scholarly journals Study on the Adsorption Properties of Iron Tailings for GO

Coatings ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 768
Author(s):  
Jiawei Zhou ◽  
Liming Yao ◽  
Yunfeng Wang ◽  
Weiqi Zhao ◽  
Jiahui Gu
Keyword(s):  
Electron Microscopy ◽  
Aqueous Solutions ◽  
Photoelectron Spectroscopy ◽  
Adsorption Process ◽  
Physical Adsorption ◽  
Exothermic Reaction ◽  
Single Layer ◽  
X Ray ◽  
Force Microscopy ◽  
Transmission Electron

Iron tailings can be used as adsorbents to effectively remove graphene oxide (GO) in aqueous solutions. Experimental data show that pH, iron tailing quality, GO concentration and temperature have significant effects on the removal of GO, the adsorption of the tail involves a single layer adsorbed Langmuir model with exothermic reaction, and it compliance with the proposed dynamics model meets the requirements, the adsorption process is a spontaneous physical adsorption process. Combining scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) to analyze the iron tail according to the mechanisms of ore adsorption of GO, it was concluded that iron tailings might be a very promising material to effectively remove GO in aqueous solutions. The results of this research provide key information for the transportation and potential fate of GO in the natural environment.

Electroless Synthesis of 1.4 nm Pd and Pt Nanoparticles on Self-Assembled Rosette Nanotubes

2011 ◽  
Vol 1301 ◽  
Author(s):  
Rahul Chhabra ◽  
Hicham Fenniri
Keyword(s):  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Pt Nanoparticles ◽  
Hierarchical Organization ◽  
X Ray ◽  
Force Microscopy ◽  
Rosette Nanotubes ◽  
Atomic Force ◽  
Transmission Electron ◽  
Self Assembled

ABSTRACTElectroless synthesis and hierarchical organization of 1.4 nm Pd and Pt nanoparticles (NPs) on self-assembled Rosette Nanotubes (RNTs) is described. The nucleated NPs are nearly monodisperse and reveal supramolecular organizations guided by RNT templates. Interestingly, the narrow size distribution is attributable to unique templating behavior of RNTs. The resulting metal NP-RNT composites were characterized by Atomic Force Microscopy (AFM), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). X-ray Photoelectron Spectroscopy (XPS) was also performed to confirm the nature and composition of RNT-templated NPs.

Carbon nanotubes and metalloporphyrins and metallophthalocyanines-based materials for electroanalysis

2012 ◽  
Vol 16 (07n08) ◽  
pp. 713-740 ◽  
Author(s):  
José H. Zagal ◽  
Sophie Griveau ◽  
Mireya Santander-Nelli ◽  
Silvia Gutierrez Granados ◽  
Fethi Bedioui
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Hybrid Materials ◽  
Photoelectron Spectroscopy ◽  
State Of The Art ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Walled Carbon Nanotubes

We discuss here the state of the art on hybrid materials made from single (SWCNT) or multi (MWCNT) walled carbon nanotubes and MN4complexes such as metalloporphyrins and metallophthalocyanines. The hybrid materials have been characterized by several methods such as cyclic voltammetry (CV), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and scanning electrochemical microscropy (SECM). The materials are employed for electrocatalysis of reactions such as oxygen and hydrogen peroxide reduction, nitric oxide oxidation, oxidation of thiols and other pollutants.

scholarly journals Ultrashort Pulsed Laser Ablation of Magnesium Diboride: Plasma Characterization and Thin Films Deposition

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Angela De Bonis ◽  
Agostino Galasso ◽  
Antonio Santagata ◽  
Roberto Teghil
Keyword(s):  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Optical Emission ◽  
Silicon Substrates ◽  
X Ray Diffraction ◽  
Laser Target ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron

A MgB2target has been ablated by Nd:glass laser with a pulse duration of 250 fs. The plasma produced by the laser-target interaction, showing two temporal separated emissions, has been characterized by time and space resolved optical emission spectroscopy and ICCD fast imaging. The films, deposited on silicon substrates and formed by the coalescence of particles with nanometric size, have been analyzed by scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, micro-Raman spectroscopy, and X-ray diffraction. The first steps of the films growth have been studied by Transmission Electron Microscopy. The films deposition has been studied by varying the substrate temperature from 25 to 500°C and the best results have been obtained at room temperature.

scholarly journals Facile Synthesis of Highly Conductive Vanadium-Doped NiO Film for Transparent Conductive Oxide

2020 ◽  
Vol 10 (16) ◽  
pp. 5415
Author(s):  
Ashique Kotta ◽  
Hyung Kee Seo
Keyword(s):  
Electron Microscopy ◽  
Nickel Oxide ◽  
Photoelectron Spectroscopy ◽  
Transparent Conductive Oxide ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Conductive Oxide ◽  
P Type

Metal-oxide-based electrodes play a crucial role in various transparent conductive oxide (TCO) applications. Among the p-type materials, nickel oxide is a promising electrically conductive material due to its good stability, large bandgap, and deep valence band. Here, we display pristine and 3 at.%V-doped NiO synthesized by the solvothermal decomposition method. The properties of both the pristine and 3 at.%V:NiO nanoparticles were characterized by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), X-ray diffractometry (XRD), Raman spectroscopy, ultraviolet–visible spectroscopy (UV–vis), and X-ray photoelectron spectroscopy (XPS). The film properties were characterized by atomic force microscopy (AFM) and a source meter. Our results suggest that incorporation of vanadium into the NiO lattice significantly improves both electrical conductivity and hole extraction. Also, 3 at.%V:NiO exhibits a lower crystalline size when compared to pristine nickel oxide, which maintains the reduction of surface roughness. These results indicate that vanadium is an excellent dopant for NiO.

scholarly journals Facile Preparation of Carbon Nitride-ZnO Hybrid Adsorbent for CO2 Capture: The Significant Role of Amine Source to Metal Oxide Ratio

Catalysts ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1253
Author(s):  
Siti Aishah Anuar ◽  
Khairul Naim Ahmad ◽  
Ahmed Al-Amiery ◽  
Mohd Shahbudin Masdar ◽  
Wan Nor Roslam Wan Isahak
Keyword(s):  
Electron Microscopy ◽  
Metal Oxide ◽  
Photoelectron Spectroscopy ◽  
Physical Adsorption ◽  
Synthesis Method ◽  
Chemical Properties ◽  
Gaseous Fuel ◽  
X Ray ◽  
Transmission Electron ◽  
Adsorption Analysis

The presence of CO2 in gaseous fuel and feedstock stream of chemical reaction was always considered undesirable. High CO2 content will decrease quality and heating value of gaseous fuel, such as biohydrogen, which needs a practical approach to remove it. Thus, this work aims to introduce the first C3N4-metal oxide hybrid for the CO2 cleaning application from a mixture of CO2-H2 gas. The samples were tested for their chemical and physical properties, using field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), physical adsorption analysis (BET), fourier-transform infrared (FTIR), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The CO2 capacity test was carried out by means of a breakthrough test at 1 atm and 25° C using air as a desorption system. Among the samples, amine/metal oxide mass ratio of 2:1 (CNHP500-2(2-1)) showed the best performance of 26.9 wt. % (6.11 mmol/g), with a stable capacity over 6 consecutive cycles. The hybrid sample also showed 3 times better performance than the raw C3N4. In addition, it was observed that the hydrothermal C3N4 synthesis method demonstrated improved chemical properties and adsorption performance than the conventional dry pyrolysis method. In summary, the performance of hybrid samples depends on the different interactive factors of surface area, pore size and distribution, basicity, concentration of amine precursors, ratio of amines precursors to metal oxide, and framework stability.

scholarly journals The Influence of Annealing on the Optical Properties and Microstructure Recrystallization of the TiO2 Layers Produced by Means of the E-BEAM Technique

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5863
Author(s):  
Katarzyna Jurek ◽  
Robert Szczesny ◽  
Marek Trzcinski ◽  
Arkadiusz Ciesielski ◽  
Jolanta Borysiuk ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Room Temperature ◽  
Dielectric Films ◽  
X Ray ◽  
Force Microscopy ◽  
Titanium Dioxide Films ◽  
Transmission Electron ◽  
Two Phases ◽  
Beam Technique

Titanium dioxide films, about 200 nm in thickness, were deposited using the e-BEAM technique at room temperature and at 227 °C (500K) and then annealed in UHV conditions (as well as in the presence of oxygen (at 850 °C). The fabricated dielectric films were examined using X-ray powder diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, atomic force microscopy, scanning electron microscopy, transmission electron microscopy, and spectroscopic ellipsometry. The applied experimental techniques allowed us to characterize the phase composition and the phase transformation of the fabricated TiO2 coatings. The films produced at room temperature are amorphous but after annealing consist of anatase crystallites. The layers fabricated at 227 °C contain both anatase and rutile phases. In this case the anatase crystallites are accumulated near the substrate interface whilst the rutile crystallites were formed closer to the surface of the TiO2 film. It should be emphasized that these two phases of TiO2 are distinctly separated from each other.

A Review of Diffusion and Interfacial Reactions in Sandwich Thin-Film Couples

2013 ◽  
Vol 344 ◽  
pp. 107-128 ◽  
Author(s):  
Amitava Ghorai ◽  
D. Roy
Keyword(s):  
Thin Film ◽  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Electron Spectroscopy ◽  
Secondary Ion Mass Spectrometry ◽  
Direct Methods ◽  
Interfacial Reactions ◽  
X Ray ◽  
Force Microscopy ◽  
Transmission Electron

In this paper different techniques for sandwich thin film production, characterization and interfacial reactions have been reviewed in order to understand the kinetic behaviour in the above systems. The contact and composite resistance measurements are the indirect methods for this purpose, while X-ray diffraction studies (XRD), Transmission electron microscopy (TEM), Scanning electron microscopy (SEM), Rutherford backscattering (RBS), Auger electron spectroscopy (AES), secondary ion mass spectrometry (SIMS), ion sputtering spectrometry (ISS), X-ray photoelectron spectroscopy (XPS) which is also referred to as electron spectroscopy for chemical analysis (ESCA) and atomic force microscopy (AFM) are some of the direct methods. Trends indicate that interfacial reactions start at room temperature.

scholarly journals Preparation and characterization of magnetic graphene oxide nanocomposite (GO-Fe3O4) for removal of strontium and cesium from aqueous solutions

2021 ◽  
Vol 4 (1) ◽  
pp. 26
Author(s):  
Sule Aytas ◽  
Sabriye Yusan ◽  
Senol Sert ◽  
Cem Gok
Keyword(s):  
Electron Microscopy ◽  
Graphene Oxide ◽  
Aqueous Solutions ◽  
Photoelectron Spectroscopy ◽  
Precipitation Method ◽  
Magnetic Graphene Oxide ◽  
X Ray ◽  
Magnetic Graphene ◽  
Transmission Electron ◽  
Co Precipitation

Magnetic graphene oxide nanocomposites (M-GO) were successfully synthesized by partial reduction co-precipitation method and used for removal of Sr(II) and Cs(I) ions from aqueous solutions. The structures and properties of the M-GO was investigated by X-ray diffraction, Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, vibrating sample magnetometer (VSM) and N2-BET measurements. It is found that M-GO has 2.103 mg/g and 142.070 mg/g adsorption capacities for Sr(II) and Cs(I) ions, respectively. The adsorption isotherm matches well with the Freundlich for Sr(II) and Dubinin–Radushkevich model for Cs(I) and kinetic analysis suggests that the adsorption process is pseudo-second-ordered.

scholarly journals Thermal Degradation and Combustion Behaviors of Polyethylene/Alumina Trihydrate/Graphene Nanoplatelets

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 772 ◽  
Author(s):  
Chunfeng Wang ◽  
Jihua Wang ◽  
Zhenlong Men ◽  
Yongliang Wang ◽  
Zhidong Han
Keyword(s):  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Expanded Graphite ◽  
Graphene Nanoplatelets ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Combustion Behaviors ◽  
Alumina Trihydrate

Graphene nanoplatelets (GNPs) were prepared from expanded graphite (EG) with fully exfoliated structure via ball milling coupled with ultrasonication. The structure of multi-layered GNPs was characterized with transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), atomic force microscopy (AFM) and Raman spectroscopy. By compounding alumina trihydrate (ATH) with GNPs, the well dispersed mixture of ATH/GNP was obtained, and it showed high flame retardant effectiveness in polyethylene (PE). The peak heat release rate (peak-HRR) decreased by 20% was proven by a cone calorimeter with the addition of GNPs as low as 0.2 wt % in PE/ATH. The results of thermogravimetric analysis (TG) illustrated the improved thermal stability and lower weight loss rate of PE/ATH/GNP than PE/ATH. A protective char with GNPs was evidenced by SEM and X-ray photoelectron spectroscopy (XPS). The well exfoliated structure and good dispersion of GNPs accounted for the formation of effective barrier, which made a profound contribution to the enhanced flame retardancy.

scholarly journals Preparation and characterization of magnetic graphene oxide nanocomposite (GO-Fe3O4) for removal of strontium and cesium from aqueous solutions

2018 ◽  
Vol 7 (1) ◽  
Author(s):  
Sabriye Yusan
Keyword(s):  
Electron Microscopy ◽  
Graphene Oxide ◽  
Aqueous Solutions ◽  
Photoelectron Spectroscopy ◽  
Precipitation Method ◽  
Magnetic Graphene Oxide ◽  
X Ray ◽  
Magnetic Graphene ◽  
Transmission Electron ◽  
Co Precipitation

<p>Magnetic graphene oxide nanocomposites (M-GO) were successfully synthesized by partial reduction co-precipitation method and used for removal of Sr(II) and Cs(I) ions from aqueous solutions. The structures and properties of the M-GO was investigated by X-ray diffraction, Fourier transformed infrared spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, vibrating sample magnetometer (VSM) and N<sub>2</sub>-BET measurements. It is found that M-GO has 2.103 mg/g and 142.070 mg/g adsorption capacities for Sr(II) and Cs(I) ions, respectively. The adsorption isotherm matches well with the Freundlich for Sr(II) and Dubinin–Radushkevich model for Cs(I) and kinetic analysis suggests that the adsorption process is pseudo-second-ordered.</p>

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