scholarly journals Mechanical Properties of Sandwich Composites Reinforced by Nanoclays: An Overview

2020 ◽  
Vol 10 (7) ◽  
pp. 2637
Author(s):  
João Parente ◽  
Paulo N. B. Reis ◽  
M. Neto ◽  
A. M. Amaro
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Exchange Capacity ◽  
Design Criteria ◽  
Sandwich Composites ◽  
Polymeric Nanocomposites ◽  
Ion Exchange Capacity ◽  
Acoustic Damping ◽  
Superior Mechanical Properties ◽  
Systematic Understanding

Structural sandwich composites have been widely used in many engineering applications, and this trend continues due to their superior mechanical properties, thermal insulation and acoustic damping. However, to further improve their mechanical properties, literature reports significant benefits obtained with nano-reinforcements. In this context, nanoclays are the most popular nano-reinforcements for polymeric nanocomposites, due to their relatively high ion exchange capacity, high aspect ratio and economic advantages. In order to stablish a systematic understanding for design criteria, this work intends to summarize all studies present in the open literature about this topic. It was possible to conclude that using nanoclays improves the mechanical properties of structural sandwich composites, especially in terms of impact strength. Nevertheless, the benefits obtained regarding fatigue performance are not adequately reported in the literature, revealing the need to develop these studies.

scholarly journals Graphene-based polymeric nano-composites: an introspection into functionalization, processing techniques and biomedical applications

2019 ◽  
Vol 9 (3) ◽  
pp. 3926-3933 ◽  
Keyword(s):  
Mechanical Properties ◽  
Biomedical Applications ◽  
Scientific Community ◽  
Polymeric Materials ◽  
Biomedical Domain ◽  
Polymeric Nanocomposites ◽  
Polymeric Matrices ◽  
Functional Capabilities ◽  
Superior Mechanical Properties ◽  
Processing Techniques

Although, there have been numerous efforts in synthesis of polymers, their mechanical properties have limited their applications. Graphene has been investigated for excellent properties such as superior mechanical properties, high thermal conductivity that has attracted the attention of scientific community to employ graphene as a filler material in polymeric matrices to form composites with multi-functional capabilities. The excellent properties possessed by Graphene has motivated users to fabricate flexible nanocomposites that can be used for applications requiring superior mechanical, chemical and thermal performances. Characteristics of both the components if explored synergistically through proper structural and interfacial organization. The investigation in this direction has resulted into combination of graphene with variety of polymeric materials and hence the development of different graphene-based nanocomposites. The present work reviews the application of graphene-based nanocomposites in the biomedical domain. With this objective, the polymeric matrices suitable for biomedical applications as well as the techniques of producing graphene polymeric nanocomposites have been discussed. Finally the application particularly in biosensing, wound healing and drug delivery system has been discussed.

Impact of Natural and Synthetic Nanofibres Presence in Polymeric Composites on Mechanical Properties

2014 ◽  
Vol 1613 ◽  
pp. 133-139 ◽  
Author(s):  
Martin Seidl ◽  
Jiří Bobek ◽  
Jiří Habr ◽  
Petr Lenfeld ◽  
Luboš Běhálek
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Coupling Agent ◽  
Flexural Modulus ◽  
Tensile Modulus ◽  
Polymeric Composites ◽  
Polymeric Nanocomposites ◽  
Cellulose Fibres ◽  
Three Phase ◽  
Natural And Synthetic

ABSTRACTThis study deals with evaluation of mechanical properties (tensile, flexural and impact strength), that verified reinforcing potential of nanofibres in polymeric composites and their applicability in dependence on the filler content of nanofibres of natural and synthetic origin. Considering the hydrophilic nature of natural nanofibres and hydrophobic polypropylene matrix was applied chemical modification that ensures effective interlock of nanofibres with the matrix, namely maleic anhydride grafted polypropylene and ionic modifier. Polymeric nanocomposites were prepared by twin screw extrusion that made possible mixing of all three components together. After cooling in water bath the composites were cut on pellets and dried for further injection moulding. The specimens were made of two- or three-phase component systems that included PP matrix, coupling agent in the volume of 4 wt.% and reinforcing nanofillers in the volume of 2, 4 and 6 wt.%. The presence of nanoparticles and coupling agents had not unambiguous impact on analysed mechanical properties. Coupling agent presence was dominant for impact strength, however, flexural and tensile properties were influenced mainly by the nanofiller type and origin. The dispersed phase and compatibilizer improved flexural modulus but tensile modulus of pure PP were not achieved by three-phase composite, not even with the highest analysed nanoparticle load. Cellulose fibres proved as more proper than the synthetic ones not only for their biodegradability and renewability but for their better toughness as well.

Radiation deterioration in mechanical properties and ion exchange capacity of Nafion N117 swelling in water

2008 ◽  
Vol 322 (1) ◽  
pp. 249-255 ◽  
Author(s):  
Yasunori Iwai ◽  
Akihiro Hiroki ◽  
Masao Tamada ◽  
Toshihiko Yamanishi
Keyword(s):  
Mechanical Properties ◽  
Ion Exchange ◽  
Exchange Capacity ◽  
Ion Exchange Capacity

Metallic Nanoneedles Arrays for TEM Sample Preparation “Lift-Out”

2012 ◽  
Author(s):  
Romaneh Jalilian ◽  
David Mudd ◽  
Neil Torrez ◽  
Jose Rivera ◽  
Mehdi M. Yazdanpanah ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Electron Microscope ◽  
Sample Preparation ◽  
Focused Ion Beam ◽  
Ion Beam ◽  
Beam System ◽  
Transmission Electron ◽  
Nanoneedle Array ◽  
Superior Mechanical Properties ◽  
And Performance

Abstract The sample preparation for transmission electron microscope can be done using a method known as "lift-out". This paper demonstrates a method of using a silver-gallium nanoneedle array for a quicker sharpening process of tungsten probes with better sample viewing, covering the fabrication steps and performance of needle-tipped probes for lift-out process. First, an array of high aspect ratio silver-gallium nanoneedles was fabricated and coated to improve their conductivity and strength. Then, the nanoneedles were welded to a regular tungsten probe in the focused ion beam system at the desired angle, and used as a sharp probe for lift-out. The paper demonstrates the superior mechanical properties of crystalline silver-gallium metallic nanoneedles. Finally, a weldless lift-out process is described whereby a nano-fork gripper was fabricated by attaching two nanoneedles to a tungsten probe.

Morphology and Mechanical Properties of Polyethylene Terephthalate/Ethylene Propylene Diene Monomer (PET/EPDM) in the Presence of Nanoclay

2020 ◽  
Vol 57 (3) ◽  
pp. 249-259
Author(s):  
Baifen Liu ◽  
Mohammad Mirjalili ◽  
Peiman Valipour ◽  
Sajad Porzal ◽  
shirin Nourbakhsh
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Thermal Destruction ◽  
Processing Temperature ◽  
Tem Analysis ◽  
Maximum Stiffness ◽  
Cloisite 30B ◽  
Nano Clay ◽  
The Matrix ◽  
Sample Maximum

This research deals with the mechanical properties, microstructure, and interrelations of triple nanocomposite based on PET/EPDM/Nanoclay. These properties were examined in different percentages of PET/EPDM blend with compatibilizer (Styrene-Ethylene/Butylene-Styrene)-G-(Maleic anhydrate) (SEBS-g-MAH). Results showed that the addition of 15% SEBS-g-MAH improved the toughness and impact strength of this nanocomposite. SEM micrographs indicated the most stable fuzzy microstructure in a 50/50 mixture of scattered phases of EPDM/SEBS-g-MAH. The effects of percentages of 1, 3, 5, 7 nanoclay Cloisite 30B (C30B) on the improvement of the properties were evaluated. With the addition of nano clay, the toughness and impact strength was reduced. Thermal destruction of nanoclay in processing temperature led to the decreasing dispersion of clay plates in the matrix and a reduction in the distances of nano clay plates in the composite compared to pure nano clay. XRD and TEM analysis was used to demonstrate the results. By adding 1% of nanoclay to the optimal sample, maximum stiffness, and Impact strength, among other nanocomposites, was achieved.

Equilibrium Sorptions in Heterogeneous Ion Exchange Membranes

1992 ◽  
Vol 57 (9) ◽  
pp. 1905-1914
Author(s):  
Miroslav Bleha ◽  
Věra Šumberová
Keyword(s):  
Experimental Data ◽  
Ion Exchange ◽  
Total Content ◽  
Distribution Coefficients ◽  
Exchange Capacity ◽  
Ion Exchange Membranes ◽  
Ion Exchange Capacity ◽  
Equilibrium Sorption ◽  
Inhomogeneity Factor

The equilibrium sorption of uni-univalent electrolytes (NaCl, KCl) in heterogeneous cation exchange membranes with various contents of the ion exchange component and in ion exchange membranes Ralex was investigated. Using experimental data which express the concentration dependence of equilibrium sorption, validity of the Donnan relation for the systems under investigation was tested and values of the Glueckauf inhomogeneity factor for Ralex membranes were determined. Determination of the equilibrium sorption allows the effect of the total content of internal water and of the ion-exchange capacity on the distribution coefficients of the electrolyte to be determined.

Effect of Dynamic Crosslinking on Mechanical Properties of PP/EPDM Blends

1993 ◽  
Vol 58 (11) ◽  
pp. 2642-2650 ◽  
Author(s):  
Zdeněk Kruliš ◽  
Ivan Fortelný ◽  
Josef Kovář
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Shear Modulus ◽  
High Impact ◽  
Necessary Condition ◽  
Step Method ◽  
Melt Mixing ◽  
One Step ◽  
High Impact Strength ◽  
Dynamic Curing

The effect of dynamic curing of PP/EPDM blends with sulfur and thiuram disulfide systems on their mechanical properties was studied. The results were interpreted using the knowledge of the formation of phase structure in the blends during their melt mixing. It was shown, that a sufficiently slow curing reaction is necessary if a high impact strength is to be obtained. Only in such case, a fine and homogeneous dispersion of elastomer can be formed, which is the necessary condition for high impact strength of the blend. Using an inhibitor of curing in the system and a one-step method of dynamic curing leads to an increase in impact strength of blends. From the comparison of shear modulus and impact strength values, it follows that, at the stiffness, the dynamically cured blends have higher impact strength than the uncured ones.

Mechanical Property Improvement of Poly(Butylene Succinate) by Reinforcing with Modified Fumed Silica

2014 ◽  
Vol 1025-1026 ◽  
pp. 215-220 ◽  
Author(s):  
Sasirada Weerasunthorn ◽  
Pranut Potiyaraj
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Flexural Strength ◽  
Fumed Silica ◽  
Tensile Modulus ◽  
Silica Particles ◽  
Melt Mixing ◽  
Butylene Succinate ◽  
Ir Spectrophotometry

Fumed silica particles (SiO2) were directly added into poly (butylene succinate) (PBS) by melt mixing process. The effects of amount of fumed silica particles on mechanical properties of PBS/fumed silica composites, those are tensile strength, tensile modulus, impact strength as well as flexural strength, were investigated. It was found that the mechanical properties decreased with increasing fumed silica loading (0-3 wt%). In order to increase polymer-filler interaction, fumed silica was treated with 3-glycidyloxypropyl trimethoxysilane (GPMS), and its structure was analyzed by FT-IR spectrophotometry. The PBS/modified was found to possess better tensile strength, tensile modulus, impact strength and flexural strength that those of PBS/fumed silica composites.

scholarly journals A Generalized Approach for Evaluating the Mechanical Properties of Polymer Nanocomposites Reinforced with Spherical Fillers

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 830
Author(s):  
Julio Cesar Martinez-Garcia ◽  
Alexandre Serraïma-Ferrer ◽  
Aitor Lopeandía-Fernández ◽  
Marco Lattuada ◽  
Janak Sapkota ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Polymeric Nanocomposites ◽  
Mechanical Reinforcement ◽  
Future Studies ◽  
Three Phase ◽  
Theoretical Predictions ◽  
Filler Network ◽  
New Research ◽  
Good Agreement ◽  
Research Avenue

In this work, the effective mechanical reinforcement of polymeric nanocomposites containing spherical particle fillers is predicted based on a generalized analytical three-phase-series-parallel model, considering the concepts of percolation and the interfacial glassy region. While the concept of percolation is solely taken as a contribution of the filler-network, we herein show that the glassy interphase between filler and matrix, which is often in the nanometers range, is also to be considered while interpreting enhanced mechanical properties of particulate filled polymeric nanocomposites. To demonstrate the relevance of the proposed generalized equation, we have fitted several experimental results which show a good agreement with theoretical predictions. Thus, the approach presented here can be valuable to elucidate new possible conceptual routes for the creation of new materials with fundamental technological applications and can open a new research avenue for future studies.

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