contaminated soil on road construction sites by detoxifying it until water-resistant products, and to make long-lasting water-resistant solutions from local raw materials that would be good for waste storage.                                                      

A possibility of using nickel concentrate, obtained as a result of hydrometallurgical enrichment of manganese-containing raw materials, at steel alloying

2020 ◽  
Vol 76 (7) ◽  
pp. 709-715
Author(s):  
O. Yu. Kichigina
Keyword(s):  
Raw Materials ◽  
Experimental Studies ◽  
Selective Extraction ◽  
Technological Parameters ◽  
Nickel Iron ◽  
Nickel Recovery ◽  
Nickel Concentrate ◽  
Steel Alloying ◽  
High Degree ◽  
Comprehensive Processing

At production of stainless steel expensive alloying elements, containing nickel, are used. To decrease the steel cost, substitution of nickel during steel alloying process by its oxides is an actual task. Results of analysis of thermodynamic and experimental studies of nickel reducing from its oxide presented, as well as methods of nickel oxide obtaining at manganese bearing complex raw materials enrichment and practice of its application during steel alloying. Technology of comprehensive processing of complex manganese-containing raw materials considered, including leaching and selective extraction out of the solution valuable components: manganese, nickel, iron, cobalt and copper. Based on theoretical and experiment studies, a possibility of substitution of metal nickel by concentrates, obtained as a result of hydrometallurgical enrichment, was confirmed. Optimal technological parameters, ensuring high degree of nickel recovery out of the initial raw materials were determined. It was established, that for direct steel alloying it is reasonable to add into the charge pellets, consisting of nickel concentrate and coke fines, that enables to reach the through nickel recovery at a level of 90%. The proposed method of alloying steel by nickel gives a possibility to decrease considerably steel cost at the expense of application of nickel concentrate, obtained out of tails of hydrometallurgical enrichment of manganese-bearing raw materials, which is much cheaper comparing with the metal nickel.

Studying dispersed and rheological properties of hydrocarbon-containing acid emulsions and their efficiency in removing asphalt-resin-paraffin deposits

2020 ◽  
pp. 128-139
Author(s):  
M. Yu. Shumakher ◽  
V. V. Konovalov ◽  
A. P. Melnikov
Keyword(s):  
Aqueous Solution ◽  
Hydrochloric Acid ◽  
Rheological Properties ◽  
Reaction Rate ◽  
Experimental Studies ◽  
Efficient Removal ◽  
Reservoir Properties ◽  
Hydrocarbon Solvents ◽  
Formation Zone ◽  
Effect Of The Composition

Currently, the treatment of the bottomhole formation zone with acidic compositions is one of the most common methods to intensify the oil inflow. The use of various modified acid compositions increases the efficiency of acid treatments on the bottomhole formation zone. Acid compositions, including those containing hydrocarbon solvents, which contribute to more efficient removal of organic colmatants, affect the reaction rate of the reagent with the rock and processing equipment, change the reservoir properties, etc.The article presents the results of experimental studies, which are aimed at establishing the effect of the composition of hydrocarbon-containing acidic emulsions consisting of an aqueous solution of hydrochloric acid, toluene and Neonol AF 9-10 on their dispersed and rheological properties, as well as their efficiency in removing paraffin deposits.

Calculation of Technical Characteristics of the Technical Fleet Vessels Involved in Ensuring Safety of the Offshore Facilities of Oil and Gas Complex

2021 ◽  
pp. 7-13
Author(s):  
S.V. Matsenko ◽  
◽  
V.M. Minko ◽  
A.A. Koshelev ◽  
V.Yu. Piven ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Oil Pollution ◽  
Raw Materials ◽  
Experimental Studies ◽  
Industrial Safety ◽  
Theoretical Studies ◽  
Physical Processes ◽  
Oil Spill Response ◽  
Sea Area

Violation of industrial safety rules during the operation of offshore facilities for the production, storage and transportation of the hydrocarbon raw materials leads in the most cases to pollution of the marine environment with oil and its components. The works on localization and elimination of such pollution are carried out with the help of vessels of the technical support fleet and booms. When developing oil spill response plans at such facilities, a calculated determination of the technical characteristics of vessels and booms is required that are sufficient to carry out the planned activities. The basic design principles for determining the towing capacity of the technical fleet vessels involved in the localization and elimination of oil and oil product spills by trawling methods are given in the article. The calculation is based on theoretical studies performed by the authors of the physical processes occurring during the movement of objects of a mobile trawling order in the sea area. The results obtained during the course of theoretical studies were confirmed by the experimental studies carried out by the authors personally using the real pieces of equipment in the actual development of tasks for training spill containment by trawling. As a result, the empirical dependencies were obtained and experimentally confirmed, which can be used to calculate technical characteristics of the ships as part of the mobile orders and anchor systems as part of stationary orders intended for the localization and elimination of oil pollution. These results can be used, among other things, for the calculated substantiation of the technical characteristics of the technical fleet vessels designed to ensure safety of the offshore facilities for production, storage, and transportation of the hydrocarbon raw materials.

Pre-Treatment Experimental Study of Organic Acid: An Alternative Means to Overcome Inorganic Scale Build-Up Problem in Deep Well

2021 ◽  
Author(s):  
Bagus Muliadi Nasution ◽  
Andrew Yonathan ◽  
Muthi Abdillah ◽  
Wang Zhen
Keyword(s):  
Hydrochloric Acid ◽  
Formic Acid ◽  
Organic Acid ◽  
Corrosion Inhibitor ◽  
Corrosion Test ◽  
Oil And Gas ◽  
Experimental Studies ◽  
Oil And Gas Industry ◽  
Scale Inhibitor ◽  
Pre Treatment

Abstract Organic acid has been widely applied for inorganic scale treatment in oil and gas industry including well stimulation and scale inhibitor. Thanks to its low corrosivity and slower reaction rate with rock, organic acid is considered to offer better performance comparing to strong acid - Hydrochloric Acid (HCl). Yet, proper treatment requires vigorous analysis and experiment in order to meet foremost expectations. Besides, mistreatment of scale could result in formation damage including clay precipitation. Pre-treatment experiments were performed on Zelda field at South East Sumatera block, that has faced with scale problem for ages. Water sample was taken from flowing Zelda A-08 well to be analyzed for mineral's saturation level. Scale was extracted from three sources including tubing, sand bailer, and Electrical Submersible Pump (ESP) of Zelda A-08. Those scale were treated in X-Ray Powder Diffraction (XRD) for mineral composition, and solubility test that utilized two types of acid system - formic acid (HCOOH) and hydrochloric acid (HCl) for comparison. Anti-swelling test and corrosion test were performed to examine the effectiveness of clay stabilizer and corrosion inhibitor. As for carbonate analysis, both formic acid 9% and HCl 15% have comparable solubility (98.17% vs 98% for tubing's scale, 91.86% vs 82.79% for ESP's scale, and 70.30% vs 68.07% for sand bailer's scale). Yet, longer reaction is carried out by formic acid 9% (1 hour) comparing to HCl 15% (18 minutes). For silicate analysis, HF-formic acid provided the higher solubility than HF-HCl (8.34% vs 5.67% for ESP's scale and 30.48% vs 25.68% for sand bailer's scale). On anti-swelling test, by reducing swelling tendency up to 62.6%, it proves that examined clay stabilizer works perfectly against swelling potential of clay, despite of high swelling tendency of sand bailer's scale (25.8%). On corrosion test, adding on corrosion inhibitor (pyridine-based) into solution results in regular HCl 15% has corrosion rate 26.279 g/m2.h which is much higher (300%) than HF-HCl (7.977 g/m2.h) and HF-formic acid (8.229 g/m2.h). Based on pre-treatment test, formic acid 9% together with examined corrosion inhibitor and clay stabilizer, can be used as an alternative to regular HCl 15% for stimulation purpose where more areas will be covered that previously left unreachable by regular acid 15%. In addition, potentially more effective squeezed scale inhibitor using organic acid can also be achieved by performing further experiments. The method presented in this paper for pre-treatment experimental studies of organic acid can provide engineers with intensive guide to meet the best result of organic acid treatment.

STUDY OF EXTERNAL MASS TRANSFER DURING DRYING OF BERRY RAW MATERIALS TAKING INTO THE SHRINKAGE PHENOMENON

2019 ◽  
Author(s):  
А.В. АКУЛИЧ ◽  
Л.А. ГОСТИНЩИКОВА
Keyword(s):  
Mass Transfer ◽  
Energy Supply ◽  
Raw Materials ◽  
Mass Transfer Rate ◽  
Experimental Studies ◽  
Volume Shrinkage ◽  
External Mass Transfer ◽  
Transfer Coefficients ◽  
Ir Radiation ◽  
Criterial Equations

Исследованы закономерности внешнего массообмена при сушке ягодного сырья для различных способов энергоподвода. Установлено, что ягоды при сушке подвержены значительной объемной (72–81%) и линейной (35–43%) усадке, которую необходимо учитывать при расчете коэффициентов массоотдачи. Объекты исследования – ягоды черники, красной и черной смородины. Проведены экспериментальные исследования по сушке ягодного сырья при конвективном и конвективном с ИК-излучением способах энергоподвода. Исследования проведены при скорости сушильного агента хса1,2 м/с и температуре tса 70°С. Получены критериальные уравнения внешнего массоообмена при сушке ягод для периода постоянной скорости, учитывающие объемную усадку. Определено, что при сушке с конвективным энергоподводом объемная усадка при одном и том же значении критерия Рейнольдса оказывает на 12–20% большее влияние на интенсивность массоообмена для красной смородины по сравнению с черникой и черной смородиной. При сушке с конвективным энергоподводом, ИК-излучением и предварительным прокалыванием объемная усадка наиболее существенно влияет на массообмен для черной смородины, протекающий в 1,5–1,8 раза интенсивнее по сравнению с черникой и красной смородиной. Полученные критериальные уравнения могут быть использованы при расчете и проектировании установок для сушки ягодного сырья. The laws of external mass transfer during drying of berry raw materials for various methods of energy supply are investigated. It is established that the berries during drying are subject to significant volumetric (72–81%) and surface (35–43%) shrinkage, which must be taken into account when calculating the mass transfer coefficients. The objects of the study were various berries: blueberries, red and black currants. Experimental studies have been carried out on the drying of selected berries both in the case of convective and convective methods with IR radiation. Investigations were carried out at a drying agent velocity хса1,2 m/s and its temperature tca70°С. The criterion equations of external mass transfer during drying of berries for a period of constant speed, taking into account the volume shrinkage, are obtained. It was determined that during drying with convective energy supply, volume shrinkage with the same value of the Reynolds criterion on 12–20% has a greater effect on the mass transfer rate for red currants. When drying with convective energy supply, IR radiation and preliminary piercing, the volume shrinkage most significantly affects the mass transfer for black currants, which is 1,5–1,8 times more intense than blueberries and red currants. The obtained criterial equations can be used in the calculation and design of berries dryers.

CONSUMER PROPERTIES OF PASTA WITH POWDER FROM MARIGOLD INFLORESCENCES (TAGETES L.)

2021 ◽  
Vol 40 (4) ◽  
pp. 102-112
Author(s):  
SHAPOVALOVA Nataliia ◽  
VEZHLIVTSEVA Svitlana ◽  
ANTIUSHKO Dmytro
Keyword(s):  
Raw Materials ◽  
Experimental Studies ◽  
The Body ◽  
Biologically Active Substances ◽  
Biologically Active ◽  
Organoleptic Properties ◽  
Biological Value ◽  
Plant Raw Materials ◽  
Active Substances

Background. The deficiency of essential nutrients in the human body is the root cause of reduced efficiency, general resistance of the body to various diseases. That is an urgent problem in the context of the spread of coronavirus infection. In this regard, the search for opportunities to meet the needs of the population in food products that contain biologically active substances (BAS) through the use of high-value and at the same time available plant raw materials is extremely important. Marigolds attract special attention among such raw materials. The aim of the work is to study the chemical composition and evaluate the consumer properties of Tagetes L. varieties, zoned in the Kiev region, to prove the possibility of increasing the biological value of pasta by adding to their recipe powder from marigold inflorescences. Materials and methods. The object of research is pasta of B group (noodles). Inflorescences of marigolds of different varieties gathered during the flowering period in July-September 2019–2020 in the territory of Vasylkiv and Obukhiv districts of Kyiv region, Ukraine were used as enriching plant raw materials. The quality of finished pasta was assessed by organoleptic and physicochemical indexes (moisture content and titratable acidity). The content of mineral elements in the fine powder of marigold inflorescences was determined on the EXHERT-3L device, the quantitative composition and BAS identification – by spectrophotometric analysis on the device Specord-200 Analytic Jena UV-vis. The integrated quality index of pasta products was calculated taking into account the importance factors of individual indexes. Results. Comparing the obtained results, we can state that all the studied varieties – Gold Kopfen, Orange Flame, Hawaii, Equinox are characterized by high biological value, regardless of the area of collection. As a result of calculated and experimental studies it was determined that the addition of 7 % of the supplement does not provide the required supply of vitamins and minerals. Replacing the flour in the recipe by 20 % significantly improves the mineral composition, but deteriorates the taste and aromatic properties of pasta. The most optimal and rational amount of added additive is 15 %, as it improves the organoleptic properties of pasta and enriches their BAS. Conclusion. The usage of non-traditional vegetable raw materials, in particular powder from marigold inflorescences, which is rich in biologically active substances, allows not only to expand the range, improve the quality of finished products, but also increase the biological value of the product. The optimal amount of additive –powder from marigold inflorescences, was defined. It is 15 % by weight of flour in the production of noodles. This concentration allows not only to improve the organoleptic properties, but also to increase the content of biologically active substances – vitamins, micro- and macronutrients. The usage of non-traditional natural raw materials (powder from marigold inflorescences) allows to abandon artificial colorsand give the finished pasta a pleasant colorand aroma.

scholarly journals ADSORPTION OF PHOSPHATE IONS ON RED SLUDGE

2017 ◽  
Vol 60 (8) ◽  
pp. 80
Author(s):  
Svetlana M. Kramer ◽  
Mariya V. Terekhova ◽  
Inna V. Artamonova
Keyword(s):  
Hydrochloric Acid ◽  
Experimental Studies ◽  
Aluminum Production ◽  
Quantitative Composition ◽  
Experimental Conditions ◽  
Initial Concentration ◽  
Phosphate Ions ◽  
Frumkin’S Isotherm ◽  
Ph Range ◽  
Red Sludge

In work the possibility of red sludge (waste of aluminum production by Bayer's method) to adsorb phosphate ions from water solutions at various concentration of ions and in the pH range from 3 to 10 is studied. Relevance of use of red sludge for receiving on its basis of sorbents is reasoned. For identification of the studied object the qualitative and quantitative composition of red sludge was established by the method of the X-ray phase analysis. The technique of red slage activation by hydrochloric acid, and also an adsorption technique of phosphate ions on the red sludge surface is described. Experimental studies of adsorption of phosphate ions on the surface of the red slage activated by hydrochloric acid depending on рН and concentration of initial solution were conducted. The dependence of adsorption phosphate ions on the red slage activated by НСl on рН and on the initial concentration of phosphate ions in solution is presented. These dependences of a relative fraction of distribution of various ions of phosphoric acid on рН are given in work. The form of ion phosphate having the greatest adsorptive activity on the red slage activated by hydrochloric acid in experimental conditions is revealed. Experimental data on dependence of adsorption of phosphate ions on their initial concentration in solution are described by Frumkin's isotherm. The constant of the adsorptive balance, limit adsorption, the parameter of intermolecular interaction of the adsorbed particles are calculated. Optimum conditions for adsorption of phosphate ions on red slage are established.Forcitation:Kramer S.M., Terekhova M.V., Artamonova I.V. Adsorption of phosphate ions on red sludge. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2017. V. 60. N 8. P. 80-83.

scholarly journals OXIDATIVE DIMERIZATION OF METHANE TO C2 HYDROCARBONS

2021 ◽  
Vol 447 (3) ◽  
pp. 18-24
Author(s):  
D.B. Augaliev ◽  
M.K. Erkibaeva ◽  
A.O. Aidarova ◽  
S.А. Tungatarova ◽  
T.S. Baizhumanova
Keyword(s):  
Natural Gas ◽  
Raw Materials ◽  
Continuous Production ◽  
Experimental Studies ◽  
Optimal Conditions ◽  
Alternative Source ◽  
Oil Reserves ◽  
Oxidative Conversion Of Methane ◽  
C2 Hydrocarbons ◽  
Shs Method

The world's oil reserves are decreasing every day due to the continuous production and processing of the most modern technologies. Scientists all over the world are looking for various raw materials and methods to use the vast resources of natural gas as a substitute for petrochemicals. In this regard, great attention is drawn to natural gas as an alternative source of raw materials for petrochemical industries. The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction. The results of the study of 20% La-10% Ce-20% Mg-50% glycine catalyst prepared by the SHS method in the process of oxidative dehydrogenation of methane into C2 hydrocarbons are presented. On the basis of experimental studies, it was found that the composition of the catalyst exhibits high activity in the above reaction under the found optimal conditions. Thus, the influence of reaction temperature on the developed composition of catalysts for oxidative conversion of methane has been determined that the optimum temperature for the selective formation of ethane and ethylene is T=700o С. It was found that for selective oxidation of a mixture of CH4: O2 : Ar in C2 hydrocarbons the optimal conditions are: T=700o С, CH4:O2=2,5:1, 5000 h-1.

scholarly journals Research into special technological effects for formation of wear resistant coatings using mineral raw materials of the far eastern region

2018 ◽  
Vol 56 ◽  
pp. 03027
Author(s):  
Viktor Makienko ◽  
Igor Romanov ◽  
Pavel Sokolov ◽  
Alexander Atenyaev ◽  
Dmitry Pervakov
Keyword(s):  
Mechanical Properties ◽  
Raw Materials ◽  
Experimental Studies ◽  
Eastern Region ◽  
Mineral Raw Materials ◽  
Wear Resistant Coatings ◽  
Thermal Fields ◽  
Additional Influence ◽  
Far Eastern

The results of the study of the possibility of using additional technological influence in the formation of doped coatings are presented. The distribution of thermal fields has been calculated, which makes it possible to estimate and predict the influence of additional influence on the formation of the coating in a simplified manner. Experimental studies have shown that additional technological influence promotes mixing of the melt, leading to an increase in the transition of alloying elements, as well as an increase in the mechanical properties and quality of the weld metal.

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