scholarly journals Progress on Modified Calcium Oxide Derived Waste-Shell Catalysts for Biodiesel Production

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 194
Author(s):  
Hui Khim Ooi ◽  
Xin Ning Koh ◽  
Hwai Chyuan Ong ◽  
Hwei Voon Lee ◽  
Mohd Sufri Mastuli ◽  
...  
Keyword(s):  
Alternative Energy ◽  
Recent Progress ◽  
Environmental Issues ◽  
Industrial Sector ◽  
Critical Discussion ◽  
Biodiesel Production ◽  
Catalyst Stability ◽  
Animal Fat ◽  
Waste Shell ◽  
Catalytic Reactivity

The dwindling of global petroleum deposits and worsening environmental issues have triggered researchers to find an alternative energy such as biodiesel. Biodiesel can be produced via transesterification of vegetable oil or animal fat with alcohol in the presence of a catalyst. A heterogeneous catalyst at an economical price has been studied widely for biodiesel production. It was noted that various types of natural waste shell are a potential calcium resource for generation of bio-based CaO, with comparable chemical characteristics, that greatly enhance the transesterification activity. However, CaO catalyzed transesterification is limited in its stability and studies have shown deterioration of catalytic reactivity when the catalyst is reused for several cycles. For this reason, different approaches are reviewed in the present study, which focuses on modification of waste-shell derived CaO based catalyst with the aim of better transesterification reactivity and high reusability of the catalyst for biodiesel production. The catalyst stability and leaching profile of the modified waste shell derived CaO is discussed. In addition, a critical discussion of the structure, composition of the waste shell, mechanism of CaO catalyzed reaction, recent progress in biodiesel reactor systems and challenges in the industrial sector are also included in this review.

scholarly journals Advances in Enzyme and Ionic Liquid Immobilization for Enhanced in MOFs for Biodiesel Production

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3512
Author(s):  
Reem Shomal ◽  
Babatunde Ogubadejo ◽  
Toyin Shittu ◽  
Eyas Mahmoud ◽  
Wei Du ◽  
...  
Keyword(s):  
Organic Ligands ◽  
Biodiesel Production ◽  
Catalyst Stability ◽  
Promising Candidate ◽  
Catalytic Systems ◽  
Highly Porous Materials ◽  
High Tunability ◽  
Catalytic Sites ◽  
Metal Organic ◽  
Highly Porous

Biodiesel is a promising candidate for sustainable and renewable energy and extensive research is being conducted worldwide to optimize its production process. The employed catalyst is an important parameter in biodiesel production. Metal–organic frameworks (MOFs), which are a set of highly porous materials comprising coordinated bonds between metals and organic ligands, have recently been proposed as catalysts. MOFs exhibit high tunability, possess high crystallinity and surface area, and their order can vary from the atomic to the microscale level. However, their catalytic sites are confined inside their porous structure, limiting their accessibility for biodiesel production. Modification of MOF structure by immobilizing enzymes or ionic liquids (ILs) could be a solution to this challenge and can lead to better performance and provide catalytic systems with higher activities. This review compiles the recent advances in catalytic transesterification for biodiesel production using enzymes or ILs. The available literature clearly indicates that MOFs are the most suitable immobilization supports, leading to higher biodiesel production without affecting the catalytic activity while increasing the catalyst stability and reusability in several cycles.

scholarly journals The Recent Progress of Natural Sources and Manufacturing Process of Biodiesel: A Review

2021 ◽  
Vol 13 (10) ◽  
pp. 5599
Author(s):  
Eko Supriyanto ◽  
Jayan Sentanuhady ◽  
Ariyana Dwiputra ◽  
Ari Permana ◽  
Muhammad Akhsin Muflikhun
Keyword(s):  
Recent Progress ◽  
Review Paper ◽  
Ghg Emissions ◽  
Production Method ◽  
Biodiesel Production ◽  
Natural Sources ◽  
Harmful Emissions ◽  
Daily Energy ◽  
The Cost ◽  
Selection Of

Biodiesel has caught the attention of many researchers because it has great potential to be a sustainable fossil fuel substitute. Biodiesel has a non-toxic and renewable nature and has been proven to emit less environmentally harmful emissions such as hydrocarbons (HC), and carbon monoxide (CO) as smoke particles during combustion. Problems related to global warming caused by greenhouse gas (GHG) emissions could also be solved by utilizing biodiesel as a daily energy source. However, the expensive cost of biodiesel production, mainly because of the cost of natural feedstock, hinders the potential of biodiesel commercialization. The selection of natural sources of biodiesel should be made with observations from economic, agricultural, and technical perspectives to obtain one feasible biodiesel with superior characteristics. This review paper presents a detailed overview of various natural sources, their physicochemical properties, the performance, emission, and combustion characteristics of biodiesel when used in a diesel engine. The recent progress in studies about natural feedstocks and manufacturing methods used in biodiesel production were evaluated in detail. Finally, the findings of the present work reveal that transesterification is currently the most superior and commonly used biodiesel production method compared to other methods available.

scholarly journals Physical Methods of Microalgal Biomass Pretreatment

2014 ◽  
Vol 28 (3) ◽  
pp. 341-348 ◽  
Author(s):  
Agata Piasecka ◽  
Izabela Krzemińska ◽  
Jerzy Tys
Keyword(s):  
Alternative Energy ◽  
Lipid Extraction ◽  
Physical Method ◽  
Extraction Methods ◽  
Biodiesel Production ◽  
Biomass Pretreatment ◽  
Microalgal Biomass ◽  
Alternative Energy Sources ◽  
Wet Biomass ◽  
Microwave Techniques

Abstract The prospect of depletion of natural energy resources on the Earth forces researchers to seek and explore new and alternative energy sources. Biomass is a composite resource that can be used in many ways leading to diversity of products. Therefore, microalgal biomass offers great potential. The main aim of this study is to find the best physical method of microalgal biomass pretreatment that guarantees efficient lipid extraction. These studies identifies biochemical composition of microalgal biomass as source for biodisel production. The influence of drying at different temperatures and lyophilization was investigated. In addition, wet and untreated biomass was examined. Cell disruption (sonication and microwave) techniques were used to improve lipid extraction from wet biomass. Additionally, two different extraction methods were carried out to select the best method of crude oil extraction. The results of this study show that wet biomass after sonication is the most suitable for extraction. The fatty acid composition of microalgal biomass includes linoleic acid (C18:2), palmitic acid (C16:0), oleic acid (C18:1), linolenic acid (C18:3), and stearic acid (C18:0), which play a key role in biodiesel production.

scholarly journals Box-Behnken Design for Optimization on Biodiesel Production from Palm Oil and Methyl Acetate using Ultrasound Assisted Interesterification Method

2021 ◽  
Author(s):  
Mahfud Mahfud ◽  
Ansori Ansori
Keyword(s):  
Palm Oil ◽  
Energy Demand ◽  
Alternative Energy ◽  
Methyl Acetate ◽  
Catalyst Concentration ◽  
Separation Process ◽  
Operating Conditions ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Box Behnken Design

Energy demand is currently increasing in line with technological and economic developments, but not accompanied by an increase in energy reserves. So we need another alternative energy that can be renewed, namely biodiesel. Biodiesel has been produced commercially through the transesterification from vegetable oil with methanol using catalyst that produces esters and glycerol. The formation of glycerol which is by-product can reduce its economic value, so it needs to be done the separation process. Therefore, a new route is proposed in this study, namely the interesterification reaction (non-alcoholic route) using methyl acetate as an alkyl group supplier and potassium methoxide catalyst. The superiority of the product produced by the interesterification reaction is biodiesel with triacetin byproducts which have an economical value and can be added to biodiesel formulations because of their solubility so that no side product separation process is needed. To increase the yield of biodiesel and the interesterification rate, the ultrasound method was used in this study. To optimize the factors that affect the interesterification reaction (molar ratio of methyl acetate to oil, catalyst concentration, temperature, and interesterification time), the Box-Behnken design (BBD) is used. Optimal operating conditions to produce the yields of biodiesel of 98.64 % are at molar ratio of methyl acetate to palm oil of 18.74, catalyst concentration of 1.24 %, temperature of 57.84 °C, and interesterification time of 12.69 minutes.

scholarly journals Animal Fat Wastes for Biodiesel Production

10.5772/26691 ◽  
2011 ◽  
Author(s):  
Vivian Feddern ◽  
Anildo Cunha ◽  
Marina Celant De Pra ◽  
Paulo Giovanni de Abreu ◽  
Jonas Irineu dos Santos Filho ◽  
...  
Keyword(s):  
Biodiesel Production ◽  
Animal Fat

scholarly journals Production of biodiesel from Annona muricata seeds

2019 ◽  
Vol 90 ◽  
pp. 01011 ◽  
Author(s):  
Wai-Leong Wong ◽  
Waye-Hong Lim ◽  
Jet Si ◽  
Man-Kee Lam ◽  
Yeek-Chia Ho
Keyword(s):  
Factorial Design ◽  
Potassium Hydroxide ◽  
Alternative Fuels ◽  
Calorific Value ◽  
Environmental Issues ◽  
Raw Material ◽  
Biodiesel Production ◽  
Fuel Quality ◽  
Annona Muricata ◽  
Temperature Time

Biodiesel is one of the effective alternative fuels to overcome the problems associated with environmental issues and energy crisis. However, the production of biodiesel from edible oil has provoked the food versus fuel dispute. Thus, a non-edible crop, Annona muricata, is selected as the raw material to produce oil for biodiesel production. In this study, A. muricata oil was extracted with n-hexane at 70 °C for 6 h. Subsequently, the oil was transesterified with methanol and potassium hydroxide (KOH) to produce biodiesel. The significance of transesterification parameters including temperature, time, catalyst concentration, and oil-to-methanol ratio on biodiesel yield (%) was established through two-level factorial design. The factorial design shows that all parameters are significant. Besides, the high content of monounsaturated fatty acid (oleic acid) in the resultant biodiesel suggests that A. muricata biodiesel could display good fuel quality. This hypothesis is proven by the excellent calorific value (39.21 MJ kg-1).

scholarly journals Widely used catalysts in biodiesel production: a review

RSC Advances ◽  
2020 ◽  
Vol 10 (68) ◽  
pp. 41625-41679
Author(s):  
Bishwajit Changmai ◽  
Chhangte Vanlalveni ◽  
Avinash Prabhakar Ingle ◽  
Rahul Bhagat ◽  
Lalthazuala Rokhum
Keyword(s):  
Energy Demand ◽  
Alternative Energy ◽  
Fossil Fuels ◽  
Fossil Fuel ◽  
Environmental Problems ◽  
Biodiesel Production

An ever-increasing energy demand and environmental problems associated with exhaustible fossil fuels have led to the search for an alternative energy. In this context, biodiesel has attracted attention worldwide as an alternative to fossil fuel.

scholarly journals Effect of crude glycerol on in-vitro ruminal fermentation kinetics

2014 ◽  
Vol 15 (1) ◽  
pp. 172-181 ◽  
Author(s):  
Vanessa Peripolli ◽  
Ênio Rosa Prates ◽  
Júlio Otávio Jardim Barcellos ◽  
Cássio André Wilbert ◽  
Cláudia Medeiros Camargo ◽  
...  
Keyword(s):  
Alternative Energy ◽  
Crude Glycerol ◽  
Energy Content ◽  
Metabolizable Energy ◽  
Neutral Detergent Fiber ◽  
Biodiesel Production ◽  
In Vitro Digestibility ◽  
Ruminal Fermentation

The interest in using crude glycerol in animal feeding has reemerged due to its increasing availability and favorable price resulting from the expansion of biofuel industry. The objective of the present study was to evaluate the effects of substituting corn for crude glycerol at different levels in the diet on ruminal fermentation using in-vitro true digestibility parameters. The experimental treatments consisted of substituting corn for liquid crude glycerol (0; 4; 8 and 12%) in dry matter basis. Diets consisted of 60% alfalfa hay and 40% corn and glycerol substituted the corn in the diet. In addition to the 48 hours traditionally applied in digestibility assays, different in-vitro digestibility times were used (0; 4; 8; 16; 48, 72 and 96 hours) in order to study digestion kinetics. The dietary corn substitution for increasing crude glycerol levels did not affect ammonia nitrogen content, metabolizable energy content, in-vitro digestibility of organic matter and neutral detergent fiber, nor ruminal degradation parameters. However this by-product of biodiesel production may be tested in-vivo as an alternative energy feedstuff in ruminant diets.

scholarly journals Synthesis of Lipase-Immobilized CeO2 Nanorods as Heterogeneous Nano-Biocatalyst for Optimized Biodiesel Production from Eruca sativa Seed Oil

Catalysts ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 231 ◽  
Author(s):  
Anam Fatima ◽  
Muhammad Waseem Mumtaz ◽  
Hamid Mukhtar ◽  
Sadia Akram ◽  
Tooba Touqeer ◽  
...  
Keyword(s):  
Ftir Spectroscopy ◽  
Alternative Energy ◽  
Immobilized Lipase ◽  
Hydrothermal Process ◽  
Biodiesel Production ◽  
Attractive Alternative ◽  
Eruca Sativa ◽  
Alternative Energy Sources ◽  
Biodiesel Synthesis ◽  
Before And After

Biodiesel has emerged as one of the most attractive alternative energy sources to meet the growing needs of energy. Many approaches have been adopted for biodiesel synthesis. In the present work, biodiesel was produced from non-edible Eruca sativa oil using nano-biocatalyst-catalysed transesterification. Nano-biocatalyst (CeO2@PDA@A. terreus Lipase) was developed via the immobilization of lipase on polydopamine coated ceria nanorods, and CeO2 nanorods were developed via a hydrothermal process. The mean diameter of nanorods were measured to be 50–60 nm, while their mean length was 150–200 nm. Lipase activity before and after immobilization was measured to be 18.32 and 16.90 U/mg/min, respectively. The immobilized lipase depicted high stability at high temperature and pH. CeO2@PDA@A. terreus Lipase-catalysed transesterification resulted in 89.3% yield of the product. Process optimization through response surface methodology was also executed, and it was depicted that the optimum/maximum E. sativa oil-based biodiesel yield was procured at conditions of 10% CeO2@PDA@A. terreus Lipase, 6:1 methanol/oil ratio, 0.6% water content, 35 °C reaction temperature, and 30 h reaction time. The fuel compatibility of synthesized biodiesel was confirmed via the estimation of fuel properties that were in agreement with the ASTM D standard. The nanorods and dopamine-modified nanorods were characterized by FTIR spectroscopy, SEM, and energy dispersive X-ray (EDX), while conversion of E. sativa oil to biodiesel was confirmed by GC/MS and FTIR spectroscopy. Conclusively, it was revealed that CeO2@PDA@A. terreus Lipase has potential to be employed as an emphatic nano-biocatalyst.

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