scholarly journals Mercury Accumulation in Marine Sediments – A Comparison of an Upwelling Area and Two Large River Mouths

2021 ◽  
Vol 8 ◽  
Author(s):  
Sara Zaferani ◽  
Harald Biester
Keyword(s):  
Elemental Mercury ◽  
Congo Basin ◽  
Geochemical Data ◽  
Minor Importance ◽  
Accumulation Rates ◽  
Data Set ◽  
Gaseous Elemental Mercury ◽  
Organic Particles ◽  
Upwelling Area ◽  
Hg Accumulation

Understanding marine mercury (Hg) biogeochemistry is crucial, as the consumption of Hg-enriched ocean fish is the most important pathway of Hg uptake in humans. Although ocean sediments are seen as the ultimate Hg sink, marine sediment studies on Hg accumulation are still rare. In this context, studying Hg behavior in the marine environment, especially in upwelling environments, is of particular interest due to its importance in these great upwelling regions for the global fishery. There are contradictory statements about the fate of Hg in upwelling regions. Some studies have suggested high biotic reduction of oxidized Hg and gaseous elemental mercury evasion to the atmosphere. More recent work has suggested that in upwelling regions, where productivity is high, evasion of gaseous elemental mercury is diminished due to scavenging and sedimentation of Hg by organic particles. In this study, we compared Hg concentrations and accumulation rates in the past ∼4,300 and 19,400 years derived from sediment cores collected in the Peruvian upwelling region (Peru Margin) and compared them with those of two other cores collected from the sediment fan of the Amazon and a core from the Congo Basin, which is influenced by both seasonal coastal upwelling and discharge from the river. Median Hg concentrations were higher at the Peru Margin (90.7 μg kg–1) and in the Congo Basin (93.4 μg kg–1) than in the Amazon Fan (35.8 μg kg–1). The average Hg accumulation rates in sediments from the Peru Margin (178 μg m–2 yr–1) were factors of ∼4 and ∼39 times higher than those from the Congo Basin (46.7 μg m–2 yr–1) and Amazon Fan (4.52 μg m–2 yr–1), respectively. Principal component analysis (PCA) of the geochemical data set reveals that Amazon Fan sediments are strongly influenced by the deposition of terrestrial material, which is of less importance in the Congo Basin and of minor importance in Peru Margin sediments. Accordingly, Hg export to sediments in upwelling areas largely surpasses that in fans of large rivers that drain large terrestrial catchments. The high Hg accumulation rates in the sediments from the upwelling area and the minor influence of terrestrial Hg fluxes there suggest that atmospheric-derived Hg in upwelling areas is effectively exported to the sediments through scavenging by organic particles.

A bottom up approach to quantify foliar uptake of gaseous elemental mercury by European forests during the 2018 growing season

2020 ◽  
Author(s):  
Lena Wohlgemuth ◽  
Stefan Osterwalder ◽  
Günter Hoch ◽  
Christine Alewell ◽  
Martin Jiskra
Keyword(s):  
Leaf Area ◽  
Tree Species ◽  
Elemental Mercury ◽  
Growing Season ◽  
Accumulation Rates ◽  
Bottom Up ◽  
Deposition Fluxes ◽  
Gaseous Elemental Mercury ◽  
Species Specific ◽  
Hg Accumulation

<p>The deposition of gaseous elemental mercury, Hg(0), from the atmosphere to terrestrial surfaces remains poorly understood mainly due to difficulties in measuring net Hg(0) fluxes on the ecosystem scale. However, there is emerging evidence that vegetation uptake of atmospheric Hg(0) represents a major deposition pathway to terrestrial surfaces. We will present a novel bottom up approach to calculate Hg(0) deposition fluxes to aboveground foliage by combining foliar Hg accumulation rates on the basis of leaf area with species-specific leaf area indices. We analyzed Hg content in 583 foliage samples from major tree species at 10 European forested research sites along a latitudinal gradient from Switzerland to Northern Finland over the course of the 2018 growing season. Foliar Hg concentrations increased over time in all tree species at all sites. We found that foliar Hg accumulation rates normalized to leaf area increased with crown height and decreased with the age of multi-year old needles. We did not detect a clear latitudinal gradient in foliar Hg accumulation rates.</p><p>On an ecosystem scale we developed a simple bottom up approach for foliar Hg(0) uptake considering the systematic variations in crown height, needle age and tree species. We calculated species-specific average foliar Hg(0) dry deposition rates for the 2018 growing season of 22 ± 4 µg Hg m<sup>-2</sup> for beech, 16 ± 8 µg Hg m<sup>-2</sup> for oak, 3 ± 0.4 µg Hg m<sup>-2</sup> for birch, 18 ± 10 µg Hg m<sup>-2</sup> for spruce and 8 ± 4 µg Hg m<sup>-2</sup> for pine. For comparison, the average Hg wet deposition flux measured at 4 of our 10 research sites during the same time period was 2.5 ± 0.2 µg Hg m<sup>-2</sup>.</p><p>Scaling up site-specific deposition rates to the forested area of Europe (EU28) resulted in a total aboveground Hg(0) deposition to foliage of approximately 20 Mg during the 2018 growing season. Our results confirm that vegetation uptake of atmospheric Hg(0) represents a major deposition pathway to terrestrial surfaces. The bottom up approach we used is a promising method to quantify Hg(0) deposition fluxes based on easy-to-do Hg concentration measurements in foliage.</p>

scholarly journals An Integrated Investigation of Atmospheric Gaseous Elemental Mercury Transport and Dispersion Around a Chlor-Alkali Plant in the Ossola Valley (Italian Central Alps)

Toxics ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 172
Author(s):  
Laura Fantozzi ◽  
Nicoletta Guerrieri ◽  
Giovanni Manca ◽  
Arianna Orrù ◽  
Laura Marziali
Keyword(s):  
Elemental Mercury ◽  
Background Concentration ◽  
Dispersion Pattern ◽  
Central Alps ◽  
Gaseous Elemental Mercury ◽  
Mercury Transport ◽  
Close Proximity ◽  
Potential Impact ◽  
Hg Accumulation

We present the first assessment of atmospheric pollution by mercury (Hg) in an industrialized area located in the Ossola Valley (Italian Central Alps), in close proximity to the Toce River. The study area suffers from a level of Hg contamination due to a Hg cell chlor-alkali plant operating from 1915 to the end of 2017. We measured gaseous elemental Hg (GEM) levels by means of a portable Hg analyzer during car surveys between autumn 2018 and summer 2020. Moreover, we assessed the long-term dispersion pattern of atmospheric Hg by analyzing the total Hg concentration in samples of lichens collected in the Ossola Valley. High values of GEM concentrations (1112 ng m−3) up to three orders of magnitude higher than the typical terrestrial background concentration in the northern hemisphere were measured in the proximity of the chlor-alkali plant. Hg concentrations in lichens ranged from 142 ng g−1 at sampling sites located north of the chlor-alkali plant to 624 ng g−1 in lichens collected south of the chlor-alkali plant. A north-south gradient of Hg accumulation in lichens along the Ossola Valley channel was observed, highlighting that the area located south of the chlor-alkali plant is more exposed to the dispersion of Hg emitted into the atmosphere from the industrial site. Long-term studies on Hg emission and dispersion in the Ossola Valley are needed to better assess potential impact on ecosystems and human health.

scholarly journals Effect of sources and meteorological conditions on the concentration and distribution of gaseous elemental mercury in the urban atmosphere

2021 ◽  
Author(s):  
Daniel Prete
Keyword(s):  
Rural Areas ◽  
Elemental Mercury ◽  
Average Concentration ◽  
Meteorological Conditions ◽  
Urban Atmosphere ◽  
Mercury Vapour ◽  
Data Set ◽  
Gaseous Elemental Mercury ◽  
Regional Sources ◽  
High Mercury

Atmospheric gaseous elemental mercury (GEM) and meteorological parameters were monitored at two sites in downtown Toronto, Canada from Oct. 2015 to Oct. 2016 using Tekran 2537A mercury vapour analyzers. The average concentration was found to be 1.78 ± 0.89 ng/m3 for Kerr Hall North (KHN) and 1.46 ± 0.54 ng/m3 for Jorgenson Hall (JOR) site. Analysis of the data reveals that sporadic events of high mercury concentration are related to local sources. Comparing this data set with that collected in 2004 revealed that the average atmospheric GEM concentration in downtown Toronto dropped from 4.5 ng/m3 to 1.78 ng/m3. Decreases in GEM were also observed over the same period in rural areas as measured by CAMNet. The decrease might be a result of policy change, as three key national and provincial environmental policies have been enacted since 2004. The data collected in Toronto suggest GEM concentration and distribution are influenced by local and regional sources, meteorological conditions, and changes in environmental policy.

scholarly journals Effect of sources and meteorological conditions on the concentration and distribution of gaseous elemental mercury in the urban atmosphere

2021 ◽  
Author(s):  
Daniel Prete
Keyword(s):  
Rural Areas ◽  
Elemental Mercury ◽  
Average Concentration ◽  
Meteorological Conditions ◽  
Urban Atmosphere ◽  
Mercury Vapour ◽  
Data Set ◽  
Gaseous Elemental Mercury ◽  
Regional Sources ◽  
High Mercury

Atmospheric gaseous elemental mercury (GEM) and meteorological parameters were monitored at two sites in downtown Toronto, Canada from Oct. 2015 to Oct. 2016 using Tekran 2537A mercury vapour analyzers. The average concentration was found to be 1.78 ± 0.89 ng/m3 for Kerr Hall North (KHN) and 1.46 ± 0.54 ng/m3 for Jorgenson Hall (JOR) site. Analysis of the data reveals that sporadic events of high mercury concentration are related to local sources. Comparing this data set with that collected in 2004 revealed that the average atmospheric GEM concentration in downtown Toronto dropped from 4.5 ng/m3 to 1.78 ng/m3. Decreases in GEM were also observed over the same period in rural areas as measured by CAMNet. The decrease might be a result of policy change, as three key national and provincial environmental policies have been enacted since 2004. The data collected in Toronto suggest GEM concentration and distribution are influenced by local and regional sources, meteorological conditions, and changes in environmental policy.

scholarly journals Air Concentrations of Gaseous Elemental Mercury and Vegetation–Air Fluxes within Saltmarshes of the Tagus Estuary, Portugal

Atmosphere ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 228
Author(s):  
Rute Cesário ◽  
Nelson J. O’Driscoll ◽  
Sara Justino ◽  
Claire E. Wilson ◽  
Carlos E. Monteiro ◽  
...  
Keyword(s):  
Leaf Area ◽  
Elemental Mercury ◽  
Ambient Air ◽  
Tagus Estuary ◽  
Contaminated Site ◽  
Gaseous Elemental Mercury ◽  
Mercury Flux ◽  
Sarcocornia Fruticosa ◽  
Air Concentrations

In situ air concentrations of gaseous elemental mercury (Hg(0)) and vegetation–atmosphere fluxes were quantified in both high (Cala Norte, CN) and low-to-moderate (Alcochete, ALC) Hg-contaminated saltmarsh areas of the Tagus estuary colonized by plant species Halimione portulacoides (Hp) and Sarcocornia fruticosa (Sf). Atmospheric Hg(0) ranged between 1.08–18.15 ng m−3 in CN and 1.18–3.53 ng m−3 in ALC. In CN, most of the high Hg(0) levels occurred during nighttime, while the opposite was observed at ALC, suggesting that photoreduction was not driving the air Hg(0) concentrations at the contaminated site. Vegetation–air Hg(0) fluxes were low in ALC and ranged from −0.76 to 1.52 ng m−2 (leaf area) h−1 for Hp and from −0.40 to 1.28 ng m−2 (leaf area) h−1 for Sf. In CN, higher Hg fluxes were observed for both plants, ranging from −9.90 to 15.45 ng m−2 (leaf area) h−1 for Hp and from −8.93 to 12.58 ng m−2 (leaf area) h−1 for Sf. Mercury flux results at CN were considered less reliable due to large and fast variations in the ambient air concentrations of Hg(0), which may have been influenced by emissions from the nearby chlor-alkali plant, or historical contamination. Improved experimental setup, the influence of high local Hg concentrations and the seasonal activity of the plants must be considered when assessing vegetation–air Hg(0) fluxes in Hg-contaminated areas.

scholarly journals Occurrence of Volcanogenic Inorganic Mercury in Wild Mice Spinal Cord: Potential Health Implications

2021 ◽  
Author(s):  
A. Navarro-Sempere ◽  
M. García ◽  
A. S. Rodrigues ◽  
P. V. Garcia ◽  
R. Camarinho ◽  
...  
Keyword(s):  
Spinal Cord ◽  
Inorganic Mercury ◽  
Elemental Mercury ◽  
Potential Health ◽  
Wild Mice ◽  
Gaseous Elemental Mercury ◽  
Lumbar Level ◽  
Quantification Analysis ◽  
Spinal Cord Potential ◽  
Cord Potential

AbstractMercury accumulation has been proposed as a toxic factor that causes neurodegenerative diseases. However, the hazardous health effects of gaseous elemental mercury exposure on the spinal cord in volcanic areas have not been reported previously in the literature. To evaluate the presence of volcanogenic inorganic mercury in the spinal cord, a study was carried out in São Miguel island (Azores, Portugal) by comparing the spinal cord of mice exposed chronically to an active volcanic environment (Furnas village) with individuals not exposed (Rabo de Peixe village), through the autometallographic silver enhancement histochemical method. Moreover, a morphometric and quantification analysis of the axons was carried out. Results exhibited mercury deposits at the lumbar level of the spinal cord in the specimens captured at the site with volcanic activity (Furnas village). A decrease in axon calibre and axonal atrophy was also observed in these specimens. Given that these are relevant hallmarks in the neurodegenerative pathologies, our results highlight the importance of the surveillance of the health of populations chronically exposed to active volcanic environments.

scholarly journals Determinants of prepaid systems of healthcare financing: a worldwide country-level perspective

2021 ◽  
Author(s):  
Andrea M. Leiter ◽  
Engelbert Theurl
Keyword(s):  
Health Care ◽  
Panel Data ◽  
Health Care Financing ◽  
Value Added ◽  
The Elderly ◽  
Dynamic Panel Data ◽  
Individual Characteristics ◽  
Minor Importance ◽  
Data Set ◽  
Country Level

AbstractIn this paper we examine determinants of prepaid modes of health care financing in a worldwide cross-country perspective. We use three different indicators to capture the role of prepaid modes in health care financing: (i) the share of total prepaid financing as percent of total current health expenditures, (ii) the share of voluntary prepaid financing as percent of total prepaid financing, and (iii) the share of compulsory health insurance as percent of total compulsory prepaid financing. In the econometric analysis, we refer to a panel data set comprising 154 countries and covering the time period 2000–2015. We apply a static as well as a dynamic panel data model. We find that the current structure of prepaid financing is significantly determined by its different forms in the past. The significant influence of GDP per capita, governmental revenues, the agricultural value added, development assistance for health, degree of urbanization and regulatory quality varies depending on the financing structure we look at. The share of the elderly and the education level are only of minor importance for explaining the variation in a country’s share of prepaid health care financing. The importance of the mentioned variables as determinants for prepaid health care financing also varies depending on the countries’ socio-economic development. From our analysis we conclude that more detailed information on indicators which reflect the distribution of individual characteristics (such as income, family size and structure and health risks) within a country’s population would be needed to gain deeper insight into the decisive determinants for prepaid health care financing.

scholarly journals Simulation of atmospheric mercury depletion events (AMDEs) during polar springtime using the MECCA box model

2008 ◽  
Vol 8 (23) ◽  
pp. 7165-7180 ◽  
Author(s):  
Z.-Q. Xie ◽  
R. Sander ◽  
U. Pöschl ◽  
F. Slemr
Keyword(s):  
Aqueous Phase ◽  
Ozone Depletion ◽  
Elemental Mercury ◽  
Atmospheric Mercury ◽  
Box Model ◽  
Rate Coefficients ◽  
Mercury Species ◽  
Phase Reaction ◽  
Gaseous Elemental Mercury ◽  
Sea Salt Aerosol

Abstract. Atmospheric mercury depletion events (AMDEs) during polar springtime are closely correlated with bromine-catalyzed tropospheric ozone depletion events (ODEs). To study gas- and aqueous-phase reaction kinetics and speciation of mercury during AMDEs, we have included mercury chemistry into the box model MECCA (Module Efficiently Calculating the Chemistry of the Atmosphere), which enables dynamic simulation of bromine activation and ODEs. We found that the reaction of Hg with Br atoms dominates the loss of gaseous elemental mercury (GEM). To explain the experimentally observed synchronous depletion of GEM and O3, the reaction rate of Hg+BrO has to be much lower than that of Hg+Br. The synchronicity is best reproduced with rate coefficients at the lower limit of the literature values for both reactions, i.e. kHg+Br≈3×10−13 and kHg+BrO≤1×10−15 cm3 molecule−1 s−1, respectively. Throughout the simulated AMDEs, BrHgOBr was the most abundant reactive mercury species, both in the gas phase and in the aqueous phase. The aqueous-phase concentrations of BrHgOBr, HgBr2, and HgCl2 were several orders of magnitude larger than that of Hg(SO3)22−. Considering chlorine chemistry outside depletion events (i.e. without bromine activation), the concentration of total divalent mercury in sea-salt aerosol particles (mostly HgCl42−) was much higher than in dilute aqueous droplets (mostly Hg(SO3)22−), and did not exhibit a diurnal cycle (no correlation with HO2 radicals).

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