scholarly journals The Effect of Formation Water Salinity on the Minimum Miscibility Pressure of CO2-Crude Oil for Y Oilfield

2021 ◽  
Vol 9 ◽  
Author(s):  
Yanfu Pi ◽  
Jinxin Liu ◽  
Li Liu ◽  
Xuan Guo ◽  
Chengliang Li ◽  
...  
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Potassium Feldspar ◽  
Water Flooding ◽  
Formation Water ◽  
Core Flooding ◽  
Rock Interaction ◽  
Minimum Miscibility Pressure ◽  
Miscible Flooding ◽  
Water Ph

CO2 miscible flooding is an important technology for enhancing oil recovery and greenhouse gas storage in the world. As a tertiary recovery technology, it is usually applied after water flooding. Therefore, the actual reservoirs usually contain a lot of injected water in addition to connate water. The salinity of these formation waters varies from place to place. CO2 is an acid gas. After it is injected into the reservoir, it easily reacts with formation water and rock and affects the physical properties of the reservoir. However, no research results have been reported whether this reaction affects the minimum miscibility pressure (MMP) of CO2-crude oil, a key parameter determining miscible flooding in formation water. Based on CO2-formation water–rock interaction experiments, this paper uses the core flooding method to measure the CO2-crude oil MMP under different salinity in formation water. Results show that CO2 causes a formation water pH decrease from 7.4 to 6.5 due to its dissolution in formation water. At the same time, CO2 reacts with formation water, albite, potassium feldspar, and carbonate minerals in the cores to generate silicate and carbonate precipitates, which could migrate to the pore throat together with the released clay particles. Overall, CO2 increased core porosity by 5.63% and reduced core permeability by 7.43%. In addition, when the salinity of formation water in cores was 0, 4,767, and 6,778 mg/L, the MMP of CO2-crude oil was 20.58, 19.85, and 19.32 MPa, respectively. In other words, the MMP of CO2-crude oil decreased with the increase of salinity of formation water.

Experimental Study on Direct Current Voltage Assisted Carbonated Water-Flooding Mechanism in Tight Oil Reservoir

2021 ◽  
Author(s):  
Rukuan Chai ◽  
Yuetian Liu ◽  
Yuting He ◽  
Qianjun Liu ◽  
Wenhuan Gu
Keyword(s):  
Crude Oil ◽  
Direct Current ◽  
Oil Recovery ◽  
Co2 Sequestration ◽  
Water Flooding ◽  
Current Voltage ◽  
Direct Current Voltage ◽  
Carbonated Water ◽  
Ft Icr Ms ◽  
Ft Icr

Abstract Tight oil reservoir plays an increasingly important role in the world energy system, but its recovery is always so low. Hence, a more effective enhanced oil recovery (EOR) technology is urgently needed. Meanwhile, greenhouse effect is more and more serious, a more effective carbon capture and sequestration (CCS) method is also badly needed. Direct current voltage assisted carbonated water-flooding is a new technology that combines direct current voltage with carbonated water-flooding to enhance oil recovery and CO2 sequestration efficiency, simultaneously. Experimental studies were conducted from macroscopic-scale to microscopic-scale to study the performance and mechanism of direct current voltage assisted carbonated water-flooding. Firstly, core flood experiments were implemented to study the effect of direct current voltage assisted carbonated water on oil recovery and CO2 sequestration efficiency. Secondly, contact angle and interfacial tension/dilatational rheology were measured to analyze the effect of direct current voltage assisted carbonated water on crude oil-water-rock interaction. Thirdly, total organic carbon (TOC), gas chromatography (GC), and electrospray ionization-fourier transform ion cyclotron resonance-mass spectrometry (ESI FT ICR-MS) were used to investigate the organic composition change of produced effluents and crude oil in direct current voltage assisted carbonated water treatment. Through direct current voltage assisted carbonated water-flooding experiments, the following results can be obtained. Firstly, direct current voltage assisted carbonated waterflooding showed greater EOR capacity and CO2 sequestration efficiency than individual carbonated water and direct current voltage treatment. With the increase of direct current voltage, oil recovery increases to 38.67% at 1.6V/cm which much higher than 29.07% of carbonated water-flooding and then decreases, meanwhile, CO2 output decreases to only 35.5% at 1.6V/cm which much lower than 45.6% of carbonated water-flooding and then increases. Secondly, in direct current voltage assisted carbonated water-flooding, the wettability alteration is mainly caused by carbonated water and the effect of direct current can be neglected. While both carbonated water and direct current have evident influence on interfacial properties. Herein, with direct current voltage increasing, the interfacial tension firstly decreases and then increases, the interfacial viscoelasticity initially strengthens and then weakens. Thirdly, GC results indicated that crude oil cracking into lighter components occurs during direct current voltage assisted carbonated water-flooding, with the short-chain organic components increasing and the long-chain components decreasing. Meanwhile, TOC and ESI FT ICR-MS results illustrated that CO2 electroreduction do occur in direct current voltage assisted carbonated water-flooding with the dissolved organic molecules increases and the emergence of formic acid. Conclusively, the synergy of CO2 electrochemical reduction into formic acid in aqueous solution and the long-chain molecules electrostimulation pyrolysis into short ones in crude oil mutually resulted in the enhancement of crude oil-carbonated water interaction. This paper proposed a new EOR & CCS technology-direct current voltage assisted carbonated water-flooding. It showed great research and application potential on tight oil development and greenhouse gas control. More work needs to be done to further explore its mechanism. This paper constructs a multiscale & interdisciplinary research system to study the multidisciplinary (EOR&CCS) problem. Specifically, a series connected physical (Core displacement, Contact angle, and Interfacial tension/rheology measurements) and chemistry (TOC, GS, and ESI FT ICR-MS) experiments are combined to explore its regularity and several physics (Atomic physics) and chemistry (Electrochemistry/Inorganic Chemistry) theories are applied to explain its mechanisms.

scholarly journals Experimental Study on Reducing CO2–Oil Minimum Miscibility Pressure with Hydrocarbon Agents

Energies ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1975 ◽  
Author(s):  
Junrong Liu ◽  
Lu Sun ◽  
Zunzhao Li ◽  
Xingru Wu
Keyword(s):  
Crude Oil ◽  
Petroleum Ether ◽  
Oil Recovery ◽  
Mass Concentration ◽  
Co2 Flooding ◽  
Oil Viscosity ◽  
Injection Wells ◽  
Boiling Range ◽  
Minimum Miscibility Pressure ◽  
Soluble Surfactants

CO2 flooding is an important method for improving oil recovery for reservoirs with low permeability. Even though CO2 could be miscible with oil in regions nearby injection wells, the miscibility could be lost in deep reservoirs because of low pressure and the dispersion effect. Reducing the CO2–oil miscibility pressure can enlarge the miscible zone, particularly when the reservoir pressure is less than the needed minimum miscible pressure (MMP). Furthermore, adding intermediate hydrocarbons in the CO2–oil system can also lower the interfacial tension (IFT). In this study, we used dead crude oil from the H Block in the X oilfield to study the IFT and the MMP changes with different hydrocarbon agents. The hydrocarbon agents, including alkanes, alcohols, oil-soluble surfactants, and petroleum ethers, were mixed with the crude oil samples from the H Block, and their performances on reducing CO2–oil IFT and CO2–oil MMP were determined. Experimental results show that the CO2–oil MMP could be reduced by 6.19 MPa or 12.17% with petroleum ether in the boiling range of 30–60 °C. The effects of mass concentration of hydrocarbon agents on CO2–oil IFT and crude oil viscosity indicate that the petroleum ether in the boiling range of 30–60 °C with a mass concentration of 0.5% would be the best hydrocarbon agent for implementing CO2 miscible flooding in the H Block.

Asphaltene Deposition Induced by Carbon Oxide and its Influence on Displacement Efficiency

2012 ◽  
Vol 594-597 ◽  
pp. 2451-2454
Author(s):  
Feng Lan Zhao ◽  
Ji Rui Hou ◽  
Shi Jun Huang
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Carbon Oxide ◽  
Viscosity Reduction ◽  
Core Flooding ◽  
Displacement Efficiency ◽  
Oil Composition ◽  
Oil Viscosity ◽  
Asphaltene Deposition ◽  
Total Oil

CO2is inclined to dissolve in crude oil in the reservoir condition and accordingly bring the changes in the crude oil composition, which will induce asphaltene deposition and following formation damage. In this paper, core flooding device is applied to study the effect of asphaltene deposition on flooding efficiency. From the flooding results, dissolution of CO2into oil leads to recovery increase because of crude oil viscosity reduction. But precipitated asphaltene particles may plug the pores and throats, which will make the flooding effects worse. Under the same experimental condition and with equivalent crude oil viscosity, the recovery of oil with higher proportion of precipitated asphaltene was relatively lower during the CO2flooding, so the asphltene precipitation would affect CO2displacement efficiSubscript textency and total oil recovery to some extent. Combination of static diffusion and dynamic oil flooding would provide basic parameters for further study of the CO2flooding mechanism and theoretical evidence for design of CO2flooding programs and forecasting of asphaltene deposition.

Optimization of Smart Water Chemical Composition for Carbonate Rocks Through Comparison of Active Cations Performance

2017 ◽  
Vol 139 (6) ◽  
Author(s):  
Malek Jalilian ◽  
Peyman Pourafshary ◽  
Behnam Sedaee Sola ◽  
Mosayyeb Kamari
Keyword(s):  
Chemical Composition ◽  
Oil Recovery ◽  
Carbonate Rocks ◽  
Low Cost ◽  
Recovery Phase ◽  
Ion Concentration ◽  
Water Flooding ◽  
Core Flooding ◽  
Smart Water ◽  
The Impact

Designing smart water (SW) by optimizing the chemical composition of injected brine is a promising low-cost technique that has been developed for both sandstone and carbonate reservoirs for several decades. In this study, the impact of SW flooding during tertiary oil recovery phase was investigated by core flooding analysis of pure limestone carbonate rocks. Increasing the sulfate ion concentration by using CaSO4 and MgSO4 of NaCl concentration and finally reducing the total salinity were the main manipulations performed to optimize SW. The main objective of this research is to compare active cations including Ca2+ and Mg2+ in the presence of sulfate ions (SO42−) with regard to their efficiency in the enhancement of oil production during SW flooding of carbonate cores. The results revealed a 14.5% increase in the recovery factor by CaSO4 proving its greater effectiveness compared to MgSO4, which led to an 11.5% production enhancement. It was also realized that low-salinity water flooding (LSWF) did not lead to a significant positive effect as it contributed less than 2% in the tertiary stage.

Characteristics of a Geobacillus sp. as an Enhanced Oil Recovery Material

2012 ◽  
Vol 496 ◽  
pp. 542-545
Author(s):  
Xiang Ping Kong
Keyword(s):  
Crude Oil ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Sewage Treatment ◽  
Core Flooding ◽  
Treatment Technology ◽  
Promising Candidate ◽  
Different Types ◽  
Displacement Experiments ◽  
Original Oil In Place

The enhanced oil recovery characteristics of a Geobacillus sp. was investigated by shake flask experiments, blind-tube oil displacement experiments and core flooding tests. The strain exhibited good properties such as resisting high temperature, taking different types of crude oil as the sole carbon source, reducing the viscosity of crude oil, emulsifying and dispersing crude oil or liquid wax. The oil in the dead area could be effectively driven out by the strain, and the oil recovery of original oil in place had been increased by 12.9-15.9% after 5 treatments in 50 days by adopting air-assistant technique (air/liquid 10:1, v/v) due to the synergistic effect of the bacteria and their metabolites such as biogas and biosurfactants. The strain seems to be a promising candidate for microbial enhanced oil recovery and underground sewage treatment technology.

Study on Minimum Miscible Pressure and Oil Displacement Law for CO2 Flooding

2011 ◽  
Vol 391-392 ◽  
pp. 1051-1054
Author(s):  
Shu Li Chen ◽  
Wen Xiang Wu ◽  
Jia Bin Tang
Keyword(s):  
Oil Recovery ◽  
Gas Injection ◽  
Injection Pressure ◽  
Water Flooding ◽  
Tube Model ◽  
Gas Oil ◽  
Core Flooding ◽  
Oil Displacement ◽  
Gas Flooding ◽  
Cumulative Recovery

In laboratory, the minimum miscible pressure (MMP) of oil and CO2 was studied by using a slim tube model. The results showed that the greater the gas injection pressure, the higher the cumulative recovery. The gas breakthrough when the gas was injected with a volume of 0.7~0.8PV, the trend of cumulative recovery increase slowed down and the produced gas-oil ratio increased dramatically. Core flooding experiments were carried to compare the effects of CO2 and water flooding. As a result, the ultimate oil recovery of CO2 flooding increased with the increase of gas injection pressure. If the gas flooding was miscible, the ultimate recovery of CO2 flooding was generally higher than that of water flooding.

scholarly journals Application of Augmented Water Flooding Using Ultrasound Energy to Improve Oil Recovery

2021 ◽  
Vol 6 (2) ◽  
pp. 1-5
Author(s):  
U. Hassan ◽  
M. B. Adamu ◽  
I. Bukar ◽  
M. A. Muhammad
Keyword(s):  
Oil Recovery ◽  
Process Model ◽  
Positive Impact ◽  
Fold Increase ◽  
Flow In Porous Media ◽  
Water Flooding ◽  
Core Flooding ◽  
Ultrasound Frequency ◽  
Sandstone Rock ◽  
Ultrasound Energy

The application of ultrasound energy in improving oil recovery is an emerging technique, it has been tested in laboratories and some field applications in different parts of the world. In this study, Nigerian crude oil of 4.21 cSt viscosity and sandstone rock samples were tested using a designed and constructed experimental rig. The rig is an analogue of a standard core flooding set up and works on the principle of fluid flow in porous media. Furthermore, a modeled equation was developed to better understand the effects of power and time on the volume of oil recovered at a constant ultrasound frequency.  Results obtained show a positive impact in the recovery of residual oil during waterflooding with the assisted ultrasound energy. About 2-fold increase in the recovery of oil was observed when the ultrasound energy was applied to augment the waterflooding process. Model equations developed were found to be adequate because the adjusted and predicted R-squared values show reasonable agreement (R-adjusted = 0.9993, R-Predicted = 0.9974). 

scholarly journals Predicting the electrokinetic properties of the crude oil/brine interface for enhanced oil recovery in low salinity water flooding

Fuel ◽  
2019 ◽  
Vol 235 ◽  
pp. 822-831 ◽  
Author(s):  
Miku Takeya ◽  
Mai Shimokawara ◽  
Yogarajah Elakneswaran ◽  
Toyoharu Nawa ◽  
Satoru Takahashi
Keyword(s):  
Crude Oil ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Water Flooding ◽  
Electrokinetic Properties ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Salinity Water

scholarly journals Insights into the Effects of Pore Size Distribution on the Flowing Behavior of Carbonate Rocks: Linking a Nano-Based Enhanced Oil Recovery Method to Rock Typing

Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 972 ◽  
Author(s):  
Amin Rezaei ◽  
Hadi Abdollahi ◽  
Zeinab Derikvand ◽  
Abdolhossein Hemmati-Sarapardeh ◽  
Amir Mosavi ◽  
...  
Keyword(s):  
Size Distribution ◽  
Enhanced Oil Recovery ◽  
Relative Permeability ◽  
Oil Recovery ◽  
Reservoir Rock ◽  
Water Flooding ◽  
Alpha Olefin Sulfonate ◽  
Core Flooding ◽  
Recovery Method ◽  
Fluid Saturation

As a fixed reservoir rock property, pore throat size distribution (PSD) is known to affect the distribution of reservoir fluid saturation strongly. This study aims to investigate the relations between the PSD and the oil–water relative permeabilities of reservoir rock with a focus on the efficiency of surfactant–nanofluid flooding as an enhanced oil recovery (EOR) technique. For this purpose, mercury injection capillary pressure (MICP) tests were conducted on two core plugs with similar rock types (in respect to their flow zone index (FZI) values), which were selected among more than 20 core plugs, to examine the effectiveness of a surfactant–nanoparticle EOR method for reducing the amount of oil left behind after secondary core flooding experiments. Thus, interfacial tension (IFT) and contact angle measurements were carried out to determine the optimum concentrations of an anionic surfactant and silica nanoparticles (NPs) for core flooding experiments. Results of relative permeability tests showed that the PSDs could significantly affect the endpoints of the relative permeability curves, and a large amount of unswept oil could be recovered by flooding a mixture of the alpha olefin sulfonate (AOS) surfactant + silica NPs as an EOR solution. Results of core flooding tests indicated that the injection of AOS + NPs solution in tertiary mode could increase the post-water flooding oil recovery by up to 2.5% and 8.6% for the carbonate core plugs with homogeneous and heterogeneous PSDs, respectively.

scholarly journals Wettability alteration analysis of smart water/novel functionalized nanocomposites for enhanced oil recovery

2020 ◽  
Vol 17 (5) ◽  
pp. 1318-1328
Author(s):  
Sara Habibi ◽  
Arezou Jafari ◽  
Zahra Fakhroueian
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Ionic Composition ◽  
Water Flooding ◽  
Wettability Alteration ◽  
Core Flooding ◽  
Sulfate Ions ◽  
Smart Water ◽  
Eor Processes ◽  
Co Precipitation

Abstract Smart water flooding, as a popular method to change the wettability of carbonate rocks, is one of the interesting and challenging issues in reservoir engineering. In addition, the recent studies show that nanoparticles have a great potential for application in EOR processes. However, little research has been conducted on the use of smart water with nanoparticles in enhanced oil recovery. In this study, stability, contact angle and IFT measurements and multi-step core flooding tests were designed to investigate the effect of the ionic composition of smart water containing SO42− and Ca2+ ions in the presence of nanofluid on EOR processes. The amine/organosiloxane@Al2O3/SiO2 (AOAS) nanocomposite previously synthesized using co-precipitation-hydrothermal method has been used here. However, for the first time the application of this nanocomposite along with smart water has been studied in this research. Results show that by increasing the concentrations of calcium and sulfate ions in smart water, oil recovery is improved by 9% and 10%, respectively, compared to seawater. In addition, the use of smart water and nanofluids simultaneously is very effective on increasing oil recovery. Finally, the best performance was observed in smart water containing two times of sulfate ions concentration (SW2S) with nanofluids, showing increased efficiency of about 7.5%.

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