scholarly journals Surface, Volumetric, and Wetting Properties of Oleic, Linoleic, and Linolenic Acids with Regards to Application of Canola Oil in Diesel Engines

2019 ◽  
Vol 9 (17) ◽  
pp. 3445 ◽  
Author(s):  
Anna Zdziennicka ◽  
Katarzyna Szymczyk ◽  
Bronisław Jańczuk ◽  
Rafał Longwic ◽  
Przemysław Sander
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Diesel Engines ◽  
Canola Oil ◽  
Contact Angles ◽  
Physiochemical Properties ◽  
Engine Valve ◽  
Wetting Properties ◽  
Main Components ◽  
Adhesion Work

Oleic, linoleic, and linolenic acids are the main components of canola oil and their physiochemical properties decide on the use of canola oil as fuel for diesel engines. Therefore, the measurements of the surface tension of oleic, linoleic, and linolenic acids being the components of the canola oil, as well as their contact angles on the polytetrafluoroethylene (PTFE), poly(methyl methacrylate) (PMMA), and engine valve, were made. Additionally, the surface tension and contact angle on PTFE, PMMA, and the engine valve of the oleic acid and n-hexane mixtures were measured. On the basis of the obtained results, the components and parameters of oleic, linoleic, and linolenic acids’ surface tension were determined and compared to those of the canola oil. Next, applying the components and parameters of these acids, their adhesion work to PTFE, PMMA, and the engine valve was calculated by means of various methods.

scholarly journals Influence of moisture content on the contact angle and surface tension measured on birch wood surfaces

2021 ◽  
Author(s):  
Rami Benkreif ◽  
Fatima Zohra Brahmia ◽  
Csilla Csiha
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Moisture Content ◽  
Solid Wood ◽  
Contact Angles ◽  
Surface Moisture ◽  
Wood Coatings ◽  
The Relationship ◽  
Wood Surfaces

AbstractSurface tension of solid wood surfaces affects the wettability and thus the adhesion of various adhesives and wood coatings. By measuring the contact angle of the wood, the surface tension can be calculated based on the Young-Dupré equation. Several publications have reported on contact angle measured with different test liquids, under different conditions. Results can only be compared if the test conditions are similar. While the roles of the drop volume, image shooting time etc., are widely recognized, the role of the wood surface moisture content (MC) is not evaluated in detail. In this study, the effect of wood moisture content on contact angle values, measured with distilled water and diiodomethane, on sanded birch (Betula pendula) surfaces was investigated, in order to find the relationship between them. With increasing MC from approximately 6% to 30%, increasing contact angle (decreasing surface tension) values were measured according to a logarithmic function. The function makes possible the calculation of contact angles that correspond to different MCs.

scholarly journals Experimental Investigation of Coal Dust Wettability Based on Surface Contact Angle

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Gang Zhou ◽  
Han Qiu ◽  
Qi Zhang ◽  
Mao Xu ◽  
Jiayuan Wang ◽  
...  
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Specific Surface ◽  
Coal Dust ◽  
Single Point ◽  
Contact Angles ◽  
Critical Surface ◽  
Volume Percentage ◽  
Surface Areas ◽  
Specific Surface Areas

Wettability is one of the key chemical properties of coal dust, which is very important to dedusting. In this paper, the theory of liquid wetting solid was presented firstly; then, taking the gas coal of Xinglongzhuang coal mine in China as an example, by determination of critical surface tension of coal piece, it can be concluded that only when the surface tension of surfactant solution is less than 45 mN/m can the coal sample be fully wetted. Due to the effect of particle dispersity, compared with the contact angle of milled coal particle, not all the contact angles of screened coal powder with different sizes have a tendency to increase. Furthermore, by the experiments of coal samples’ specific surface areas and porosities, it can be achieved that the volume of single-point total pore decreases with the gradual decreasing of coal’s porosity, while the ultramicropores’ dispersities and multipoint BET specific surface areas increase. Besides, by a series of contact angle experiments with different surfactants, it can be found that with the increasing of porosity and the decreasing of volume percentage of ultramicropore, the contact angle tends to reduce gradually and the coal dust is much easier to get wetted.

Investigation of Pool Boiling Critical Heat Flux Enhancement on a Modified Surface Through the Dynamic Wetting of Water Droplets

2012 ◽  
Vol 134 (7) ◽  
Author(s):  
Ho Seon Ahn ◽  
Joonwon Kim ◽  
Moo Hwan Kim
Keyword(s):  
Surface Tension ◽  
Heat Flux ◽  
Contact Angle ◽  
Critical Heat Flux ◽  
Pool Boiling ◽  
Water Layer ◽  
Contact Angles ◽  
Water Droplets ◽  
Dynamic Wetting ◽  
Modified Surface

Dynamic wetting behaviors of water droplet on the modified surface were investigated experimentally. Dynamic contact angles were measured as a characterization method to explain the extraordinary pool boiling critical heat flux (CHF) enhancement on the zirconium surface by anodic oxidation modification. The sample surface is rectangular zirconium alloy plates (20 × 25 × 0.7 mm), and 12 μl of deionized water droplets were fallen from 40 mm of height over the surface. Dynamic wetting movement of water on the surface showed different characteristics depending on static contact angle (49.3 deg–0 deg) and surface temperature (120 °C–280 °C). Compared with bare surface, wettable and spreading surface had no-receding contact angle jump and seemed stable evaporating meniscus of liquid droplet in dynamic wetting condition on hot surface. This phenomenon could be explained by the interaction between the evaporation recoil and the surface tension forces. The surface tension force increased by micro/nanostructure of the modified zirconium surface suppresses the vapor recoil force by evaporation which makes the water layer unstable on the heated surface. Thus, such increased surface force could sustain the water layer stable in pool boiling CHF condition so that the extraordinary CHF enhancement could be possible.

scholarly journals Amphiphobic Nanostructured Coatings for Industrial Applications

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 787 ◽  
Author(s):  
Federico Veronesi ◽  
Giulio Boveri ◽  
Mariarosa Raimondo
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Photoelectron Spectroscopy ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Friction Reduction ◽  
Hybrid Coatings ◽  
Wetting Behavior ◽  
Wide Range ◽  
Solid Liquid

The search for surfaces with non-wetting behavior towards water and low-surface tension liquids affects a wide range of industries. Surface wetting is regulated by morphological and chemical features interacting with liquid phases under different ambient conditions. Most of the approaches to the fabrication of liquid-repellent surfaces are inspired by living organisms and require the fabrication of hierarchically organized structures, coupled with low surface energy chemical composition. This paper deals with the design of amphiphobic metals (AM) and alloys by deposition of nano-oxides suspensions in alcoholic or aqueous media, coupled with perfluorinated compounds and optional infused lubricant liquids resulting in, respectively, solid–liquid–air and solid–liquid–liquid working interfaces. Nanostructured organic/inorganic hybrid coatings with contact angles against water above 170°, contact angle with n-hexadecane (surface tension γ = 27 mN/m at 20 °C) in the 140–150° range and contact angle hysteresis lower than 5° have been produced. A full characterization of surface chemistry has been undertaken by X-ray photoelectron spectroscopy (XPS) analyses, while field-emission scanning electron microscope (FE-SEM) observations allowed the estimation of coatings thicknesses (300–400 nm) and their morphological features. The durability of fabricated amphiphobic surfaces was also assessed with a wide range of tests that showed their remarkable resistance to chemically aggressive environments, mechanical stresses and ultraviolet (UV) radiation. Moreover, this work analyzes the behavior of amphiphobic surfaces in terms of anti-soiling, snow-repellent and friction-reduction properties—all originated from their non-wetting behavior. The achieved results make AM materials viable solutions to be applied in different sectors answering several and pressing technical needs.

Spreading-Droplet Simulation With Surface Tension Model Using Inter-Particle Force in Particle Method

2013 ◽  
Author(s):  
Eiji Ishii ◽  
Taisuke Sugii
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Dynamic Contact Angle ◽  
Particle Method ◽  
Dynamic Contact ◽  
Contact Angles ◽  
Particle Methods ◽  
Static Contact ◽  
Particle Force ◽  
Surface Tension Model

Predicting the spreading behavior of droplets on a wall is important for designing micro/nano devices used for reagent dispensation in micro-electro-mechanical systems, printing processes of ink-jet printers, and condensation of droplets on a wall during spray forming in atomizers. Particle methods are useful for simulating the behavior of many droplets generated by micro/nano devices in practical computational time; the motion of each droplet is simulated using a group of particles, and no particles are assigned in the gas region if interactions between the droplets and gas are weak. Furthermore, liquid-gas interfaces obtained from the particle method remain sharp by using the Lagrangian description. However, conventional surface tension models used in the particle methods are used for predicting the static contact angle at a three-phase interface, not for predicting the dynamic contact angle. The dynamic contact angle defines the shape of a spreading droplet on a wall. We previously developed a surface tension model using inter-particle force in the particle method; the static contact angle of droplets on the wall was verified at various contact angles, and the heights of droplets agreed well with those obtained theoretically. In this study, we applied our surface tension model to the simulation of a spreading droplet on a wall. The simulated dynamic contact angles for some Weber numbers were compared with those measured by Šikalo et al, and they agreed well. Our surface tension model was useful for simulating droplet motion under static and dynamic conditions.

Measurements of the Contact Angles for Various Fluids Which Are Widely Used in the Oilfields to Improve Oil Recovery

2018 ◽  
Author(s):  
M. Elsharafi ◽  
K. Vidal ◽  
R. Thomas
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Dynamic Contact Angle ◽  
Dynamic Contact ◽  
Contact Angles ◽  
Rock Face ◽  
Angle Measurements ◽  
Contact Angle Measurements

Contact angle measurements are important to determine surface and interfacial tension between solids and fluids. A ‘water-wet’ condition on the rock face is necessary in order to extract oil. In this research, the objectives are to determine the wettability (water-wet or oil-wet), analyze how different brine concentrations will affect the wettability, and study the effect of the temperature on the dynamic contact angle measurements. This will be carried out by using the Cahn Dynamic Contact Angle. Analyzer DCA 315 to measure the contact angle between different fluids such as surfactant, alkaline, and mineral oil. This instrument is also used to measure the surface properties such as surface tension, contact angle, and interfacial tension of solid and liquid samples by using the Wilhelmy technique. The work used different surfactant and oil mixed with different alkaline concentrations. Varying alkaline concentrations from 20ml to 1ml were used, whilst keeping the surfactant concentration constant at 50ml.. It was observed that contact angle measurements and surface tension increase with increased alkaline concentrations. Therefore, we can deduce that they are directly proportional. We noticed that changing certain values on the software affected our results. It was found that after calculating the density and inputting it into the CAHN software, more accurate readings for the surface tension were obtained. We anticipate that the surfactant and alkaline can change the surface tension of the solid surface. In our research, surfactant is desirable as it maintains a high surface tension even when alkaline percentage is increased.

scholarly journals Surface tension and wetting properties of rapeseed oil to biofuel conversion by-products

2018 ◽  
Vol 32 (2) ◽  
pp. 247-252 ◽  
Author(s):  
Siemowit Muszyński ◽  
Agnieszka Sujak ◽  
Andrzej Stępniewski ◽  
Krzysztof Kornarzyński ◽  
Marta Ejtel ◽  
...  
Keyword(s):  
Surface Tension ◽  
Physical Properties ◽  
Rapeseed Oil ◽  
Contact Angles ◽  
Biofuel Production ◽  
Technical Grade ◽  
Accurate Analysis ◽  
Wetting Properties ◽  
Fuel Blends ◽  
By Products

AbstractThis work presents a study on the surface tension, density and wetting behaviour of distilled glycerol, technical grade glycerol and the matter organic non-glycerin fraction. The research was conducted to expand the knowledge about the physical properties of wastes from the rapeseed oil biofuel production. The results show that the densities of technical grade glycerol (1.300 g cm-3) and distilled glycerol (1.267 g cm-3) did not differ and were significantly lower than the density of the matter organic non-glycerin fraction (1.579 g cm-3). Furthermore, the surface tension of distilled glycerol (49.6 mN m-1) was significantly higher than the matter organic non-glycerin fraction (32.7 mN m-1) and technical grade glycerol (29.5 mN m-1). As a result, both technical grade glycerol and the matter organic non-glycerin fraction had lower contact angles than distilled glycerol. The examined physical properties of distilled glycerol were found to be very close to that of the commercially available pure glycerol. The results suggest that technical grade glycerol may have potential application in the production of glycerol/fuel blends or biosurfactants. The presented results indicate that surface tension measurements are more useful when examining the quality of biofuel wastes than is density determination, as they allow for a more accurate analysis of the effects of impurities on the physical properties of the biofuel by-products.

scholarly journals Does the Use of Adjuvants Alter Surface Tension and Contact Angle of Herbicide Spray Droplets on Leaves of Sida spp.?

2019 ◽  
Vol 37 ◽  
Author(s):  
R.T.S. SANTOS ◽  
M.C. FERREIRA ◽  
R.G. VIANA
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Contact Angles ◽  
Control Surface ◽  
Droplet Spreading ◽  
Spray Solution ◽  
Randomized Design ◽  
Plant Surfaces ◽  
Sida Rhombifolia ◽  
Lower Contact

ABSTRACT: Droplet spreading on plant surfaces may indicate greater efficiency in herbicide application. The aim of this study was to evaluate surface tension and contact angle of the aminopyralid + fluroxypir herbicide droplets associated with adjuvants on the leaf surface of three species of the genus Sida. The experiment was carried out in a completely randomized design, in a 4x2+1 factorial arrangement, with four replications. Four treatments containing two rates of the herbicide (0.04 + 0.08 kg a.i. ha-1 and 0.08+0.16 kg a.i. ha-1) were evaluated, associated or not with the adjuvants vegetable oil, mineral oil and lecthin; and water was used as a control. Surface tension and contact angle of the syringes were measured with a tensiometer. Surface tension was evaluated at 5, 15 and 25 seconds after droplet formation. Contact angle was measured at 5, 15 and 25 seconds after droplet deposition on the adaxial and abaxial surfaces of Sida rhombifolia, S. glaziovii and S. cordifolia. The results were submitted to analysis of variance by the F-test and the means of the treatments were compared by Tukey’s test (p>0.05). There was no interaction between the factors for surface tension. The contact angles of S. cordifolia and S. glaziovii were lower after addition of lecthin on the adaxial face. The addition of the adjuvants to the spray solution provided lower contact angles at the rate of 0.04 + 0.08 kg a.i. ha-1, except for S. rhombifolia, whose contact angle was lower with the spray solution without adjuvant.

scholarly journals Role of Intermolecular Forces on the Contact Angle of Vegetable Oil Droplets during the Cooling Process

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Muhammad Akhlis Rizza ◽  
Widya Wijayanti ◽  
Nurkholis Hamidi ◽  
I. N. G. Wardana
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Hydrogen Bonds ◽  
Vegetable Oil ◽  
Intermolecular Forces ◽  
Contact Angles ◽  
Droplet Surface ◽  
Water Molecules ◽  
Oil Droplets

This study aims to experimentally determine the role of intermolecular forces on the contact angle of vegetable oil droplets. Contact angles were recorded using a microscope and measured using digital software. The results show that the surface tension of vegetable oils is influenced by the London force between the electron clouds of molecules. The process of cooling increases vegetable oil contact angles, due to the decreased kinetic energy of constituent molecules and increased London force on the molecules. A decrease in temperature causes the surrounding water vapor to condense, which adheres to the droplet surface (due to the hydrophilic properties of molecules). Hydrogen bonds develop after moisture adheres to the surface. Further, water molecules on the droplet surface reduce the surface tension, because of hydrogen bonds between the molecules on the droplet surface and moisture. Hydrogen bonds among the molecules force water molecules to accumulate on the droplet surface, which suppresses the droplet surface; therefore the contact angle decreases.

The Wetting of Insect Cuticles by Water

1955 ◽  
Vol 32 (3) ◽  
pp. 591-617 ◽  
Author(s):  
M. W. HOLDGATE
Keyword(s):  
Surface Roughness ◽  
Contact Angle ◽  
Surface Properties ◽  
Surface Composition ◽  
Contact Angles ◽  
Aquatic Species ◽  
Water Contact ◽  
Calliphora Erythrocephala ◽  
Wetting Properties ◽  
Wide Range

1. The water contact angles of insects show a wide range of variation, which is broadly correlated with surface roughness and with habitat. 2. The contact angles of species inhabiting stored products or carrion are greatly modified by contamination. This produces large variations between apparently similar individuals. 3. In terrestrial insects surface roughness increases the contact angles to very large apparent values. Detailed analyses of its effect have been made in the pupa of Tenebrio molitor and the adult Calliphora erythrocephala. In some aquatic insects surface roughness leads to a reduction in the contact angles; this has been studied in the nymph of Anax imperator. 4. Prolonged immersion in water causes a lowering of the contact angles of all the insects examined, and the low angles of many aquatic species may therefore be the direct effect of their environment. In some aquatic species there is evidence of the active maintenance of a large contact angle during life. 5. Changes in contact angle accompany processes of cuticle secretion and will occur at any moult if changes in roughness or habitat take place. 6. The observed variations of surface properties can be explained without assuming any variation in the chemical composition of the cuticle surface. Wetting properties are of little value as indicators of cuticle surface composition. 7. The biological aspects of insect surface properties are briefly discussed.

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